Osmotically assisted reverse osmosis for high salinity brine treatment
Abstract
Here, this work evaluates a novel osmotically assisted reverse osmosis (OARO) process for dewatering high salinity brines using readily available membranes and equipment. While traditional reverse osmosis processes are limited to treating brines with osmotic pressures below the membrane burst pressure, in OARO, the osmotic pressure difference across a membrane is reduced with a permeate side saline sweep. A series of OARO stages can be used to sequentially reduce the concentration of the feed until a traditional RO process can obtain fully desalinated water. This paper develops an OARO model to identify feasible operating conditions for this process and to estimate the water recovery and energy consumption across a range of brine feed concentrations. For a feed of 100–140 g/L sodium chloride, we estimate that the OARO process is capable of a 35–50% water recovery with an energy consumption of 6–19 kWh per m3 of product water. Finally, the results suggest that an OARO dewatering process improves upon the recovery of reverse osmosis for high salinity brines and has a comparable or lower energy consumption than mechanical vapor compression.
- Authors:
-
- Carnegie Mellon Univ., Pittsburgh, PA (United States). Department of Civil and Environmental Engineering; National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)
- Carnegie Mellon Univ., Pittsburgh, PA (United States). Department of Civil and Environmental Engineering
- National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)
- Carnegie Mellon Univ., Pittsburgh, PA (United States). Department of Civil and Environmental Engineering and Department of Engineering and Public Policy
- Publication Date:
- Research Org.:
- National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE); USDOE Office of Fossil Energy and Carbon Management (FECM)
- OSTI Identifier:
- 1479651
- Alternate Identifier(s):
- OSTI ID: 1550527
- Grant/Contract Number:
- CBET-1554117; CBET-1215845
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Desalination
- Additional Journal Information:
- Journal Volume: 421; Journal Issue: C; Journal ID: ISSN 0011-9164
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Bartholomew, Timothy V., Mey, Laura, Arena, Jason T., Siefert, Nicholas S., and Mauter, Meagan S. Osmotically assisted reverse osmosis for high salinity brine treatment. United States: N. p., 2017.
Web. doi:10.1016/j.desal.2017.04.012.
Bartholomew, Timothy V., Mey, Laura, Arena, Jason T., Siefert, Nicholas S., & Mauter, Meagan S. Osmotically assisted reverse osmosis for high salinity brine treatment. United States. https://doi.org/10.1016/j.desal.2017.04.012
Bartholomew, Timothy V., Mey, Laura, Arena, Jason T., Siefert, Nicholas S., and Mauter, Meagan S. Sat .
"Osmotically assisted reverse osmosis for high salinity brine treatment". United States. https://doi.org/10.1016/j.desal.2017.04.012. https://www.osti.gov/servlets/purl/1479651.
@article{osti_1479651,
title = {Osmotically assisted reverse osmosis for high salinity brine treatment},
author = {Bartholomew, Timothy V. and Mey, Laura and Arena, Jason T. and Siefert, Nicholas S. and Mauter, Meagan S.},
abstractNote = {Here, this work evaluates a novel osmotically assisted reverse osmosis (OARO) process for dewatering high salinity brines using readily available membranes and equipment. While traditional reverse osmosis processes are limited to treating brines with osmotic pressures below the membrane burst pressure, in OARO, the osmotic pressure difference across a membrane is reduced with a permeate side saline sweep. A series of OARO stages can be used to sequentially reduce the concentration of the feed until a traditional RO process can obtain fully desalinated water. This paper develops an OARO model to identify feasible operating conditions for this process and to estimate the water recovery and energy consumption across a range of brine feed concentrations. For a feed of 100–140 g/L sodium chloride, we estimate that the OARO process is capable of a 35–50% water recovery with an energy consumption of 6–19 kWh per m3 of product water. Finally, the results suggest that an OARO dewatering process improves upon the recovery of reverse osmosis for high salinity brines and has a comparable or lower energy consumption than mechanical vapor compression.},
doi = {10.1016/j.desal.2017.04.012},
journal = {Desalination},
number = C,
volume = 421,
place = {United States},
year = {Sat Apr 29 00:00:00 EDT 2017},
month = {Sat Apr 29 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Desalination and Reuse of High-Salinity Shale Gas Produced Water: Drivers, Technologies, and Future Directions
journal, August 2013
- Shaffer, Devin L.; Arias Chavez, Laura H.; Ben-Sasson, Moshe
- Environmental Science & Technology, Vol. 47, Issue 17
Assessment of desalination technologies for treatment of a highly saline brine from a potential CO2 storage site
journal, February 2017
- Kaplan, Ruth; Mamrosh, Darryl; Salih, Hafiz H.
- Desalination, Vol. 404
Management and dewatering of brines extracted from geologic carbon storage sites
journal, August 2017
- Arena, Jason T.; Jain, Jinesh C.; Lopano, Christina L.
- International Journal of Greenhouse Gas Control, Vol. 63
Developments in thermal desalination processes: Design, energy, and costing aspects
journal, August 2007
- Al-Sahali, Mohammad; Ettouney, Hisham
- Desalination, Vol. 214, Issue 1-3
Membrane distillation: A comprehensive review
journal, February 2012
- Alkhudhiri, Abdullah; Darwish, Naif; Hilal, Nidal
- Desalination, Vol. 287
Energy consumption in desalinating produced water from shale oil and gas extraction
journal, June 2015
- Thiel, Gregory P.; Tow, Emily W.; Banchik, Leonardo D.
- Desalination, Vol. 366
State-of-the-art of reverse osmosis desalination
journal, October 2007
- Fritzmann, C.; Löwenberg, J.; Wintgens, T.
