Ignition delay time and H2O measurements during methanol oxidation behind reflected shock waves

Pinzón, L. T.; Mathieu, O.; Mulvihill, C. R.; Schoegl, I.; Petersen, E. L.

doi:10.1016/j.combustflame.2019.01.036

Title: Ignition delay time and H₂O measurements during methanol oxidation behind reflected shock waves

Abstract

To improve detailed chemical kinetics models, the oxidation of methanol was investigated behind reflected shock waves in shock tubes. Ignition delay times of methanol–air mixtures, with Ar as diluent, were studied between 940 and 1540 K in a heated shock tube, for pressures up to 14.9 atm and for equivalence ratios of 0.5, 1.0, and 2.0. Water profiles were measured by utilizing a laser absorption technique in the 1350-to-1600-K temperature range, at an average pressure of 1.3 atm and for similar equivalence ratios. The present study shows here the ignition delay times of methanol to be in very good agreement with results from the literature (Fieweger et al., 1997), whereas the other conditions have never been investigated before. The ignition delay time data are also in good agreement with modern detailed kinetics mechanisms such as the AramcoMech 3.0 model. The water time-history profiles were modeled using well-known literature mechanisms. Discrepancies were observed between these kinetics mechanisms, and poor predictions were observed for the lower temperatures investigated. Sensitivity and rate-of-production analyses were performed using 3 literature mechanisms (namely, AramcoMech 3.0, Princeton, and JetSurfII). Discrepancies were found among the models when predicting important reactions dominating the oxidation of methanol as well asmore » the rate-of-production of H₂O.« less

Authors:

Pinzón, L. T. ^[1]; Mathieu, O. ^[1];

^[1];

^[2];

^[1]

Texas A & M University, College Station, TX (United States)
Louisiana State University, Baton Rouge, LA (United States)

Publication Date:: Fri Feb 22 00:00:00 EST 2019

Research Org.:: Louisiana State Univ., Baton Rouge, LA (United States); Texas A & M Univ., College Station, TX (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Science Foundation (NSF); USDOE

OSTI Identifier:: 1495676

Alternate Identifier(s):: OSTI ID: 1547722

Grant/Contract Number:: EE0007981; CBET-1706825

Resource Type:: Accepted Manuscript

Journal Name:: Combustion and Flame

Additional Journal Information:: Journal Volume: 203; Journal ID: ISSN 0010-2180

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 42 ENGINEERING; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; methanol; shock tube; ignition; H2O laser absorption

Citation Formats


                    Pinzón, L. T., Mathieu, O., Mulvihill, C. R., Schoegl, I., and Petersen, E. L. Ignition delay time and H2O measurements during methanol oxidation behind reflected shock waves.  United States: N. p., 2019. 
Web.  doi:10.1016/j.combustflame.2019.01.036.

Copy to clipboard


                    Pinzón, L. T., Mathieu, O., Mulvihill, C. R., Schoegl, I., & Petersen, E. L. Ignition delay time and H2O measurements during methanol oxidation behind reflected shock waves.  United States.  https://doi.org/10.1016/j.combustflame.2019.01.036

Copy to clipboard


                    Pinzón, L. T., Mathieu, O., Mulvihill, C. R., Schoegl, I., and Petersen, E. L. Fri .  
"Ignition delay time and H2O measurements during methanol oxidation behind reflected shock waves".  United States.  https://doi.org/10.1016/j.combustflame.2019.01.036.  https://www.osti.gov/servlets/purl/1495676.

Copy to clipboard


                    
@article{osti_1495676,

  title        = {Ignition delay time and H2O measurements during methanol oxidation behind reflected shock waves},

  author       = {Pinzón, L. T. and Mathieu, O. and Mulvihill, C. R. and Schoegl, I. and Petersen, E. L.},

  abstractNote = {To improve detailed chemical kinetics models, the oxidation of methanol was investigated behind reflected shock waves in shock tubes. Ignition delay times of methanol–air mixtures, with Ar as diluent, were studied between 940 and 1540 K in a heated shock tube, for pressures up to 14.9 atm and for equivalence ratios of 0.5, 1.0, and 2.0. Water profiles were measured by utilizing a laser absorption technique in the 1350-to-1600-K temperature range, at an average pressure of 1.3 atm and for similar equivalence ratios. The present study shows here the ignition delay times of methanol to be in very good agreement with results from the literature (Fieweger et al., 1997), whereas the other conditions have never been investigated before. The ignition delay time data are also in good agreement with modern detailed kinetics mechanisms such as the AramcoMech 3.0 model. The water time-history profiles were modeled using well-known literature mechanisms. Discrepancies were observed between these kinetics mechanisms, and poor predictions were observed for the lower temperatures investigated. Sensitivity and rate-of-production analyses were performed using 3 literature mechanisms (namely, AramcoMech 3.0, Princeton, and JetSurfII). Discrepancies were found among the models when predicting important reactions dominating the oxidation of methanol as well as the rate-of-production of H2O.},

