DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Heteronuclear {TbxEu1-x} furoate 1D polymers presenting luminescent properties and SMM behavior

Abstract

New synthesized polymeric mixed complexes {Tb x Eu 1−x } exhibit both tunable luminescence and SMM behavior.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [2];  [3];  [2]; ORCiD logo [2];  [4];  [2];  [2];  [5]; ORCiD logo [6];  [7]
  1. Escola Univ. Salesiana de Sarrià (EUSS), Barcelona (Spain)
  2. Univ. de Zaragoza (Spain)
  3. Univ. de Zaragoza (Spain) Centro Univ. de la Defensa (Spain)
  4. Escuela de Ingeniería y Arquitectura de Zaragoza (ISQCH) (Spain)
  5. Academy of Sciences of Moldova, Chisinau (Moldova, Republic of)
  6. Academy of Sciences of Moldova, Chisinau (Moldova, Republic of); Ames Lab., Ames, IA (United States)
  7. Inst. of Macromolecular Chemistry “Petru Poni” Iasi, (Romania)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1556121
Alternate Identifier(s):
OSTI ID: 1436528
Report Number(s):
IS-J 9675
Journal ID: ISSN 2050-7526; JMCCCX
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Volume: 6; Journal Issue: 19; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Bartolomé, E., Bartolomé, J., Arauzo, A., Luzón, J., Cases, R., Fuertes, S., Sicilia, V., Sánchez-Cano, A. I., Aporta, J., Melnic, S., Prodius, D., and Shova, S. Heteronuclear {TbxEu1-x} furoate 1D polymers presenting luminescent properties and SMM behavior. United States: N. p., 2018. Web. doi:10.1039/C8TC00832A.
Bartolomé, E., Bartolomé, J., Arauzo, A., Luzón, J., Cases, R., Fuertes, S., Sicilia, V., Sánchez-Cano, A. I., Aporta, J., Melnic, S., Prodius, D., & Shova, S. Heteronuclear {TbxEu1-x} furoate 1D polymers presenting luminescent properties and SMM behavior. United States. https://doi.org/10.1039/C8TC00832A
Bartolomé, E., Bartolomé, J., Arauzo, A., Luzón, J., Cases, R., Fuertes, S., Sicilia, V., Sánchez-Cano, A. I., Aporta, J., Melnic, S., Prodius, D., and Shova, S. Tue . "Heteronuclear {TbxEu1-x} furoate 1D polymers presenting luminescent properties and SMM behavior". United States. https://doi.org/10.1039/C8TC00832A. https://www.osti.gov/servlets/purl/1556121.
@article{osti_1556121,
title = {Heteronuclear {TbxEu1-x} furoate 1D polymers presenting luminescent properties and SMM behavior},
author = {Bartolomé, E. and Bartolomé, J. and Arauzo, A. and Luzón, J. and Cases, R. and Fuertes, S. and Sicilia, V. and Sánchez-Cano, A. I. and Aporta, J. and Melnic, S. and Prodius, D. and Shova, S.},
abstractNote = {New synthesized polymeric mixed complexes {Tb x Eu 1−x } exhibit both tunable luminescence and SMM behavior.},
doi = {10.1039/C8TC00832A},
journal = {Journal of Materials Chemistry C},
number = 19,
volume = 6,
place = {United States},
year = {Tue May 01 00:00:00 EDT 2018},
month = {Tue May 01 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 19 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Strategies towards single molecule magnets based on lanthanide ions
journal, October 2009


Taking advantage of luminescent lanthanide ions
journal, January 2005

  • Bünzli, Jean-Claude G.; Piguet, Claude
  • Chemical Society Reviews, Vol. 34, Issue 12
  • DOI: 10.1039/b406082m

Lanthanide luminescence for functional materials and bio-sciences
journal, January 2010

  • Eliseeva, Svetlana V.; Bünzli, Jean-Claude G.
  • Chem. Soc. Rev., Vol. 39, Issue 1
  • DOI: 10.1039/B905604C

Rare earth metal-containing ionic liquids
journal, May 2018


Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies
journal, June 2013

  • Zhang, Peng; Guo, Yun-Nan; Tang, Jinkui
  • Coordination Chemistry Reviews, Vol. 257, Issue 11-12
  • DOI: 10.1016/j.ccr.2013.01.012

Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level
journal, July 2003

  • Ishikawa, Naoto; Sugita, Miki; Ishikawa, Tadahiko
  • Journal of the American Chemical Society, Vol. 125, Issue 29
  • DOI: 10.1021/ja029629n

