Flux Crystal Growth of the RE2Ru3Ge5 (RE = La, Ce, Nd, Gd, Tb) Series and Their Magnetic and Metamagnetic Transitions

Bugaris, Daniel E.; Malliakas, Christos D.; Bud?ko, Sergey L.; Calta, Nicholas P.; Chung, Duck Young; Kanatzidis, Mercouri G.

doi:10.1021/acs.inorgchem.7b02389

Title: Flux Crystal Growth of the RE₂Ru₃Ge₅ (RE = La, Ce, Nd, Gd, Tb) Series and Their Magnetic and Metamagnetic Transitions

Authors:

^[1]; Malliakas, Christos D. ^[2]; Bud?ko, Sergey L. ^[3]; Calta, Nicholas P. ^[4]; Chung, Duck Young ^[5];

^[6]

Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division ; Northwestern Univ., Evanston, IL (United States). Department of Chemistry
Iowa State Univ., Ames, IA (United States). Department of Physics and Astronomy; Ames Lab., Ames, IA (United States). Division of Materials Science & Engineering
Northwestern Univ., Evanston, IL (United States). Department of Chemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division ; Northwestern Univ., Evanston, IL (United States). Department of Chemistry

Publication Date:: Tue Nov 21 00:00:00 EST 2017

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States); Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

OSTI Identifier:: 1418275

Alternate Identifier(s):: OSTI ID: 1556935

Report Number(s):: IS-J 9536
Journal ID: ISSN 0020-1669; 138350

Grant/Contract Number:: AC02-06CH11357; AC02-07CH11358; DE-AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Inorganic Chemistry

Additional Journal Information:: Journal Volume: 56; Journal Issue: 23; Journal ID: ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Bugaris, Daniel E., Malliakas, Christos D., Bud?ko, Sergey L., Calta, Nicholas P., Chung, Duck Young, and Kanatzidis, Mercouri G. Flux Crystal Growth of the RE2Ru3Ge5 (RE = La, Ce, Nd, Gd, Tb) Series and Their Magnetic and Metamagnetic Transitions.  United States: N. p., 2017. 
Web.  doi:10.1021/acs.inorgchem.7b02389.

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                    Bugaris, Daniel E., Malliakas, Christos D., Bud?ko, Sergey L., Calta, Nicholas P., Chung, Duck Young, & Kanatzidis, Mercouri G. Flux Crystal Growth of the RE2Ru3Ge5 (RE = La, Ce, Nd, Gd, Tb) Series and Their Magnetic and Metamagnetic Transitions.  United States.  https://doi.org/10.1021/acs.inorgchem.7b02389

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                    Bugaris, Daniel E., Malliakas, Christos D., Bud?ko, Sergey L., Calta, Nicholas P., Chung, Duck Young, and Kanatzidis, Mercouri G. Tue .  
"Flux Crystal Growth of the RE2Ru3Ge5 (RE = La, Ce, Nd, Gd, Tb) Series and Their Magnetic and Metamagnetic Transitions".  United States.  https://doi.org/10.1021/acs.inorgchem.7b02389.  https://www.osti.gov/servlets/purl/1418275.

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@article{osti_1418275,

  title        = {Flux Crystal Growth of the RE2Ru3Ge5 (RE = La, Ce, Nd, Gd, Tb) Series and Their Magnetic and Metamagnetic Transitions},

  author       = {Bugaris, Daniel E. and Malliakas, Christos D. and Bud?ko, Sergey L. and Calta, Nicholas P. and Chung, Duck Young and Kanatzidis, Mercouri G.},

  abstractNote = {},

  doi          = {10.1021/acs.inorgchem.7b02389},

  journal      = {Inorganic Chemistry},

  number       = 23,

  volume       = 56,

  place        = {United States},

  year         = {Tue Nov 21 00:00:00 EST 2017},

  month        = {Tue Nov 21 00:00:00 EST 2017}

}

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Works referenced in this record:

Superconductivity of rare earth-iron silicides
journal, February 1980

Braun, Hans F.
Physics Letters A, Vol. 75, Issue 5
DOI: 10.1016/0375-9601(80)90849-X

Low-temperature heat capacity of superconducting ternary iron silicides
journal, March 1983

Vining, C. B.; Shelton, R. N.; Braun, H. F.
Physical Review B, Vol. 27, Issue 5
DOI: 10.1103/PhysRevB.27.2800