  doi          = {10.1016/j.combustflame.2019.01.036},

  journal      = {Combustion and Flame},

  number       = ,

  volume       = 203,

  place        = {United States},

  year         = {Fri Feb 22 00:00:00 EST 2019},

  month        = {Fri Feb 22 00:00:00 EST 2019}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1016/j.combustflame.2019.01.036

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 17 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Methanol as a fuel for internal combustion engines
journal, January 2019

Verhelst, Sebastian; Turner, James WG; Sileghem, Louis
Progress in Energy and Combustion Science, Vol. 70
DOI: 10.1016/j.pecs.2018.10.001

A detailed chemical kinetic modeling, ignition delay time and jet-stirred reactor study of methanol oxidation
journal, March 2016

Burke, Ultan; Metcalfe, Wayne K.; Burke, Sinead M.
Combustion and Flame, Vol. 165
DOI: 10.1016/j.combustflame.2015.11.004

A comprehensive kinetic mechanism for CO, CH ₂ O, and CH ₃ OH combustion : Comprehensive Kinetic Mechanism for CO, CH
journal, January 2007

Li, Juan; Zhao, Zhenwei; Kazakov, Andrei
International Journal of Chemical Kinetics, Vol. 39, Issue 3
DOI: 10.1002/kin.20218

Assessment of modern detailed kinetics mechanisms to predict CO formation from methane combustion using shock-tube laser-absorption measurements
journal, January 2019

Mathieu, Olivier; Mulvihill, Clayton R.; Petersen, Eric L.
Fuel, Vol. 236
DOI: 10.1016/j.fuel.2018.09.029

Alcohol combustion chemistry
journal, October 2014

Sarathy, S. Mani; Oßwald, Patrick; Hansen, Nils
Progress in Energy and Combustion Science, Vol. 44
DOI: 10.1016/j.pecs.2014.04.003

Flame profiles and combustion mechanisms of methanol-air flames under reduced pressure
journal, January 1978

Akrich, R.; Vovelle, C.; Delbourgo, R.
Combustion and Flame, Vol. 32
DOI: 10.1016/0010-2180(78)90091-3

A Comprehensive Study of Methanol Kinetics in Freely-Propagating and Burner-Stabilized Flames, Flow and Static Reactors, and Shock Tubes
journal, May 1992

Egolfopoulos, F. N.; Du, D. X.; Law, C. K.
Combustion Science and Technology, Vol. 83, Issue 1-3
DOI: 10.1080/00102209208951823

A comparative experimental and computational study of methanol, ethanol, and n-butanol flames
journal, October 2010

Veloo, Peter S.; Wang, Yang L.; Egolfopoulos, Fokion N.
Combustion and Flame, Vol. 157, Issue 10
DOI: 10.1016/j.combustflame.2010.04.001

Investigation on the oxidation chemistry of methanol in laminar premixed flames
journal, June 2017

Zhang, Xiaoyuan; Wang, Guoqing; Zou, Jiabiao
Combustion and Flame, Vol. 180
DOI: 10.1016/j.combustflame.2017.02.016

Burning velocities of mixtures of air with methanol, isooctane, and indolene at high pressure and temperature
journal, January 1982

Metghalchi, Mohamad; Keck, James C.
Combustion and Flame, Vol. 48
DOI: 10.1016/0010-2180(82)90127-4

Laminar Burning Velocities of Methanol, Isooctane and Isooctane/Methanol Blends
journal, August 1983

Gulder, ÖMer L.
Combustion Science and Technology, Vol. 33, Issue 1-4
DOI: 10.1080/00102208308923674

Laminar burning velocities for mixtures of methanol and air at elevated temperatures
journal, March 2007

Liao, S. Y.; Jiang, D. M.; Huang, Z. H.
Energy Conversion and Management, Vol. 48, Issue 3
DOI: 10.1016/j.enconman.2006.08.017

