Adsorption and oxidation of 3-nitro-1,2,4-triazole-5-one (NTO) and its transformation product (3-amino-1,2,4-triazole-5-one, ATO) at ferrihydrite and birnessite surfaces

doi:10.1016/j.envpol.2018.04.034

Title: Adsorption and oxidation of 3-nitro-1,2,4-triazole-5-one (NTO) and its transformation product (3-amino-1,2,4-triazole-5-one, ATO) at ferrihydrite and birnessite surfaces

Full Record
Other Related Research

Authors:

;

; Sierra-Alvarez, Reyes;

;

Publication Date:: 2018-09-01

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1548217

Grant/Contract Number:: AC02-76SF00515

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Environmental Pollution

Additional Journal Information:: Journal Name: Environmental Pollution Journal Volume: 240 Journal Issue: C; Journal ID: ISSN 0269-7491

Publisher:: Elsevier

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Khatiwada, Raju, Abrell, Leif, Li, Guangbin, Root, Robert A., Sierra-Alvarez, Reyes, Field, James A., and Chorover, Jon. Adsorption and oxidation of 3-nitro-1,2,4-triazole-5-one (NTO) and its transformation product (3-amino-1,2,4-triazole-5-one, ATO) at ferrihydrite and birnessite surfaces.  United Kingdom: N. p., 2018. 
        Web.  doi:10.1016/j.envpol.2018.04.034.

Copy to clipboard


                    Khatiwada, Raju, Abrell, Leif, Li, Guangbin, Root, Robert A., Sierra-Alvarez, Reyes, Field, James A., & Chorover, Jon. Adsorption and oxidation of 3-nitro-1,2,4-triazole-5-one (NTO) and its transformation product (3-amino-1,2,4-triazole-5-one, ATO) at ferrihydrite and birnessite surfaces.  United Kingdom.  doi:10.1016/j.envpol.2018.04.034.

Copy to clipboard


                    Khatiwada, Raju, Abrell, Leif, Li, Guangbin, Root, Robert A., Sierra-Alvarez, Reyes, Field, James A., and Chorover, Jon. Sat .  
        "Adsorption and oxidation of 3-nitro-1,2,4-triazole-5-one (NTO) and its transformation product (3-amino-1,2,4-triazole-5-one, ATO) at ferrihydrite and birnessite surfaces".  United Kingdom.  doi:10.1016/j.envpol.2018.04.034.

Copy to clipboard


                    
@article{osti_1548217,

  title        = {Adsorption and oxidation of 3-nitro-1,2,4-triazole-5-one (NTO) and its transformation product (3-amino-1,2,4-triazole-5-one, ATO) at ferrihydrite and birnessite surfaces},

  author       = {Khatiwada, Raju and Abrell, Leif and Li, Guangbin and Root, Robert A. and Sierra-Alvarez, Reyes and Field, James A. and Chorover, Jon},

  abstractNote = {},

  doi          = {10.1016/j.envpol.2018.04.034},

  journal      = {Environmental Pollution},

  number       = C,

  volume       = 240,

  place        = {United Kingdom},

  year         = {2018},

  month        = {9}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: 10.1016/j.envpol.2018.04.034

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 1 work

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar records in OSTI.GOV collections:

NTO decomposition studies

Book Oxley, J.C. ; Smith, J.L. ; Yeager, K.E. ; ...

To examine the thermal decomposition of 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO) in detail, isotopic labeling studies were undertaken. NTO samples labeled with {sup 15}N in three different locations [N(1) and N(2), N(4), and N(6)] were prepared. Upon thermolysis, the majority of the NTO condensed-phase product was a brown, insoluble residue, but small quantities of 2,4-dihydro-3H-1,2,4-triazol-3-one (TO) and triazole were detected. Gases comprised the remainder of the NTO decomposition products. The analysis of these gases is reported along with mechanistic implications of these observations.
Thermal decomposition of energetic materials; 65: Conversion of insensitive explosives (NTO, ANTA) and related compounds to polymeric melon-like cyclic azine burn-rate suppressants

Journal Article Williams, G.K. ; Palopoli, S.F. ; Brill, T.B. - Combustion and Flame; (United States)

Selected triazole, tetrazole, triazine, tetrazine, furazan, and acyclic backbone compounds are shown by IR spectroscopy to convert to polymeric, melon-like, cyclic azine residues upon heating to T [ge] 500 C. These compounds include the insensitive explosives 3-nitro-1,2,4-triazol-5-one (NTO), 3-amino-5-nitro-1,2,4-triazole (ANTA), and nitroguanidine. The melon-like residue could suppress the burn rate if these compounds are formulated into solid rocket propellants. The IR-active gaseous products from thermolysis are determined as a function of pressure and are related to the atom connectivity in the parent molecules.
DOI: 10.1016/0010-2180(94)90235-6
Ethanol-metabolizing pathways in deermice. Estimation of flux calculated from isotope effects

