Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks
Abstract
We report three electrically conductive metal–organic frameworks (MOFs) based on a tetrathiafulvalene linker and La 3+ .
- Authors:
-
[1];
[2];
[3];
[1]
- Department of Chemistry, Massachusetts Institute of Technology, Cambridge, USA
- Samara Center for Theoretical Material Science (SCTMS), Samara State Technical University, Samara, Russia, SCTMS
- Samara Center for Theoretical Material Science (SCTMS), Samara State Technical University, Samara, Russia, Dipartimento di Chimica
- Publication Date:
- Research Org.:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1547669
- Alternate Identifier(s):
- OSTI ID: 1601983
- Grant/Contract Number:
- SC0018235
- Resource Type:
- Published Article
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Name: Chemical Science Journal Volume: 10 Journal Issue: 37; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Xie, Lilia S., Alexandrov, Eugeny V., Skorupskii, Grigorii, Proserpio, Davide M., and Dincă, Mircea. Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9SC03348C.
Xie, Lilia S., Alexandrov, Eugeny V., Skorupskii, Grigorii, Proserpio, Davide M., & Dincă, Mircea. Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks. United Kingdom. https://doi.org/10.1039/C9SC03348C
Xie, Lilia S., Alexandrov, Eugeny V., Skorupskii, Grigorii, Proserpio, Davide M., and Dincă, Mircea. Wed .
"Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks". United Kingdom. https://doi.org/10.1039/C9SC03348C.
@article{osti_1547669,
title = {Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks},
author = {Xie, Lilia S. and Alexandrov, Eugeny V. and Skorupskii, Grigorii and Proserpio, Davide M. and Dincă, Mircea},
abstractNote = {We report three electrically conductive metal–organic frameworks (MOFs) based on a tetrathiafulvalene linker and La 3+ .},
doi = {10.1039/C9SC03348C},
journal = {Chemical Science},
number = 37,
volume = 10,
place = {United Kingdom},
year = {Wed Sep 25 00:00:00 EDT 2019},
month = {Wed Sep 25 00:00:00 EDT 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C9SC03348C
https://doi.org/10.1039/C9SC03348C
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 102 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001
- Eddaoudi, Mohamed; Moler, David B.; Li, Hailian
- Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330
Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis
journal, August 2011
- Wang, Cheng; Xie, Zhigang; deKrafft, Kathryn E.
- Journal of the American Chemical Society, Vol. 133, Issue 34, p. 13445-13454
Deconstruction of Crystalline Networks into Underlying Nets: Relevance for Terminology Guidelines and Crystallographic Databases
journal, May 2018
- Bonneau, Charlotte; O’Keeffe, Michael; Proserpio, Davide M.
- Crystal Growth & Design, Vol. 18, Issue 6
Redox Activities of Metal–Organic Frameworks Incorporating Rare-Earth Metal Chains and Tetrathiafulvalene Linkers
journal, February 2019
- Su, Jian; Hu, Tian-Hao; Murase, Ryuichi
- Inorganic Chemistry, Vol. 58, Issue 6
Blue photoluminescent 3D Zn(II) metal-organic framework constructing from pyridine-2,4,6-tricarboxylate
journal, August 2008
- Li, Xing; Wang, Xian-Wen; Zhang, Yong-Hua
- Inorganic Chemistry Communications, Vol. 11, Issue 8
The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets
journal, December 2008
- O’Keeffe, Michael; Peskov, Maxim A.; Ramsden, Stuart J.
- Accounts of Chemical Research, Vol. 41, Issue 12, p. 1782-1789
Is iron unique in promoting electrical conductivity in MOFs?
journal, January 2017
- Sun, Lei; Hendon, Christopher H.; Park, Sarah S.
- Chemical Science, Vol. 8, Issue 6
A spectroscopic and electrochemical investigation of a tetrathiafulvalene series of metal–organic frameworks
journal, November 2018
- Leong, Chanel F.; Wang, Chun-Hai; Ling, Chris D.
- Polyhedron, Vol. 154
Selective Vapor Pressure Dependent Proton Transport in a Metal–Organic Framework with Two Distinct Hydrophilic Pores
journal, February 2018
- Park, Sarah S.; Rieth, Adam J.; Hendon, Christopher H.
- Journal of the American Chemical Society, Vol. 140, Issue 6
A Guest-Responsive Fluorescent 3D Microporous Metal−Organic Framework Derived from a Long-Lifetime Pyrene Core
journal, March 2010
- Stylianou, Kyriakos C.; Heck, Romain; Chong, Samantha Y.
- Journal of the American Chemical Society, Vol. 132, Issue 12, p. 4119-4130
Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials
journal, November 2012
- Cook, Timothy R.; Zheng, Yao-Rong; Stang, Peter J.