Characterization of laminar premixed methanol–air flames
journal, July 2006

Liao, S.; Jiang, D.; Huang, Z.
Fuel, Vol. 85, Issue 10-11
DOI: 10.1016/j.fuel.2005.12.015

Measurements of laminar burning velocities and Markstein lengths for methanol–air–nitrogen mixtures at elevated pressures and temperatures
journal, November 2008

Zhang, Zhiyuan; Huang, Zuohua; Wang, Xiangang
Combustion and Flame, Vol. 155, Issue 3
DOI: 10.1016/j.combustflame.2008.07.005

Temperature Dependence of the Laminar Burning Velocity of Methanol Flames
journal, February 2012

Vancoillie, J.; Christensen, M.; Nilsson, E. J. K.
Energy & Fuels, Vol. 26, Issue 3
DOI: 10.1021/ef2016683

Laminar burning velocities of primary reference fuels and simple alcohols
journal, January 2014

Sileghem, L.; Alekseev, V. A.; Vancoillie, J.
Fuel, Vol. 115
DOI: 10.1016/j.fuel.2013.07.004

Experimental investigation of the laminar burning velocities of methanol, ethanol, n-propanol, and n-butanol at high pressure
journal, January 2014

Beeckmann, J.; Cai, L.; Pitsch, H.
Fuel, Vol. 117
DOI: 10.1016/j.fuel.2013.09.025

Kinetics of the pyrolysis of methanol
journal, December 1977

Aronowitz, D.; Naegeli, D. W.; Glassman, I.
The Journal of Physical Chemistry, Vol. 81, Issue 25
DOI: 10.1021/j100540a037

Some New Observations on Methanol Oxidation Chemistry
journal, January 1989

Norton, Thomas S.; Dryer, Frederick L.
Combustion Science and Technology, Vol. 63, Issue 1
DOI: 10.1080/00102208908947121

An experimental and computational study of methanol oxidation in the intermediate-and high-temperature regimes
journal, January 1994

Held, T. J.; Dryer, F. L.
Symposium (International) on Combustion, Vol. 25, Issue 1
DOI: 10.1016/S0082-0784(06)80725-3

Methanol Oxidation and Its Interaction with Nitric Oxide
journal, April 2001

Alzueta, M. U.; Bilbao, R.; Finestra, M.
Energy & Fuels, Vol. 15, Issue 3
DOI: 10.1021/ef0002602

Development of a detailed high-pressure reaction model for methane/methanol mixtures under pyrolytic and oxidative conditions and comparison with experimental data
journal, September 2003

Ing, Wen-Chiun; Sheng, Chad Y.; Bozzelli, Joseph W.
Fuel Processing Technology, Vol. 83, Issue 1-3
DOI: 10.1016/S0378-3820(03)00062-6

Methanol oxidation in a flow reactor: Implications for the branching ratio of the CH3OH+OH reaction
journal, January 2008

Rasmussen, Christian Lund; Wassard, Karin Hedebo; Dam-Johansen, Kim
International Journal of Chemical Kinetics, Vol. 40, Issue 7
DOI: 10.1002/kin.20323

Experimental and Kinetic Modeling Study of Methanol Ignition and Oxidation at High Pressure: STUDY OF METHANOL IGNITION AND OXIDATION AT HIGH PRESSURE
journal, March 2013

Aranda, V.; Christensen, J. M.; Alzueta, M. U.
International Journal of Chemical Kinetics, Vol. 45, Issue 5
DOI: 10.1002/kin.20764

Experimental and detailed kinetic modeling study of the high pressure oxidation of methanol sensitized by nitric oxide and nitrogen dioxide
journal, January 2007

Dayma, Guillaume; Ali, Kamal Hadj; Dagaut, Philippe
Proceedings of the Combustion Institute, Vol. 31, Issue 1
DOI: 10.1016/j.proci.2006.07.143

Autoignition of methanol: Experiments and computations: Autoignition of Methanol: Experiments and Computations
journal, February 2011

Kumar, Kamal; Sung, Chih-Jen
International Journal of Chemical Kinetics, Vol. 43, Issue 4
DOI: 10.1002/kin.20546

A shock-tube study of the ignition of methanol and ethanol with oxygen
journal, June 1971

Cooke, D. F.; Dodson, M. G.; Williams, Alan
Combustion and Flame, Vol. 16, Issue 3
DOI: 10.1016/S0010-2180(71)80093-7

Self-ignition of S.I. engine model fuels: A shock tube investigation at high pressure
journal, June 1997

