On the structure of monohalomercury(II) complexes in dimethylsulfoxide, pyridine and N,N-dimetylthioformamide solution

doi:10.1016/j.poly.2017.09.045

Title: On the structure of monohalomercury(II) complexes in dimethylsulfoxide, pyridine and N,N-dimetylthioformamide solution

Full Record
Other Related Research

Authors:: Persson, Ingmar

Publication Date:: 2018-01-01

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

OSTI Identifier:: 1549495

Grant/Contract Number:: AC02-76SF00515

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Polyhedron

Additional Journal Information:: Journal Name: Polyhedron Journal Volume: 139 Journal Issue: C; Journal ID: ISSN 0277-5387

Publisher:: Elsevier

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Persson, Ingmar. On the structure of monohalomercury(II) complexes in dimethylsulfoxide, pyridine and N,N-dimetylthioformamide solution.  United Kingdom: N. p., 2018. 
        Web.  doi:10.1016/j.poly.2017.09.045.

Copy to clipboard


                    Persson, Ingmar. On the structure of monohalomercury(II) complexes in dimethylsulfoxide, pyridine and N,N-dimetylthioformamide solution.  United Kingdom.  doi:10.1016/j.poly.2017.09.045.

Copy to clipboard


                    Persson, Ingmar. Mon .  
        "On the structure of monohalomercury(II) complexes in dimethylsulfoxide, pyridine and N,N-dimetylthioformamide solution".  United Kingdom.  doi:10.1016/j.poly.2017.09.045.

Copy to clipboard


                    
@article{osti_1549495,

  title        = {On the structure of monohalomercury(II) complexes in dimethylsulfoxide, pyridine and N,N-dimetylthioformamide solution},

  author       = {Persson, Ingmar},

  abstractNote = {},

  doi          = {10.1016/j.poly.2017.09.045},

  journal      = {Polyhedron},

  number       = C,

  volume       = 139,

  place        = {United Kingdom},

  year         = {2018},

  month        = {1}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: 10.1016/j.poly.2017.09.045

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

A Structural study of the hydrated and the dimethylsulfoxide,N,N-dimethylpropyleneurea, acetonitrile, pyridine,N,N-dimethylthioformamide solvated nickel(II) ion insolution and solid state

Journal Article Kristiansson, O - Inorganica Chimica Acta

No abstract prepared.
DOI: 10.1016/S0020-1693(02)01322-1
On the structure of the N,N'-dimethylpropyleneurea and dimethylsulfoxide solvated gallium(III) and indium(III) ions and bromide complexes in solution and solid state, and the complex formation of the gallium(III) and indium(III) bromide systems in N,N'-dimethylpropyleneurea

Journal Article Topel, O. ; Persson, I. ; Lundberg, D. ; ... - Inorg. Chim. Acta 363:988,2010
A Structural Study of the Hydrated And the Dimethylsulfoxide, N,N'-Dimethylpropyleneurea, And N,N-Dimethylthioformamide Solvated Iron(Ii) And Iron(Iii) Ions in Solution And Solid State

Journal Article Lundberg, D ; Ullstrom, A -S ; D'Angelo, P ; ... - Inorg. Chim. Acta 360:1809,2007

No abstract prepared.
DOI: 10.1016/j.ica.2006.09.014
Structure of a Hydrated Sulfonatotitanyl(IV) Complex in Aqueous Solution and the Dimethylsulfoxide Solvated Titanyl(IV) Ion in Solution and Solid State

Journal Article Lundberg, Daniel ; Persson, Ingmar - Journal of Solution Chemistry

The coordination chemistry of oxotitanium(IV) or titanyl(IV), TiO²⁺, has been studied in solution by X-ray methods. The titanyl(IV) ion hydrolyzes easily in aqueous systems to solid titanium dioxide as long as it is not stabilized through complexation. In this study the structures of the hydrated bissulfatotitanyl(IV) complex and the dimethylsulfoxide (DMSO) solvated titanyl(IV) ions have been determined. In isolated monomeric titanyl complexes titanium(IV) binds strongly to a doubly bound oxo group at ca. 1.64 Å, to four ligands in the equatorial plane almost perpendicular to the Ti=O bond at ca. 2.02 Å, and there is one weakly bound ligand, transmore »« less
Cited by 2
DOI: 10.1007/s10953-017-0581-3

Full Text Available
Crystal structure and physical properties of a ruthenium(II) bipyridine dimethylsulfoxide complex

Journal Article Wang, Y ; Eichhorn, D M ; Goswami, N ; ... - Journal of Chemical Crystallography

The complex [Ru(bpy){sub 2}(DMSO)C1]PF{sub 6}, where bpy is 2,2{prime}-bipyridine and DMSO is dimethyl-sulfoxide, crystallizes in the triclinic space group P{bar 1} ({number{underscore}sign}2) with a = 8.873 (2), b = 12.805 (4), c = 12.864 (4) {angstrom}, {alpha} = 97.76(3), {beta} = 106.45(2), {gamma} = 107.88(2); Z = 2, and d{sub calc} = 1.75 mg/m{sup 3}. The coordination geometry is that of a distorted octahedron with a cis-RuN{sub 4}SCl arrangement of coordinating atoms. The four Ru-N distances to the bpy ligands are 2.082(5), 2.092(4), 2.044(4), and 2.078(5) {angstrom}. The Ru-Cl distance is 2.421(2) {angstrom} and the Ru-S distance to DMSO ismore »« less
DOI: 10.1023/A:1009513616056

Similar Records