Self-supported branched poly(ethyleneimine) materials for CO 2 adsorption from simulated flue gas

Yoo, Chun-Jae; Narayanan, Pavithra; Jones, Christopher W.

doi:10.1039/C9TA04662C

Title: Self-supported branched poly(ethyleneimine) materials for CO ₂ adsorption from simulated flue gas

Abstract

A family of self-supported, cross-linked PEI materials is demonstrated as promising CO ₂ adsorbents, displaying (i) good CO ₂ capacity (ii) rapid uptake kinetics, and (iii) good stability relative to conventional supported amine adsorbents.

Authors:

^[1]; Narayanan, Pavithra ^[1];

^[1]

School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, Atlanta, USA

Publication Date:: 2019-08-20

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1548795

Grant/Contract Number:: SC0012577

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Materials Chemistry. A

Additional Journal Information:: Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 33; Journal ID: ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Yoo, Chun-Jae, Narayanan, Pavithra, and Jones, Christopher W. Self-supported branched poly(ethyleneimine) materials for CO 2 adsorption from simulated flue gas.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9TA04662C.

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                    Yoo, Chun-Jae, Narayanan, Pavithra, & Jones, Christopher W. Self-supported branched poly(ethyleneimine) materials for CO 2 adsorption from simulated flue gas.  United Kingdom.  https://doi.org/10.1039/C9TA04662C

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                    Yoo, Chun-Jae, Narayanan, Pavithra, and Jones, Christopher W. Tue .  
"Self-supported branched poly(ethyleneimine) materials for CO 2 adsorption from simulated flue gas".  United Kingdom.  https://doi.org/10.1039/C9TA04662C.

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@article{osti_1548795,

  title        = {Self-supported branched poly(ethyleneimine) materials for CO 2 adsorption from simulated flue gas},

  author       = {Yoo, Chun-Jae and Narayanan, Pavithra and Jones, Christopher W.},

  abstractNote = {A family of self-supported, cross-linked PEI materials is demonstrated as promising CO 2 adsorbents, displaying (i) good CO 2 capacity (ii) rapid uptake kinetics, and (iii) good stability relative to conventional supported amine adsorbents.},

  doi          = {10.1039/C9TA04662C},

  journal      = {Journal of Materials Chemistry. A},

  number       = 33,

  volume       = 7,

  place        = {United Kingdom},

  year         = {2019},

  month        = {8}

}

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Aminopolymers confined within mesoporous supports have shown promise as materials for direct capture of CO₂ from ambient air. In spite of this, relatively little is known about the energetics of CO2 binding in these materials, and the limited calorimetric studies published to date have focused on materials made using molecular aminosilanes rather than amine polymers. In this work, poly(ethylenimine) (PEI) is impregnated within mesoporous SBA-15, and the heats of CO₂ adsorption at 30 °C are investigated using a Tian-Calvet calorimeter with emphasis on the role of PEI loading and CO₂ pressure in the compositional region relevant to direct capture ofmore »« less
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https://doi.org/10.1021/acs.langmuir.6b03793

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Title: Self-supported branched poly(ethyleneimine) materials for CO 2 adsorption from simulated flue gas

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Omniphilic Polymeric Sponges by Ice Templating journal, February 2016

Post-Combustion CO2 Capture Using Solid Sorbents: A Review journal, September 2011

Preparation and characterization of novel CO2 “molecular basket” adsorbents based on polymer-modified mesoporous molecular sieve MCM-41 journal, August 2003

Preparation of Three-Dimensional Graphene Oxide–Polyethylenimine Porous Materials as Dye and Gas Adsorbents journal, September 2013

Aminopropyl-functionalized mesoporous silicas as CO2 adsorbents journal, October 2005

The “Missing” Bicarbonate in CO 2 Chemisorption Reactions on Solid Amine Sorbents journal, June 2018

Poly(ethylenimine)-Functionalized Monolithic Alumina Honeycomb Adsorbents for CO 2 Capture from Air journal, June 2016

Novel Polyethylenimine-Modified Mesoporous Molecular Sieve of MCM-41 Type as High-Capacity Adsorbent for CO2 Capture journal, November 2002

The Mechanism of CO 2 Adsorption under Dry and Humid Conditions in Mesoporous Silica-Supported Amine Sorbents journal, October 2016

