DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Charge Heterogeneity and Surface Chemistry in Polycrystalline Cathode Materials

Journal Article · · Joule

Not Available

Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC02-05CH11231; AC02-76SF00515
OSTI ID:
1548833
Alternate ID(s):
OSTI ID: 1601173
Journal Information:
Joule, Journal Name: Joule Journal Issue: 3 Vol. 2; ISSN 2542-4351
Publisher:
Elsevier - Cell PressCopyright Statement
Country of Publication:
United States
Language:
English

References (42)

Applications of Hard X‐ray Full‐Field Transmission X‐ray Microscopy at SSRL conference January 2011
Proton Insertion into Oxide Cathodes during Chemical Delithiation journal January 2006
Development of Microstrain in Aged Lithium Transition Metal Oxides journal June 2014
Colorimetric Determination of Lithium Content in Electrodes of Lithium-Ion Batteries journal January 2008
Evaluation of the effective reaction zone in a composite cathode for lithium ion batteries journal September 2014
Direct Observation of a Metastable Crystal Phase of Li x FePO 4 under Electrochemical Phase Transition journal April 2013
Elucidation of the surface characteristics and electrochemistry of high-performance LiNiO 2 journal January 2016
Direct in situ measurements of Li transport in Li-ion battery negative electrodes journal January 2010
Study of the LiFePO 4 /FePO 4 Two-Phase System by High-Resolution Electron Energy Loss Spectroscopy journal November 2006
Structural and Electrochemical Investigation of Li(Ni[sub 0.4]Co[sub 0.15]Al[sub 0.05]Mn[sub 0.4])O[sub 2] Cathode Material journal January 2010
Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries journal January 2014
Spectroscopic X-ray Diffraction for Microfocus Inspection of Li-Ion Batteries journal August 2014
Continuity and performance in composite electrodes journal August 2010
Investigation of the Charge Compensation Mechanism on the Electrochemically Li-Ion Deintercalated Li 1 - x Co 1/3 Ni 1/3 Mn 1/3 O 2 Electrode System by Combination of Soft and Hard X-ray Absorption Spectroscopy journal December 2005
A review of Ni-based layered oxides for rechargeable Li-ion batteries journal January 2017
TXM-Wizard : a program for advanced data collection and evaluation in full-field transmission X-ray microscopy journal January 2012
Key electronic states in lithium battery materials probed by soft X-ray spectroscopy journal October 2013
A method for normalization of X-ray absorption spectra journal June 2005
Visualization of Inhomogeneous Reaction Distribution in the Model LiCoO 2 Composite Electrode of Lithium Ion Batteries journal January 2017
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries journal March 2014
Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles journal August 2016
Phase retrieval using polychromatic illumination for transmission X-ray microscopy journal January 2011
High-Rate Charging Induced Intermediate Phases and Structural Changes of Layer-Structured Cathode for Lithium-Ion Batteries journal August 2016
A Combined Computational/Experimental Study on LiNi 1/3 Co 1/3 Mn 1/3 O 2 journal September 2003
Local State-of-Charge Mapping of Lithium-Ion Battery Electrodes journal July 2011
Differences between L3 and L2 X-ray absorption spectra journal March 1995
In situ Visualization of State-of-Charge Heterogeneity within a LiCoO 2 Particle that Evolves upon Cycling at Different Rates journal April 2017
Three Dimensional Simulation of Galvanostatic Discharge of LiCoO 2 Cathode Based on X-ray Nano-CT Images journal January 2012
Soft x-ray spectroscopy for probing electronic and chemical states of battery materials journal January 2016
In situ x-ray absorption spectroscopic study of the Li[Ni1∕3Co1∕3Mn1∕3]O2 cathode material journal June 2005
Intercalation Pathway in Many-Particle LiFePO 4 Electrode Revealed by Nanoscale State-of-Charge Mapping journal February 2013
Reprint of “Studies of local degradation phenomena in composite cathodes for lithium-ion batteries” journal December 2007
A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries journal January 2017
In Situ X-Ray Absorption Study of a Layered Manganese-Chromium Oxide-Based Cathode Material journal January 2002
Visualization of Charge Distribution in a Lithium Battery Electrode journal June 2010
Investigation of the Local Structure of the LiNi[sub 0.5]Mn[sub 0.5]O[sub 2] Cathode Material during Electrochemical Cycling by X-Ray Absorption and NMR Spectroscopy journal January 2002
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal June 2005
Visualization of the State-of-Charge Distribution in a LiCoO 2 Cathode by In Situ Raman Imaging journal January 2013
Persistent State-of-Charge Heterogeneity in Relaxed, Partially Charged Li 1− x Ni 1/3 Co 1/3 Mn 1/3 O 2 Secondary Particles journal May 2016
Three-dimensional imaging of chemical phase transformations at the nanoscale with full-field transmission X-ray microscopy journal July 2011
Phase transformation mechanism in lithium manganese nickel oxide revealed by single-crystal hard X-ray microscopy journal February 2017
Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes journal September 2014