Steric control of dioxygen activation pathways for Mn II complexes supported by pentadentate, amide-containing ligands

doi:10.1039/C9DT02682G

This content will become publicly available on August 13, 2020

Title: Steric control of dioxygen activation pathways for Mn ^II complexes supported by pentadentate, amide-containing ligands

Abstract

Steric control of dioxygen activation is demonstrated through O ₂ titration and isotopic labeling experiments for two Mn( ii ) complexes.

Authors:

Parham, Joshua D. ^[1];

^[1]; Mayfield, Jaycee R. ^[1];

^[1]

Department of Chemistry and Center for Environmentally Beneficial Catalysis, University of Kansas, Lawrence, USA

Publication Date:: 2019-01-01

Sponsoring Org.:: USDOE

OSTI Identifier:: 1557007

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Dalton Transactions

Additional Journal Information:: Journal Name: Dalton Transactions; Journal ID: ISSN 1477-9226

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Parham, Joshua D., Wijeratne, Gayan B., Mayfield, Jaycee R., and Jackson, Timothy A. Steric control of dioxygen activation pathways for Mn II complexes supported by pentadentate, amide-containing ligands.  United Kingdom: N. p., 2019. 
        Web.  doi:10.1039/C9DT02682G.

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                    Parham, Joshua D., Wijeratne, Gayan B., Mayfield, Jaycee R., & Jackson, Timothy A. Steric control of dioxygen activation pathways for Mn II complexes supported by pentadentate, amide-containing ligands.  United Kingdom.  doi:10.1039/C9DT02682G.

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                    Parham, Joshua D., Wijeratne, Gayan B., Mayfield, Jaycee R., and Jackson, Timothy A. Tue .  
        "Steric control of dioxygen activation pathways for Mn II complexes supported by pentadentate, amide-containing ligands".  United Kingdom.  doi:10.1039/C9DT02682G.

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@article{osti_1557007,

  title        = {Steric control of dioxygen activation pathways for Mn II complexes supported by pentadentate, amide-containing ligands},

  author       = {Parham, Joshua D. and Wijeratne, Gayan B. and Mayfield, Jaycee R. and Jackson, Timothy A.},

  abstractNote = {Steric control of dioxygen activation is demonstrated through O 2 titration and isotopic labeling experiments for two Mn( ii ) complexes.},

  doi          = {10.1039/C9DT02682G},

  journal      = {Dalton Transactions},

  number       = ,

  volume       = ,

  place        = {United Kingdom},

  year         = {2019},

  month        = {1}

}

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DOI: 10.1039/C9DT02682G

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Works referenced in this record:

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy
journal, January 2005

Weigend, Florian; Ahlrichs, Reinhart
Physical Chemistry Chemical Physics, Vol. 7, Issue 18, p. 3297-3305
DOI: 10.1039/b508541a

Density‐functional thermochemistry. III. The role of exact exchange
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Becke, Axel D.
The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652
DOI: 10.1063/1.464913

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This content will become publicly available on August 13, 2020

Title: Steric control of dioxygen activation pathways for Mn II complexes supported by pentadentate, amide-containing ligands

Abstract

Citation Formats

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy journal, January 2005

Density‐functional thermochemistry. III. The role of exact exchange journal, April 1993

Title: Steric control of dioxygen activation pathways for Mn ^II complexes supported by pentadentate, amide-containing ligands

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy
journal, January 2005

Density‐functional thermochemistry. III. The role of exact exchange
journal, April 1993