Carbon nanotube/PVA aerogels impregnated with PEI: solid adsorbents for CO 2 capture journal, January 2018

Infrared Study of CO 2 Sorption over “Molecular Basket” Sorbent Consisting of Polyethylenimine-Modified Mesoporous Molecular Sieve journal, April 2009

Ice crystal morphology and growth rates at low supersaturations and high temperatures journal, May 1983

Composite Hydrogels with Tunable Anisotropic Morphologies and Mechanical Properties journal, May 2016

Preparation of a macroporous flexible three dimensional graphene sponge using an ice-template as the anode material for microbial fuel cells journal, January 2014

Polyethylenimine-Impregnated Mesoporous Silica: Effect of Amine Loading and Surface Alkyl Chains on CO 2 Adsorption journal, October 2011

Simple synthesis of nitrogen-rich polymer network and its further amination with PEI for CO2 adsorption journal, March 2018

Tuning the textural properties of HMS mesoporous silica. Functionalization towards CO 2 adsorption journal, April 2018

Direct CO 2 Capture from Air using Poly(ethylenimine)-Loaded Polymer/Silica Fiber Sorbents journal, February 2019

Facile preparation of cross-linked polyimide aerogels with carboxylic functionalization for CO 2 capture journal, August 2017

Microporous Functionalized Triazine-Based Polyimides with High CO 2 Capture Capacity journal, March 2013

Practical methods for measuring the tortuosity of porous materials from binary or gray-tone tomographic reconstructions journal, August 2009

Effects of freezing conditions on the morphology and mechanical properties of clay and polymer/clay aerogels journal, March 2013

Adsorption characteristics of carbon dioxide on organically functionalized SBA-15 journal, September 2005

A new biodegradable polymer: PEGylated chitosan-g-PEI possessing a hydroxyl group at the PEG end journal, November 2007

Investigation of structure formation during freeze-casting from very slow to very fast solidification velocities journal, August 2011

Amine-modified mesocellular silica foams for CO2 capture journal, April 2011

Polyethylenimine-Impregnated Resin for High CO 2 Adsorption: An Efficient Adsorbent for CO 2 Capture from Simulated Flue Gas and Ambient Air journal, July 2013

Imine-Linked Porous Polymer Frameworks with High Small Gas (H 2 , CO 2 , CH 4 , C 2 H 2 ) Uptake and CO 2 /N 2 Selectivity journal, April 2013

Direct Capture of CO2 from Ambient Air journal, August 2016

Probing Intramolecular versus Intermolecular CO 2 Adsorption on Amine-Grafted SBA-15 journal, November 2015

Role of Additives in Composite PEI/Oxide CO 2 Adsorbents: Enhancement in the Amine Efficiency of Supported PEI by PEG in CO 2 Capture from Simulated Ambient Air journal, November 2015

Carbon Dioxide Reaction Kinetics and Transport in Aqueous Amine Membranes journal, August 1980

CO2 adsorption on branched polyethyleneimine-impregnated mesoporous silica SBA-15 journal, June 2010

Adsorptive removal of carbon dioxide using polyethyleneimine-loaded mesoporous silica materials journal, August 2008

Oxidation‐Resistant, Cost‐Effective Epoxide‐Modified Polyamine Adsorbents for CO 2 Capture from Various Sources Including Air journal, April 2019

Effect of the Pore Length on CO 2 Adsorption over Amine-Modified Mesoporous Silicas journal, September 2011

CO2 adsorption on Santa Barbara Amorphous-15 (SBA-15) and amine-modified Santa Barbara Amorphous-15 (SBA-15) with and without controlled microporosity journal, January 2013

Mesoporous Alumina-Supported Amines as Potential Steam-Stable Adsorbents for Capturing CO 2 from Simulated Flue Gas and Ambient Air journal, November 2011

Thermal, Oxidative, and CO 2 -Induced Degradation of Supported Polyethylenimine Adsorbents journal, May 2012

High-Capacity and Low-Cost Carbon-Based “Molecular Basket” Sorbent for CO 2 Capture from Flue Gas journal, January 2011

Ice-templated porous alumina structures journal, April 2007

Bromine pre-functionalized porous polyphenylenes: New platforms for one-step grafting and applications in reversible CO2 capture journal, March 2019

