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Title: Heat capacity and thermodynamic functions of crystalline and amorphous forms of the metal organic framework zinc 2-ethylimidazolate, Zn(EtIm)2

Authors:
; ; ; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1549469
Grant/Contract Number:  
SC0016446; SC0016573
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Chemical Thermodynamics
Additional Journal Information:
Journal Name: Journal of Chemical Thermodynamics Journal Volume: 116 Journal Issue: C; Journal ID: ISSN 0021-9614
Publisher:
Elsevier
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Calvin, Jason J., Asplund, Megan, Akimbekov, Zamirbek, Ayoub, Ghada, Katsenis, Athanasios D., Navrotsky, Alexandra, Friščić, Tomislav, and Woodfield, Brian F. Heat capacity and thermodynamic functions of crystalline and amorphous forms of the metal organic framework zinc 2-ethylimidazolate, Zn(EtIm)2. United Kingdom: N. p., 2018. Web. doi:10.1016/j.jct.2017.10.002.
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Calvin, Jason J., Asplund, Megan, Akimbekov, Zamirbek, Ayoub, Ghada, Katsenis, Athanasios D., Navrotsky, Alexandra, Friščić, Tomislav, & Woodfield, Brian F. Heat capacity and thermodynamic functions of crystalline and amorphous forms of the metal organic framework zinc 2-ethylimidazolate, Zn(EtIm)2. United Kingdom. https://doi.org/10.1016/j.jct.2017.10.002
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Calvin, Jason J., Asplund, Megan, Akimbekov, Zamirbek, Ayoub, Ghada, Katsenis, Athanasios D., Navrotsky, Alexandra, Friščić, Tomislav, and Woodfield, Brian F. Mon . "Heat capacity and thermodynamic functions of crystalline and amorphous forms of the metal organic framework zinc 2-ethylimidazolate, Zn(EtIm)2". United Kingdom. https://doi.org/10.1016/j.jct.2017.10.002.
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@article{osti_1549469,
title = {Heat capacity and thermodynamic functions of crystalline and amorphous forms of the metal organic framework zinc 2-ethylimidazolate, Zn(EtIm)2},
author = {Calvin, Jason J. and Asplund, Megan and Akimbekov, Zamirbek and Ayoub, Ghada and Katsenis, Athanasios D. and Navrotsky, Alexandra and Friščić, Tomislav and Woodfield, Brian F.},
abstractNote = {},
doi = {10.1016/j.jct.2017.10.002},
journal = {Journal of Chemical Thermodynamics},
number = C,
volume = 116,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}
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Free Publicly Available Full Text
Accepted Manuscript (Publisher)
Publisher's Version of Record
https://doi.org/10.1016/j.jct.2017.10.002
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Works referenced in this record:

Zeolite-like metal–organic frameworks (ZMOFs): design, synthesis, and properties
journal, January 2015

  • Eddaoudi, Mohamed; Sava, Dorina F.; Eubank, Jarrod F.
  • Chemical Society Reviews, Vol. 44, Issue 1
  • DOI: 10.1039/C4CS00230J

Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001

  • Eddaoudi, Mohamed; Moler, David B.; Li, Hailian
  • Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330
  • DOI: 10.1021/ar000034b

Recognition of 1,3-Butadiene by a Porous Coordination Polymer
journal, October 2016

  • Kishida, Keisuke; Okumura, Yoshikuni; Watanabe, Yoshihiro
  • Angewandte Chemie International Edition, Vol. 55, Issue 44
  • DOI: 10.1002/anie.201607676

Experimental and Theoretical Evaluation of the Stability of True MOF Polymorphs Explains Their Mechanochemical Interconversions
journal, June 2017

  • Akimbekov, Zamirbek; Katsenis, Athanassios D.; Nagabhushana, G. P.
  • Journal of the American Chemical Society, Vol. 139, Issue 23
  • DOI: 10.1021/jacs.7b03144

Synthesis and characterization of isostructural cadmium zeolitic imidazolate frameworks via solvent-assisted linker exchange
journal, January 2012

  • Karagiaridi, Olga; Bury, Wojciech; Sarjeant, Amy A.
  • Chemical Science, Vol. 3, Issue 11, p. 3256-3260
  • DOI: 10.1039/c2sc20558k

Tunable Rare-Earth fcu-MOFs: A Platform for Systematic Enhancement of CO2 Adsorption Energetics and Uptake
journal, May 2013

  • Xue, Dong-Xu; Cairns, Amy J.; Belmabkhout, Youssef
  • Journal of the American Chemical Society, Vol. 135, Issue 20, p. 7660-7667
  • DOI: 10.1021/ja401429x

Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
journal, March 2012

Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber
journal, January 2017

An improved technique for accurate heat capacity measurements on powdered samples using a commercial relaxation calorimeter
journal, August 2011

  • Shi, Quan; Boerio-Goates, Juliana; Woodfield, Brian F.
  • The Journal of Chemical Thermodynamics, Vol. 43, Issue 8
  • DOI: 10.1016/j.jct.2011.03.018

Exceptional Hydrophobicity of a Large-Pore Metal–Organic Zeolite
journal, May 2015

