Computational Screening of Cathode Coatings for Solid-State Batteries
Abstract
Solid-state batteries are on the roadmap for commercialization as the next generation of batteries because of their potential for improved safety, power density, and energy density compared with conventional Li-ion batteries. However, the interfacial reactivity and resulting resistance between the cathode and solid-state electrolyte (SSE) lead to deterioration of cell performance. Although reduction of the cathode/SSE interfacial impedance can be achieved using cathode coatings, optimizing their compositions remains a challenge. In this work, we employ a computational framework to evaluate and screen Li-containing materials as cathode coatings, focusing on their phase stability, electrochemical and chemical stability, and ionic conductivity. From this tiered screening, polyanionic oxide coatings were identified as exhibiting optimal properties, with LiH2PO4, LiTi2(PO4)3, and LiPO3 being particularly appealing candidates. Some lithium borates exhibiting excellent (electro)chemical stability at various interfaces are also highlighted. These results highlight the promise of using optimized polyanionic materials as cathode coatings for solid-state batteries.
- Authors:
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; National Science Foundation (NSF); Samsung Advanced Inst. of Technology
- OSTI Identifier:
- 1547598
- Alternate Identifier(s):
- OSTI ID: 1765551
- Grant/Contract Number:
- AC02-05CH11231; ACI-1548562; KC23MP
- Resource Type:
- Published Article
- Journal Name:
- Joule
- Additional Journal Information:
- Journal Name: Joule Journal Volume: 3 Journal Issue: 5; Journal ID: ISSN 2542-4351
- Publisher:
- Elsevier - Cell Press
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; solid-state batteries; electrode/electrolyte interfaces; interfacial resistance; cathode coatings; polyanionic oxides; first-principles calculations; high-throughput screening; electrochemical stability; chemical stability; ionic conductivity
Citation Formats
Xiao, Yihan, Miara, Lincoln J., Wang, Yan, and Ceder, Gerbrand. Computational Screening of Cathode Coatings for Solid-State Batteries. United States: N. p., 2019.
Web. doi:10.1016/j.joule.2019.02.006.
Xiao, Yihan, Miara, Lincoln J., Wang, Yan, & Ceder, Gerbrand. Computational Screening of Cathode Coatings for Solid-State Batteries. United States. https://doi.org/10.1016/j.joule.2019.02.006
Xiao, Yihan, Miara, Lincoln J., Wang, Yan, and Ceder, Gerbrand. Wed .
"Computational Screening of Cathode Coatings for Solid-State Batteries". United States. https://doi.org/10.1016/j.joule.2019.02.006.
@article{osti_1547598,
title = {Computational Screening of Cathode Coatings for Solid-State Batteries},
author = {Xiao, Yihan and Miara, Lincoln J. and Wang, Yan and Ceder, Gerbrand},
abstractNote = {Solid-state batteries are on the roadmap for commercialization as the next generation of batteries because of their potential for improved safety, power density, and energy density compared with conventional Li-ion batteries. However, the interfacial reactivity and resulting resistance between the cathode and solid-state electrolyte (SSE) lead to deterioration of cell performance. Although reduction of the cathode/SSE interfacial impedance can be achieved using cathode coatings, optimizing their compositions remains a challenge. In this work, we employ a computational framework to evaluate and screen Li-containing materials as cathode coatings, focusing on their phase stability, electrochemical and chemical stability, and ionic conductivity. From this tiered screening, polyanionic oxide coatings were identified as exhibiting optimal properties, with LiH2PO4, LiTi2(PO4)3, and LiPO3 being particularly appealing candidates. Some lithium borates exhibiting excellent (electro)chemical stability at various interfaces are also highlighted. These results highlight the promise of using optimized polyanionic materials as cathode coatings for solid-state batteries.},
