Development of Molybdenum Phosphide Catalysts for Higher Alcohol Synthesis from Syngas by Exploiting Support and Promoter Effects

ten Have, Iris C.; Valle, Eduardo; Gallo, Alessandro; Snider, Jonathan L.; Duyar, Melis S.; Jaramillo, Thomas F.

doi:10.1002/ente.201801102

Title: Development of Molybdenum Phosphide Catalysts for Higher Alcohol Synthesis from Syngas by Exploiting Support and Promoter Effects

Journal Article · 05 February 2019 · Energy Technology

DOI: https://doi.org/10.1002/ente.201801102 · OSTI ID:1547286

^[1]; Valle, Eduardo ^[2];

^[2]; Snider, Jonathan L. ^[2];

^[2]; Jaramillo, Thomas F. ^[2]

Stanford Univ., CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States); Univ. of Utrecht (Netherlands)
Stanford Univ., CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Molybdenum phosphide (MoP) catalysts have recently attracted attention due to their robust methanol synthesis activity from CO/CO ₂ . Synthesis strategies are used to steer MoP selectivity toward higher alcohols by investigating the promotion effects of alkali (K) and CO‐dissociating (Co, Ni) and non‐CO‐dissociating (Pd) metals. A systematic study with transmission electron microscopy, X‐ray diffraction, X‐ray photoelectron spectroscopy, and X‐ray absorption spectroscopy (XAS) showed that critical parameters governing the activity of MoP catalysts are P/Mo ratio and K loading, both facilitating MoP formation. The kinetic studies of mesoporous silica‐supported MoP catalysts show a twofold role of K, which also acts as an electronic promoter by increasing the total alcohol selectivity and chain length. Palladium (Pd) increases CO conversion, but decreases alcohol chain length. The use of mesoporous carbon (MC) support has the most significant effect on catalyst performance and yields a KMoP/MC catalyst that ranks among the state‐of‐the‐art in terms of selectivity to higher alcohols.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE; National Science Foundation (NSF)

Grant/Contract Number:: AC02-76SF00515; ECCS-1542152

OSTI ID:: 1547286

Alternate ID(s):: OSTI ID: 1506724

Journal Information:: Energy Technology, Vol. 7, Issue 5; ISSN 2194-4288

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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