Deca-B-fluorination of diammonioboranes. Structures and NMR characterization of 1,2-, 1,7-, and 1,12-B12H10(NH3)2 and 1,2-, 1,7-, and 1,12-B12F10(NH3)2

Pluntze, Amanda M.; Bukovsky, Eric V.; Lacroix, Matthew R.; Newell, Brian S.; Rithner, Christopher D.; Strauss, Steven H.

doi:10.1016/j.jfluchem.2018.01.014

Title: Deca-B-fluorination of diammonioboranes. Structures and NMR characterization of 1,2-, 1,7-, and 1,12-B12H10(NH3)2 and 1,2-, 1,7-, and 1,12-B12F10(NH3)2

Full Record
Other Related Research

Authors:: Pluntze, Amanda M.; Bukovsky, Eric V.; Lacroix, Matthew R.; Newell, Brian S.; Rithner, Christopher D.; Strauss, Steven H.

Publication Date:: 2018-05-01

Sponsoring Org.:: USDOE

OSTI Identifier:: 1547120

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Fluorine Chemistry

Additional Journal Information:: Journal Name: Journal of Fluorine Chemistry Journal Volume: 209 Journal Issue: C; Journal ID: ISSN 0022-1139

Publisher:: Elsevier

Country of Publication:: Switzerland

Language:: English

Citation Formats


                    Pluntze, Amanda M., Bukovsky, Eric V., Lacroix, Matthew R., Newell, Brian S., Rithner, Christopher D., and Strauss, Steven H. Deca-B-fluorination of diammonioboranes. Structures and NMR characterization of 1,2-, 1,7-, and 1,12-B12H10(NH3)2 and 1,2-, 1,7-, and 1,12-B12F10(NH3)2.  Switzerland: N. p., 2018. 
Web.  https://doi.org/10.1016/j.jfluchem.2018.01.014.

Copy to clipboard


                    Pluntze, Amanda M., Bukovsky, Eric V., Lacroix, Matthew R., Newell, Brian S., Rithner, Christopher D., & Strauss, Steven H. Deca-B-fluorination of diammonioboranes. Structures and NMR characterization of 1,2-, 1,7-, and 1,12-B12H10(NH3)2 and 1,2-, 1,7-, and 1,12-B12F10(NH3)2.  Switzerland.  https://doi.org/10.1016/j.jfluchem.2018.01.014

Copy to clipboard


                    Pluntze, Amanda M., Bukovsky, Eric V., Lacroix, Matthew R., Newell, Brian S., Rithner, Christopher D., and Strauss, Steven H. Tue .  
"Deca-B-fluorination of diammonioboranes. Structures and NMR characterization of 1,2-, 1,7-, and 1,12-B12H10(NH3)2 and 1,2-, 1,7-, and 1,12-B12F10(NH3)2".  Switzerland.  https://doi.org/10.1016/j.jfluchem.2018.01.014.

Copy to clipboard


                    
@article{osti_1547120,

  title        = {Deca-B-fluorination of diammonioboranes. Structures and NMR characterization of 1,2-, 1,7-, and 1,12-B12H10(NH3)2 and 1,2-, 1,7-, and 1,12-B12F10(NH3)2},

  author       = {Pluntze, Amanda M. and Bukovsky, Eric V. and Lacroix, Matthew R. and Newell, Brian S. and Rithner, Christopher D. and Strauss, Steven H.},

  abstractNote = {},

  doi          = {10.1016/j.jfluchem.2018.01.014},

  journal      = {Journal of Fluorine Chemistry},

  number       = C,

  volume       = 209,

  place        = {Switzerland},

  year         = {2018},

  month        = {5}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.jfluchem.2018.01.014

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 2 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Deca-B-fluorination of diammonioboranes. Structures and NMR characterization of 1,2-, 1,7-, and 1,12-B₁₂H₁₀(NH₃)₂ and 1,2-, 1,7-, and 1,12-B₁₂F₁₀(NH₃)₂

Journal Article Pluntze, Amanda M. ; Bukovsky, Eric V. ; Lacroix, Matthew R. ; ... - Journal of Fluorine Chemistry
https://doi.org/10.1016/j.jfluchem.2018.01.014
Synthesis and characterization of cationic technetium complexes of 1,2-bis(dimethylphosphino)ethane (DMPE): structure determinations of trans-(Tc/sup v/(DMPE)/sub 2/(OH)(O))(F/sub 3/CSO/sub 3/)/sub 2/, trans-(Tc/sup III/(DMPE)/sub 2/Cl/sub 2/)F/sub 3/CSO/sub 3/, and (Tc/sup I/(DMPE)/sub 3/)/sup +/ using x-ray diffraction, EXAFS, and /sup 99/Tc NMR

