Heterostructured Bismuth Vanadate/Cobalt Phosphate Photoelectrodes Promote TEMPO-Mediated Oxidation of 5-Hydroxymethylfurfural
Abstract
Motivated by replacing the kinetically unfavorable oxygen evolution reaction (OER) and producing value-added products in photoelectrochemical cells (PECs), we report that bismuth vanadate (BiVO4) photoelectrodes modified with a cobalt phosphate (CoPi) overlayer facilitate 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-mediated selective oxidation of 5-hydroxymethylfurfural (HMF). CoPi layers with sufficient thickness were found to reduce the potential required for TEMPO oxidation by 0.5 V, as well as increase charge injection efficiency sevenfold compared to BiVO4 without CoPi. Furthermore, the undesired OER was completely suppressed when using the heterostructured photoanodes. Transient photocurrent measurements suggested that CoPi alleviates recombination losses resulting from the back reduction of oxidized TEMPO. The PECs with BiVO4/CoPi bilayer achieved 88 % yield to 2,5-furandicarboxylic acid (FDCA) from HMF oxidation under mild conditions, whereas <1 % FDCA was generated with BiVO4. In conclusion, these findings suggest that suppression of the back reduction process substantially improves the efficiency of the oxidation, giving a potential route to more efficient solar fuel/chemical production.
- Authors:
-
- Iowa State Univ., Ames, IA (United States)
- Ames Lab. and Iowa State Univ., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1556105
- Alternate Identifier(s):
- OSTI ID: 1532790
- Report Number(s):
- IS-J-9987
Journal ID: ISSN 2196-0216
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemElectroChem
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 13; Journal ID: ISSN 2196-0216
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; alcohol oxidation; TEMPO; photoelectrocatalysis; bismuth vanadate; biomass
Citation Formats
Chadderdon, David J., Wu, Li‐Pin, McGraw, Zachary A., Panthani, Matthew, and Li, Wenzhen. Heterostructured Bismuth Vanadate/Cobalt Phosphate Photoelectrodes Promote TEMPO-Mediated Oxidation of 5-Hydroxymethylfurfural. United States: N. p., 2019.
Web. doi:10.1002/celc.201900482.
Chadderdon, David J., Wu, Li‐Pin, McGraw, Zachary A., Panthani, Matthew, & Li, Wenzhen. Heterostructured Bismuth Vanadate/Cobalt Phosphate Photoelectrodes Promote TEMPO-Mediated Oxidation of 5-Hydroxymethylfurfural. United States. doi:10.1002/celc.201900482.
Chadderdon, David J., Wu, Li‐Pin, McGraw, Zachary A., Panthani, Matthew, and Li, Wenzhen. Fri .
"Heterostructured Bismuth Vanadate/Cobalt Phosphate Photoelectrodes Promote TEMPO-Mediated Oxidation of 5-Hydroxymethylfurfural". United States. doi:10.1002/celc.201900482. https://www.osti.gov/servlets/purl/1556105.