doi = {10.1016/j.joule.2019.02.006},
journal = {Joule},
number = 5,
volume = 3,
place = {United States},
year = {2019},
month = {5}
}
https://doi.org/10.1016/j.joule.2019.02.006
Web of Science
Works referenced in this record:
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Co-sinterable lithium garnet-type oxide electrolyte with cathode for all-solid-state lithium ion battery
journal, November 2014
- Ohta, Shingo; Seki, Juntaro; Yagi, Yusuke
- Journal of Power Sources, Vol. 265
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials
journal, May 2016
- Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander
- Nature Chemistry, Vol. 8, Issue 7
Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations
journal, October 2015
- Zhu, Yizhou; He, Xingfeng; Mo, Yifei
- ACS Applied Materials & Interfaces, Vol. 7, Issue 42
Effect of Co3(PO4)2 coating on Li[Co0.1Ni0.15Li0.2Mn0.55]O2 cathode material for lithium rechargeable batteries
journal, September 2008
- Lee, Sang Hyo; Koo, Bon Keup; Kim, Jin-Chul
- Journal of Power Sources, Vol. 184, Issue 1
Improvement of electrochemical performance of all-solid-state lithium secondary batteries by surface modification of LiMn2O4 positive electrode
journal, June 2011
- Kitaura, Hirokazu; Hayashi, Akitoshi; Tadanaga, Kiyoharu
- Solid State Ionics, Vol. 192, Issue 1
Thin Film Batteries with Li3PO4 Solid Electrolyte Fabricated by Pulsed Laser Deposition
journal, August 2009
- Kuwata, Naoaki; Iwagami, Naoya; Matsuda, Yasutaka
- ECS Transactions, Vol. 16, Issue 26
High lithium ionic conductivity in the garnet-type oxide Li7−XLa3(Zr2−X, NbX)O12 (X=0–2)
journal, March 2011
- Ohta, Shingo; Kobayashi, Tetsuro; Asaoka, Takahiko
- Journal of Power Sources, Vol. 196, Issue 6, p. 3342-3345
Effect of substitution (Ta, Al, Ga) on the conductivity of Li7La3Zr2O12
journal, May 2012
- Allen, J. L.; Wolfenstine, J.; Rangasamy, E.
- Journal of Power Sources, Vol. 206, p. 315-319
Progress and prospective of solid-state lithium batteries
journal, February 2013
- Takada, Kazunori
- Acta Materialia, Vol. 61, Issue 3, p. 759-770
Mastering the interface for advanced all-solid-state lithium rechargeable batteries
journal, November 2016
- Li, Yutao; Zhou, Weidong; Chen, Xi
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 47
Fast ion transport in oxide glasses
journal, July 1980
- Tuller, H. L.; Button, D. P.; Uhlmann, D. R.
- Journal of Non-Crystalline Solids, Vol. 40, Issue 1-3
Electrical and mechanical properties of hot-pressed versus sintered LiTi2(PO4)3
journal, June 2009
- Wolfenstine, J.; Allen, J. L.; Sumner, J.
- Solid State Ionics, Vol. 180, Issue 14-16
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
journal, January 1998
- Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.
- Physical Review B, Vol. 57, Issue 3, p. 1505-1509
First Principles Study of the Li10GeP2S12 Lithium Super Ionic Conductor Material
journal, December 2011
- Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand
- Chemistry of Materials, Vol. 24, Issue 1, p. 15-17
A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride
journal, January 1997
- Yu, Xiaohua; Bates, J. B.; Jellison, G. E.
- Journal of The Electrochemical Society, Vol. 144, Issue 2, p. 524-532
First-Principles Studies on Cation Dopants and Electrolyte|Cathode Interphases for Lithium Garnets
journal, May 2015
- Miara, Lincoln J.; Richards, William Davidson; Wang, Yan E.
