Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals
Abstract
Perovskite-phase cesium bismuth halide (Cs3Bi2X9; X= Cl, Br, I) nanocrystals were synthesized using a hot-injection approach. These nanocrystals adopted ordered-vacancy perovskite crystal structures and demonstrated composition-tunable optical properties. Growth occurred by initial formation of Bi0 seeds, and morphology was controlled by precursor and seed concentration. The Cs3Bi2I9 nanocrystals demonstrated excellent stability under ambient conditions for several months. Contrary to previous reports, we find that photoluminescence originates from the precursor material as opposed to the perovskite nanocrystals.
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1556931
- Alternate Identifier(s):
- OSTI ID: 1434096
- Report Number(s):
- IS-J-9654
Journal ID: ISSN 1359-7345; CHCOFS
- Grant/Contract Number:
- AC02-07CH11358; DGE1247194
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 29; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Nelson, R. D., Santra, K., Wang, Y., Hadi, A., Petrich, J. W., and Panthani, M. G. Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals. United States: N. p., 2018.
Web. doi:10.1039/c7cc07223f.
Nelson, R. D., Santra, K., Wang, Y., Hadi, A., Petrich, J. W., & Panthani, M. G. Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals. United States. https://doi.org/10.1039/c7cc07223f
Nelson, R. D., Santra, K., Wang, Y., Hadi, A., Petrich, J. W., and Panthani, M. G. Tue .
"Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals". United States. https://doi.org/10.1039/c7cc07223f. https://www.osti.gov/servlets/purl/1556931.
@article{osti_1556931,
title = {Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals},
author = {Nelson, R. D. and Santra, K. and Wang, Y. and Hadi, A. and Petrich, J. W. and Panthani, M. G.},
abstractNote = {Perovskite-phase cesium bismuth halide (Cs3Bi2X9; X= Cl, Br, I) nanocrystals were synthesized using a hot-injection approach. These nanocrystals adopted ordered-vacancy perovskite crystal structures and demonstrated composition-tunable optical properties. Growth occurred by initial formation of Bi0 seeds, and morphology was controlled by precursor and seed concentration. The Cs3Bi2I9 nanocrystals demonstrated excellent stability under ambient conditions for several months. Contrary to previous reports, we find that photoluminescence originates from the precursor material as opposed to the perovskite nanocrystals.},
doi = {10.1039/c7cc07223f},
journal = {ChemComm},
number = 29,
volume = 54,
place = {United States},
year = {Tue Mar 13 00:00:00 EDT 2018},
month = {Tue Mar 13 00:00:00 EDT 2018}
}
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