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Title: Heteronuclear {Tb xEu 1-x} furoate 1D polymers presenting luminescent properties and SMM behavior

Abstract

New synthesized polymeric mixed complexes {Tb x Eu 1−x } exhibit both tunable luminescence and SMM behavior.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [2];  [3];  [2]; ORCiD logo [2];  [4];  [2];  [2];  [5]; ORCiD logo [6];  [7]
  1. Escola Univ. Salesiana de Sarrià (EUSS), Barcelona (Spain)
  2. Univ. de Zaragoza (Spain)
  3. Univ. de Zaragoza (Spain) Centro Univ. de la Defensa (Spain)
  4. Escuela de Ingeniería y Arquitectura de Zaragoza (ISQCH) (Spain)
  5. Academy of Sciences of Moldova, Chisinau (Moldova, Republic of)
  6. Academy of Sciences of Moldova, Chisinau (Moldova, Republic of); Ames Lab., Ames, IA (United States)
  7. Inst. of Macromolecular Chemistry “Petru Poni” Iasi, (Romania)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1556121
Alternate Identifier(s):
OSTI ID: 1436528
Report Number(s):
IS-J 9675
Journal ID: ISSN 2050-7526; JMCCCX
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Volume: 6; Journal Issue: 19; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Bartolomé, E., Bartolomé, J., Arauzo, A., Luzón, J., Cases, R., Fuertes, S., Sicilia, V., Sánchez-Cano, A. I., Aporta, J., Melnic, S., Prodius, D., and Shova, S. Heteronuclear {TbxEu1-x} furoate 1D polymers presenting luminescent properties and SMM behavior. United States: N. p., 2018. Web. doi:10.1039/C8TC00832A.
Bartolomé, E., Bartolomé, J., Arauzo, A., Luzón, J., Cases, R., Fuertes, S., Sicilia, V., Sánchez-Cano, A. I., Aporta, J., Melnic, S., Prodius, D., & Shova, S. Heteronuclear {TbxEu1-x} furoate 1D polymers presenting luminescent properties and SMM behavior. United States. doi:10.1039/C8TC00832A.
Bartolomé, E., Bartolomé, J., Arauzo, A., Luzón, J., Cases, R., Fuertes, S., Sicilia, V., Sánchez-Cano, A. I., Aporta, J., Melnic, S., Prodius, D., and Shova, S. Tue . "Heteronuclear {TbxEu1-x} furoate 1D polymers presenting luminescent properties and SMM behavior". United States. doi:10.1039/C8TC00832A. https://www.osti.gov/servlets/purl/1556121.
@article{osti_1556121,
title = {Heteronuclear {TbxEu1-x} furoate 1D polymers presenting luminescent properties and SMM behavior},
author = {Bartolomé, E. and Bartolomé, J. and Arauzo, A. and Luzón, J. and Cases, R. and Fuertes, S. and Sicilia, V. and Sánchez-Cano, A. I. and Aporta, J. and Melnic, S. and Prodius, D. and Shova, S.},
abstractNote = {New synthesized polymeric mixed complexes {Tb x Eu 1−x } exhibit both tunable luminescence and SMM behavior.},
doi = {10.1039/C8TC00832A},
journal = {Journal of Materials Chemistry C},
number = 19,
volume = 6,
place = {United States},
year = {2018},
month = {5}
}

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Cited by: 5 works
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    Works referencing / citing this record:

    Influence of Peripheral Substitution on the Magnetic Behavior of Single-Ion Magnets Based on Homo- and Heteroleptic Tb III Bis(phthalocyaninate)
    journal, November 2012

    • Ganivet, Carolina R.; Ballesteros, Beatriz; de la Torre, Gema
    • Chemistry - A European Journal, Vol. 19, Issue 4
    • DOI: 10.1002/chem.201202600

    Heterodinuclear Lanthanoid-Containing Polyoxometalates: Stepwise Synthesis and Single-Molecule Magnet Behavior
    journal, September 2013