- Chemistry of Materials, Vol. 27, Issue 11
New developments in the Inorganic Crystal Structure Database (ICSD): accessibility in support of materials research and design
journal, May 2002
- Belsky, Alec; Hellenbrandt, Mariette; Karen, Vicky Lynn
- Acta Crystallographica Section B Structural Science, Vol. 58, Issue 3
Li 3 BO 3 –Li 2 CO 3 : Rationally Designed Buffering Phase for Sulfide All-Solid-State Li-Ion Batteries
journal, October 2018
- Jung, Sung Hoo; Oh, Kyungbae; Nam, Young Jin
- Chemistry of Materials, Vol. 30, Issue 22
The effects of LiTi 2 (PO 4 ) 3 modification on the performance of spherical Li 1.5 Ni 0.25 Mn 0.75 O 2+δ cathode material
journal, January 2016
- Wang, Gang; Wang, Xianyou; Yi, Liling
- RSC Advances, Vol. 6, Issue 52
Lithium mobility in titanium based Nasicon Li1+xTi2−xAlx(PO4)3 and LiTi2−x Zrx(PO4)3 materials followed by NMR and impedance spectroscopy
journal, January 2007
- Arbi, K.; Rojo, J. M.; Sanz, J.
- Journal of the European Ceramic Society, Vol. 27, Issue 13-15
First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries
journal, January 2016
- Zhu, Yizhou; He, Xingfeng; Mo, Yifei
- Journal of Materials Chemistry A, Vol. 4, Issue 9
Fast ionic lithium conduction in solid lithium nitride chloride
journal, April 1979
- Hartwig, P.; Weppner, W.; Wichelhaus, W.
- Materials Research Bulletin, Vol. 14, Issue 4
A climbing image nudged elastic band method for finding saddle points and minimum energy paths
journal, December 2000
- Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes
- The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904
A new ultrafast superionic Li-conductor: ion dynamics in Li 11 Si 2 PS 12 and comparison with other tetragonal LGPS-type electrolytes
journal, January 2014
- Kuhn, Alexander; Gerbig, Oliver; Zhu, Changbao
- Phys. Chem. Chem. Phys., Vol. 16, Issue 28
High Rate Micron-Sized Ordered LiNi[sub 0.5]Mn[sub 1.5]O[sub 4]
journal, January 2010
- Ma, Xiaohua; Kang, Byoungwoo; Ceder, Gerbrand
- Journal of The Electrochemical Society, Vol. 157, Issue 8
Enhanced electrochemical properties of LiNi1/3Co1/3Mn1/3O2 cathode material by coating with LiAlO2 nanoparticles
journal, October 2006
- Kim, Hyun-Soo; Kim, Youngsik; Kim, Seong-Il
- Journal of Power Sources, Vol. 161, Issue 1
Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries
journal, January 2007
- Lee, Hyunjung; Kim, Min Gyu; Cho, Jaephil
- Electrochemistry Communications, Vol. 9, Issue 1
The Detrimental Effects of Carbon Additives in Li 10 GeP 2 S 12 -Based Solid-State Batteries
journal, October 2017
- Zhang, Wenbo; Leichtweiß, Thomas; Culver, Sean P.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 41
Nickel sulfide synthesized by ball milling as an attractive cathode material for rechargeable lithium batteries
journal, March 2003
- Han, Sang-Cheol; Kim, Hyun-Seok; Song, Min-Sang
- Journal of Alloys and Compounds, Vol. 351, Issue 1-2
Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12
journal, October 2007
- Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner
- Angewandte Chemie International Edition, Vol. 46, Issue 41, p. 7778-7781
Monolithic All-Phosphate Solid-State Lithium-Ion Battery with Improved Interfacial Compatibility
journal, June 2018
- Yu, Shicheng; Mertens, Andreas; Tempel, Hermann
- ACS Applied Materials & Interfaces, Vol. 10, Issue 26
Equations for transport in solid oxides and sulfides of transition metals
journal, January 1975
- Wagner, C.
- Progress in Solid State Chemistry, Vol. 10
Fabrication of High-Voltage, High-Capacity All-Solid-State Lithium Polymer Secondary Batteries by Application of the Polymer Electrolyte/Inorganic Electrolyte Composite Concept
journal, April 2005
- Seki, Shiro; Kobayashi, Yo; Miyashiro, Hajime
- Chemistry of Materials, Vol. 17, Issue 8, p. 2041-2045
Localization of vacancies and mobility of lithium ions in Li2ZrO3 as obtained by 6,7Li NMR
journal, December 2013
- Baklanova, Ya. V.; Arapova, I. Yu.; Buzlukov, A. L.