Fieweger, K.; Blumenthal, R.; Adomeit, G.
Combustion and Flame, Vol. 109, Issue 4
DOI: 10.1016/S0010-2180(97)00049-7

Comparative High Temperature Shock Tube Ignition of C1−C4 Primary Alcohols
journal, November 2010

Noorani, Khalid Emilio; Akih-Kumgeh, Benjamin; Bergthorson, Jeffrey M.
Energy & Fuels, Vol. 24, Issue 11
DOI: 10.1021/ef1009692

A shock-tube investigation of the high-temperature oxidation of methanol
journal, August 1975

Bowman, Craig T.
Combustion and Flame, Vol. 25
DOI: 10.1016/0010-2180(75)90106-6

Shock tube study on homogeneous thermal oxidation of methanol
journal, January 1981

Tsuboi, Takao; Hashimoto, Kazunobu
Combustion and Flame, Vol. 42
DOI: 10.1016/0010-2180(81)90142-5

Shock tube study of methanol, methyl formate pyrolysis: CH3OH and CO time-history measurements
journal, December 2013

Ren, Wei; Dames, Enoch; Hyland, Derrek
Combustion and Flame, Vol. 160, Issue 12
DOI: 10.1016/j.combustflame.2013.06.016

A shock tube kinetic study on the branching ratio of methanol + OH reaction
journal, January 2019

Liu, Dapeng; Giri, Binod Raj; Farooq, Aamir
Proceedings of the Combustion Institute, Vol. 37, Issue 1
DOI: 10.1016/j.proci.2018.05.179

Experimental investigation into the combustion characteristics of a methanol-Diesel heavy duty engine operated in RCCI mode
journal, August 2018

Jia, Zhiqin; Denbratt, Ingemar
Fuel, Vol. 226
DOI: 10.1016/j.fuel.2018.03.088

An experimental and modeling study of dimethyl ether/methanol blends autoignition at low temperature
journal, December 2018

Wang, Hongfu; Fang, Ruozhou; Weber, Bryan W.
Combustion and Flame, Vol. 198
DOI: 10.1016/j.combustflame.2018.09.012

An investigation on the characteristics of and influence factors for NO2 formation in diesel/methanol dual fuel engine
journal, January 2019

Lu, Han; Yao, Anren; Yao, Chunde
Fuel, Vol. 235
DOI: 10.1016/j.fuel.2018.08.061

A facility for gas- and condensed-phase measurements behind shock waves
journal, July 2005

Petersen, Eric L.; Rickard, Matthew J. A.; Crofton, Mark W.
Measurement Science and Technology, Vol. 16, Issue 9
DOI: 10.1088/0957-0233/16/9/003

Ignition and kinetic modeling of methane and ethane fuel blends with oxygen: A design of experiments approach
journal, July 2013

Aul, Christopher J.; Metcalfe, Wayne K.; Burke, Sinéad M.
Combustion and Flame, Vol. 160, Issue 7
DOI: 10.1016/j.combustflame.2013.01.019

Experimental and modelling study of 1CH2 in premixed very rich methane flames
journal, September 2016

Fomin, Alexey; Zavlev, Tatyana; Alekseev, Vladimir A.
Combustion and Flame, Vol. 171
DOI: 10.1016/j.combustflame.2016.06.020

An experimental and chemical kinetic modeling study of 1,3-butadiene combustion: Ignition delay time and laminar flame speed measurements
journal, November 2018

Zhou, Chong-Wen; Li, Yang; Burke, Ultan
Combustion and Flame, Vol. 197
DOI: 10.1016/j.combustflame.2018.08.006

Interpreting Endwall and Sidewall Measurements in Shock-Tube Ignition Studies
journal, September 2009

Petersen, Eric L.
Combustion Science and Technology, Vol. 181, Issue 9
DOI: 10.1080/00102200902973323

An ignition delay time and chemical kinetic modeling study of the pentane isomers
journal, January 2016

Bugler, John; Marks, Brandon; Mathieu, Olivier
Combustion and Flame, Vol. 163
DOI: 10.1016/j.combustflame.2015.09.014

Shock tube studies of ethanol preignition
journal, December 2018

Figueroa-Labastida, Miguel; Badra, Jihad; Elbaz, Ayman M.
Combustion and Flame, Vol. 198
DOI: 10.1016/j.combustflame.2018.09.011