Reentrant superconductivity in Tm2Fe3Si5
journal, October 1981

Segre, C. U.; Braun, H. F.
Physics Letters A, Vol. 85, Issue 6-7
DOI: 10.1016/0375-9601(81)90334-0

Superconductivity in the ternary nickel silicide ${Lu}_{2}$ ${Ni}_{3}$ ${Si}_{5}$
journal, November 1994

Mazumdar, Chandan; Ghosh, K.; Ramakrishnan, S.
Physical Review B, Vol. 50, Issue 18
DOI: 10.1103/PhysRevB.50.13879

Structure, superconductivity and magnetism of new rare earth-rhodium silicides RE2Rh3Si5 of U2Co3Si5-type
journal, September 1982

Chevalier, Bernard; Lejay, Pascal; Etourneau, Jean
Materials Research Bulletin, Vol. 17, Issue 9
DOI: 10.1016/0025-5408(82)90071-X

Low-temperature studies of the magnetic and superconducting properties of the $R_{2} {Ir}_{3} {Si}_{5}$ $(R = Y, La, Ce − Nd, Gd − Tm)$ system
journal, August 2004

Singh, Yogesh; Pal, D.; Ramakrishnan, S.
Physical Review B, Vol. 70, Issue 6
DOI: 10.1103/PhysRevB.70.064403

Magnetic ordering and superconductivity in the $R_{2} {Ir}_{3} {Ge}_{5} (R = Y, L a, Ce - N d, Gd - T m, Lu)$ system
journal, May 2004

Singh, Yogesh; Ramakrishnan, S.
Physical Review B, Vol. 69, Issue 17
DOI: 10.1103/PhysRevB.69.174423

Possible multigap superconductivity and magnetism in single crystals of superconducting La $_{2}$ Pt $_{3}$ Ge $_{5}$ and Pr $_{2}$ Pt $_{3}$ Ge $_{5}$
journal, December 2012

Sung, N. H.; Roh, C. J.; Kim, K. S.
Physical Review B, Vol. 86, Issue 22
DOI: 10.1103/PhysRevB.86.224507

Antiferromagnetic transitions in the Kondo lattice system ${Ce}_{2} {Ni}_{3} {Ge}_{5}$
journal, October 2000

Hossain, Z.; Hamashima, S.; Umeo, K.
Physical Review B, Vol. 62, Issue 13
DOI: 10.1103/PhysRevB.62.8950

A change of electronic state tuned by pressure: pressure-induced superconductivity of the antiferromagnet Ce ₂ Ni ₃ Ge ₅
journal, July 2005

Nakashima, M.; Kohara, H.; Thamizhavel, A.
Journal of Physics: Condensed Matter, Vol. 17, Issue 28
DOI: 10.1088/0953-8984/17/28/012

Antiferromagnetism in the Kondo lattice compound ${Ce}_{2} {Pd}_{3} {Si}_{5}$
journal, April 2002

Huo, Dexuan; Sakurai, Junji; Kuwai, Tomohiko
Physical Review B, Vol. 65, Issue 14
DOI: 10.1103/PhysRevB.65.144450

Antiferromagnetic Kondo-lattice systems ${Ce}_{2} {Rh}_{3} {Ge}_{5}$ and ${Ce}_{2} {Ir}_{3} {Ge}_{5}$ with moderate heavy-fermion behavior
journal, October 1999

Hossain, Z.; Ohmoto, H.; Umeo, K.
Physical Review B, Vol. 60, Issue 14
DOI: 10.1103/PhysRevB.60.10383

Physical properties of the Kondo-lattice compound ${Yb}_{2} {Ir}_{3} {Ge}_{5}$
journal, August 2003

Singh, Yogesh; Ramakrishnan, S.
Physical Review B, Vol. 68, Issue 5
DOI: 10.1103/PhysRevB.68.054419

Magnetic order in ${Pr}_{2} {Pd}_{3} {Ge}_{5}$ and possible heavy-fermion behavior in ${Pr}_{2} {Rh}_{3} {Ge}_{5}$
journal, May 2008

Anand, V. K.; Hossain, Z.; Geibel, C.
Physical Review B, Vol. 77, Issue 18
DOI: 10.1103/PhysRevB.77.184407

${Ce}_{2}$ ${Ni}_{3}$ ${Si}_{5}$ : A mixed-valence cerium compound
journal, October 1992