Tuning the magneto-optical response of TbPc 2 single molecule magnets by the choice of the substrate
journal, January 2015

  • Robaschik, Peter; Fronk, Michael; Toader, Marius
  • Journal of Materials Chemistry C, Vol. 3, Issue 31
  • DOI: 10.1039/C5TC01520K

Magnetic Interaction Between a Radical Spin and a Single-Molecule Magnet in a Molecular Spin-Valve
journal, February 2015


Influence of Peripheral Substitution on the Magnetic Behavior of Single-Ion Magnets Based on Homo- and Heteroleptic Tb III Bis(phthalocyaninate)
journal, November 2012

  • Ganivet, Carolina R.; Ballesteros, Beatriz; de la Torre, Gema
  • Chemistry - A European Journal, Vol. 19, Issue 4
  • DOI: 10.1002/chem.201202600

A Tetranuclear 3d−4f Single Molecule Magnet:  [Cu II LTb III (hfac) 2 ] 2
journal, January 2004

  • Osa, Shutaro; Kido, Takafumi; Matsumoto, Naohide
  • Journal of the American Chemical Society, Vol. 126, Issue 2
  • DOI: 10.1021/ja037365e

A N 2 3– Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K
journal, September 2011

  • Rinehart, Jeffrey D.; Fang, Ming; Evans, William J.
  • Journal of the American Chemical Society, Vol. 133, Issue 36
  • DOI: 10.1021/ja206286h

Interaction between f-Electronic Systems in Dinuclear Lanthanide Complexes with Phthalocyanines
journal, September 2002

  • Ishikawa, Naoto; Iino, Tomochika; Kaizu, Youkoh
  • Journal of the American Chemical Society, Vol. 124, Issue 38
  • DOI: 10.1021/ja027119n

Impact of the coordination environment on the magnetic properties of single-molecule magnets based on homo- and hetero-dinuclear terbium( iii ) heteroleptic tris(crownphthalocyaninate)
journal, January 2016

  • Holmberg, Rebecca J.; Polovkova, Marina A.; Martynov, Alexander G.
  • Dalton Transactions, Vol. 45, Issue 22
  • DOI: 10.1039/C6DT00777E

Heterodinuclear Lanthanoid-Containing Polyoxometalates: Stepwise Synthesis and Single-Molecule Magnet Behavior
journal, September 2013

  • Sato, Rinta; Suzuki, Kosuke; Sugawa, Midori
  • Chemistry - A European Journal, Vol. 19, Issue 39
  • DOI: 10.1002/chem.201302596

Molecular Prototypes for Spin-Based CNOT and SWAP Quantum Gates
journal, September 2011


Heterodimetallic [LnLn′] Lanthanide Complexes: Toward a Chemical Design of Two-Qubit Molecular Spin Quantum Gates
journal, August 2014

  • Aguilà, David; Barrios, Leoní A.; Velasco, Verónica
  • Journal of the American Chemical Society, Vol. 136, Issue 40
  • DOI: 10.1021/ja507809w

Design of magnetic coordination complexes for quantum computing
journal, January 2012

  • Aromí, Guillem; Aguilà, David; Gamez, Patrick
  • Chem. Soc. Rev., Vol. 41, Issue 2
  • DOI: 10.1039/C1CS15115K

Synthesis and Properties of a Family of Unsymmetric Dinuclear Complexes of Ln III (Ln = Eu, Gd, Tb)
journal, August 2010

  • Aguilà, David; Barrios, Leoní A.; Luis, Fernando
  • Inorganic Chemistry, Vol. 49, Issue 15
  • DOI: 10.1021/ic1008285

Pyrazine bridged Ln2 (La, Nd, Eu and Tb) complexes containing fluorinated β-diketone
journal, June 2012


A family of acetato-diphenoxo triply bridged dimetallic Zn II Ln III complexes: SMM behavior and luminescent properties
journal, January 2016

  • Oyarzabal, Itziar; Artetxe, Beñat; Rodríguez-Diéguez, Antonio
  • Dalton Transactions, Vol. 45, Issue 23
  • DOI: 10.1039/C6DT01327A

The Role of the Ligand-to-Metal Charge-Transfer State in the Dipivaloylmethanate-Lanthanide Intramolecular Energy Transfer Process: LMCT in Dipivaloylmethanate-Lanthanide
journal, June 2015

  • Miranda, Yolanda C.; Pereira, Leide L. A. L.; Barbosa, José H. P.
  • European Journal of Inorganic Chemistry, Vol. 2015, Issue 18
  • DOI: 10.1002/ejic.201500263