    • Sato, Rinta; Suzuki, Kosuke; Sugawa, Midori
    • Chemistry - A European Journal, Vol. 19, Issue 39
    • DOI: 10.1002/chem.201302596

    The Role of the Ligand-to-Metal Charge-Transfer State in the Dipivaloylmethanate-Lanthanide Intramolecular Energy Transfer Process: LMCT in Dipivaloylmethanate-Lanthanide
    journal, June 2015

    • Miranda, Yolanda C.; Pereira, Leide L. A. L.; Barbosa, José H. P.
    • European Journal of Inorganic Chemistry, Vol. 2015, Issue 18
    • DOI: 10.1002/ejic.201500263

    Strategies towards single molecule magnets based on lanthanide ions
    journal, October 2009


    Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies
    journal, June 2013

    • Zhang, Peng; Guo, Yun-Nan; Tang, Jinkui
    • Coordination Chemistry Reviews, Vol. 257, Issue 11-12
    • DOI: 10.1016/j.ccr.2013.01.012

    Interpretation of europium(III) spectra
    journal, July 2015


    Rare earth metal-containing ionic liquids
    journal, May 2018


    Parallel implementation of the MAGPACK package for the analysis of high-nuclearity spin clusters
    journal, December 2010

    • Ramos, E.; Roman, J. E.; Cardona-Serra, S.
    • Computer Physics Communications, Vol. 181, Issue 12
    • DOI: 10.1016/j.cpc.2010.09.007

    Synthesis, crystal structure, magnetic and luminescence investigations of new 2Ln3+–Sr2+ heteronuclear polymers with 2-furoic acid
    journal, June 2007

    • Turta, Constantin; Melnic, Silvia; Bettinelli, Marco
    • Inorganica Chimica Acta, Vol. 360, Issue 9
    • DOI: 10.1016/j.ica.2007.02.045

    Color tunable emission and low-temperature luminescent sensing of europium and terbium carboxylic acid complexes
    journal, January 2018


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    journal, June 2012


    Intracluster interactions in “butterfly” {Fe3LnO2} molecules
    journal, February 2016

    • Badía-Romano, L.; Rubín, J.; Bartolomé, F.
    • Journal of Magnetism and Magnetic Materials, Vol. 400
    • DOI: 10.1016/j.jmmm.2015.07.001

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    journal, July 2006


    Synthesis and characterization of new heterodinuclear (Eu,Tb) lanthanide pivalates
    journal, February 2013


    Rare Earth Polyoxometalates
    journal, August 2017


    Brightness and Color Tuning in a Series of Lanthanide-Based Coordination Polymers with Benzene-1,2,4,5-tetracarboxylic Acid as a Ligand
    journal, November 2015


    Magnetic Interaction Between a Radical Spin and a Single-Molecule Magnet in a Molecular Spin-Valve
    journal, February 2015


    Synthesis and Properties of a Family of Unsymmetric Dinuclear Complexes of Ln III (Ln = Eu, Gd, Tb)
    journal, August 2010

    • Aguilà, David; Barrios, Leoní A.; Luis, Fernando
    • Inorganic Chemistry, Vol. 49, Issue 15
    • DOI: 10.1021/ic1008285

    Bifunctional Mixed-Lanthanide Cyano-Bridged Coordination Polymers Ln 0.5 Ln′ 0.5 (H 2 O) 5 [W(CN) 8 ] (Ln/Ln′ = Eu 3+ /Tb 3+ , Eu 3+ /Gd 3+ , Tb 3+ /Sm 3+ )
    journal, August 2012

    • Chelebaeva, Elena; Long, Jérôme; Larionova, Joulia
    • Inorganic Chemistry, Vol. 51, Issue 16
    • DOI: 10.1021/ic301144j

    An Unprecedented Family of Lanthanide-Containing Coordination Polymers with Highly Tunable Emission Properties
    journal, April 2009