- Journal of Solid State Chemistry, Vol. 208
Understanding the Anomalous Capacity of Li / Li [ NixLi ( 1 / 3 − 2x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O2 Cells Using In Situ X-Ray Diffraction and Electrochemical Studies
journal, January 2002
- Lu, Zhonghua; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 149, Issue 7, p. A815-A822
Compatibility issues between electrodes and electrolytes in solid-state batteries
journal, January 2017
- Tian, Yaosen; Shi, Tan; Richards, William D.
- Energy & Environmental Science, Vol. 10, Issue 5
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Preparation and electrochemical properties of LiAlO 2 -coated Li(Ni 1/3 Mn 1/3 Co 1/3 )O 2 for all-solid-state batteries
journal, February 2014
- Okada, Kazuya; Machida, Nobuya; Naito, Muneyuki
- Solid State Ionics, Vol. 255
Holistic computational structure screening of more than 12 000 candidates for solid lithium-ion conductor materials
journal, January 2017
- Sendek, Austin D.; Yang, Qian; Cubuk, Ekin D.
- Energy & Environmental Science, Vol. 10, Issue 1
Ionic conductivity of quenched alkali niobate and tantalate glasses
journal, September 1978
- Glass, A. M.; Nassau, K.; Negran, T. J.
- Journal of Applied Physics, Vol. 49, Issue 9
Ionic Conduction in Phosphate Glasses
journal, August 1991
- Martin, Steve W.
- Journal of the American Ceramic Society, Vol. 74, Issue 8
The crystal structure, thermal behaviour and ionic conductivity of a novel lithium gadolinium polyphosphate LiGd(PO3)4
journal, October 2006
- Ettis, Hasna; Naïli, Houcine; Mhiri, Tahar
- Journal of Solid State Chemistry, Vol. 179, Issue 10
Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries
journal, September 2018
- Asano, Tetsuya; Sakai, Akihiro; Ouchi, Satoru
- Advanced Materials, Vol. 30, Issue 44
Band theory and Mott insulators: Hubbard U instead of Stoner I
journal, July 1991
- Anisimov, Vladimir I.; Zaanen, Jan; Andersen, Ole K.
- Physical Review B, Vol. 44, Issue 3, p. 943-954
About the Compatibility between High Voltage Spinel Cathode Materials and Solid Oxide Electrolytes as a Function of Temperature
journal, September 2016
- Miara, Lincoln; Windmüller, Anna; Tsai, Chih-Long
- ACS Applied Materials & Interfaces, Vol. 8, Issue 40
Enhancing the Lithium Ion Conductivity in Lithium Superionic Conductor (LISICON) Solid Electrolytes through a Mixed Polyanion Effect
journal, February 2017
- Deng, Yue; Eames, Christopher; Fleutot, Benoit
- ACS Applied Materials & Interfaces, Vol. 9, Issue 8
Lithium ion conduction in lithium metaphosphate based systems
journal, May 2007
- Money, B. K.; Hariharan, K.
- Applied Physics A, Vol. 88, Issue 4
Empowering the Lithium Metal Battery through a Silicon-Based Superionic Conductor
journal, January 2014
- Whiteley, Justin M.; Woo, Jae H.; Hu, Enyuan
- Journal of The Electrochemical Society, Vol. 161, Issue 12
High-throughput computational design of cathode coatings for Li-ion batteries
journal, December 2016
- Aykol, Muratahan; Kim, Soo; Hegde, Vinay I.
- Nature Communications, Vol. 7, Issue 1
Phase stability, electrochemical stability and ionic conductivity of the Li 10±1 MP 2 X 12 (M = Ge, Si, Sn, Al or P, and X = O, S or Se) family of superionic conductors
journal, January 2013
- Ong, Shyue Ping; Mo, Yifei; Richards, William Davidson
- Energy Environ. Sci., Vol. 6, Issue 1
AC and DC conductivity study of LiH2PO4 compound using impedance spectroscopy
journal, November 2017
- Rhimi, T.; Leroy, G.; Duponchel, B.
