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Title: Disentangling the 1MLCT transition of [Ru(bpy)3]2+ by Stark absorption spectroscopy

Authors:
; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1549856
Grant/Contract Number:  
SC 0001035
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Photochemistry and Photobiology. A, Chemistry
Additional Journal Information:
Journal Name: Journal of Photochemistry and Photobiology. A, Chemistry Journal Volume: 353 Journal Issue: C; Journal ID: ISSN 1010-6030
Publisher:
Elsevier
Country of Publication:
Switzerland
Language:
English

Citation Formats

Kawamoto, Keisuke, Tamiya, Yudai, Storr, Tim, Cogdell, Richard J., Kinoshita, Isamu, and Hashimoto, Hideki. Disentangling the 1MLCT transition of [Ru(bpy)3]2+ by Stark absorption spectroscopy. Switzerland: N. p., 2018. Web. doi:10.1016/j.jphotochem.2017.08.025.
Kawamoto, Keisuke, Tamiya, Yudai, Storr, Tim, Cogdell, Richard J., Kinoshita, Isamu, & Hashimoto, Hideki. Disentangling the 1MLCT transition of [Ru(bpy)3]2+ by Stark absorption spectroscopy. Switzerland. https://doi.org/10.1016/j.jphotochem.2017.08.025
Kawamoto, Keisuke, Tamiya, Yudai, Storr, Tim, Cogdell, Richard J., Kinoshita, Isamu, and Hashimoto, Hideki. Thu . "Disentangling the 1MLCT transition of [Ru(bpy)3]2+ by Stark absorption spectroscopy". Switzerland. https://doi.org/10.1016/j.jphotochem.2017.08.025.
@article{osti_1549856,
title = {Disentangling the 1MLCT transition of [Ru(bpy)3]2+ by Stark absorption spectroscopy},
author = {Kawamoto, Keisuke and Tamiya, Yudai and Storr, Tim and Cogdell, Richard J. and Kinoshita, Isamu and Hashimoto, Hideki},
abstractNote = {},
doi = {10.1016/j.jphotochem.2017.08.025},
journal = {Journal of Photochemistry and Photobiology. A, Chemistry},
number = C,
volume = 353,
place = {Switzerland},
year = {2018},
month = {2}
}

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Works referenced in this record:

Electron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture)
journal, August 1993

  • Marcus, Rudolph A.
  • Angewandte Chemie International Edition in English, Vol. 32, Issue 8
  • DOI: 10.1002/anie.199311113

Concerning the absorption spectra of the ions M(bpy)32+ (M = Fe, Ru, Os; bpy = 2,2'-bipyridine)
journal, November 1982

  • Kober, Edward M.; Meyer, Thomas J.
  • Inorganic Chemistry, Vol. 21, Issue 11
  • DOI: 10.1021/ic00141a021

An electronic structural model for the emitting MLCT excited states of Ru(bpy)32+ and Os(bpy)32+
journal, November 1984

  • Kober, Edward M.; Meyer, Thomas J.
  • Inorganic Chemistry, Vol. 23, Issue 24
  • DOI: 10.1021/ic00192a009

Origin of transition dipole-moment polarizability and hyperpolarizability in hydrazones
journal, March 2003


Stark effect spectra of Ru(diimine)32+ complexes
journal, February 1989

  • Oh, Dennis H.; Boxer, Steven G.
  • Journal of the American Chemical Society, Vol. 111, Issue 3
  • DOI: 10.1021/ja00185a054

Electroabsorption (Stark effect) spectroscopy of mono- and biruthenium charge-transfer complexes: measurements of changes in dipole moments and other electrooptic properties
journal, August 1991

  • Oh, Dennis H.; Sano, Mitsuru; Boxer, Steven G.
  • Journal of the American Chemical Society, Vol. 113, Issue 18
  • DOI: 10.1021/ja00018a026

A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films
journal, October 1991

  • O'Regan, Brian; Grätzel, Michael
  • Nature, Vol. 353, Issue 6346, p. 737-740
  • DOI: 10.1038/353737a0