- Chemical Reviews, Vol. 113, Issue 1
Three-Dimensional Metal−Organic Network Architecture with Large π-Conjugated Indolocarbazole Derivative: Synthesis, Supramolecular Structure, and Highly Enhanced Fluorescence
journal, January 2008
- Liu, Hui-Jun; Tao, Xu-Tang; Yang, Jia-Xiang
- Crystal Growth & Design, Vol. 8, Issue 1
Electronic, Structural and Functional Versatility in Tetrathiafulvalene‐Lanthanide Metal–Organic Frameworks
journal, August 2019
- Castells‐Gil, Javier; Mañas‐Valero, Samuel; Vitórica‐Yrezábal, Iñigo J.
- Chemistry – A European Journal, Vol. 25, Issue 54
Reticular synthesis and the design of new materials
journal, June 2003
- Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
- Nature, Vol. 423, Issue 6941, p. 705-714
Luminescent Functional Metal–Organic Frameworks
journal, June 2011
- Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong
- Chemical Reviews, Vol. 112, Issue 2
Hydrogen storage in metal–organic frameworks
journal, January 2009
- Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
Tunable Mixed-Valence Doping toward Record Electrical Conductivity in a Three-Dimensional Metal–Organic Framework
journal, May 2018
- Xie, Lilia S.; Sun, Lei; Wan, Ruomeng
- Journal of the American Chemical Society, Vol. 140, Issue 24
Metal–Organic Frameworks as Active Materials in Electronic Sensor Devices
journal, May 2017
- Campbell, Michael; Dincă, Mircea
- Sensors, Vol. 17, Issue 5
Synthesis and Structure of (ET)[Ni{SC(CN)?C(CN)S}2], a Radical Cation Salt of Bis(ethylenedithio)tetrathiafulvalene
journal, May 1988
- Reith, Walter; Polborn, Kurt; Amberger, Eberhard
- Angewandte Chemie International Edition in English, Vol. 27, Issue 5
The role of temperature in the synthesis of hybrid inorganic–organic materials: the example of cobalt succinates
journal, January 2004
- Forster, Paul M.; Burbank, Andrea R.; Livage, Carine
- Chem. Commun., Issue 4
Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks
journal, December 2017
- Su, Jian; Yuan, Shuai; Wang, Hai-Ying
- Nature Communications, Vol. 8, Issue 1
Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal–Organic Framework
journal, July 2018
- Souto, Manuel; Romero, Jorge; Calbo, Joaquín
- Journal of the American Chemical Society, Vol. 140, Issue 33
Novel Topology in Semiconducting Tetrathiafulvalene Lanthanide Metal-Organic Frameworks
journal, August 2018
- Xie, Lilia S.; Dincă, Mircea
- Israel Journal of Chemistry, Vol. 58, Issue 9-10
The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels
journal, March 2017
- Park, Sarah S.; Hendon, Christopher H.; Fielding, Alistair J.
- Journal of the American Chemical Society, Vol. 139, Issue 10
Crystal Structures, Gas Adsorption, and Electrochemical Properties of Electroactive Coordination Polymers Based on the Tetrathiafulvalene-Tetrabenzoate Ligand
journal, February 2015
- Chen, Bin; Lv, Zhong-Peng; Leong, Chanel F.
- Crystal Growth & Design, Vol. 15, Issue 4
Electrical conductivity and electroluminescence of a new anthracene-based metal–organic framework with π-conjugated zigzag chains
journal, January 2016
- Chen, Dashu; Xing, Hongzhu; Su, Zhongmin
- Chemical Communications, Vol. 52, Issue 10
An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors
journal, January 2017
- Stassen, Ivo; Burtch, Nicholas; Talin, Alec
- Chemical Society Reviews, Vol. 46, Issue 11
Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011
- O’Keeffe, Michael; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 675-702
Secondary building units as the turning point in the development of the reticular chemistry of MOFs
journal, October 2018
- Kalmutzki, Markus J.; Hanikel, Nikita; Yaghi, Omar M.
- Science Advances, Vol. 4, Issue 10
Crystal and molecular structure of the aromatic sulphur compound 2,2′-bi-1,3-dithiole. Evidence for d-orbital participation in bonding
journal, January 1971
- Cooper, W. F.; Kenny, N. C.; Edmonds, J. W.
- J. Chem. Soc. D, Vol. 0, Issue 16
Tunable Rare Earth fcu -MOF Platform: Access to Adsorption Kinetics Driven Gas/Vapor Separations via Pore Size Contraction
journal, April 2015
- Xue, Dong-Xu; Belmabkhout, Youssef; Shekhah, Osama
- Journal of the American Chemical Society, Vol. 137, Issue 15
Distinguishing Metal–Organic Frameworks
journal, January 2018
- Barthel, Senja; Alexandrov, Eugeny V.; Proserpio, Davide M.
- Crystal Growth & Design, Vol. 18, Issue 3
Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks
journal, October 2015
- Campbell, Michael G.; Liu, Sophie F.; Swager, Timothy M.