- Ionics, Vol. 24, Issue 5
High catalytic activity and stability of nickel sulfide and cobalt sulfide hierarchical nanospheres on the counter electrodes for dye-sensitized solar cells
journal, January 2014
- Yang, Jie; Bao, Chunxiong; Zhu, Kai
- Chem. Commun., Vol. 50, Issue 37
Ionic Conductivity of Solid Electrolytes Based on Lithium Titanium Phosphate
journal, January 1990
- Aono, Hiromichi
- Journal of The Electrochemical Society, Vol. 137, Issue 4
Finding Nature’s Missing Ternary Oxide Compounds Using Machine Learning and Density Functional Theory
journal, June 2010
- Hautier, Geoffroy; Fischer, Christopher C.; Jain, Anubhav
- Chemistry of Materials, Vol. 22, Issue 12
Improvement of High-Rate Performance of All-Solid-State Lithium Secondary Batteries Using LiCoO[sub 2] Coated with Li[sub 2]O–SiO[sub 2] Glasses
journal, January 2008
- Sakuda, Atsushi; Kitaura, Hirokazu; Hayashi, Akitoshi
- Electrochemical and Solid-State Letters, Vol. 11, Issue 1
Python Materials Genomics (pymatgen): A robust, open-source python library for materials analysis
journal, February 2013
- Ong, Shyue Ping; Richards, William Davidson; Jain, Anubhav
- Computational Materials Science, Vol. 68
Probing Solid–Solid Interfacial Reactions in All-Solid-State Sodium-Ion Batteries with First-Principles Calculations
journal, December 2017
- Tang, Hanmei; Deng, Zhi; Lin, Zhuonan
- Chemistry of Materials, Vol. 30, Issue 1
Lithium mobility in the NASICON-type compound by nuclear magnetic resonance and impedance spectroscopies
journal, July 1996
- París, Miguel A.; Martínez-Juárez, Ana; Rojo, José M.
- Journal of Physics: Condensed Matter, Vol. 8, Issue 29
Role of Point Defects in Spinel Mg Chalcogenide Conductors
journal, November 2017
- Canepa, Pieremanuele; Sai Gautam, Gopalakrishnan; Broberg, Danny
- Chemistry of Materials, Vol. 29, Issue 22
Negating interfacial impedance in garnet-based solid-state Li metal batteries
journal, December 2016
- Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin)
- Nature Materials, Vol. 16, Issue 5
A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries
journal, January 2014
- Seino, Yoshikatsu; Ota, Tsuyoshi; Takada, Kazunori
- Energy Environ. Sci., Vol. 7, Issue 2
Modeling Li-ion conductivity in LiLa(PO3)4 powder
journal, July 2012
- Mounir, Ferhi; Karima, Horchani-Naifer; Khaled, Ben Saad
- Physica B: Condensed Matter, Vol. 407, Issue 13
Ion transport in sodium ion conducting solid electrolytes
journal, October 2012
- Fergus, Jeffrey W.
- Solid State Ionics, Vol. 227
Phosphates as Lithium-Ion Battery Cathodes: An Evaluation Based on High-Throughput ab Initio Calculations
journal, August 2011
- Hautier, Geoffroy; Jain, Anubhav; Ong, Shyue Ping
- Chemistry of Materials, Vol. 23, Issue 15
A rocking chair type all-solid-state lithium ion battery adopting Li2O–ZrO2 coated LiNi0.8Co0.15Al0.05O2 and a sulfide based electrolyte
journal, February 2014
- Ito, Seitaro; Fujiki, Satoshi; Yamada, Takanobu
- Journal of Power Sources, Vol. 248
FireWorks: a dynamic workflow system designed for high-throughput applications: FireWorks: A Dynamic Workflow System Designed for High-Throughput Applications
journal, May 2015
- Jain, Anubhav; Ong, Shyue Ping; Chen, Wei
- Concurrency and Computation: Practice and Experience, Vol. 27, Issue 17
Li 10 SnP 2 S 12 : An Affordable Lithium Superionic Conductor
journal, October 2013
- Bron, Philipp; Johansson, Sebastian; Zick, Klaus
- Journal of the American Chemical Society, Vol. 135, Issue 42
Intrinsic concentration, effective densities of states, and effective mass in silicon
journal, March 1990
- Green, Martin A.