The HITRAN 2004 molecular spectroscopic database
journal, December 2005

Rothman, L. S.; Jacquemart, D.; Barbe, A.
Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 96, Issue 2
DOI: 10.1016/j.jqsrt.2004.10.008

Diode laser measurements of temperature-dependent collisional-narrowing and broadening parameters of Ar-perturbed H2O transitions at 1391.7 and 1397.8nm
journal, January 2008

Li, Hejie; Farooq, Aamir; Jeffries, Jay B.
Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 109, Issue 1
DOI: 10.1016/j.jqsrt.2007.05.008

Shock-tube water time-histories and ignition delay time measurements for H2S near atmospheric pressure
journal, January 2017

Mathieu, Olivier; Mulvihill, Clayton; Petersen, Eric L.
Proceedings of the Combustion Institute, Vol. 36, Issue 3
DOI: 10.1016/j.proci.2016.06.027

Ignition delay times, laminar flame speeds, and species time-histories in the H2S/CH4 system at atmospheric pressure
journal, January 2019

Mulvihill, Clayton R.; Keesee, Charles L.; Sikes, Travis
Proceedings of the Combustion Institute, Vol. 37, Issue 1
DOI: 10.1016/j.proci.2018.06.034

Ethanol pyrolysis kinetics using H2O time history measurements behind reflected shock waves
journal, January 2019

Pinzón, Laura T.; Mathieu, Olivier; Mulvihill, Clayton R.
Proceedings of the Combustion Institute, Vol. 37, Issue 1
DOI: 10.1016/j.proci.2018.07.088

Kinetics of the Reaction of Methyl Radical with Hydroxyl Radical and Methanol Decomposition ^†
journal, May 2007

Jasper, Ahren W.; Klippenstein, Stephen J.; Harding, Lawrence B.
The Journal of Physical Chemistry A, Vol. 111, Issue 19
DOI: 10.1021/jp067585p

Non-arrhenius behavior of the reaction of hydroxymethyl radicals with molecular oxygen
journal, July 1988

Grotheer, Horst Henning; Riekert, Gottfried; Walter, Dieter
The Journal of Physical Chemistry, Vol. 92, Issue 14
DOI: 10.1021/j100325a007

Similar Records in DOE PAGES and OSTI.GOV collections:

An Experimental Kinetics Study of Isopropanol Pyrolysis and Oxidation behind Reflected Shock Waves

Journal Article Cooper, Sean P. ; Grégoire, Claire M. ; Mohr, Darryl J. ; ... - Energies

Isopropanol has potential as a future bio-derived fuel and is a promising substitute for ethanol in gasoline blends. Even so, little has been done in terms of high-temperature chemical kinetic speciation studies of this molecule. To this end, experiments were conducted in a shock tube using simultaneous CO and H₂O laser absorption measurements. Water and CO formation during isopropanol pyrolysis was also examined at temperatures between 1127 and 2162 K at an average pressure of 1.42 atm. Species profiles were collected at temperatures between 1332 and 1728 K and at an average pressure of 1.26 atm for equivalence ratios ofmore »« less
https://doi.org/10.3390/en14206808
Experimental study of ethanol oxidation behind reflected shock waves: Ignition delay time and H₂O laser-absorption measurements

Journal Article Mathieu, Olivier ; Pinzón, Laura T. ; Atherley, Tatyana M. ; ... - Combustion and Flame

The oxidation of ethanol was investigated in shock tubes by measuring ignition delay times and water time history profiles. A laser absorption technique was used in the latter case. Ignition delay times were investigated for three equivalence ratios, 0.5, 1.0, and 2.0, and for pressures ranging from 1.3 to 53 atm. The fuel concentration and the type of diluent used were also varied. The ignition delay times were in very good agreement with results from the literature for the very few overlapping conditions, and most of the experimental conditions have never been studied before. A high level of accuracy wasmore »« less
Cited by 25
https://doi.org/10.1016/j.combustflame.2019.07.005

Full Text Available
Ethane ignition and oxidation behind reflected shock waves

Journal Article de Vries, Jaap ; Hall, Joel M ; Simmons, Stefanie L ; ... - Combustion and Flame