- Desalination, Vol. 216, Issue 1-3
Forward osmosis: Principles, applications, and recent developments
journal, September 2006
- Cath, T.; Childress, A.; Elimelech, M.
- Journal of Membrane Science, Vol. 281, Issue 1-2
Effect of hydraulic pressure and membrane orientation on water flux and reverse solute flux in pressure assisted osmosis
journal, September 2014
- Oh, Yoontaek; Lee, Sangho; Elimelech, Menachem
- Journal of Membrane Science, Vol. 465
Pressure retarded osmosis: From the vision of Sidney Loeb to the first prototype installation — Review
journal, October 2010
- Achilli, Andrea; Childress, Amy E.
- Desalination, Vol. 261, Issue 3
The Future of Seawater Desalination: Energy, Technology, and the Environment
journal, August 2011
- Elimelech, M.; Phillip, W. A.
- Science, Vol. 333, Issue 6043
Membrane assisted crystallization using reverse osmosis: Influence of solubility characteristics on experimental application and energy saving potential
journal, May 2010
- Lakerveld, Richard; Kuhn, Jelan; Kramer, Herman J. M.
- Chemical Engineering Science, Vol. 65, Issue 9
Effect of porous support fabric on osmosis through a Loeb-Sourirajan type asymmetric membrane
journal, July 1997
- Loeb, S.
- Journal of Membrane Science, Vol. 129, Issue 2
Influence of concentrative and dilutive internal concentration polarization on flux behavior in forward osmosis
journal, November 2006
- McCutcheon, Jeffrey R.; Elimelech, Menachem
- Journal of Membrane Science, Vol. 284, Issue 1-2
Selection of inorganic-based draw solutions for forward osmosis applications
journal, November 2010
- Achilli, Andrea; Cath, Tzahi Y.; Childress, Amy E.
- Journal of Membrane Science, Vol. 364, Issue 1-2
Isotonic Solutions. I. The Chemical Potential of Water in Aqueous Solutions of Sodium Chloride, Potassium Chloride, Sulfuric Acid, Sucrose, Urea and Glycerol at 25° 1
journal, December 1938
- Scatchard, George; Hamer, W. J.; Wood, S. E.
- Journal of the American Chemical Society, Vol. 60, Issue 12
Osmotic power production from salinity gradient resource by pressure retarded osmosis: Effects of operating conditions and reverse solute diffusion
journal, May 2012
- She, Qianhong; Jin, Xue; Tang, Chuyang Y.
- Journal of Membrane Science, Vol. 401-402
Colloidal fouling of reverse osmosis membranes
journal, November 1986
- Cohen, R. D.; Probstein, R. F.
- Journal of Colloid and Interface Science, Vol. 114, Issue 1
Modeling concentration polarization in reverse osmosis processes
journal, December 2005
- Kim, Suhan; Hoek, Eric M. V.
- Desalination, Vol. 186, Issue 1-3
Desalination by ammonia–carbon dioxide forward osmosis: Influence of draw and feed solution concentrations on process performance
journal, July 2006
- McCutcheon, Jeffrey R.; McGinnis, Robert L.; Elimelech, Menachem
- Journal of Membrane Science, Vol. 278, Issue 1-2
Modified models to predict flux behavior in forward osmosis in consideration of external and internal concentration polarizations
journal, October 2008
- Tan, Chien Hsiang; Ng, How Yong
- Journal of Membrane Science, Vol. 324, Issue 1-2
Novel spacer design improves observed flux
journal, February 2004
- Schwinge, J.; Wiley, D. E.; Fane, A. G.
- Journal of Membrane Science, Vol. 229, Issue 1-2
Hydrodynamics of sinusoidal spacers for improved reverse osmosis performance
journal, March 2014
- Xie, Peng; Murdoch, Lawrence C.; Ladner, David A.
- Journal of Membrane Science, Vol. 453
The Merck Index: 12th edition 1996
journal, April 1997
- Maynard, R. L.
- Occupational and Environmental Medicine, Vol. 54, Issue 4
Relating performance of thin-film composite forward osmosis membranes to support layer formation and structure
journal, February 2011
- Tiraferri, Alberto; Yip, Ngai Yin; Phillip, William A.
- Journal of Membrane Science, Vol. 367, Issue 1-2
Impact of temperature on power density in closed-loop pressure retarded osmosis for grid storage
journal, April 2015
- Anastasio, Daniel D.; Arena, Jason T.; Cole, Emily A.
- Journal of Membrane Science, Vol. 479
Effects of Transmembrane Hydraulic Pressure on Performance of Forward Osmosis Membranes
journal, February 2013
- Coday, Bryan D.; Heil, Dean M.; Xu, Pei
- Environmental Science & Technology, Vol. 47, Issue 5
Mechanical vapour compression to treat oil field produced water
journal, September 1994
- Koren, A.; Nadav, N.
- Desalination, Vol. 98, Issue 1-3
Works referencing / citing this record:
Effect of Short-Term Contact with C1–C4 Monohydric Alcohols on the Water Permeance of MPD-TMC Thin-Film Composite Reverse Osmosis Membranes
journal, July 2019
- Idarraga-Mora, Jaime A.; Lemelin, Michael A.; Weinman, Steven T.
- Membranes, Vol. 9, Issue 8
Effect of Short-Term Contact with C1–C4 Monohydric Alcohols on the Water Permeance of MPD-TMC Thin-Film Composite Reverse Osmosis Membranes
journal, July 2019
- Idarraga-Mora, Jaime A.; Lemelin, Michael A.; Weinman, Steven T.
- Membranes, Vol. 9, Issue 8