Brightness and Color Tuning in a Series of Lanthanide-Based Coordination Polymers with Benzene-1,2,4,5-tetracarboxylic Acid as a Ligand
journal, November 2015


Heteronuclear lanthanide-based coordination polymers exhibiting tunable multiple emission spectra
journal, January 2014

  • Fan, X.; Freslon, S.; Daiguebonne, C.
  • Journal of Materials Chemistry C, Vol. 2, Issue 28
  • DOI: 10.1039/c4tc00506f

Color tunable emission and low-temperature luminescent sensing of europium and terbium carboxylic acid complexes
journal, January 2018


Eu3+-doped Tb3+ metal–organic frameworks emitting tunable three primary colors towards white light
journal, January 2013

  • Liu, Zhi-Fa; Wu, Mei-Feng; Wang, Shuai-Hua
  • Journal of Materials Chemistry C, Vol. 1, Issue 31
  • DOI: 10.1039/c3tc30733f

Heterodinuclear (Sm, Tb) lanthanide pivalates with heterocyclic N-donors: synthesis, structure, thermal behavior, and magnetic and photoluminescence properties
journal, January 2014

  • Fomina, Irina G.; Dobrokhotova, Zhanna V.; Ilyukhin, Andrey B.
  • Dalton Trans., Vol. 43, Issue 48
  • DOI: 10.1039/C4DT02590C

Luminescence of Europium(III) and Terbium(III) Complexes Incorporated in Poly(Vinyl Pyrrolidone) Matrix
journal, November 2001

  • Li, Quan; Li, Tao; Wu, Jinguang
  • The Journal of Physical Chemistry B, Vol. 105, Issue 49
  • DOI: 10.1021/jp012922+

Synthesis and characterization of new heterodinuclear (Eu,Tb) lanthanide pivalates
journal, February 2013


Bifunctional Mixed-Lanthanide Cyano-Bridged Coordination Polymers Ln 0.5 Ln′ 0.5 (H 2 O) 5 [W(CN) 8 ] (Ln/Ln′ = Eu 3+ /Tb 3+ , Eu 3+ /Gd 3+ , Tb 3+ /Sm 3+ )
journal, August 2012

  • Chelebaeva, Elena; Long, Jérôme; Larionova, Joulia
  • Inorganic Chemistry, Vol. 51, Issue 16
  • DOI: 10.1021/ic301144j

Light-Emitting Diodes
book, January 2006


Thiacalix[4]arene-Supported Planar Ln 4 (Ln = Tb III , Dy III ) Clusters: Toward Luminescent and Magnetic Bifunctional Materials
journal, December 2009

  • Bi, Yanfeng; Wang, Xiu-Teng; Liao, Wuping
  • Inorganic Chemistry, Vol. 48, Issue 24
  • DOI: 10.1021/ic9017807

A series of rare earth complexes with novel non-interpenetrating 3D networks: synthesis, structures, magnetic and optical properties
journal, January 2014

  • Wei, Xiao-Hua; Yang, Lin-Yan; Liao, Sheng-Yun
  • Dalton Transactions, Vol. 43, Issue 15
  • DOI: 10.1039/c3dt53112k

Rare Earth Polyoxometalates
journal, August 2017


{Dy(α-fur)3}n: from double relaxation single-ion magnet behavior to 3D ordering
journal, January 2013

  • Bartolomé, Elena; Bartolomé, Juan; Melnic, Silvia
  • Dalton Transactions, Vol. 42, Issue 28
  • DOI: 10.1039/c3dt51080h

Antiferromagnetic single-chain magnet slow relaxation in the {Tb(α-fur) 3 } n polymer with non-Kramers ions
journal, January 2016

  • Bartolomé, E.; Bartolomé, J.; Arauzo, A.
  • Journal of Materials Chemistry C, Vol. 4, Issue 22
  • DOI: 10.1039/C6TC00919K

Synthesis, crystal structure, magnetic and luminescence investigations of new 2Ln3+–Sr2+ heteronuclear polymers with 2-furoic acid
journal, June 2007

  • Turta, Constantin; Melnic, Silvia; Bettinelli, Marco
  • Inorganica Chimica Acta, Vol. 360, Issue 9
  • DOI: 10.1016/j.ica.2007.02.045

Magnetic relaxation versus 3D long-range ordering in {Dy 2 Ba(α-fur) 8 } n furoate polymers
journal, January 2014