- Journal of the American Chemical Society, Vol. 137, Issue 43
The crystal structure of the 1:1 radical cation–radical anion salt of 2,2'-bis-l,3-dithiole (TTF) and 7,7,8,8-tetracyanoquinodimethane (TCNQ)
journal, March 1974
- Kistenmacher, T. J.; Phillips, T. E.; Cowan, D. O.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 30, Issue 3
An EXAFS study of the formation of a nanoporous metal–organic framework: evidence for the retention of secondary building units during synthesis
journal, January 2006
- Surblé, Suzy; Millange, Franck; Serre, Christian
- Chemical Communications, Issue 14
High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
journal, July 2012
- Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu
- Journal of the American Chemical Society, Vol. 134, Issue 31
Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks
journal, January 2015
- Park, Sarah S.; Hontz, Eric R.; Sun, Lei
- Journal of the American Chemical Society, Vol. 137, Issue 5
Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
journal, January 2009
- Tranchemontagne, David J.; Mendoza-Cortés, José L.; O’Keeffe, Michael
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1257-1283
Charge Delocalization and Bulk Electronic Conductivity in the Mixed-Valence Metal–Organic Framework Fe(1,2,3-triazolate) 2 (BF 4 ) x
journal, June 2018
- Park, Jesse G.; Aubrey, Michael L.; Oktawiec, Julia
- Journal of the American Chemical Society, Vol. 140, Issue 27
Charge Transport in Organic Semiconductors
journal, April 2007
- Coropceanu, Veaceslav; Cornil, Jérôme; da Silva Filho, Demetrio A.
- Chemical Reviews, Vol. 107, Issue 4
Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database
journal, January 2011
- Alexandrov, E. V.; Blatov, V. A.; Kochetkov, A. V.
- CrystEngComm, Vol. 13, Issue 12
Electroactive Metalorganic Frameworks
journal, October 2018
- Medina, Dana D.; Mähringer, Andre; Bein, Thomas
- Israel Journal of Chemistry, Vol. 58, Issue 9-10
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002
- Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
- Science, Vol. 295, Issue 5554, p. 469-472
Topological Analysis of Metal–Organic Frameworks with Polytopic Linkers and/or Multiple Building Units and the Minimal Transitivity Principle
journal, November 2013
- Li, Mian; Li, Dan; O’Keeffe, Michael
- Chemical Reviews, Vol. 114, Issue 2
Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units
journal, February 2005
- Rosi, Nathaniel L.; Kim, Jaheon; Eddaoudi, Mohamed
- Journal of the American Chemical Society, Vol. 127, Issue 5, p. 1504-1518
Applied Topological Analysis of Crystal Structures with the Program Package ToposPro
journal, May 2014
- Blatov, Vladislav A.; Shevchenko, Alexander P.; Proserpio, Davide M.
- Crystal Growth & Design, Vol. 14, Issue 7
Room-Temperature and Solution-State Observation of the Mixed-Valence Cation Radical Dimer of Tetrathiafulvalene, [(TTF) 2 ] +• , within a Self-Assembled Cage
journal, October 2005
- Yoshizawa, Michito; Kumazawa, Kazuhisa; Fujita, Makoto
- Journal of the American Chemical Society, Vol. 127, Issue 39
Cu 3 (hexaiminotriphenylene) 2 : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing
journal, February 2015
- Campbell, Michael G.; Sheberla, Dennis; Liu, Sophie F.
- Angewandte Chemie International Edition, Vol. 54, Issue 14
A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation
journal, January 2006
- Cho, So-Hye; Ma, Baoqing; Nguyen, SonBinh T.
- Chem. Commun., Vol. 0, Issue 24, p. 2563-2565
Structures of Metal–Organic Frameworks with Rod Secondary Building Units
journal, September 2016
- Schoedel, Alexander; Li, Mian; Li, Dan
- Chemical Reviews, Vol. 116, Issue 19
Electron delocalization and charge mobility as a function of reduction in a metal–organic framework
journal, June 2018
- Aubrey, Michael L.; Wiers, Brian M.; Andrews, Sean C.
- Nature Materials, Vol. 17, Issue 7
Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks
journal, March 2005
- Ockwig, Nathan W.; Delgado-Friedrichs, Olaf; O'Keeffe, Michael
- Accounts of Chemical Research, Vol. 38, Issue 3, p. 176-182
Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials
journal, January 2009
- Nelson, Andrew P.; Farha, Omar K.; Mulfort, Karen L.
- Journal of the American Chemical Society, Vol. 131, Issue 2, p. 458-460
Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
journal, February 2013
- Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.
- Nature, Vol. 495, Issue 7439, p. 80-84
Inside Cover: A Rotational BODIPY Nucleotide: An Environment-Sensitive Fluorescence-Lifetime Probe for DNA Interactions and Applications in Live-Cell Microscopy (Angew. Chem. Int. Ed. 1/2016)
journal, December 2015
- Dziuba, Dmytro; Jurkiewicz, Piotr; Cebecauer, Marek
- Angewandte Chemie International Edition, Vol. 55, Issue 1
Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd 2 (TTFTB) as a Case Study
journal, October 2016
- Sun, Lei; Park, Sarah S.; Sheberla, Dennis
- Journal of the American Chemical Society, Vol. 138, Issue 44
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012
- Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
- Angewandte Chemie International Edition, Vol. 51, Issue 41