Journal Article Alderman, J. ; Takagi, T. ; Lieber, C.S. - J. Biol. Chem.; (United States)

The apparent deuterium isotope effects on Vmax/Km (D(V/K) of ethanol oxidation in two deermouse strains (one having and one lacking hepatic alcohol dehydrogenase (ADH) were used to calculate flux through the ADH, microsomal ethanol-oxidizing system (MEOS), and catalase pathways. In vitro, D(V/K) values were 3.22 for ADH, 1.13 for MEOS, and 1.83 for catalase under physiological conditions of pH, temperature, and ionic strength. In vivo, in deermice lacking ADH (ADH-), D(V/K) was 1.20 +/- 0.09 (mean +/- S.E.) at 7.0 +/- 0.5 mM blood ethanol and 1.08 +/- 0.10 at 57.8 +/- 10.2 mM blood ethanol, consistent with ethanol oxidationmore »« less
Dimensional modulation and magnetic properties of triazole- and bis(triazole)-based copper(II) coordination polymers tuned by aromatic polycarboxylates

Journal Article Zhang, Ju-Wen ; Zhao, Wei ; Lu, Qi-Lin ; ... - Journal of Solid State Chemistry

Five new metal–organic coordination polymers ([Cu{sub 3}(μ{sub 2}-OH){sub 2}(atrz){sub 2}(nph){sub 2}(H{sub 2}O){sub 2}]·2H{sub 2}O){sub n} (1), ([Cu{sub 2}(μ{sub 3}-OH)(atrz)(1,2,4-btc)]·2H{sub 2}O){sub n} (2), ([Cu{sub 2}(μ{sub 3}-OH)(atrz)(1,2,4-btc)(H{sub 2}O)]·H{sub 2}O){sub n} (3), [Cu(dth){sub 0.5}(nph)(H{sub 2}O)]{sub n} (4) and [Cu(dth)(Hnip){sub 2}]{sub n} (5) [atrz=4-amino-1,2,4-triazole, dth=N,N'-di(4H-1,2,4-triazole)hexanamide, H{sub 2}nph=3-nitrophthalic acid, 1,2,4-H{sub 3}btc=1,2,4-benzenetricarboxylic acid and H{sub 2}nip=5-nitroisophthalic acid] were hydrothermally synthesized and structurally characterized. Polymer 1 shows a one-dimensional (1D) chain. Polymers 2 and 3 exhibit similar tetranuclear Cu{sup II}{sub 4} cluster-based three-dimensional (3D) frameworks with the same components. Polymer 4 possesses a 3D framework with a 4{sup 12}·6{sup 3}-pcu topology. Polymer 5 displays a 3D frameworkmore »« less
DOI: 10.1016/J.JSSC.2014.01.026
Selective adsorption in two porous triazolate–oxalate-bridged antiferromagnetic metal-azolate frameworks obtained via in situ decarboxylation of 3-amino-1,2,4-triazole-5-carboxylic acid

Journal Article Hou, Juan-Juan ; Xu, Xia ; Jiang, Ning ; ... - Journal of Solid State Chemistry

Solvothermal reactions of metal salts, 3-amino-1,2,4-triazole-5-carboxylic acid (H{sub 2}atzc) and ammonium oxalate in different temperature produced two metal azolate frameworks, namely, [Cu{sub 3}(atzc){sub 2}(atz)(ox)]·1.5H{sub 2}O (1) and [Co{sub 5}(atz){sub 4}(ox){sub 3}(HCOO){sub 2}]·DMF (2) (H{sub 2}atzc=3-amino-1,2,4-triazole-5-carboxylic acid, Hatz=3-amino-1,2,4-triazole, and ox=oxalate), in which the atzc precusor was in situ decarboxylated. Structural determination reveals that 1 contains [Cu{sub 3}(atzc){sub 2}(atz)]{sup 2−} layers of mixed μ{sub 4}-atzc and μ{sub 3}-atz ligands, which are pillared by ox{sup 2−} groups to form a 3D porous framework. Compound 2 contains 2D layers with basic spindle-shaped decanuclear units, which extended by ox{sup 2−} and formates to form 3Dmore »« less
DOI: 10.1016/J.JSSC.2014.06.016

Similar Records