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Title: Hydrodeoxygenation of γ-valerolactone on bimetallic NiMo phosphide catalysts

Authors:
; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1549701
Grant/Contract Number:  
26289301; FG02-96ER14669
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Catalysis
Additional Journal Information:
Journal Name: Journal of Catalysis Journal Volume: 353 Journal Issue: C; Journal ID: ISSN 0021-9517
Publisher:
Elsevier
Country of Publication:
United States
Language:
English

Citation Formats

Yun, Gwang-Nam, Ahn, So-Jin, Takagaki, Atsushi, Kikuchi, Ryuji, and Oyama, S. Ted. Hydrodeoxygenation of γ-valerolactone on bimetallic NiMo phosphide catalysts. United States: N. p., 2017. Web. doi:10.1016/j.jcat.2017.07.006.
Yun, Gwang-Nam, Ahn, So-Jin, Takagaki, Atsushi, Kikuchi, Ryuji, & Oyama, S. Ted. Hydrodeoxygenation of γ-valerolactone on bimetallic NiMo phosphide catalysts. United States. https://doi.org/10.1016/j.jcat.2017.07.006
Yun, Gwang-Nam, Ahn, So-Jin, Takagaki, Atsushi, Kikuchi, Ryuji, and Oyama, S. Ted. Fri . "Hydrodeoxygenation of γ-valerolactone on bimetallic NiMo phosphide catalysts". United States. https://doi.org/10.1016/j.jcat.2017.07.006.
@article{osti_1549701,
title = {Hydrodeoxygenation of γ-valerolactone on bimetallic NiMo phosphide catalysts},
author = {Yun, Gwang-Nam and Ahn, So-Jin and Takagaki, Atsushi and Kikuchi, Ryuji and Oyama, S. Ted},
abstractNote = {},
doi = {10.1016/j.jcat.2017.07.006},
journal = {Journal of Catalysis},
number = C,
volume = 353,
place = {United States},
year = {Fri Sep 01 00:00:00 EDT 2017},
month = {Fri Sep 01 00:00:00 EDT 2017}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1016/j.jcat.2017.07.006

Citation Metrics:
Cited by: 25 works
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Works referenced in this record:

The Influence of the Support on the Formation of Ni 2 P Based Catalysts by a New Synthetic Approach. Study of the Catalytic Activity in the Hydrodesulfurization of Dibenzothiophene
journal, September 2009

  • Cecilia, J. A.; Infantes-Molina, A.; Rodríguez-Castellón, E.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 39
  • DOI: 10.1021/jp904263c

Structure cristalline de NiMoP
journal, September 1977

  • Guérin, R.; Sergent, M.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 33, Issue 9
  • DOI: 10.1107/S0567740877009546

Synthesis and Hydrodeoxygenation Properties of Ruthenium Phosphide Catalysts
journal, July 2011

  • Bowker, Richard H.; Smith, Mica C.; Pease, Melissa L.
  • ACS Catalysis, Vol. 1, Issue 8
  • DOI: 10.1021/cs200238v

Investigation of the Reaction Network of Benzofuran Hydrodeoxygenation over Sulfided and Reduced Ni–Mo/Al2O3 Catalysts
journal, March 2002


The active site of nickel phosphide catalysts for the hydrodesulfurization of 4,6-DMDBT
journal, September 2008


Molecular Orbital View of Chemisorbed Carbon Monoxide
journal, October 1964

  • Blyholder, George
  • The Journal of Physical Chemistry, Vol. 68, Issue 10
  • DOI: 10.1021/j100792a006

NiMoS HDS catalysts – The effect of the Ti and Zr incorporation into the silica support and of the catalyst preparation methodology on the orientation and activity of the formed MoS2 slabs
journal, November 2016

  • da Silva Neto, Alano Viera; Leite, Edson Roberto; da Silva, Victor Teixeira
  • Applied Catalysis A: General, Vol. 528
  • DOI: 10.1016/j.apcata.2016.09.019