  • He, Chun-Ting; Jiang, Lu; Ye, Zi-Ming
  • Journal of the American Chemical Society, Vol. 137, Issue 22
  • DOI: 10.1021/jacs.5b03727

Techno-economic Analysis of Metal–Organic Frameworks for Hydrogen and Natural Gas Storage
journal, January 2017

Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials
journal, August 2010

  • Farha, Omar K.; Hupp, Joseph T.
  • Accounts of Chemical Research, Vol. 43, Issue 8, p. 1166-1175
  • DOI: 10.1021/ar1000617

Controlling guest conformation for efficient purification of butadiene
journal, June 2017

Mechanochemical dry conversion of zinc oxide to zeolitic imidazolate framework
journal, January 2013

  • Tanaka, Shunsuke; Kida, Koji; Nagaoka, Takuya
  • Chemical Communications, Vol. 49, Issue 72
  • DOI: 10.1039/c3cc43028f

Framework-Topology-Dependent Catalytic Activity of Zirconium-Based (Porphinato)zinc(II) MOFs
journal, October 2016

  • Deria, Pravas; Gómez-Gualdrón, Diego A.; Hod, Idan
  • Journal of the American Chemical Society, Vol. 138, Issue 43
  • DOI: 10.1021/jacs.6b09113

Thermochemical study of the stability of frameworks in high silica zeolites
journal, December 1993

  • Petrovic, Ivan; Navrotsky, Alexandra; Davis, Mark E.
  • Chemistry of Materials, Vol. 5, Issue 12
  • DOI: 10.1021/cm00036a019

Zeolitic Imidazolate Framework- Enabled Membranes: Challenges and Opportunities
journal, September 2015

Little Thermodynamic Penalty for the Synthesis of Ultraporous Metal Organic Frameworks
journal, January 2016

Mineral neogenesis as an inspiration for mild, solvent-free synthesis of bulk microporous metal–organic frameworks from metal (Zn, Co) oxides
journal, January 2013

  • Mottillo, Cristina; Lu, Yuneng; Pham, Minh-Hao
  • Green Chemistry, Vol. 15, Issue 8
  • DOI: 10.1039/c3gc40520f

Template-directed synthesis of metal–organic materials
journal, January 2014

  • Zhang, Zhenjie; Zaworotko, Michael J.
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00075G

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006

  • Park, K. S.; Ni, Z.; Cote, A. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
  • DOI: 10.1073/pnas.0602439103

Accurate heat capacity measurements on powdered samples using a Quantum Design physical property measurement system
journal, September 2010

  • Shi, Quan; Snow, Claine L.; Boerio-Goates, Juliana
  • The Journal of Chemical Thermodynamics, Vol. 42, Issue 9
  • DOI: 10.1016/j.jct.2010.04.008

Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels
journal, May 2013

Water-resistant porous coordination polymers for gas separation
journal, February 2017

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
journal, January 2010

  • Phan, Anh; Doonan, Christian J.; Uribe-Romo, Fernando J.
  • Accounts of Chemical Research, Vol. 43, Issue 1, p. 58-67
  • DOI: 10.1021/ar900116g

Accelerated aging: a low energy, solvent-free alternative to solvothermal and mechanochemical synthesis of metal–organic materials
journal, January 2012

  • Cliffe, Matthew J.; Mottillo, Cristina; Stein, Robin S.
  • Chemical Science, Vol. 3, Issue 8
  • DOI: 10.1039/c2sc20344h

In situ X-ray diffraction monitoring of a mechanochemical reaction reveals a unique topology metal-organic framework
journal, March 2015

  • Katsenis, Athanassios D.; Puškarić, Andreas; Štrukil, Vjekoslav
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7662

Entropy of Pure-Silica Molecular Sieves
journal, June 2001

  • Piccione, Patrick M.; Woodfield, Brian F.; Boerio-Goates, Juliana
  • The Journal of Physical Chemistry B, Vol. 105, Issue 25
  • DOI: 10.1021/jp010491p

Development of a Debye heat capacity model for vibrational modes with a gap in the density of states
journal, June 2015

Seven Post-synthetic Covalent Reactions in Tandem Leading to Enzyme-like Complexity within Metal–Organic Framework Crystals
journal, June 2016

  • Fracaroli, Alejandro M.; Siman, Peter; Nagib, David A.
  • Journal of the American Chemical Society, Vol. 138, Issue 27
  • DOI: 10.1021/jacs.6b04204

Thermodynamics of solvent interaction with the metal–organic framework MOF-5
journal, January 2016

  • Akimbekov, Zamirbek; Wu, Di; Brozek, Carl K.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 2
  • DOI: 10.1039/C5CP05370F

Catalytic aromatization of methane
journal, January 2014

  • Spivey, James J.; Hutchings, Graham
  • Chem. Soc. Rev., Vol. 43, Issue 3
  • DOI: 10.1039/C3CS60259A

Metal-Organic Framework as a Template for Porous Carbon Synthesis
journal, April 2008

  • Liu, Bo; Shioyama, Hiroshi; Akita, Tomoki
  • Journal of the American Chemical Society, Vol. 130, Issue 16
  • DOI: 10.1021/ja7106146