  • Bartolomé, E.; Bartolomé, J.; Melnic, S.
  • Dalton Trans., Vol. 43, Issue 28
  • DOI: 10.1039/C4DT00538D

Synthesis, structure and properties of heterotrinuclear carboxylate complexes [Fe2M(Ca, Sr, Ba)O(CCl3COO)6(THF)n]
journal, July 2006


Field-induced internal Fe and Ln spin reorientation in butterfly { Fe 3 LnO 2 } (Ln = Dy and Gd) single-molecule magnets
journal, May 2013


Intracluster interactions in butterfly { Fe 3 LnO 2 } molecules with the non-Kramers ions Tb(III) and Ho(III)
journal, August 2015


Intracluster interactions in “butterfly” {Fe3LnO2} molecules
journal, February 2016

  • Badía-Romano, L.; Rubín, J.; Bartolomé, F.
  • Journal of Magnetism and Magnetic Materials, Vol. 400
  • DOI: 10.1016/j.jmmm.2015.07.001

Interpretation of europium(III) spectra
journal, July 2015


Tb 3+ →Eu 3+ Energy Transfer in Mixed-Lanthanide-Organic Frameworks
journal, September 2012

  • Rodrigues, Marcelo O.; Dutra, José Diogo Lisboa; Nunes, Luiz Antônio O.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 37
  • DOI: 10.1021/jp3054789

An Unprecedented Family of Lanthanide-Containing Coordination Polymers with Highly Tunable Emission Properties
journal, April 2009

  • Kerbellec, N.; Kustaryono, D.; Haquin, V.
  • Inorganic Chemistry, Vol. 48, Issue 7
  • DOI: 10.1021/ic801616y

Parallel implementation of the MAGPACK package for the analysis of high-nuclearity spin clusters
journal, December 2010

  • Ramos, E.; Roman, J. E.; Cardona-Serra, S.
  • Computer Physics Communications, Vol. 181, Issue 12
  • DOI: 10.1016/j.cpc.2010.09.007

Statistical Mechanics of the Anisotropic Linear Heisenberg Model
journal, September 1962


Phonon bottleneck effect leads to observation of quantum tunneling of the magnetization and butterfly hysteresis loops in ( Et 4 N ) 3 Fe 2 F 9
journal, November 2005

  • Schenker, Ralph; Leuenberger, Michael N.; Chaboussant, Grégory
  • Physical Review B, Vol. 72, Issue 18
  • DOI: 10.1103/PhysRevB.72.184403

The influence of thermal conduction in spin-lattice relaxation experiments
journal, August 1978


On the influence of heat transport on low- frequency paramagnetic spin—Lattice relaxation experiments
journal, October 1974


Direct solid-phase synthesis of molecular heterooligonuclear lanthanoid-complexes
journal, March 2020


Works referencing / citing this record:

Chirality and Magnetic Properties of One-dimensional Ln (Ln = Gd, Dy) Polymers: Chirality and Magnetic Properties of One-dimensional Ln (Ln = Gd, Dy) Polymers
journal, May 2020

  • Li, Ning-Fang; Ji, Jiuyang; Jiang, Wei
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 646, Issue 10
  • DOI: 10.1002/zaac.202000144

Slow magnetic relaxation in a Tb( iii )-based coordination polymer
journal, January 2018

  • Yoshida, Takefumi; Narayana, Yemineni S. L. V.; Abe, Hitoshi
  • Dalton Transactions, Vol. 47, Issue 45
  • DOI: 10.1039/c8dt03125h

An intense luminescent Dy( iii ) single-ion magnet with the acylpyrazolonate ligand showing two slow magnetic relaxation processes
journal, January 2018

  • Li, Xi-Li; Li, Junfeng; Zhu, Cancan
  • New Journal of Chemistry, Vol. 42, Issue 20
  • DOI: 10.1039/c8nj03345e

TbO + in a calcium apatite matrix featuring a triple trigger-type relaxation of magnetization
journal, January 2019

  • Kazin, Pavel E.; Zykin, Mikhail A.; Magdysyuk, Oxana V.
  • Dalton Transactions, Vol. 48, Issue 16
  • DOI: 10.1039/c9dt01120j

High relaxation barrier in neodymium furoate-based field-induced SMMs
journal, January 2019

  • Bartolomé, E.; Arauzo, A.; Luzón, J.
  • Dalton Transactions, Vol. 48, Issue 41
  • DOI: 10.1039/c9dt02047k

Field Induced Slow Magnetic Relaxation in a Non Kramers Tb(III) Based Single Chain Magnet
journal, December 2018