Charge-transfer spectra of iron(II)- and ruthenium(II)-tris(2,2'-bipyridyl) complexes
journal, May 1981

  • Ceulemans, A.; Vanquickenborne, L. G.
  • Journal of the American Chemical Society, Vol. 103, Issue 9
  • DOI: 10.1021/ja00399a017

Electrochromism in the near-infrared absorption spectra of bridged ruthenium mixed-valence complexes
journal, October 1990

  • Oh, Dennis H.; Boxer, Steven G.
  • Journal of the American Chemical Society, Vol. 112, Issue 22
  • DOI: 10.1021/ja00178a047

STARK SPECTROSCOPY: Applications in Chemistry, Biology, and Materials Science
journal, October 1997


Femtosecond Dynamics of Excited-State Evolution in [Ru(bpy)3]2+
journal, January 1997


Excited state dipole moments and polarizabilities of centrosymmetric and dimeric molecules. II. Polyenes, polyynes and cumulenes
journal, March 1988


Parameters Affecting Electron Injection Dynamics from Ruthenium Dyes to Titanium Dioxide Nanocrystalline Thin Film
journal, July 2003

  • Asbury, John B.; Anderson, Neil A.; Hao, Encai
  • The Journal of Physical Chemistry B, Vol. 107, Issue 30
  • DOI: 10.1021/jp034148r

[Ru(bpy)3]2+* and other remarkable metal-to-ligand charge transfer (MLCT) excited states
journal, June 2013

  • Thompson, David W.; Ito, Akitaka; Meyer, Thomas J.
  • Pure and Applied Chemistry, Vol. 85, Issue 7
  • DOI: 10.1351/PAC-CON-13-03-04

Rationalizing the molecular origins of Ru- and Fe-based dyes for dye-sensitized solar cells
journal, March 2012

  • Low, Kian Sing; Cole, Jacqueline M.; Zhou, Xiaolan
  • Acta Crystallographica Section B Structural Science, Vol. 68, Issue 2
  • DOI: 10.1107/S0108768112009263

Three-Dimensional Nonlinear Optical Chromophores Based on Metal-to-Ligand Charge-Transfer from Ruthenium(II) or Iron(II) Centers
journal, September 2005

  • Coe, Benjamin J.; Harris, James A.; Brunschwig, Bruce S.
  • Journal of the American Chemical Society, Vol. 127, Issue 38
  • DOI: 10.1021/ja053879x

Broadband Femtosecond Fluorescence Spectroscopy of [Ru(bpy)3]2+
journal, May 2006

  • Cannizzo, Andrea; van Mourik, Frank; Gawelda, Wojciech
  • Angewandte Chemie International Edition, Vol. 45, Issue 19
  • DOI: 10.1002/anie.200600125

Quantum efficiencies on transition metal complexes. II. Charge-transfer luminescence
journal, June 1971

  • Crosby, G. A.; Demas, J. N.
  • Journal of the American Chemical Society, Vol. 93, Issue 12
  • DOI: 10.1021/ja00741a003

Rationale for Kinetic Heterogeneity of Ultrafast Light-Induced Electron Transfer from Ru(II) Complex Sensitizers to Nanocrystalline TiO 2
journal, September 2005

  • Wenger, Bernard; Grätzel, Michael; Moser, Jacques-E.
  • Journal of the American Chemical Society, Vol. 127, Issue 35
  • DOI: 10.1021/ja042141x

Influence of Ancillary Ligands in Dye-Sensitized Solar Cells
journal, August 2016


The electronic spectrum of tris(2,2'-bipyridine)ruthenium(2+)
journal, June 1980

  • Felix, Franz; Ferguson, James; Guedel, Hans U.
  • Journal of the American Chemical Society, Vol. 102, Issue 12
  • DOI: 10.1021/ja00532a019

Structures and non-linear optical properties of polar carotenoid analogues
journal, January 1999

  • Hashimoto, Hideki; Nakashima, T.; Hattori, Kingo
  • Pure and Applied Chemistry, Vol. 71, Issue 12
  • DOI: 10.1351/pac199971122225