Camphor sulfonic acid doped PPy/α-Fe 2 O 3 hybrid nanocomposites as NO 2 sensors journal, January 2014

FTIR Study of CO2 Adsorption on Amine-Grafted SBA-15: Elucidation of Adsorbed Species journal, May 2011

Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources journal, September 2009

Clover leaf-shaped Al2O3 extrudate as a support for high-capacity and cost-effective CO2 sorbent journal, September 2011

Amine-Based CO 2 Capture Technology Development from the Beginning of 2013—A Review journal, January 2015

Synthesis and Characterization of Polyethylene Glycol Mediated Silver Nanoparticles by the Green Method journal, May 2012

FT-IR characterization and hydrolysis of PLA-PEG-PLA based copolyester hydrogels with short PLA segments and a cytocompatibility study journal, September 2013

Amine-modified MCM-41 mesoporous silica for carbon dioxide capture journal, August 2011

CO 2 -Induced Degradation of Amine-Containing Adsorbents: Reaction Products and Pathways journal, August 2012

Amine-impregnated silica monolith with a hierarchical pore structure: enhancement of CO2 capture capacity journal, January 2009

Aligned two- and three-dimensional structures by directional freezing of polymers and nanoparticles journal, September 2005

Effect of Humidity on the CO 2 Adsorption of Tertiary Amine Grafted SBA-15 journal, October 2017

Amine-oxide hybrid materials for acid gas separations journal, January 2011

CO2 capture using mesoporous alumina prepared by a sol–gel process journal, January 2011

Capture of carbon dioxide by amine-impregnated as-synthesized MCM-41 journal, October 2010

Control of Lamellae Spacing During Freeze Casting of Ceramics Using Double-Side Cooling as a Novel Processing Route journal, January 2009

Carbon capture with polyethylenimine hydrogel beads (PEI HBs) journal, January 2018

Epoxide-functionalization of polyethyleneimine for synthesis of stable carbon dioxide adsorbent in temperature swing adsorption journal, August 2016

Elucidation of Surface Species through in Situ FTIR Spectroscopy of Carbon Dioxide Adsorption on Amine-Grafted SBA-15 journal, August 2016

Glycidyl Ether Reactions with Alcohols, Phenols, Carboxylic Acids, and Acid Anhydrides journal, January 1956

Glycidyl Ether Reactions with Amines journal, January 1956

Synthesis and CO 2 Capture Behavior of Porous Cross-Linked Polymers Containing Pendant Triazole Groups journal, August 2017

Amino functionalized mesostructured SBA-15 silica for CO2 capture: Exploring the relation between the adsorption capacity and the distribution of amino groups by TEM journal, August 2012

Amine-Based Nanofibrillated Cellulose As Adsorbent for CO 2 Capture from Air journal, October 2011

Fully organic CO2 absorbent obtained by a Schiff base reaction between branched poly(ethyleneimine) and glutaraldehyde journal, March 2018

Flue gas treatment via CO2 adsorption journal, July 2011

Kinetics of carbamate formation and breakdown journal, November 1968

Spectroscopic Investigation of the Mechanisms Responsible for the Superior Stability of Hybrid Class 1/Class 2 CO 2 Sorbents: A New Class 4 Category journal, May 2016

Carbon Dioxide Capture Adsorbents: Chemistry and Methods journal, March 2017

Novel Nitrogen and Sulfur Rich Hyper-Cross-Linked Microporous Poly-Triazine-Thiophene Copolymer for Superior CO 2 Capture journal, June 2016

Growth Rates and Habits of Ice Crystals between −20° and −70°C journal, March 2004

Title: Self-supported branched poly(ethyleneimine) materials for CO ₂ adsorption from simulated flue gas

Omniphilic Polymeric Sponges by Ice Templating
journal, February 2016

Post-Combustion CO₂ Capture Using Solid Sorbents: A Review
journal, September 2011

Preparation and characterization of novel CO2 “molecular basket” adsorbents based on polymer-modified mesoporous molecular sieve MCM-41
journal, August 2003

Preparation of Three-Dimensional Graphene Oxide–Polyethylenimine Porous Materials as Dye and Gas Adsorbents
journal, September 2013

Aminopropyl-functionalized mesoporous silicas as CO2 adsorbents
journal, October 2005

The “Missing” Bicarbonate in CO ₂ Chemisorption Reactions on Solid Amine Sorbents
journal, June 2018