Deoxygenation of methyl laurate to hydrocarbons on silica-supported Ni-Mo phosphides: Effect of calcination temperatures of precursor
journal, January 2015


Mössbauer studies of solid solution systems of Fe(P, As), (Fe, Co)P, (Fe, Mn)P and (Fe, W)P
journal, April 1973


Deep HDS of FCC gasoline over alumina supported CoMoS catalyst: Inhibiting effects of carbon monoxide and water
journal, April 2016


Bifunctional nature of a SiO2-supported Ni2P catalyst for hydrotreating: EXAFS and FTIR studies
journal, April 2006


The hydrodeoxygenation of bioderived furans into alkanes
journal, April 2013

  • Sutton, Andrew D.; Waldie, Fraser D.; Wu, Ruilian
  • Nature Chemistry, Vol. 5, Issue 5, p. 428-432
  • DOI: 10.1038/nchem.1609

Metal Phosphides: Preparation, Characterization and Catalytic Reactivity
journal, November 2012


Hydrodeoxygenation of Anisole over Silica-Supported Ni 2 P, MoP, and NiMoP Catalysts
journal, March 2011

  • Li, Kelun; Wang, Rijie; Chen, Jixiang
  • Energy & Fuels, Vol. 25, Issue 3
  • DOI: 10.1021/ef101258j

Dispersion effects of Ni2P catalysts on hydrotreating of light cycle oil
journal, May 2014


Characterization and Activity of Unsupported Ni-Mo Sulfide Catalysts in HDN/HDS Reactions
journal, July 1994

  • Ozkan, Umit S.; Zhang, Liping; Ni, Shuangyao
  • Energy & Fuels, Vol. 8, Issue 4
  • DOI: 10.1021/ef00046a003

Upgrading of pyrolysis bio-oil using nickel phosphide catalysts
journal, January 2016


Epoxidation of propylene with H2 and O2 in the explosive regime in a packed-bed catalytic membrane reactor
journal, July 2008


Hydrodeoxygenation of guaiacol as model compound for pyrolysis oil on transition metal phosphide hydroprocessing catalysts
journal, January 2011


Mössbauer spectroscopy investigation and hydrodesulfurization properties of iron–nickel phosphide catalysts
journal, May 2010

  • Gaudette, Amy F.; Burns, Autumn W.; Hayes, John R.
  • Journal of Catalysis, Vol. 272, Issue 1, p. 18-27
  • DOI: 10.1016/j.jcat.2010.03.016

Alternative catalytic materials: carbides, nitrides, phosphides and amorphous boron alloys
journal, January 2010

  • Alexander, Anne-Marie; Hargreaves, Justin S. J.
  • Chemical Society Reviews, Vol. 39, Issue 11
  • DOI: 10.1039/b916787k

Highly selective bimetallic FeMoP catalyst for C–O bond cleavage of aryl ethers
journal, September 2013


Dibenzothiophene hydrodesulfurization activity and surface sites of silica-supported MoP, Ni2P, and NiMoP catalysts
journal, December 2004


Fractionation of Bio-Oil
journal, August 2014

  • Lindfors, Christian; Kuoppala, Eeva; Oasmaa, Anja
  • Energy & Fuels, Vol. 28, Issue 9
  • DOI: 10.1021/ef500754d

Physical and Chemical Properties of MoP, Ni 2 P, and MoNiP Hydrodesulfurization Catalysts:  Time-Resolved X-ray Diffraction, Density Functional, and Hydrodesulfurization Activity Studies
journal, July 2003

  • Rodriguez, José A.; Kim, Jae-Yong; Hanson, Jonathan C.
  • The Journal of Physical Chemistry B, Vol. 107, Issue 26
  • DOI: 10.1021/jp022639q

Mössbauer studies of FeNiP and related compounds
journal, June 1973


X-Ray Investigations of Mn3P, Mn2P, and Ni2P.
journal, January 1962


Effects of the Support on the Performance and Promotion of (Ni)MoS 2 Catalysts for Simultaneous Hydrodenitrogenation and Hydrodesulfurization
journal, April 2014

