CuZnCoOx multifunctional catalyst for in situ hydrogenation of 5-hydroxymethylfurfural with ethanol as hydrogen carrier

Zhang, Zihao; Yao, Siyu; Wang, Changxue; Liu, Miaomiao; Zhang, Feng; Hu, Xiaobing; Chen, Hao; Gou, Xin; Chen, Kequan; Zhu, Yimei; Lu, Xiuyang; Ouyang, Pingkai; Fu, Jie

doi:10.1016/j.jcat.2019.04.011

Title: CuZnCoO_x multifunctional catalyst for in situ hydrogenation of 5-hydroxymethylfurfural with ethanol as hydrogen carrier

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Abstract

Catalytic in situ hydrogenation of 5-hydroxymethylfurfural 1 (5-HMF) to 2,5- dimethylfuran (DMF) has received a great interest in recent years. However, the issue of the consumption of expensive hydrogen donors, such as secondary alcohols, limits its applications. In this work, a ternary CuZnCoO_x catalyst, exhibiting a 99% yield of DMF from in situ hydrogenation of 5-HMF with ethanol as economical hydrogen donor, is developed. High resolution transmission electron microscopy (HRTEM), energy dispersive X-ray spectroscopy (EDS-mapping), X-ray diffraction (XRD) and temperature programmed reduction (TPR) reveal the synergy effect of each components. Reaction mechanism studies unravel the CoO_x results in promoting in situ H₂ production from ethanol, the zinc oxide accelerates the aldehyde group (-CHO) hydrogenation to hydroxymethyl group (-CH₂OH) and the formation of Cu-Co alloy significantly facilitate the hydrogenation of 5-HMF. Additionally, this ternary CuZnCoO_x catalyst exhibits superior recyclability without losing any activity during 6 cycles experiment.

Authors:

Zhang, Zihao ^[1]; Yao, Siyu ^[2]; Wang, Changxue ^[1]; Liu, Miaomiao ^[3]; Zhang, Feng ^[2]; Hu, Xiaobing ^[2];

^[1]; Gou, Xin ^[1]; Chen, Kequan ^[4]; Zhu, Yimei ^[2]; Lu, Xiuyang ^[1]; Ouyang, Pingkai ^[5];

^[1]

Zhejiang Univ., Hangzhou (China).
Brookhaven National Lab. (BNL), Upton, NY (United States)
East China Univ. of Science & Technology, Shanghai (China)
Nanjing Tech Univ., Nanjing (China)
Zhejiang Univ., Hangzhou (China).; Nanjing Tech Univ., Nanjing (China)

Publication Date:: 2019-04-22

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1557113

Report Number(s):: BNL-211975-2019-JAAM
Journal ID: ISSN 0021-9517

Grant/Contract Number:: SC0012704

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Catalysis

Additional Journal Information:: Journal Volume: 373; Journal Issue: C; Journal ID: ISSN 0021-9517

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

Citation Formats


                    Zhang, Zihao, Yao, Siyu, Wang, Changxue, Liu, Miaomiao, Zhang, Feng, Hu, Xiaobing, Chen, Hao, Gou, Xin, Chen, Kequan, Zhu, Yimei, Lu, Xiuyang, Ouyang, Pingkai, and Fu, Jie. CuZnCoOx multifunctional catalyst for in situ hydrogenation of 5-hydroxymethylfurfural with ethanol as hydrogen carrier.  United States: N. p., 2019. 
Web.  doi:10.1016/j.jcat.2019.04.011.

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                    Zhang, Zihao, Yao, Siyu, Wang, Changxue, Liu, Miaomiao, Zhang, Feng, Hu, Xiaobing, Chen, Hao, Gou, Xin, Chen, Kequan, Zhu, Yimei, Lu, Xiuyang, Ouyang, Pingkai, & Fu, Jie. CuZnCoOx multifunctional catalyst for in situ hydrogenation of 5-hydroxymethylfurfural with ethanol as hydrogen carrier.  United States.  https://doi.org/10.1016/j.jcat.2019.04.011

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                    Zhang, Zihao, Yao, Siyu, Wang, Changxue, Liu, Miaomiao, Zhang, Feng, Hu, Xiaobing, Chen, Hao, Gou, Xin, Chen, Kequan, Zhu, Yimei, Lu, Xiuyang, Ouyang, Pingkai, and Fu, Jie. Mon .  
"CuZnCoOx multifunctional catalyst for in situ hydrogenation of 5-hydroxymethylfurfural with ethanol as hydrogen carrier".  United States.  https://doi.org/10.1016/j.jcat.2019.04.011.  https://www.osti.gov/servlets/purl/1557113.

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@article{osti_1557113,

  title        = {CuZnCoOx multifunctional catalyst for in situ hydrogenation of 5-hydroxymethylfurfural with ethanol as hydrogen carrier},

  author       = {Zhang, Zihao and Yao, Siyu and Wang, Changxue and Liu, Miaomiao and Zhang, Feng and Hu, Xiaobing and Chen, Hao and Gou, Xin and Chen, Kequan and Zhu, Yimei and Lu, Xiuyang and Ouyang, Pingkai and Fu, Jie},

  abstractNote = {Catalytic in situ hydrogenation of 5-hydroxymethylfurfural 1 (5-HMF) to 2,5- dimethylfuran (DMF) has received a great interest in recent years. However, the issue of the consumption of expensive hydrogen donors, such as secondary alcohols, limits its applications. In this work, a ternary CuZnCoOx catalyst, exhibiting a 99% yield of DMF from in situ hydrogenation of 5-HMF with ethanol as economical hydrogen donor, is developed. High resolution transmission electron microscopy (HRTEM), energy dispersive X-ray spectroscopy (EDS-mapping), X-ray diffraction (XRD) and temperature programmed reduction (TPR) reveal the synergy effect of each components. Reaction mechanism studies unravel the CoOx results in promoting in situ H2 production from ethanol, the zinc oxide accelerates the aldehyde group (-CHO) hydrogenation to hydroxymethyl group (-CH2OH) and the formation of Cu-Co alloy significantly facilitate the hydrogenation of 5-HMF. Additionally, this ternary CuZnCoOx catalyst exhibits superior recyclability without losing any activity during 6 cycles experiment.},

  doi          = {10.1016/j.jcat.2019.04.011},

  journal      = {Journal of Catalysis},

  number       = C,

  volume       = 373,

  place        = {United States},

  year         = {2019},

  month        = {4}

}

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Title: CuZnCoOx multifunctional catalyst for in situ hydrogenation of 5-hydroxymethylfurfural with ethanol as hydrogen carrier

Abstract

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Title: CuZnCoO_x multifunctional catalyst for in situ hydrogenation of 5-hydroxymethylfurfural with ethanol as hydrogen carrier