Journal Article Vanderheyden, J L ; Ketring, A R ; Libson, K ; ... - Inorg. Chem.; (United States)

Three distinct cationic complexes of technetium, containing Tc(V), Tc(III), and Tc(I) centers, have been prepared by reduction of pertechnetate with bis(1,2-dimethylphosphino)ethane (DMPE). Careful control of reaction conditions allows the synthesis of any one of three trans-complexes in greater than 90% yield. All complexes have been characterized by visible-, uv-, and ir-spectrophotometry, elemental analyses, and high-performance liquid chromatography. The Tc(I) complex has been additionally characterized by /sup 31/P and /sup 99/Tc NMR, as well as a new type of extended x-ray absorption fine structure analysis (EXAFS), which show that this is an octahedral species with a Tc-P bond length of 2.40A.more »« less
https://doi.org/10.1021/ic00188a031
Synthesis and characterization of nido-[1,1,2,2-(CO){sub 4}-1,2-(PPh{sub 3}){sub 2}-1,2-FeIrB{sub 2}H{sub 5}]: A heterobimetallaborane analogue of nido-[B{sub 4}H{sub 7}]{sup -}

Journal Article Bould, J ; Rath, N P ; Barton, L - Inorganic Chemistry

The synthesis and characterization of nido-[1,1,2,2-(CO){sub 4}-1,2-(PPh{sub 3}){sub 2}-1,2-FeIrB{sub 2}H{sub 5}] (1) is reported. 1 is formed in low yield as a degradation product from the reaction between [({mu}-Fe(CO){sub 4})B{sub 6}H{sub 9}]{sup -} and trans-Ir(CO)Cl(PPh{sub 3}){sub 2} in THF and is characterized from NMR, IR, and analytical data and by a single-crystal X-ray diffraction study. 1 crystallizes in the monoclinic space group P2/n with a = 12.8622(12), b = 14.3313(12), c = 23.579(3) {angstrom}, {beta} = 97.12(2){degrees}, Z = 4, V = 4257.0(8) {angstrom}{sup 3}, R = 4.83%, and wR{sub 2}(F{sup 2}) = 12.43%. The heterobimetallaborane structure may be viewedmore »« less
https://doi.org/10.1021/ic950696a
Efficient direct fluorination of the B12H11(NH3)− anion in acetonitrile and comparison of the structures of Na(H2O)4(B12F11(NH3)), Na(H3O)(H2O)3(B12F12), and Na2(H2O)4(B12F12)

Journal Article Bukovsky, Eric V. ; Pluntze, Amanda M. ; Strauss, Steven H. - Journal of Fluorine Chemistry
Cited by 3
https://doi.org/10.1016/j.jfluchem.2017.06.006
Thiolato-technetium complexes. 1. Synthesis and characterization of bis(tertiary diphosphine)technetium(III) complexes containing methanethiolato ligands. Single-crystal structural analyses of trans-(Tc/sup III/(SCH/sub 3/)/sub 2/(DMPE)/sub 2/)CF/sub 3/SO/sub 3/ and trans-(Tc/sup III/(SCH/sub 3/)/sub 2/(DEPE)/sub 2/)PF/sub 6/, where DMPE = 1,2-bis(dimethylphosphino)ethane and DEPE = 1,2-bis(diethylphosphino)ethane

Journal Article Konno, T ; Heeg, M J ; Deutsch, E - Inorg. Chem.; (United States)

The Tc(III) methanethiolato complexes trans-(Tc(SCH/sub 3/)/sub 2/D/sub 2/)/sup +/, where D is either 1,2-bis(dimethylphosphino)ethane (DMPE) or 1,2-bis(diethylphosphino)ethane (DEPE), have been synthesized and characterized. Preparation of these complexes from (Tc/sup V/(O)(OH)D/sub 2/)/sup 2+/ utilizes excess NaSCH/sub 3/ as reductant and ligand. The x-ray crystal structures of both title complexes are examined, and the crystal parameters are reported. In both structures the Tc atom occupies an inversion center. The visible spectra of these trans-(Tc(SCH/sub 3/)/sub 2/D/sub 2/)/sup +/ complexes in acetonitrile show sulfur-technetium charge-transfer bands at 16,810 and 28,490 cm/sup /minus/1/ for D = DMPE and at 16,610 and 28,830 cm/sup /minus/1/more »« less
https://doi.org/10.1021/ic00296a008

Similar Records