Poly(ethylenimine)-Functionalized Monolithic Alumina Honeycomb Adsorbents for CO ₂ Capture from Air
journal, June 2016

Novel Polyethylenimine-Modified Mesoporous Molecular Sieve of MCM-41 Type as High-Capacity Adsorbent for CO₂ Capture
journal, November 2002

The Mechanism of CO ₂ Adsorption under Dry and Humid Conditions in Mesoporous Silica-Supported Amine Sorbents
journal, October 2016

Carbon nanotube/PVA aerogels impregnated with PEI: solid adsorbents for CO ₂ capture
journal, January 2018

Infrared Study of CO ₂ Sorption over “Molecular Basket” Sorbent Consisting of Polyethylenimine-Modified Mesoporous Molecular Sieve
journal, April 2009

Ice crystal morphology and growth rates at low supersaturations and high temperatures
journal, May 1983

Composite Hydrogels with Tunable Anisotropic Morphologies and Mechanical Properties
journal, May 2016

Preparation of a macroporous flexible three dimensional graphene sponge using an ice-template as the anode material for microbial fuel cells
journal, January 2014

Polyethylenimine-Impregnated Mesoporous Silica: Effect of Amine Loading and Surface Alkyl Chains on CO ₂ Adsorption
journal, October 2011

Simple synthesis of nitrogen-rich polymer network and its further amination with PEI for CO2 adsorption
journal, March 2018

Tuning the textural properties of HMS mesoporous silica. Functionalization towards CO 2 adsorption
journal, April 2018

Direct CO ₂ Capture from Air using Poly(ethylenimine)-Loaded Polymer/Silica Fiber Sorbents
journal, February 2019

Facile preparation of cross-linked polyimide aerogels with carboxylic functionalization for CO 2 capture
journal, August 2017

Microporous Functionalized Triazine-Based Polyimides with High CO ₂ Capture Capacity
journal, March 2013

Practical methods for measuring the tortuosity of porous materials from binary or gray-tone tomographic reconstructions
journal, August 2009

Effects of freezing conditions on the morphology and mechanical properties of clay and polymer/clay aerogels
journal, March 2013

Adsorption characteristics of carbon dioxide on organically functionalized SBA-15
journal, September 2005

A new biodegradable polymer: PEGylated chitosan-g-PEI possessing a hydroxyl group at the PEG end
journal, November 2007

Investigation of structure formation during freeze-casting from very slow to very fast solidification velocities
journal, August 2011

Amine-modified mesocellular silica foams for CO2 capture
journal, April 2011

Polyethylenimine-Impregnated Resin for High CO ₂ Adsorption: An Efficient Adsorbent for CO ₂ Capture from Simulated Flue Gas and Ambient Air
journal, July 2013

Imine-Linked Porous Polymer Frameworks with High Small Gas (H ₂ , CO ₂ , CH ₄ , C ₂ H ₂ ) Uptake and CO ₂ /N ₂ Selectivity
journal, April 2013

Direct Capture of CO₂ from Ambient Air
journal, August 2016

Probing Intramolecular versus Intermolecular CO ₂ Adsorption on Amine-Grafted SBA-15
journal, November 2015

Role of Additives in Composite PEI/Oxide CO ₂ Adsorbents: Enhancement in the Amine Efficiency of Supported PEI by PEG in CO ₂ Capture from Simulated Ambient Air
journal, November 2015

Carbon Dioxide Reaction Kinetics and Transport in Aqueous Amine Membranes
journal, August 1980

CO2 adsorption on branched polyethyleneimine-impregnated mesoporous silica SBA-15
journal, June 2010

Adsorptive removal of carbon dioxide using polyethyleneimine-loaded mesoporous silica materials
journal, August 2008

Oxidation‐Resistant, Cost‐Effective Epoxide‐Modified Polyamine Adsorbents for CO ₂ Capture from Various Sources Including Air
journal, April 2019

Effect of the Pore Length on CO ₂ Adsorption over Amine-Modified Mesoporous Silicas
journal, September 2011

CO2 adsorption on Santa Barbara Amorphous-15 (SBA-15) and amine-modified Santa Barbara Amorphous-15 (SBA-15) with and without controlled microporosity
journal, January 2013