Several diluted C{sub 2}H{sub 6}/O{sub 2}/Ar mixtures of varying concentrations and equivalence ratios (0.5<{phi}<2.0) were studied at temperatures between 1218 and 1860 K and at pressures between 0.57 and 3.0 atm using a shock tube. The argon dilution ranged from 91 to 98% by volume. Reaction progress was monitored using chemiluminescence emission from OH{sup *} and CH{sup *} at 307 and 431 nm, respectively. The dependence of ignition delay time on temperature, activation energy, and reactant concentrations is given in a master correlation of all the experimental data. The overall activation energy was found to be 39.6 kcal/mol over themore »« less
https://doi.org/10.1016/J.COMBUSTFLAME.2006.10.008
Isopropanol dehydration reaction rate kinetics measurement using H₂O time histories

Journal Article Cooper, Sean P. ; Mulvihill, Clayton R. ; Mathieu, Olivier ; ... - International Journal of Chemical Kinetics

H₂O formation during thermal decomposition of isopropanol was measured behind reflected shock waves at temperatures ranging from 1127 to 1621 K at an average pressure of 1.42 atm using a laser absorption technique. Of the five modern chemical kinetics models used to compare the H₂O time histories, the model from Li et al (Combust. Flame 2019;207:171-185) showed the best overall agreement. Sensitivity and rate of production analyses using the Li et al model (as well as those from AramcoMech 3.0, CRECK, and Togbe et al (Energy Fuel. 2011;25:676-683)) showed unimolecular dehydration of isopropanol, iC₃H₇OH ⇌ H₂O + C₃H₆ (R1), ismore »« less
https://doi.org/10.1002/kin.21463

Full Text Available
New insights into the shock tube ignition of H₂/O₂ at low to moderate temperatures using high-speed end-wall imaging

Journal Article Ninnemann, Erik ; Koroglu, Batikan ; Pryor, Owen ; ... - Combustion and Flame

In this study, the effects of pre-ignition energy releases on H₂—O₂ mixtures were explored in a shock tube with the aid of high-speed imaging and conventional pressure and emission diagnostics. Ignition delay times and time-resolved camera image sequences were taken behind the reflected shockwaves for two hydrogen mixtures. High concentration experiments spanned temperatures between 858 and 1035 K and pressures between 2.74 and 3.91 atm for a 15% H₂\18% O₂\Ar mixture. Low concentration data were also taken at temperatures between 960 and 1131 K and pressures between 3.09 and 5.44 atm for a 4% H₂\2% O₂\Ar mixture. These two modelmore »« less
Cited by 50
https://doi.org/10.1016/j.combustflame.2017.08.021

Full Text Available

Similar Records

Title: Ignition delay time and H2O measurements during methanol oxidation behind reflected shock waves

Abstract

Citation Formats

Methanol as a fuel for internal combustion engines journal, January 2019

A detailed chemical kinetic modeling, ignition delay time and jet-stirred reactor study of methanol oxidation journal, March 2016

A comprehensive kinetic mechanism for CO, CH 2 O, and CH 3 OH combustion : Comprehensive Kinetic Mechanism for CO, CH journal, January 2007

Assessment of modern detailed kinetics mechanisms to predict CO formation from methane combustion using shock-tube laser-absorption measurements journal, January 2019

Alcohol combustion chemistry journal, October 2014

Flame profiles and combustion mechanisms of methanol-air flames under reduced pressure journal, January 1978

A Comprehensive Study of Methanol Kinetics in Freely-Propagating and Burner-Stabilized Flames, Flow and Static Reactors, and Shock Tubes journal, May 1992

A comparative experimental and computational study of methanol, ethanol, and n-butanol flames journal, October 2010

Investigation on the oxidation chemistry of methanol in laminar premixed flames journal, June 2017

Burning velocities of mixtures of air with methanol, isooctane, and indolene at high pressure and temperature journal, January 1982

Laminar Burning Velocities of Methanol, Isooctane and Isooctane/Methanol Blends journal, August 1983

Laminar burning velocities for mixtures of methanol and air at elevated temperatures journal, March 2007

Characterization of laminar premixed methanol–air flames journal, July 2006

Measurements of laminar burning velocities and Markstein lengths for methanol–air–nitrogen mixtures at elevated pressures and temperatures journal, November 2008

Temperature Dependence of the Laminar Burning Velocity of Methanol Flames journal, February 2012

Laminar burning velocities of primary reference fuels and simple alcohols journal, January 2014

Experimental investigation of the laminar burning velocities of methanol, ethanol, n-propanol, and n-butanol at high pressure journal, January 2014

Kinetics of the pyrolysis of methanol journal, December 1977

Some New Observations on Methanol Oxidation Chemistry journal, January 1989

An experimental and computational study of methanol oxidation in the intermediate-and high-temperature regimes journal, January 1994