Mazumdar, Chandan; Nagarajan, R.; Dhar, S. K.
Physical Review B, Vol. 46, Issue 14
DOI: 10.1103/PhysRevB.46.9009

${Eu}_{2}$ ${Ni}_{3}$ ${Si}_{5}$ : A new valence-fluctuation system
journal, May 1988

Patil, Sujata; Nagarajan, R.; Gupta, L. C.
Physical Review B, Vol. 37, Issue 13
DOI: 10.1103/PhysRevB.37.7708

Magnetism and mixed valence in some R2M3X5 compounds: R = Ce, Eu, U; M = d metals, X = Si, Ge
journal, December 1988

Godart, C.; Gupta, L. C.; Tomy, C. V.
Materials Research Bulletin, Vol. 23, Issue 12
DOI: 10.1016/0025-5408(88)90189-4

Mixed valence and metamagnetism in a metal flux grown compound Eu2Pt3Si5
journal, May 2015

Sarkar, Sumanta; Subbarao, Udumula; Joseph, Boby
Journal of Solid State Chemistry, Vol. 225
DOI: 10.1016/j.jssc.2014.12.023

Anomalous magnetoresistance in antiferromagnetic polycrystalline materials R2Ni3Si5 (R=rare earth)
journal, April 1997

Mazumdar, Chandan; Nigam, A. K.; Nagarajan, R.
Journal of Applied Physics, Vol. 81, Issue 8
DOI: 10.1063/1.364666

Dy2Co3Si5, Lu2Co3Si5, Y2Co3Si5 and Sc2Co3Si5 with a monoclinic structural deformation variant of the orthorhombic U2Co3Si5 structure type
journal, March 1985

Chabot, B.; Parthé, E.
Journal of the Less Common Metals, Vol. 106, Issue 1
DOI: 10.1016/0022-5088(85)90365-0

De nouveaux stannures ternaires de rhodium et d'elements des terres rares : TR2Rh3Sn5 OU TR = Y, Gd, Tb, Dy, Ho. structure cristalline et proprietes electriques et magnetiques de Y2Rh3Sn5
journal, September 1984

Meot-Meyer, M.; Venturini, G.; MaLaman, B.
Materials Research Bulletin, Vol. 19, Issue 9
DOI: 10.1016/0025-5408(84)90069-2

The stannides YbPtSn and Yb ₂ Pt ₃ Sn ₅
journal, March 1999

,
Zeitschrift für Kristallographie - Crystalline Materials, Vol. 214, Issue 3
DOI: 10.1524/zkri.1999.214.3.143

Evolution des coordinations dans les structures d'isotypes de U2Co3Si5:R2T3X5 (R ≡; La, Y; T ≡; Ru, Rh, Ir; X ≡; Si, Ge, Sn)
journal, June 1989

Venturini, G.; Malaman, B.; Roques, B.
Journal of the Less Common Metals, Vol. 152, Issue 1
DOI: 10.1016/0022-5088(89)90071-4

De nouveaux isotypes de U2Co3Si5 ou Lu2Co3Si5 dans les systems R-T-Ge (R = Elements Des Terres Rares; T = Ru, Co, Rh, Ir). Supraconductivite de Y2Ir3Ge5
journal, January 1986

Venturini, G.; Méot-Meyer, M.; Marêché, J. F.
Materials Research Bulletin, Vol. 21, Issue 1
DOI: 10.1016/0025-5408(86)90026-7

Charge Density Wave in the New Polymorphs of RE ₂ Ru ₃ Ge ₅ ( RE = Pr, Sm, Dy)
journal, March 2017

Bugaris, Daniel E.; Malliakas, Christos D.; Han, Fei
Journal of the American Chemical Society, Vol. 139, Issue 11
DOI: 10.1021/jacs.7b00284

A short history of SHELX
journal, December 2007

Sheldrick, George M.
Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
DOI: 10.1107/S0108767307043930

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965

Kohn, W.; Sham, L. J.
Physical Review, Vol. 140, Issue 4A, p. A1133-A1138
DOI: 10.1103/PhysRev.140.A1133

Inhomogeneous Electron Gas
journal, November 1964

Hohenberg, P.; Kohn, W.
Physical Review, Vol. 136, Issue 3B, p. B864-B871
DOI: 10.1103/PhysRev.136.B864