@article{osti_1556105,
title = {Heterostructured Bismuth Vanadate/Cobalt Phosphate Photoelectrodes Promote TEMPO-Mediated Oxidation of 5-Hydroxymethylfurfural},
author = {Chadderdon, David J. and Wu, Li‐Pin and McGraw, Zachary A. and Panthani, Matthew and Li, Wenzhen},
abstractNote = {Motivated by replacing the kinetically unfavorable oxygen evolution reaction (OER) and producing value-added products in photoelectrochemical cells (PECs), we report that bismuth vanadate (BiVO4) photoelectrodes modified with a cobalt phosphate (CoPi) overlayer facilitate 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-mediated selective oxidation of 5-hydroxymethylfurfural (HMF). CoPi layers with sufficient thickness were found to reduce the potential required for TEMPO oxidation by 0.5 V, as well as increase charge injection efficiency sevenfold compared to BiVO4 without CoPi. Furthermore, the undesired OER was completely suppressed when using the heterostructured photoanodes. Transient photocurrent measurements suggested that CoPi alleviates recombination losses resulting from the back reduction of oxidized TEMPO. The PECs with BiVO4/CoPi bilayer achieved 88 % yield to 2,5-furandicarboxylic acid (FDCA) from HMF oxidation under mild conditions, whereas <1 % FDCA was generated with BiVO4. In conclusion, these findings suggest that suppression of the back reduction process substantially improves the efficiency of the oxidation, giving a potential route to more efficient solar fuel/chemical production.},
doi = {10.1002/celc.201900482},
journal = {ChemElectroChem},
number = 13,
volume = 6,
place = {United States},
year = {2019},
month = {5}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 6 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Simultaneous H 2 Generation and Biomass Upgrading in Water by an Efficient Noble-Metal-Free Bifunctional Electrocatalyst
journal, July 2016
- You, Bo; Jiang, Nan; Liu, Xuan
- Angewandte Chemie International Edition, Vol. 55, Issue 34
New Stable Catalytic Electrodes Functionalized with TEMPO for the Waste-Free Oxidation of Alcohol
journal, August 2018
- Karimi, Babak; Ghahremani, Mina; Ciriminna, Rosaria
- Organic Process Research & Development, Vol. 22, Issue 9
Ultrathin FeOOH Nanolayers with Abundant Oxygen Vacancies on BiVO 4 Photoanodes for Efficient Water Oxidation
journal, February 2018
- Zhang, Beibei; Wang, Lei; Zhang, Yajun
- Angewandte Chemie International Edition, Vol. 57, Issue 8
Enzyme-Catalyzed Oxidation of 5-Hydroxymethylfurfural to Furan-2,5-dicarboxylic Acid
journal, May 2014
- Dijkman, Willem P.; Groothuis, Daphne E.; Fraaije, Marco W.
- Angewandte Chemie International Edition, Vol. 53, Issue 25
Simultaneous enhancements in photon absorption and charge transport of bismuth vanadate photoanodes for solar water splitting
journal, October 2015
- Kim, Tae Woo; Ping, Yuan; Galli, Giulia A.
- Nature Communications, Vol. 6, Issue 1
Combined biomass valorization and hydrogen production in a photoelectrochemical cell
journal, March 2015
- Cha, Hyun Gil; Choi, Kyoung-Shin
- Nature Chemistry, Vol. 7, Issue 4, p. 328-333
Kinetics of light-driven oxygen evolution at α-Fe 2 O 3 electrodes
journal, January 2012
- Peter, Laurence M.; Wijayantha, K. G. Upul; Tahir, Asif A.
- Faraday Discuss., Vol. 155
Cobalt-phosphate (Co-Pi) catalyst modified Mo-doped BiVO4 photoelectrodes for solar water oxidation
journal, January 2011
- Pilli, Satyananda Kishore; Furtak, Thomas E.; Brown, Logan D.
- Energy & Environmental Science, Vol. 4, Issue 12
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
journal, January 2015
- Jiao, Yan; Zheng, Yao; Jaroniec, Mietek
- Chemical Society Reviews, Vol. 44, Issue 8
Progress in bismuth vanadate photoanodes for use in solar water oxidation
journal, January 2013
- Park, Yiseul; McDonald, Kenneth J.; Choi, Kyoung-Shin
- Chem. Soc. Rev., Vol. 42, Issue 6, p. 2321-2337
Efficient H 2 Evolution Coupled with Oxidative Refining of Alcohols via A Hierarchically Porous Nickel Bifunctional Electrocatalyst
journal, June 2017
- You, Bo; Liu, Xuan; Liu, Xin
- ACS Catalysis, Vol. 7, Issue 7
Electrode materials for electrosynthesis
journal, July 1990
- Couper, A. Mottram; Pletcher, Derek; Walsh, Frank C.
- Chemical Reviews, Vol. 90, Issue 5
Künstliche Photosynthese für die Produktion von nachhaltigen Kraftstoffen und chemischen Produkten
journal, January 2015
- Kim, Dohyung; Sakimoto, Kelsey K.; Hong, Dachao
- Angewandte Chemie, Vol. 127, Issue 11
Mechanistic Study of the Electrocatalytic Oxidation of Alcohols by TEMPO and NHPI
journal, July 2013
- Rafiee, Mohammad; Karimi, Babak; Alizadeh, Saber
- ChemElectroChem, Vol. 1, Issue 2, p. 455-462
Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals
journal, February 2009
- Binder, Joseph B.; Raines, Ronald T.