    • Kerbellec, N.; Kustaryono, D.; Haquin, V.
    • Inorganic Chemistry, Vol. 48, Issue 7
    • DOI: 10.1021/ic801616y

    Thiacalix[4]arene-Supported Planar Ln 4 (Ln = Tb III , Dy III ) Clusters: Toward Luminescent and Magnetic Bifunctional Materials
    journal, December 2009

    • Bi, Yanfeng; Wang, Xiu-Teng; Liao, Wuping
    • Inorganic Chemistry, Vol. 48, Issue 24
    • DOI: 10.1021/ic9017807

    Interaction between f-Electronic Systems in Dinuclear Lanthanide Complexes with Phthalocyanines
    journal, September 2002

    • Ishikawa, Naoto; Iino, Tomochika; Kaizu, Youkoh
    • Journal of the American Chemical Society, Vol. 124, Issue 38
    • DOI: 10.1021/ja027119n

    Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level
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    • Ishikawa, Naoto; Sugita, Miki; Ishikawa, Tadahiko
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    A Tetranuclear 3d−4f Single Molecule Magnet:  [Cu II LTb III (hfac) 2 ] 2
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    • Osa, Shutaro; Kido, Takafumi; Matsumoto, Naohide
    • Journal of the American Chemical Society, Vol. 126, Issue 2
    • DOI: 10.1021/ja037365e

    A N 2 3– Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K
    journal, September 2011

    • Rinehart, Jeffrey D.; Fang, Ming; Evans, William J.
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    • DOI: 10.1021/ja206286h

    Heterodimetallic [LnLn′] Lanthanide Complexes: Toward a Chemical Design of Two-Qubit Molecular Spin Quantum Gates
    journal, August 2014

    • Aguilà, David; Barrios, Leoní A.; Velasco, Verónica
    • Journal of the American Chemical Society, Vol. 136, Issue 40
    • DOI: 10.1021/ja507809w

    Tb 3+ →Eu 3+ Energy Transfer in Mixed-Lanthanide-Organic Frameworks
    journal, September 2012

    • Rodrigues, Marcelo O.; Dutra, José Diogo Lisboa; Nunes, Luiz Antônio O.
    • The Journal of Physical Chemistry C, Vol. 116, Issue 37
    • DOI: 10.1021/jp3054789

    Taking advantage of luminescent lanthanide ions
    journal, January 2005

    • Bünzli, Jean-Claude G.; Piguet, Claude
    • Chemical Society Reviews, Vol. 34, Issue 12
    • DOI: 10.1039/b406082m

    {Dy(α-fur)3}n: from double relaxation single-ion magnet behavior to 3D ordering
    journal, January 2013

    • Bartolomé, Elena; Bartolomé, Juan; Melnic, Silvia
    • Dalton Transactions, Vol. 42, Issue 28
    • DOI: 10.1039/c3dt51080h

    A series of rare earth complexes with novel non-interpenetrating 3D networks: synthesis, structures, magnetic and optical properties
    journal, January 2014

    • Wei, Xiao-Hua; Yang, Lin-Yan; Liao, Sheng-Yun
    • Dalton Transactions, Vol. 43, Issue 15
    • DOI: 10.1039/c3dt53112k

    Eu3+-doped Tb3+ metal–organic frameworks emitting tunable three primary colors towards white light
    journal, January 2013

    • Liu, Zhi-Fa; Wu, Mei-Feng; Wang, Shuai-Hua
    • Journal of Materials Chemistry C, Vol. 1, Issue 31
    • DOI: 10.1039/c3tc30733f

    Heteronuclear lanthanide-based coordination polymers exhibiting tunable multiple emission spectra
    journal, January 2014

    • Fan, X.; Freslon, S.; Daiguebonne, C.
    • Journal of Materials Chemistry C, Vol. 2, Issue 28
    • DOI: 10.1039/c4tc00506f

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    High relaxation barrier in neodymium furoate-based field-induced SMMs
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