Generalized Gradient Approximation Made Simple
journal, October 1996

Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
DOI: 10.1103/PhysRevLett.77.3865

A technique for relativistic spin-polarised calculations
journal, August 1977

Koelling, D. D.; Harmon, B. N.
Journal of Physics C: Solid State Physics, Vol. 10, Issue 16
DOI: 10.1088/0022-3719/10/16/019

Crystal growth and ambient and high pressure study of the re-entrant superconductor Tm ₂ Fe ₃ Si ₅
journal, May 2008

Singh, Yogesh; Ramakrishnan, S.
Journal of Physics: Condensed Matter, Vol. 20, Issue 23
DOI: 10.1088/0953-8984/20/23/235243

Anisotropic superconductivity in Lu2Fe3Si5
journal, September 2007

Tamegai, T.; Nakagawa, T.; Tokunaga, M.
Physica C: Superconductivity and its Applications, Vol. 460-462
DOI: 10.1016/j.physc.2007.03.283

High-field magnetization of Er2Fe3Si5
journal, July 1994

Noguchi, S.; Okuda, K.; Fukushima, T.
Physica B: Condensed Matter, Vol. 201
DOI: 10.1016/0921-4526(94)91058-8

Magnetic and structural studies of a Tb2Ni3Si5 single crystal
journal, September 1999

Hashimoto, Y.; Kajio, T.; Kawano, S.
Journal of Physics and Chemistry of Solids, Vol. 60, Issue 8-9
DOI: 10.1016/S0022-3697(99)00089-X

Unusual Ordering Behavior in Single-Crystal $U_{2} {Rh}_{3} {Si}_{5}$
journal, February 1997

Becker, B.; Ramakrishnan, S.; Menovsky, A. A.
Physical Review Letters, Vol. 78, Issue 7
DOI: 10.1103/PhysRevLett.78.1347

Coupling of rare earth moment and charge density wave ordering in a single crystal Er ₂ Ir ₃ Si ₅
journal, March 2015

Lalngilneia, P. C.; Thamizhavel, A.; Ramakrishnan, S.
Journal of Physics: Conference Series, Vol. 592
DOI: 10.1088/1742-6596/592/1/012094

Multiple charge-density-wave transitions in single-crystalline ${Lu}_{2} {Ir}_{3} {Si}_{5}$
journal, May 2015

Sangeetha, N. S.; Thamizhavel, A.; Tomy, C. V.
Physical Review B, Vol. 91, Issue 20
DOI: 10.1103/PhysRevB.91.205131

Pressure-induced magnetic instability in ${Ce}_{2} {Rh}_{3} {Ge}_{5}$
journal, September 2001

Umeo, K.; Takabatake, T.; Suzuki, T.
Physical Review B, Vol. 64, Issue 14
DOI: 10.1103/PhysRevB.64.144412

Complex magnetic order in Pr ₂ Pd ₃ Ge ₅ : a single crystal study
journal, October 2012

Anand, V. K.; Thamizhavel, A.; Ramakrishnan, S.
Journal of Physics: Condensed Matter, Vol. 24, Issue 45
DOI: 10.1088/0953-8984/24/45/456003

Thermoelectric properties of the intermediate valent cerium intermetallic Ce2Ni3Si5 doped with Pd, Co, and Cu
journal, November 1999

Proctor, K. J.; Regan, K. A.; Littman, A.
Journal of Alloys and Compounds, Vol. 292, Issue 1-2
DOI: 10.1016/S0925-8388(99)00483-1

Anisotropic Magnetic Properties of a Pressure-induced Superconductor Ce ₂ Ni ₃ Ge ₅
journal, October 2005

Thamizhavel, Arumugam; Nakashima, Hiroshi; Obiraki, Yoshiko
Journal of the Physical Society of Japan, Vol. 74, Issue 10
DOI: 10.1143/JPSJ.74.2843

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds
journal, November 2005

Kanatzidis, Mercouri G.; Pöttgen, Rainer; Jeitschko, Wolfgang
Angewandte Chemie International Edition, Vol. 44, Issue 43
DOI: 10.1002/anie.200462170

Molten Gallium as a Non-Reactive Solvent: Synthesis of the Silicides RE2Ni3+xSi5-x (RE = Sm, Gd and Tb)
journal, July 2003

Zhuravleva, Marina A.; Kanatzidis, Mercouri G.
Zeitschrift für Naturforschung B, Vol. 58, Issue 7
DOI: 10.1515/znb-2003-0708