Methanol Oxidation and Its Interaction with Nitric Oxide journal, April 2001

Development of a detailed high-pressure reaction model for methane/methanol mixtures under pyrolytic and oxidative conditions and comparison with experimental data journal, September 2003

Methanol oxidation in a flow reactor: Implications for the branching ratio of the CH3OH+OH reaction journal, January 2008

Experimental and Kinetic Modeling Study of Methanol Ignition and Oxidation at High Pressure: STUDY OF METHANOL IGNITION AND OXIDATION AT HIGH PRESSURE journal, March 2013

Experimental and detailed kinetic modeling study of the high pressure oxidation of methanol sensitized by nitric oxide and nitrogen dioxide journal, January 2007

Autoignition of methanol: Experiments and computations: Autoignition of Methanol: Experiments and Computations journal, February 2011

A shock-tube study of the ignition of methanol and ethanol with oxygen journal, June 1971

Self-ignition of S.I. engine model fuels: A shock tube investigation at high pressure journal, June 1997

Comparative High Temperature Shock Tube Ignition of C1−C4 Primary Alcohols journal, November 2010

A shock-tube investigation of the high-temperature oxidation of methanol journal, August 1975

Shock tube study on homogeneous thermal oxidation of methanol journal, January 1981

Shock tube study of methanol, methyl formate pyrolysis: CH3OH and CO time-history measurements journal, December 2013

A shock tube kinetic study on the branching ratio of methanol + OH reaction journal, January 2019

Experimental investigation into the combustion characteristics of a methanol-Diesel heavy duty engine operated in RCCI mode journal, August 2018

An experimental and modeling study of dimethyl ether/methanol blends autoignition at low temperature journal, December 2018

An investigation on the characteristics of and influence factors for NO2 formation in diesel/methanol dual fuel engine journal, January 2019

A facility for gas- and condensed-phase measurements behind shock waves journal, July 2005

Ignition and kinetic modeling of methane and ethane fuel blends with oxygen: A design of experiments approach journal, July 2013

Experimental and modelling study of 1CH2 in premixed very rich methane flames journal, September 2016

An experimental and chemical kinetic modeling study of 1,3-butadiene combustion: Ignition delay time and laminar flame speed measurements journal, November 2018

Interpreting Endwall and Sidewall Measurements in Shock-Tube Ignition Studies journal, September 2009

An ignition delay time and chemical kinetic modeling study of the pentane isomers journal, January 2016

Shock tube studies of ethanol preignition journal, December 2018

The HITRAN 2004 molecular spectroscopic database journal, December 2005

Diode laser measurements of temperature-dependent collisional-narrowing and broadening parameters of Ar-perturbed H2O transitions at 1391.7 and 1397.8nm journal, January 2008

Shock-tube water time-histories and ignition delay time measurements for H2S near atmospheric pressure journal, January 2017

Ignition delay times, laminar flame speeds, and species time-histories in the H2S/CH4 system at atmospheric pressure journal, January 2019

Ethanol pyrolysis kinetics using H2O time history measurements behind reflected shock waves journal, January 2019

Kinetics of the Reaction of Methyl Radical with Hydroxyl Radical and Methanol Decomposition † journal, May 2007

Non-arrhenius behavior of the reaction of hydroxymethyl radicals with molecular oxygen journal, July 1988

Title: Ignition delay time and H₂O measurements during methanol oxidation behind reflected shock waves

Methanol as a fuel for internal combustion engines
journal, January 2019

A detailed chemical kinetic modeling, ignition delay time and jet-stirred reactor study of methanol oxidation
journal, March 2016

A comprehensive kinetic mechanism for CO, CH ₂ O, and CH ₃ OH combustion : Comprehensive Kinetic Mechanism for CO, CH
journal, January 2007

Assessment of modern detailed kinetics mechanisms to predict CO formation from methane combustion using shock-tube laser-absorption measurements
journal, January 2019

Alcohol combustion chemistry
journal, October 2014

Flame profiles and combustion mechanisms of methanol-air flames under reduced pressure
journal, January 1978

A Comprehensive Study of Methanol Kinetics in Freely-Propagating and Burner-Stabilized Flames, Flow and Static Reactors, and Shock Tubes
journal, May 1992

A comparative experimental and computational study of methanol, ethanol, and n-butanol flames
journal, October 2010

Investigation on the oxidation chemistry of methanol in laminar premixed flames
journal, June 2017

