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Title: Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro‐oxidation of Liquid Fuels

Authors:
ORCiD logo [1];  [2];  [1];  [3];  [1];  [4];  [4];  [3];  [2]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of ChemistryBrown University Providence RI 02912 USA
  2. Department of ChemistryGeorgetown University 37th and O Streets, NW Washington DC 20057 USA
  3. Center for Nanophase Materials Sciences DivisionOak Ridge National Laboratory Oak Ridge TN 37831 USA
  4. Department of ChemistryDalhousie University Halifax Nova Scotia B3H 4R2 Canada
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1546814
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 33; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Li, Junrui, Jilani, Safia Z., Lin, Honghong, Liu, Xiaoming, Wei, Kecheng, Jia, Yukai, Zhang, Peng, Chi, Miaofang, Tong, YuYe J., Xi, Zheng, and Sun, Shouheng. Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro‐oxidation of Liquid Fuels. Germany: N. p., 2019. Web. doi:10.1002/ange.201906137.
Li, Junrui, Jilani, Safia Z., Lin, Honghong, Liu, Xiaoming, Wei, Kecheng, Jia, Yukai, Zhang, Peng, Chi, Miaofang, Tong, YuYe J., Xi, Zheng, & Sun, Shouheng. Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro‐oxidation of Liquid Fuels. Germany. doi:10.1002/ange.201906137.
Li, Junrui, Jilani, Safia Z., Lin, Honghong, Liu, Xiaoming, Wei, Kecheng, Jia, Yukai, Zhang, Peng, Chi, Miaofang, Tong, YuYe J., Xi, Zheng, and Sun, Shouheng. Tue . "Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro‐oxidation of Liquid Fuels". Germany. doi:10.1002/ange.201906137.
@article{osti_1546814,
title = {Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro‐oxidation of Liquid Fuels},
author = {Li, Junrui and Jilani, Safia Z. and Lin, Honghong and Liu, Xiaoming and Wei, Kecheng and Jia, Yukai and Zhang, Peng and Chi, Miaofang and Tong, YuYe J. and Xi, Zheng and Sun, Shouheng},
abstractNote = {},
doi = {10.1002/ange.201906137},
journal = {Angewandte Chemie},
number = 33,
volume = 131,
place = {Germany},
year = {2019},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/ange.201906137

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Works referenced in this record:

Electro-oxidation of methanol and formic acid on PtRu and PtAu for direct liquid fuel cells
journal, December 2006


Alternative Polymer Systems for Proton Exchange Membranes (PEMs)
journal, October 2004

  • Hickner, Michael A.; Ghassemi, Hossein; Kim, Yu Seung
  • Chemical Reviews, Vol. 104, Issue 10
  • DOI: 10.1021/cr020711a

Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction
journal, January 2015

  • Scofield, Megan E.; Koenigsmann, Christopher; Wang, Lei
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE02162B

Composition Effects of FePt Alloy Nanoparticles on the Electro-Oxidation of Formic Acid
journal, October 2007

  • Chen, Wei; Kim, Jaemin; Sun, Shouheng
  • Langmuir, Vol. 23, Issue 22
  • DOI: 10.1021/la7016648

How a gold substrate can increase the reactivity of a Pt overlayer
journal, May 1999


Golden single-atomic-site platinum electrocatalysts
journal, September 2018


Pt-Rich core /Sn-Rich subsurface /Pt skin Nanocubes As Highly Active and Stable Electrocatalysts for the Ethanol Oxidation Reaction
journal, February 2018

  • Rizo, Rubén; Arán-Ais, Rosa M.; Padgett, Elliot
  • Journal of the American Chemical Society, Vol. 140, Issue 10
  • DOI: 10.1021/jacs.8b00588

Synthesis of Pt 3 Sn Alloy Nanoparticles and Their Catalysis for Electro-Oxidation of CO and Methanol
journal, October 2011

  • Liu, Yi; Li, Dongguo; Stamenkovic, Vojislav R.
  • ACS Catalysis, Vol. 1, Issue 12
  • DOI: 10.1021/cs200430r

Platinum Monolayer Electrocatalysts for Anodic Oxidation of Alcohols
journal, November 2012

  • Li, Meng; Liu, Ping; Adzic, Radoslav R.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 23
  • DOI: 10.1021/jz3016155

Structurally Ordered FePt Nanoparticles and Their Enhanced Catalysis for Oxygen Reduction Reaction
journal, April 2010

  • Kim, Jaemin; Lee, Youngmin; Sun, Shouheng
  • Journal of the American Chemical Society, Vol. 132, Issue 14
  • DOI: 10.1021/ja1009629

Electrooxidation of ethanol on a Pt electrode in acid solutions: in situ ATR-SEIRAS study
journal, April 2005


At Least Three Contiguous Atoms Are Necessary for CO Formation during Methanol Electrooxidation on Platinum
journal, October 2006

  • Cuesta, Angel
  • Journal of the American Chemical Society, Vol. 128, Issue 41
  • DOI: 10.1021/ja0644172

A first principles comparison of the mechanism and site requirements for the electrocatalytic oxidation of methanol and formic acid over Pt
journal, January 2009

  • Neurock, Matthew; Janik, Michael; Wieckowski, Andrzej
  • Faraday Discuss., Vol. 140
  • DOI: 10.1039/B804591G