Magnetic order in Pu ₂ M ₃ Si ₅ (M = Co, Ni)
journal, February 2011

Bauer, E. D.; Tobash, P. H.; Mitchell, J. N.
Journal of Physics: Condensed Matter, Vol. 23, Issue 9
DOI: 10.1088/0953-8984/23/9/094223

Anisotropic magnetic properties of
journal, March 2007

Dung, N. D.; Haga, Y.; Matsuda, T. D.
Journal of Magnetism and Magnetic Materials, Vol. 310, Issue 2
DOI: 10.1016/j.jmmm.2006.10.563

Single-crystal study of new Ce compound
journal, April 2008

Muro, Y.; Nakano, M.; Motoya, K.
Physica B: Condensed Matter, Vol. 403, Issue 5-9
DOI: 10.1016/j.physb.2007.10.071

Magnetic, Thermal and Transport Properties of YbPt_2Si_2 and Yb_2Pt_3Si_5 Single Crystals
journal, July 2014

Fikáček, J.; Prchal, J.; Sechovský, V.
Acta Physica Polonica A, Vol. 126, Issue 1
DOI: 10.12693/APhysPolA.126.310

Magnetic properties of ferromagnetic Pu2Pt3Si5
journal, November 2013

Griveau, J. -C.; Colineau, E.; Bouëxiere, D.
Journal of Alloys and Compounds, Vol. 576
DOI: 10.1016/j.jallcom.2013.05.168

Synthesis of Ce ₂ Rh ₃ Ge ₅ Crystals from a Bismuth Flux
journal, March 2013

Voßwinkel, Daniel; Pöttgen, Rainer
Zeitschrift für Naturforschung B, Vol. 68, Issue 3
DOI: 10.5560/znb.2013-3015

The R2Pd3Ge5 (R = La–Nd, Sm) germanides: synthesis, crystal structure and symmetry reduction
journal, August 2016

Solokha, Pavlo; Freccero, Riccardo; De Negri, Serena
Structural Chemistry, Vol. 27, Issue 6
DOI: 10.1007/s11224-016-0812-z

Pressure-Induced Valence Transition and Heavy Fermion State in Eu ₂ Ni ₃ Ge ₅ and EuRhSi ₃
journal, May 2015

Nakamura, Ai; Okazaki, Tomoya; Nakashima, Miho
Journal of the Physical Society of Japan, Vol. 84, Issue 5
DOI: 10.7566/JPSJ.84.053701

The orthorhombic crystal structure of Ru2Si3, Ru2Ge3, Os2Si3 and Os2Ge3
journal, November 1974

Poutcharovsky, D. J.; Parthé, E.
Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 30, Issue 11
DOI: 10.1107/S0567740874007825

X-ray single crystal refinements on some RT2Ge2 compounds (R = Ca, Y, La, Nd, U; T = Mn-Cu, Ru-Pd): evolution of the chemical bonds
journal, March 1996

Venturini, G.; Malaman, B.
Journal of Alloys and Compounds, Vol. 235, Issue 2
DOI: 10.1016/0925-8388(95)02140-X

Effects of the alkali metal counter ions on the germanium–germanium double bond length in a heavier group 14 element ethenide salt
journal, January 2004

Richards, Anne F.; Brynda, Marcin; Power, Philip P.
Chem. Commun., Issue 14
DOI: 10.1039/B401507J

Intermetallic Compounds with Near Zintl Phase Behavior: RE ₂ Zn ₃ Ge ₆ (RE = La, Ce, Pr, Nd) Grown from Liquid Indium
journal, October 2005

Salvador, James R.; Bilc, Daniel; Gour, Jeffrey R.
Inorganic Chemistry, Vol. 44, Issue 24
DOI: 10.1021/ic050941i

Stabilization of New Forms of the Intermetallic Phases β -RENiGe ₂ (RE = Dy, Ho, Er, Tm, Yb, Lu) in Liquid Indium
journal, February 2004

Salvador, J. R.; Gour, J. R.; Bilc, D.
Inorganic Chemistry, Vol. 43, Issue 4
DOI: 10.1021/ic035303j

R2Ru3Si5 (R  Er, Tb) with the orthorhombic U2Co3Si5-type structure and R2Ru3Si4.6 (R  Gd, Tb, Dy, Ho, Er) and R2Os3Si4.6 (R  Tb, Er) with the tetragonal Sc2Fe3Si5-type structure
journal, October 1990