Reticular Chemistry—Construction, Properties, and Precision Reactions of Frameworks
journal, November 2016

  • Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 138, Issue 48
  • DOI: 10.1021/jacs.6b11821

Solution mediated phase transformation (RHO to SOD) in porous Co-imidazolate based zeolitic frameworks with high water stability
journal, January 2012

  • Biswal, Bishnu P.; Panda, Tamas; Banerjee, Rahul
  • Chemical Communications, Vol. 48, Issue 97
  • DOI: 10.1039/c2cc36651g

Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
journal, September 2011

  • Zhang, Jie-Peng; Zhang, Yue-Biao; Lin, Jian-Bin
  • Chemical Reviews, Vol. 112, Issue 2
  • DOI: 10.1021/cr200139g

Mechanochemistry: opportunities for new and cleaner synthesis
journal, January 2012

  • James, Stuart L.; Adams, Christopher J.; Bolm, Carsten
  • Chem. Soc. Rev., Vol. 41, Issue 1
  • DOI: 10.1039/C1CS15171A

Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry
journal, November 2010

  • Beldon, Patrick J.; Fábián, László; Stein, Robin S.
  • Angewandte Chemie International Edition, Vol. 49, Issue 50
  • DOI: 10.1002/anie.201005547

Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs
journal, May 2008

  • Wang, Bo; Côté, Adrien P.; Furukawa, Hiroyasu
  • Nature, Vol. 453, Issue 7192, p. 207-211
  • DOI: 10.1038/nature06900

Non-, Micro-, and Mesoporous Metal−Organic Framework Isomers: Reversible Transformation, Fluorescence Sensing, and Large Molecule Separation
journal, April 2010

  • Jiang, Hai-Long; Tatsu, Yoshiro; Lu, Zhang-Hui
  • Journal of the American Chemical Society, Vol. 132, Issue 16
  • DOI: 10.1021/ja101541s

Efficient purification of ethene by an ethane-trapping metal-organic framework
journal, October 2015

  • Liao, Pei-Qin; Zhang, Wei-Xiong; Zhang, Jie-Peng
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9697

Thermochemistry of Zeolitic Imidazolate Frameworks of Varying Porosity
journal, December 2012

  • Hughes, James T.; Bennett, Thomas D.; Cheetham, Anthony K.
  • Journal of the American Chemical Society, Vol. 135, Issue 2
  • DOI: 10.1021/ja311237m

Extra adsorption and adsorbate superlattice formation in metal-organic frameworks
journal, November 2015

  • Sung Cho, Hae; Deng, Hexiang; Miyasaka, Keiichi
  • Nature, Vol. 527, Issue 7579
  • DOI: 10.1038/nature15734

Enforcing Ostwald's rule of stages: Isolation of paracetamol forms III and II
journal, August 2007

  • Burley, Jonathan C.; Duer, Melinda J.; Stein, Robin S.
  • European Journal of Pharmaceutical Sciences, Vol. 31, Issue 5
  • DOI: 10.1016/j.ejps.2007.04.002

Synthesis and Gas Sorption Properties of a Metal-Azolium Framework (MAF) Material
journal, November 2009

  • Lee, Jeong Yong; Roberts, John M.; Farha, Omar K.
  • Inorganic Chemistry, Vol. 48, Issue 21, p. 9971-9973
  • DOI: 10.1021/ic901174p

Metal–organic frameworks meet scalable and sustainable synthesis
journal, January 2017

  • Julien, Patrick A.; Mottillo, Cristina; Friščić, Tomislav
  • Green Chemistry, Vol. 19, Issue 12
  • DOI: 10.1039/C7GC01078H

Urea Metal–Organic Frameworks as Effective and Size-Selective Hydrogen-Bond Catalysts
journal, February 2012

  • Roberts, John M.; Fini, Branden M.; Sarjeant, Amy A.
  • Journal of the American Chemical Society, Vol. 134, Issue 7
  • DOI: 10.1021/ja2108118

High Methane Storage Working Capacity in Metal–Organic Frameworks with Acrylate Links
journal, August 2016

  • Jiang, Juncong; Furukawa, Hiroyasu; Zhang, Yue-Biao
  • Journal of the American Chemical Society, Vol. 138, Issue 32
  • DOI: 10.1021/jacs.6b05261

The Silica-Like Extended Polymorphism of Cobalt(II) Imidazolate Three-Dimensional Frameworks: X-ray Single-Crystal Structures and Magnetic Properties
journal, November 2003

  • Tian, Yun-Qi; Cai, Chen-Xin; Ren, Xiao-Ming
  • Chemistry - A European Journal, Vol. 9, Issue 22
  • DOI: 10.1002/chem.200304957

Real-time and in situ monitoring of mechanochemical milling reactions
journal, December 2012

  • Friščić, Tomislav; Halasz, Ivan; Beldon, Patrick J.
  • Nature Chemistry, Vol. 5, Issue 1
  • DOI: 10.1038/nchem.1505

Metal–Organic Frameworks as Platforms for Functional Materials
journal, February 2016

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