Burning velocities of mixtures of air with methanol, isooctane, and indolene at high pressure and temperature
journal, January 1982

Laminar Burning Velocities of Methanol, Isooctane and Isooctane/Methanol Blends
journal, August 1983

Laminar burning velocities for mixtures of methanol and air at elevated temperatures
journal, March 2007

Characterization of laminar premixed methanol–air flames
journal, July 2006

Measurements of laminar burning velocities and Markstein lengths for methanol–air–nitrogen mixtures at elevated pressures and temperatures
journal, November 2008

Temperature Dependence of the Laminar Burning Velocity of Methanol Flames
journal, February 2012

Laminar burning velocities of primary reference fuels and simple alcohols
journal, January 2014

Experimental investigation of the laminar burning velocities of methanol, ethanol, n-propanol, and n-butanol at high pressure
journal, January 2014

Kinetics of the pyrolysis of methanol
journal, December 1977

Some New Observations on Methanol Oxidation Chemistry
journal, January 1989

An experimental and computational study of methanol oxidation in the intermediate-and high-temperature regimes
journal, January 1994

Methanol Oxidation and Its Interaction with Nitric Oxide
journal, April 2001

Development of a detailed high-pressure reaction model for methane/methanol mixtures under pyrolytic and oxidative conditions and comparison with experimental data
journal, September 2003

Methanol oxidation in a flow reactor: Implications for the branching ratio of the CH3OH+OH reaction
journal, January 2008

Experimental and Kinetic Modeling Study of Methanol Ignition and Oxidation at High Pressure: STUDY OF METHANOL IGNITION AND OXIDATION AT HIGH PRESSURE
journal, March 2013

Experimental and detailed kinetic modeling study of the high pressure oxidation of methanol sensitized by nitric oxide and nitrogen dioxide
journal, January 2007

Autoignition of methanol: Experiments and computations: Autoignition of Methanol: Experiments and Computations
journal, February 2011

A shock-tube study of the ignition of methanol and ethanol with oxygen
journal, June 1971

Self-ignition of S.I. engine model fuels: A shock tube investigation at high pressure
journal, June 1997

Comparative High Temperature Shock Tube Ignition of C1−C4 Primary Alcohols
journal, November 2010

A shock-tube investigation of the high-temperature oxidation of methanol
journal, August 1975

Shock tube study on homogeneous thermal oxidation of methanol
journal, January 1981

Shock tube study of methanol, methyl formate pyrolysis: CH3OH and CO time-history measurements
journal, December 2013

A shock tube kinetic study on the branching ratio of methanol + OH reaction
journal, January 2019

Experimental investigation into the combustion characteristics of a methanol-Diesel heavy duty engine operated in RCCI mode
journal, August 2018

An experimental and modeling study of dimethyl ether/methanol blends autoignition at low temperature
journal, December 2018

An investigation on the characteristics of and influence factors for NO2 formation in diesel/methanol dual fuel engine
journal, January 2019

A facility for gas- and condensed-phase measurements behind shock waves
journal, July 2005

Ignition and kinetic modeling of methane and ethane fuel blends with oxygen: A design of experiments approach
journal, July 2013

Experimental and modelling study of 1CH2 in premixed very rich methane flames
journal, September 2016

An experimental and chemical kinetic modeling study of 1,3-butadiene combustion: Ignition delay time and laminar flame speed measurements
journal, November 2018

Interpreting Endwall and Sidewall Measurements in Shock-Tube Ignition Studies
journal, September 2009

An ignition delay time and chemical kinetic modeling study of the pentane isomers
journal, January 2016

Shock tube studies of ethanol preignition
journal, December 2018

The HITRAN 2004 molecular spectroscopic database
journal, December 2005

Diode laser measurements of temperature-dependent collisional-narrowing and broadening parameters of Ar-perturbed H2O transitions at 1391.7 and 1397.8nm
journal, January 2008

Shock-tube water time-histories and ignition delay time measurements for H2S near atmospheric pressure
journal, January 2017

Ignition delay times, laminar flame speeds, and species time-histories in the H2S/CH4 system at atmospheric pressure
journal, January 2019

Ethanol pyrolysis kinetics using H2O time history measurements behind reflected shock waves
journal, January 2019

Kinetics of the Reaction of Methyl Radical with Hydroxyl Radical and Methanol Decomposition ^†
journal, May 2007

Non-arrhenius behavior of the reaction of hydroxymethyl radicals with molecular oxygen
journal, July 1988