Paccard, D.; Paccard, L.
Journal of the Less Common Metals, Vol. 163, Issue 2
DOI: 10.1016/0022-5088(90)90606-K

Rare Earth Ruthenium Gallides with the Ideal Composition Ln2Ru3Ga5 (Ln = La-Nd, Sm) crystallizing with U2Mn3Si5 (Sc2Fe3Si5) Type Structure
journal, April 2010

Jeitschko, Wolfgang; Schlüter, Martin
Zeitschrift für anorganische und allgemeine Chemie, Vol. 636, Issue 6
DOI: 10.1002/zaac.200900530

New Stannides CaTSn2 (T = Rh, Pd, Ir) and Ca ₂ Pt ₃ Sn ₅ - Synthesis, Structure and Chemical Bonding
journal, June 1999

Hoffmann, Rolf-Dieter; Kußmann, Dirk; Rodewald, Ute Ch.
Zeitschrift für Naturforschung B, Vol. 54, Issue 6
DOI: 10.1515/znb-1999-0602

New Yb2Pt3Sn5 Type Stannides
journal, February 2000

Kußmann, Dirk; Pöttgen, Rainer; Kotzyba, Gunter
Journal of Solid State Chemistry, Vol. 150, Issue 1
DOI: 10.1006/jssc.1999.8555

Magnetic ordering and crystal field effects in the $R_{2}$ Ir $_{3}$ Sn $_{5}$ ( $R$ $=$ La–Nd, Gd–Tm) system
journal, August 2011

Sangeetha, N. S.; Thamizhavel, A.; Tomy, C. V.
Physical Review B, Vol. 84, Issue 6
DOI: 10.1103/PhysRevB.84.064430

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New ternary intermetallics RE{sub 5}Ru{sub 3}Al{sub 2} (RE = La, Ce, Pr): Synthesis, crystal structures, magnetic and electric properties

Journal Article Murashova, E.V., E-mail: murashovaev@rambler.ru ; Tursina, A. I. ; Bukhanko, N. G. ; ... - Materials Research Bulletin

Intermetallics RE{sub 5}Ru{sub 3}Al{sub 2} (RE = La, Ce, Pr) were prepared by arc melting of the elemental components with subsequent annealing at 820 K. The crystal structures were determined from single-crystal (Ce{sub 5}Ru{sub 3}Al{sub 2}, Pr{sub 5}Ru{sub 3}Al{sub 2}) and powder (La{sub 5}Ru{sub 3}Al{sub 2}) X-ray diffraction at room temperature. The compounds belong to new structural types: space group R3, Z = 6, a = 13.9270(3) A, c = 8.3260(2) A for Ce{sub 5}Ru{sub 3}Al{sub 2} and space group I2{sub 1}3, Z = 4, a = 9.95419(6) A and 9.8084(3) A for La{sub 5}Ru{sub 3}Al{sub 2} and Pr{sub 5}Ru{submore »« less
https://doi.org/10.1016/J.MATERRESBULL.2010.04.006

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Citation Formats

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Low-temperature heat capacity of superconducting ternary iron silicides journal, March 1983

Reentrant superconductivity in Tm2Fe3Si5 journal, October 1981

Superconductivity in the ternary nickel silicide Lu 2 Ni 3 Si 5 journal, November 1994

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Charge Density Wave in the New Polymorphs of RE 2 Ru 3 Ge 5 ( RE = Pr, Sm, Dy) journal, March 2017

A short history of SHELX journal, December 2007

Self-Consistent Equations Including Exchange and Correlation Effects journal, November 1965

Inhomogeneous Electron Gas journal, November 1964

Generalized Gradient Approximation Made Simple journal, October 1996

A technique for relativistic spin-polarised calculations journal, August 1977

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Anisotropic superconductivity in Lu2Fe3Si5 journal, September 2007

High-field magnetization of Er2Fe3Si5 journal, July 1994

Magnetic and structural studies of a Tb2Ni3Si5 single crystal journal, September 1999

Unusual Ordering Behavior in Single-Crystal U 2 Rh 3 Si 5 journal, February 1997

Coupling of rare earth moment and charge density wave ordering in a single crystal Er 2 Ir 3 Si 5 journal, March 2015