Mesoporous Alumina-Supported Amines as Potential Steam-Stable Adsorbents for Capturing CO ₂ from Simulated Flue Gas and Ambient Air
journal, November 2011

Thermal, Oxidative, and CO ₂ -Induced Degradation of Supported Polyethylenimine Adsorbents
journal, May 2012

High-Capacity and Low-Cost Carbon-Based “Molecular Basket” Sorbent for CO ₂ Capture from Flue Gas
journal, January 2011

Ice-templated porous alumina structures
journal, April 2007

Bromine pre-functionalized porous polyphenylenes: New platforms for one-step grafting and applications in reversible CO2 capture
journal, March 2019

Camphor sulfonic acid doped PPy/α-Fe ₂ O ₃ hybrid nanocomposites as NO ₂ sensors
journal, January 2014

FTIR Study of CO₂ Adsorption on Amine-Grafted SBA-15: Elucidation of Adsorbed Species
journal, May 2011

Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources
journal, September 2009

Clover leaf-shaped Al2O3 extrudate as a support for high-capacity and cost-effective CO2 sorbent
journal, September 2011

Amine-Based CO ₂ Capture Technology Development from the Beginning of 2013—A Review
journal, January 2015

Synthesis and Characterization of Polyethylene Glycol Mediated Silver Nanoparticles by the Green Method
journal, May 2012

FT-IR characterization and hydrolysis of PLA-PEG-PLA based copolyester hydrogels with short PLA segments and a cytocompatibility study
journal, September 2013

Amine-modified MCM-41 mesoporous silica for carbon dioxide capture
journal, August 2011

CO ₂ -Induced Degradation of Amine-Containing Adsorbents: Reaction Products and Pathways
journal, August 2012

Amine-impregnated silica monolith with a hierarchical pore structure: enhancement of CO2 capture capacity
journal, January 2009

Aligned two- and three-dimensional structures by directional freezing of polymers and nanoparticles
journal, September 2005

Effect of Humidity on the CO ₂ Adsorption of Tertiary Amine Grafted SBA-15
journal, October 2017

Amine-oxide hybrid materials for acid gas separations
journal, January 2011

CO2 capture using mesoporous alumina prepared by a sol–gel process
journal, January 2011

Capture of carbon dioxide by amine-impregnated as-synthesized MCM-41
journal, October 2010

Control of Lamellae Spacing During Freeze Casting of Ceramics Using Double-Side Cooling as a Novel Processing Route
journal, January 2009

Carbon capture with polyethylenimine hydrogel beads (PEI HBs)
journal, January 2018

Epoxide-functionalization of polyethyleneimine for synthesis of stable carbon dioxide adsorbent in temperature swing adsorption
journal, August 2016

Elucidation of Surface Species through in Situ FTIR Spectroscopy of Carbon Dioxide Adsorption on Amine-Grafted SBA-15
journal, August 2016

Glycidyl Ether Reactions with Alcohols, Phenols, Carboxylic Acids, and Acid Anhydrides
journal, January 1956

Glycidyl Ether Reactions with Amines
journal, January 1956

Synthesis and CO ₂ Capture Behavior of Porous Cross-Linked Polymers Containing Pendant Triazole Groups
journal, August 2017

Amino functionalized mesostructured SBA-15 silica for CO2 capture: Exploring the relation between the adsorption capacity and the distribution of amino groups by TEM
journal, August 2012

Amine-Based Nanofibrillated Cellulose As Adsorbent for CO ₂ Capture from Air
journal, October 2011

Fully organic CO2 absorbent obtained by a Schiff base reaction between branched poly(ethyleneimine) and glutaraldehyde
journal, March 2018

Flue gas treatment via CO2 adsorption
journal, July 2011

Kinetics of carbamate formation and breakdown
journal, November 1968

Spectroscopic Investigation of the Mechanisms Responsible for the Superior Stability of Hybrid Class 1/Class 2 CO ₂ Sorbents: A New Class 4 Category
journal, May 2016

Carbon Dioxide Capture Adsorbents: Chemistry and Methods
journal, March 2017

Novel Nitrogen and Sulfur Rich Hyper-Cross-Linked Microporous Poly-Triazine-Thiophene Copolymer for Superior CO ₂ Capture
journal, June 2016

Growth Rates and Habits of Ice Crystals between −20° and −70°C
journal, March 2004