- Journal of the American Chemical Society, Vol. 131, Issue 5, p. 1979-1985
Catalyst Deposition on Photoanodes: The Roles of Intrinsic Catalytic Activity, Catalyst Electrical Conductivity, and Semiconductor Morphology
journal, March 2018
- Qiu, Jingjing; Hajibabaei, Hamed; Nellist, Michael R.
- ACS Energy Letters, Vol. 3, Issue 4
Nanotechnology makes biomass electrolysis more energy efficient than water electrolysis
journal, June 2014
- Chen, Y. X.; Lavacchi, A.; Miller, H. A.
- Nature Communications, Vol. 5, Issue 1
Self-Supported Pd x Bi Catalysts for the Electrooxidation of Glycerol in Alkaline Media
journal, February 2014
- Zalineeva, Anna; Serov, Alexey; Padilla, Monica
- Journal of the American Chemical Society, Vol. 136, Issue 10
Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by “Co-Pi” Catalyst-Modified W:BiVO 4
journal, November 2011
- Zhong, Diane K.; Choi, Sujung; Gamelin, Daniel R.
- Journal of the American Chemical Society, Vol. 133, Issue 45
Electrochemical Synthesis of Photoelectrodes and Catalysts for Use in Solar Water Splitting
journal, August 2015
- Kang, Donghyeon; Kim, Tae Woo; Kubota, Stephen R.
- Chemical Reviews, Vol. 115, Issue 23
Enhanced Photoelectrochemical Water Oxidation on Bismuth Vanadate by Electrodeposition of Amorphous Titanium Dioxide
journal, August 2014
- Eisenberg, David; Ahn, Hyun S.; Bard, Allen J.
- Journal of the American Chemical Society, Vol. 136, Issue 40
Photoelectrochemical and Impedance Spectroscopic Investigation of Water Oxidation with “Co–Pi”-Coated Hematite Electrodes
journal, September 2012
- Klahr, Benjamin; Gimenez, Sixto; Fabregat-Santiago, Francisco
- Journal of the American Chemical Society, Vol. 134, Issue 40
Enhanced Surface Reaction Kinetics and Charge Separation of p–n Heterojunction Co 3 O 4 /BiVO 4 Photoanodes
journal, June 2015
- Chang, Xiaoxia; Wang, Tuo; Zhang, Peng
- Journal of the American Chemical Society, Vol. 137, Issue 26
Enzyme-Catalyzed Oxidation of 5-Hydroxymethylfurfural to Furan-2,5-dicarboxylic Acid
journal, May 2014
- Dijkman, Willem P.; Groothuis, Daphne E.; Fraaije, Marco W.
- Angewandte Chemie, Vol. 126, Issue 25
How Important is the Back Reaction of Electrons via the Substrate in Dye-Sensitized Nanocrystalline Solar Cells?
journal, January 2005
- Cameron, Petra J.; Peter, Laurence M.; Hore, Sarmimala
- The Journal of Physical Chemistry B, Vol. 109, Issue 2
Nanoporous BiVO4 Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting
journal, February 2014
- Kim, Tae Woo; Choi, Kyoung-Shin
- Science, Vol. 343, Issue 6174, p. 990-994
Ultrathin FeOOH Nanolayers with Abundant Oxygen Vacancies on BiVO 4 Photoanodes for Efficient Water Oxidation
journal, February 2018
- Zhang, Beibei; Wang, Lei; Zhang, Yajun
- Angewandte Chemie, Vol. 130, Issue 8
Artificial Photosynthesis for Sustainable Fuel and Chemical Production
journal, January 2015
- Kim, Dohyung; Sakimoto, Kelsey K.; Hong, Dachao
- Angewandte Chemie International Edition, Vol. 54, Issue 11
Simultaneous H 2 Generation and Biomass Upgrading in Water by an Efficient Noble-Metal-Free Bifunctional Electrocatalyst
journal, July 2016
- You, Bo; Jiang, Nan; Liu, Xuan
- Angewandte Chemie, Vol. 128, Issue 34
Efficient and Stable Photo-Oxidation of Water by a Bismuth Vanadate Photoanode Coupled with an Iron Oxyhydroxide Oxygen Evolution Catalyst
journal, January 2012
- Seabold, Jason A.; Choi, Kyoung-Shin
- Journal of the American Chemical Society, Vol. 134, Issue 4, p. 2186-2192
Solar Water Splitting Cells
journal, November 2010
- Walter, Michael G.; Warren, Emily L.; McKone, James R.
- Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
Photoinduced Absorption Spectroscopy of CoPi on BiVO 4 : The Function of CoPi during Water Oxidation
journal, May 2016
- Ma, Yimeng; Kafizas, Andreas; Pendlebury, Stephanie R.
- Advanced Functional Materials, Vol. 26, Issue 27
Development of Bismuth-Modified PtPd Nanocatalysts for the Electrochemical Reforming of Polyols into Hydrogen and Value-Added Chemicals
journal, August 2016
- González-Cobos, Jésus; Baranton, Stève; Coutanceau, Christophe
- ChemElectroChem, Vol. 3, Issue 10
Photocurrent of BiVO 4 is limited by surface recombination, not surface catalysis
journal, January 2017
- Zachäus, Carolin; Abdi, Fatwa F.; Peter, Laurence M.
- Chemical Science, Vol. 8, Issue 5
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+
journal, August 2008
- Kanan, M. W.; Nocera, D. G.
- Science, Vol. 321, Issue 5892, p. 1072-1075
Catalytic dehydration of C 6 carbohydrates for the production of hydroxymethylfurfural (HMF) as a versatile platform chemical
journal, January 2014
- Wang, Tianfu; Nolte, Michael W.; Shanks, Brent H.
- Green Chem., Vol. 16, Issue 2
Selective Oxidation of 1,2-Propanediol in Alkaline Anion-Exchange Membrane Electrocatalytic Flow Reactors: Experimental and DFT Investigations
journal, October 2015
- Chadderdon, David J.; Xin, Le; Qi, Ji
- ACS Catalysis, Vol. 5, Issue 11
A new electrochemical synthesis route for a BiOI electrode and its conversion to a highly efficient porous BiVO4 photoanode for solar water oxidation
journal, January 2012
- McDonald, Kenneth J.; Choi, Kyoung-Shin
- Energy & Environmental Science, Vol. 5, Issue 9, p. 8553-8557
Towards Solar Fuels from Water and CO 2
journal, February 2010
- Centi, Gabriele; Perathoner, Siglinda
- ChemSusChem, Vol. 3, Issue 2
Electronic Structure of Monoclinic BiVO 4
journal, September 2014
- Cooper, Jason K.; Gul, Sheraz; Toma, Francesca M.
- Chemistry of Materials, Vol. 26, Issue 18
Efficient BiVO 4 Thin Film Photoanodes Modified with Cobalt Phosphate Catalyst and W-doping
journal, November 2012
- Abdi, Fatwa F.; Firet, Nienke; van de Krol, Roel
- ChemCatChem, Vol. 5, Issue 2
Kinetic analysis of photoelectrochemical water oxidation by mesostructured Co-Pi/α-Fe 2 O 3 photoanodes
journal, January 2016
- Carroll, Gerard M.; Gamelin, Daniel R.
- Journal of Materials Chemistry A, Vol. 4, Issue 8
Photoelectrochemical oxidation of organic substrates in organic media
journal, August 2017
- Li, Tengfei; Kasahara, Takahito; He, Jingfu
- Nature Communications, Vol. 8, Issue 1
Dynamics of photogenerated holes in undoped BiVO 4 photoanodes for solar water oxidation
journal, January 2014
- Ma, Yimeng; Pendlebury, Stephanie R.; Reynal, Anna
- Chem. Sci., Vol. 5, Issue 8