  • Gutiérrez, Oliver Y.; Singh, Srujan; Schachtl, Eva
  • ACS Catalysis, Vol. 4, Issue 5
  • DOI: 10.1021/cs500034d

First-principles calculations and thermodynamic modeling of the Ni–Mo system
journal, April 2005


Preparation of Unsupported NiMoP Catalysts for 4,6-Dimethyldibenzothiophene Hydrodesulfurization
journal, June 2014


Kinetic studies of hydrodeoxygenation of 2-methyltetrahydrofuran on a Ni2P/SiO2 catalyst at medium pressure
journal, March 2014


Infrared Spectroscopic Investigation of CO Adsorption on Silica-Supported Nickel Phosphide Catalysts
journal, July 2004

  • Layman, Kathryn A.; Bussell, Mark E.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 30
  • DOI: 10.1021/jp037101e

Recent Advances in Hydrotreating of Pyrolysis Bio-Oil and Its Oxygen-Containing Model Compounds
journal, April 2013

  • Wang, Huamin; Male, Jonathan; Wang, Yong
  • ACS Catalysis, Vol. 3, Issue 5
  • DOI: 10.1021/cs400069z

Kinetic and FTIR studies of 2-methyltetrahydrofuran hydrodeoxygenation on Ni2P/SiO2
journal, October 2014


Experimental and Theoretical Insights into the Hydrogen-Efficient Direct Hydrodeoxygenation Mechanism of Phenol over Ru/TiO 2
journal, October 2015


Steric Effect and Evolution of Surface Species in the Hydrodeoxygenation of Bio-Oil Model Compounds over Pt/HBEA
journal, January 2016


Hydrodeoxygenation of gamma-valerolactone on transition metal phosphide catalysts
journal, January 2017

  • Yun, Gwang-Nam; Takagaki, Atsushi; Kikuchi, Ryuji
  • Catalysis Science & Technology, Vol. 7, Issue 1
  • DOI: 10.1039/C6CY02252A

Synthesis and Structure of Bimetallic Nickel Molybdenum Phosphide Solid Solutions
journal, July 2004

  • Ma, Ding; Xiao, Tiancun; Xie, Songhai
  • Chemistry of Materials, Vol. 16, Issue 14
  • DOI: 10.1021/cm035233e

Synthesis and Activity of a New Catalyst for Hydroprocessing: Tungsten Phosphide
journal, May 2001


Effect of hydrogen sulphide on the hydrodeoxygenation of aromatic and aliphatic oxygenates on sulphided catalysts
journal, November 2007

  • Şenol, O. İ.; Ryymin, E. -M.; Viljava, T. -R.
  • Journal of Molecular Catalysis A: Chemical, Vol. 277, Issue 1-2
  • DOI: 10.1016/j.molcata.2007.07.033

Synthesis and hydrodeoxygenation activity of Ni2P/C – Effect of the palladium salt on lowering the nickel phosphide synthesis temperature
journal, August 2016


Ligand and Ensemble Effects in Bimetallic NiFe Phosphide Catalysts for the Hydrodeoxygenation of 2-Methyltetrahydrofuran
journal, September 2012


Microkinetic analysis of ring opening and decarboxylation of γ-valerolactone over silica alumina
journal, December 2016

  • Bond, Jesse Q.; Jungong, Christian S.; Chatzidimitriou, Anargyros
  • Journal of Catalysis, Vol. 344
  • DOI: 10.1016/j.jcat.2016.10.021

On the surface sites of MoP/SiO2 catalyst under sulfiding conditions: IR spectroscopy and catalytic reactivity studies
journal, February 2004


X-Ray Studies of Molybdenum and Tungsten Phosphides.
journal, January 1963


Synthesis and characterization of silica-supported transition-metal phosphides as HDN catalysts
journal, October 2003


Transition metal phosphide hydroprocessing catalysts: A review
journal, May 2009