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Title: Stabilization of a High-Capacity and High-Power Nickel-Based Cathode for Li-Ion Batteries

Authors:
; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1548830
Alternate Identifier(s):
OSTI ID: 1461443; OSTI ID: 1496486
Grant/Contract Number:  
AC0-206CH11357; AC02-06CH11357
Resource Type:
Published Article
Journal Name:
Chem
Additional Journal Information:
Journal Name: Chem Journal Volume: 4 Journal Issue: 4; Journal ID: ISSN 2451-9294
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; high capacity; high power; nickel-based cathode; Li-ion battery; electrical vehicle

Citation Formats

Zeng, Xiaoqiao, Zhan, Chun, Lu, Jun, and Amine, Khalil. Stabilization of a High-Capacity and High-Power Nickel-Based Cathode for Li-Ion Batteries. United States: N. p., 2018. Web. doi:10.1016/j.chempr.2017.12.027.
Zeng, Xiaoqiao, Zhan, Chun, Lu, Jun, & Amine, Khalil. Stabilization of a High-Capacity and High-Power Nickel-Based Cathode for Li-Ion Batteries. United States. doi:10.1016/j.chempr.2017.12.027.
Zeng, Xiaoqiao, Zhan, Chun, Lu, Jun, and Amine, Khalil. Sun . "Stabilization of a High-Capacity and High-Power Nickel-Based Cathode for Li-Ion Batteries". United States. doi:10.1016/j.chempr.2017.12.027.
@article{osti_1548830,
title = {Stabilization of a High-Capacity and High-Power Nickel-Based Cathode for Li-Ion Batteries},
author = {Zeng, Xiaoqiao and Zhan, Chun and Lu, Jun and Amine, Khalil},
abstractNote = {},
doi = {10.1016/j.chempr.2017.12.027},
journal = {Chem},
number = 4,
volume = 4,
place = {United States},
year = {2018},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1016/j.chempr.2017.12.027

Citation Metrics:
Cited by: 36 works
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Figures / Tables:

Figure 1 Figure 1: Lattice structure and activation barrier of lithium transition metal oxide (a) The structure of Li(Ni0.5Mn0.5)O2 consists of layers of transition metal (Ni and Mn) separated from Li layers by oxygen. In materials made by a conventional high-temperature synthesis, partial exchange of Li and Ni ions is always observed,more » which contracts the space through which Li can move. (b) Li moves from one octahedral site to another by passing through an intermediate tetrahedral site where it encounters strong repulsion from a nearby transition-metal cation. The table shows the activation barrier for Li motion for various transition metals near the activated state. Values were calculated by GGA density functional theory for various chemistries and Li contents.9 (Adopted with permission; Copyright ©Science 2006)« less

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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.