- Journal of Applied Physics, Vol. 67, Issue 6
A lithium superionic conductor
journal, July 2011
- Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
- Nature Materials, Vol. 10, Issue 9, p. 682-686
Etude des propriétés de conduction électrique des polyphosphates: Li3Ba2(PO3)7, LiPb2(PO3)5, LiCs(PO3)2, et αLiK(PO3)2
journal, February 1991
- El Horr, N.; Hammou, A.; Bagieu, M.
- Journal of Solid State Chemistry, Vol. 90, Issue 2
Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O5
journal, December 1997
- Fu, J.
- Solid State Ionics, Vol. 104, Issue 3-4
Structure, ionic conductivity and phase transformation of double chloride spinels
journal, September 1988
- Kanno, R.
- Solid State Ionics, Vol. 28-30
Growth of self-textured Ga 3+ -substituted Li 7 La 3 Zr 2 O 12 ceramics by solid state reaction and their significant enhancement in ionic conductivity
journal, March 2018
- Qin, Shiying; Zhu, Xiaohong; Jiang, Yue
- Applied Physics Letters, Vol. 112, Issue 11
Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification
journal, September 2006
- Ohta, N.; Takada, K.; Zhang, L.
- Advanced Materials, Vol. 18, Issue 17, p. 2226-2229
Density functional theory and the band gap problem
journal, March 1985
- Perdew, John P.
- International Journal of Quantum Chemistry, Vol. 28, Issue S19
High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016
- Kato, Yuki; Hori, Satoshi; Saito, Toshiya
- Nature Energy, Vol. 1, Issue 4
First-principles study of native point defects in ZnO
journal, June 2000
- Kohan, A. F.; Ceder, G.; Morgan, D.
- Physical Review B, Vol. 61, Issue 22
Interface reactions between LiPON and lithium studied by in-situ X-ray photoemission
journal, May 2015
- Schwöbel, André; Hausbrand, René; Jaegermann, Wolfram
- Solid State Ionics, Vol. 273
Effect of Structure on the Fe[sup 3+]∕Fe[sup 2+] Redox Couple in Iron Phosphates
journal, January 1997
- Padhi, A. K.
- Journal of The Electrochemical Society, Vol. 144, Issue 5
Influence of sputtering conditions on ionic conductivity of LiPON thin films
journal, January 2006
- Hamon, Y.; Douard, A.; Sabary, F.
- Solid State Ionics, Vol. 177, Issue 3-4
Investigation on the interface between Li10GeP2S12 electrolyte and carbon conductive agents in all-solid-state lithium battery
journal, May 2018
- Yoon, Kyungho; Kim, Jung-Joon; Seong, Won Mo
- Scientific Reports, Vol. 8, Issue 1
Electrochemical Stability of Li 10 GeP 2 S 12 and Li 7 La 3 Zr 2 O 12 Solid Electrolytes
journal, January 2016
- Han, Fudong; Zhu, Yizhou; He, Xingfeng
- Advanced Energy Materials, Vol. 6, Issue 8
Chloride spinels: A new group of solid lithium electrolytes
journal, January 1981
- Lutz, H. D.; Schmidt, W.; Haeuseler, H.
- Journal of Physics and Chemistry of Solids, Vol. 42, Issue 4
Structural and Electronic-State Changes of a Sulfide Solid Electrolyte during the Li Deinsertion–Insertion Processes
journal, May 2017
- Hakari, Takashi; Deguchi, Minako; Mitsuhara, Kei
- Chemistry of Materials, Vol. 29, Issue 11
Interfacial modification for high-power solid-state lithium batteries
journal, September 2008
- Takada, Kazunori; Ohta, Narumi; Zhang, Lianqi
- Solid State Ionics, Vol. 179, Issue 27-32
Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment
journal, April 2009
- Kang, Sun-Ho; Thackeray, Michael M.