Multiple charge-density-wave transitions in single-crystalline Lu 2 Ir 3 Si 5 journal, May 2015

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Magnetic order in Pu 2 M 3 Si 5 (M = Co, Ni) journal, February 2011

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Superconductivity of rare earth-iron silicides
journal, February 1980

Low-temperature heat capacity of superconducting ternary iron silicides
journal, March 1983

Reentrant superconductivity in Tm2Fe3Si5
journal, October 1981

Superconductivity in the ternary nickel silicide ${Lu}_{2}$ ${Ni}_{3}$ ${Si}_{5}$
journal, November 1994

Structure, superconductivity and magnetism of new rare earth-rhodium silicides RE2Rh3Si5 of U2Co3Si5-type
journal, September 1982

Low-temperature studies of the magnetic and superconducting properties of the $R_{2} {Ir}_{3} {Si}_{5}$ $(R = Y, La, Ce − Nd, Gd − Tm)$ system
journal, August 2004

Magnetic ordering and superconductivity in the $R_{2} {Ir}_{3} {Ge}_{5} (R = Y, L a, Ce - N d, Gd - T m, Lu)$ system
journal, May 2004

Possible multigap superconductivity and magnetism in single crystals of superconducting La $_{2}$ Pt $_{3}$ Ge $_{5}$ and Pr $_{2}$ Pt $_{3}$ Ge $_{5}$
journal, December 2012

Antiferromagnetic transitions in the Kondo lattice system ${Ce}_{2} {Ni}_{3} {Ge}_{5}$
journal, October 2000

A change of electronic state tuned by pressure: pressure-induced superconductivity of the antiferromagnet Ce ₂ Ni ₃ Ge ₅
journal, July 2005

Antiferromagnetism in the Kondo lattice compound ${Ce}_{2} {Pd}_{3} {Si}_{5}$
journal, April 2002

Antiferromagnetic Kondo-lattice systems ${Ce}_{2} {Rh}_{3} {Ge}_{5}$ and ${Ce}_{2} {Ir}_{3} {Ge}_{5}$ with moderate heavy-fermion behavior
journal, October 1999

Physical properties of the Kondo-lattice compound ${Yb}_{2} {Ir}_{3} {Ge}_{5}$
journal, August 2003

Magnetic order in ${Pr}_{2} {Pd}_{3} {Ge}_{5}$ and possible heavy-fermion behavior in ${Pr}_{2} {Rh}_{3} {Ge}_{5}$
journal, May 2008

${Ce}_{2}$ ${Ni}_{3}$ ${Si}_{5}$ : A mixed-valence cerium compound
journal, October 1992

${Eu}_{2}$ ${Ni}_{3}$ ${Si}_{5}$ : A new valence-fluctuation system
journal, May 1988

Magnetism and mixed valence in some R2M3X5 compounds: R = Ce, Eu, U; M = d metals, X = Si, Ge
journal, December 1988

Mixed valence and metamagnetism in a metal flux grown compound Eu2Pt3Si5
journal, May 2015

Anomalous magnetoresistance in antiferromagnetic polycrystalline materials R2Ni3Si5 (R=rare earth)
journal, April 1997

Dy2Co3Si5, Lu2Co3Si5, Y2Co3Si5 and Sc2Co3Si5 with a monoclinic structural deformation variant of the orthorhombic U2Co3Si5 structure type
journal, March 1985

De nouveaux stannures ternaires de rhodium et d'elements des terres rares : TR2Rh3Sn5 OU TR = Y, Gd, Tb, Dy, Ho. structure cristalline et proprietes electriques et magnetiques de Y2Rh3Sn5
journal, September 1984

The stannides YbPtSn and Yb ₂ Pt ₃ Sn ₅
journal, March 1999

Evolution des coordinations dans les structures d'isotypes de U2Co3Si5:R2T3X5 (R ≡; La, Y; T ≡; Ru, Rh, Ir; X ≡; Si, Ge, Sn)
journal, June 1989

De nouveaux isotypes de U2Co3Si5 ou Lu2Co3Si5 dans les systems R-T-Ge (R = Elements Des Terres Rares; T = Ru, Co, Rh, Ir). Supraconductivite de Y2Ir3Ge5
journal, January 1986

Charge Density Wave in the New Polymorphs of RE ₂ Ru ₃ Ge ₅ ( RE = Pr, Sm, Dy)
journal, March 2017