- Electrochemistry Communications, Vol. 11, Issue 4, p. 748-751
Bottle-necked ionic transport in Li 2 ZrO 3 : high temperature neutron diffraction and impedance spectroscopy
journal, August 2016
- Sherstobitova, E. A.; Gubkin, A. F.; Bobrikov, I. A.
- Electrochimica Acta, Vol. 209
Interfacial phenomena in solid-state lithium battery with sulfide solid electrolyte
journal, October 2012
- Takada, Kazunori; Ohta, Narumi; Zhang, Lianqi
- Solid State Ionics, Vol. 225
Optimization of NASICON composition for Na+ recognition
journal, May 1997
- Khireddine, H.; Fabry, P.; Caneiro, A.
- Sensors and Actuators B: Chemical, Vol. 40, Issue 2-3
Characterization of Electronic and Ionic Transport in Li 1- x Ni 0.33 Mn 0.33 Co 0.33 O 2 (NMC 333 ) and Li 1- x Ni 0.50 Mn 0.20 Co 0.30 O 2 (NMC 523 ) as a Function of Li Content
journal, January 2016
- Amin, Ruhul; Chiang, Yet-Ming
- Journal of The Electrochemical Society, Vol. 163, Issue 8
Insights into the Performance Limits of the Li 7 P 3 S 11 Superionic Conductor: A Combined First-Principles and Experimental Study
journal, March 2016
- Chu, Iek-Heng; Nguyen, Han; Hy, Sunny
- ACS Applied Materials & Interfaces, Vol. 8, Issue 12
A perspective on the high-voltage LiMn1.5Ni0.5O4 spinel cathode for lithium-ion batteries
journal, January 2014
- Manthiram, Arumugam; Chemelewski, Katharine; Lee, Eun-Sung
- Energy & Environmental Science, Vol. 7, Issue 4
All-solid-state lithium battery with LiBH4 solid electrolyte
journal, March 2013
- Takahashi, Kuniaki; Hattori, Kazuto; Yamazaki, Toshihiro
- Journal of Power Sources, Vol. 226
Interfacial Observation between LiCoO 2 Electrode and Li 2 S−P 2 S 5 Solid Electrolytes of All-Solid-State Lithium Secondary Batteries Using Transmission Electron Microscopy †
journal, February 2010
- Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Chemistry of Materials, Vol. 22, Issue 3
High performance LiNi 0.5 Mn 1.5 O 4 cathode material with a bi-functional coating for lithium ion batteries
journal, January 2016
- Chong, Jin; Zhang, Jingping; Xie, Haiming
- RSC Advances, Vol. 6, Issue 23
In-situ Li7La3Zr2O12/LiCoO2 interface modification for advanced all-solid-state battery
journal, August 2014
- Kato, Takehisa; Hamanaka, Tadashi; Yamamoto, Kazuo
- Journal of Power Sources, Vol. 260
Preparation and ionic conductivities of (100 − x)(0.75Li2S·0.25P2S5)·xLiBH4 glass electrolytes
journal, December 2013
- Yamauchi, Akihiro; Sakuda, Atsushi; Hayashi, Akitoshi
- Journal of Power Sources, Vol. 244
The electronic structure and band gap of LiFePO4 and LiMnPO4
journal, October 2004
- Zhou, Fei; Kang, Kisuk; Maxisch, Thomas
- Solid State Communications, Vol. 132, Issue 3-4
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013
- Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
- APL Materials, Vol. 1, Issue 1
Formation enthalpies by mixing GGA and GGA calculations
journal, July 2011
- Jain, Anubhav; Hautier, Geoffroy; Ong, Shyue Ping
- Physical Review B, Vol. 84, Issue 4
Capacity Fade in Solid-State Batteries: Interphase Formation and Chemomechanical Processes in Nickel-Rich Layered Oxide Cathodes and Lithium Thiophosphate Solid Electrolytes
journal, June 2017
- Koerver, Raimund; Aygün, Isabel; Leichtweiß, Thomas
- Chemistry of Materials, Vol. 29, Issue 13
LiNbO3-coated LiCoO2 as cathode material for all solid-state lithium secondary batteries
journal, July 2007
- Ohta, Narumi; Takada, Kazunori; Sakaguchi, Isao
- Electrochemistry Communications, Vol. 9, Issue 7
Relationship between Activation Energy and Bottleneck Size for Li + Ion Conduction in NASICON Materials of Composition LiMM‘(PO 4 ) 3 ; M, M‘ = Ge, Ti, Sn, Hf
journal, January 1998
- Martínez-Juárez, Ana; Pecharromán, Carlos; Iglesias, Juan E.