A short history of SHELX
journal, December 2007

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965

Inhomogeneous Electron Gas
journal, November 1964

Generalized Gradient Approximation Made Simple
journal, October 1996

A technique for relativistic spin-polarised calculations
journal, August 1977

Crystal growth and ambient and high pressure study of the re-entrant superconductor Tm ₂ Fe ₃ Si ₅
journal, May 2008

Anisotropic superconductivity in Lu2Fe3Si5
journal, September 2007

High-field magnetization of Er2Fe3Si5
journal, July 1994

Magnetic and structural studies of a Tb2Ni3Si5 single crystal
journal, September 1999

Unusual Ordering Behavior in Single-Crystal $U_{2} {Rh}_{3} {Si}_{5}$
journal, February 1997

Coupling of rare earth moment and charge density wave ordering in a single crystal Er ₂ Ir ₃ Si ₅
journal, March 2015

Multiple charge-density-wave transitions in single-crystalline ${Lu}_{2} {Ir}_{3} {Si}_{5}$
journal, May 2015

Pressure-induced magnetic instability in ${Ce}_{2} {Rh}_{3} {Ge}_{5}$
journal, September 2001

Complex magnetic order in Pr ₂ Pd ₃ Ge ₅ : a single crystal study
journal, October 2012

Thermoelectric properties of the intermediate valent cerium intermetallic Ce2Ni3Si5 doped with Pd, Co, and Cu
journal, November 1999

Anisotropic Magnetic Properties of a Pressure-induced Superconductor Ce ₂ Ni ₃ Ge ₅
journal, October 2005

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds
journal, November 2005

Molten Gallium as a Non-Reactive Solvent: Synthesis of the Silicides RE2Ni3+xSi5-x (RE = Sm, Gd and Tb)
journal, July 2003

Magnetic order in Pu ₂ M ₃ Si ₅ (M = Co, Ni)
journal, February 2011

Anisotropic magnetic properties of
journal, March 2007

Single-crystal study of new Ce compound
journal, April 2008

Magnetic, Thermal and Transport Properties of YbPt_2Si_2 and Yb_2Pt_3Si_5 Single Crystals
journal, July 2014

Magnetic properties of ferromagnetic Pu2Pt3Si5
journal, November 2013

Synthesis of Ce ₂ Rh ₃ Ge ₅ Crystals from a Bismuth Flux
journal, March 2013

The R2Pd3Ge5 (R = La–Nd, Sm) germanides: synthesis, crystal structure and symmetry reduction
journal, August 2016

Pressure-Induced Valence Transition and Heavy Fermion State in Eu ₂ Ni ₃ Ge ₅ and EuRhSi ₃
journal, May 2015

The orthorhombic crystal structure of Ru2Si3, Ru2Ge3, Os2Si3 and Os2Ge3
journal, November 1974

X-ray single crystal refinements on some RT2Ge2 compounds (R = Ca, Y, La, Nd, U; T = Mn-Cu, Ru-Pd): evolution of the chemical bonds
journal, March 1996

Effects of the alkali metal counter ions on the germanium–germanium double bond length in a heavier group 14 element ethenide salt
journal, January 2004

Intermetallic Compounds with Near Zintl Phase Behavior: RE ₂ Zn ₃ Ge ₆ (RE = La, Ce, Pr, Nd) Grown from Liquid Indium
journal, October 2005

Stabilization of New Forms of the Intermetallic Phases β -RENiGe ₂ (RE = Dy, Ho, Er, Tm, Yb, Lu) in Liquid Indium
journal, February 2004

R2Ru3Si5 (R  Er, Tb) with the orthorhombic U2Co3Si5-type structure and R2Ru3Si4.6 (R  Gd, Tb, Dy, Ho, Er) and R2Os3Si4.6 (R  Tb, Er) with the tetragonal Sc2Fe3Si5-type structure
journal, October 1990

Rare Earth Ruthenium Gallides with the Ideal Composition Ln2Ru3Ga5 (Ln = La-Nd, Sm) crystallizing with U2Mn3Si5 (Sc2Fe3Si5) Type Structure
journal, April 2010

New Stannides CaTSn2 (T = Rh, Pd, Ir) and Ca ₂ Pt ₃ Sn ₅ - Synthesis, Structure and Chemical Bonding
journal, June 1999

New Yb2Pt3Sn5 Type Stannides
journal, February 2000

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journal, August 2011