- The Journal of Physical Chemistry B, Vol. 102, Issue 2
Interface Stability in Solid-State Batteries
journal, December 2015
- Richards, William D.; Miara, Lincoln J.; Wang, Yan
- Chemistry of Materials, Vol. 28, Issue 1
Characterization of the interface between LiCoO2 and Li7La3Zr2O12 in an all-solid-state rechargeable lithium battery
journal, January 2011
- Kim, Ki Hyun; Iriyama, Yasutoshi; Yamamoto, Kazuo
- Journal of Power Sources, Vol. 196, Issue 2
Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries
journal, January 2018
- Fan, Lei; Wei, Shuya; Li, Siyuan
- Advanced Energy Materials, Vol. 8, Issue 11
Electrolytes for solid-state lithium rechargeable batteries: recent advances and perspectives
journal, January 2011
- Quartarone, Eliana; Mustarelli, Piercarlo
- Chemical Society Reviews, Vol. 40, Issue 5
Works referencing / citing this record:
Ni‐Rich Layered Cathode Materials with Electrochemo‐Mechanically Compliant Microstructures for All‐Solid‐State Li Batteries
journal, December 2019
- Jung, Sung Hoo; Kim, Un‐Hyuck; Kim, Jae‐Hyung
- Advanced Energy Materials, Vol. 10, Issue 6
Enabling a Durable Electrochemical Interface via an Artificial Amorphous Cathode Electrolyte Interphase for Hybrid Solid/Liquid Lithium‐Metal Batteries
journal, February 2020
- Liang, Jia‐Yan; Zhang, Xu‐Dong; Zeng, Xian‐Xiang
- Angewandte Chemie, Vol. 132, Issue 16
First Principle Material Genome Approach for All Solid‐State Batteries
journal, September 2019
- Xu, Hongjie; Yu, Yuran; Wang, Zhuo
- ENERGY & ENVIRONMENTAL MATERIALS, Vol. 2, Issue 4
Computational screening of anode materials for potassium‐ion batteries
journal, August 2019
- Yu, Seungho; Kim, Sang‐Ok; Kim, Hyung‐Seok
- International Journal of Energy Research
Free-standing transition metal oxide electrode architectures for electrochemical energy storage
journal, July 2019
- Spencer, Michael A.; Augustyn, Veronica
- Journal of Materials Science, Vol. 54, Issue 20
High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes
journal, March 2020
- Lee, Yong-Gun; Fujiki, Satoshi; Jung, Changhoon
- Nature Energy, Vol. 5, Issue 4
Understanding interface stability in solid-state batteries
journal, December 2019
- Xiao, Yihan; Wang, Yan; Bo, Shou-Hang
- Nature Reviews Materials, Vol. 5, Issue 2
Nanomechanical elasticity and fracture studies of lithium phosphate (LPO) and lithium tantalate (LTO) solid-state electrolytes
journal, January 2019
- Amirmaleki, Maedeh; Cao, Changhong; Wang, Biqiong
- Nanoscale, Vol. 11, Issue 40
Understanding the effects of chemical reactions at the cathode–electrolyte interface in sulfide based all-solid-state batteries
journal, January 2019
- Jung, Sung-Kyun; Gwon, Hyeokjo; Lee, Seok-Soo
- Journal of Materials Chemistry A, Vol. 7, Issue 40
Decoration by dual-phase Li 2 ZrO 3 islands with core–shell structures enhances the electrochemical performance of high-voltage LiNi 0.5 Mn 1.5 O 4
journal, January 2020
- Zhao, R.; Li, L.; Li, Y. P.
- Applied Physics Letters, Vol. 116, Issue 2