New Approach to Fully Ordered fct-FePt Nanoparticles for Much Enhanced Electrocatalysis in Acid
journal, March 2015


Platinum–Cobalt alloy networks for methanol oxidation electrocatalysis
journal, January 2012

  • Xu, Jiangfeng; Liu, Xinyu; Chen, Yu
  • Journal of Materials Chemistry, Vol. 22, Issue 44
  • DOI: 10.1039/c2jm35649j

Pt-rich shell coated Ni nanoparticles as catalysts for methanol electro-oxidation in alkaline media
journal, August 2009


Comparison of different promotion effect of PtRu/C and PtSn/C electrocatalysts for ethanol electro-oxidation
journal, August 2007


FePt and CoPt Nanowires as Efficient Catalysts for the Oxygen Reduction Reaction
journal, February 2013

  • Guo, Shaojun; Li, Dongguo; Zhu, Huiyuan
  • Angewandte Chemie International Edition, Vol. 52, Issue 12
  • DOI: 10.1002/anie.201209871

Formic Acid Decomposition on Polycrystalline Platinum and Palladized Platinum Electrodes
journal, November 1999

  • Lu, Guo-Qiang; Crown, Alechia; Wieckowski, Andrzej
  • The Journal of Physical Chemistry B, Vol. 103, Issue 44
  • DOI: 10.1021/jp992297x

Kinetic study of formic acid oxidation on carbon-supported platinum electrocatalyst
journal, August 2005

  • Lović, J. D.; Tripković, A. V.; Gojković, S. Lj.
  • Journal of Electroanalytical Chemistry, Vol. 581, Issue 2, p. 294-302
  • DOI: 10.1016/j.jelechem.2005.05.002

Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2
journal, January 2009

  • Kowal, A.; Li, M.; Shao, M.
  • Nature Materials, Vol. 8, Issue 4, p. 325-330
  • DOI: 10.1038/nmat2359

Highly Durable and Active PtFe Nanocatalyst for Electrochemical Oxygen Reduction Reaction
journal, December 2015

  • Chung, Dong Young; Jun, Samuel Woojoo; Yoon, Gabin
  • Journal of the American Chemical Society, Vol. 137, Issue 49
  • DOI: 10.1021/jacs.5b09653

Synthesis, Shape Control, and Methanol Electro-oxidation Properties of Pt–Zn Alloy and Pt 3 Zn Intermetallic Nanocrystals
journal, May 2012

  • Kang, Yijin; Pyo, Jun Beom; Ye, Xingchen
  • ACS Nano, Vol. 6, Issue 6
  • DOI: 10.1021/nn301583g

Fe Stabilization by Intermetallic L1 0 -FePt and Pt Catalysis Enhancement in L1 0 -FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells
journal, February 2018

  • Li, Junrui; Xi, Zheng; Pan, Yung-Tin
  • Journal of the American Chemical Society, Vol. 140, Issue 8
  • DOI: 10.1021/jacs.7b12829

Platinum-Tin Oxide Core–Shell Catalysts for Efficient Electro-Oxidation of Ethanol
journal, July 2014

  • Du, Wenxin; Yang, Guangxing; Wong, Emily
  • Journal of the American Chemical Society, Vol. 136, Issue 31
  • DOI: 10.1021/ja505456w

Coulomb correlations and magnetic anisotropy in ordered L 1 0 CoPt and FePt alloys
journal, May 2003


Insight into the Effect of Sn on CO and Formic Acid Oxidation at PtSn Catalysts
journal, December 2013

  • Stevanović, S.; Tripković, D.; Tripković, V.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 1
  • DOI: 10.1021/jp408207u

Sub-4 nm PtZn Intermetallic Nanoparticles for Enhanced Mass and Specific Activities in Catalytic Electrooxidation Reaction
journal, March 2017

  • Qi, Zhiyuan; Xiao, Chaoxian; Liu, Cong
  • Journal of the American Chemical Society, Vol. 139, Issue 13
  • DOI: 10.1021/jacs.6b12780

Formic Acid as a Hydrogen Energy Carrier
journal, December 2016


Origin of the current peak of negative scan in the cyclic voltammetry of methanol electro-oxidation on Pt-based electrocatalysts: a revisit to the current ratio criterion
journal, January 2012

  • Hofstead-Duffy, Augusta M.; Chen, De-Jun; Sun, Shi-Gang
  • Journal of Materials Chemistry, Vol. 22, Issue 11
  • DOI: 10.1039/c2jm15426a

Pt–Ni Octahedra as Electrocatalysts for the Ethanol Electro-Oxidation Reaction
journal, July 2017


Recent Advances on Electro-Oxidation of Ethanol on Pt- and Pd-Based Catalysts: From Reaction Mechanisms to Catalytic Materials
journal, September 2015


Recent advances in direct formic acid fuel cells (DFAFC)
journal, July 2008


Theoretical Study of Methanol Oxidation on the PtAu(111) Bimetallic Surface: CO Pathway vs Non-CO Pathway
journal, January 2012

  • Zhong, Wenhui; Liu, Yuxia; Zhang, Dongju
  • The Journal of Physical Chemistry C, Vol. 116, Issue 4
  • DOI: 10.1021/jp210304z

Shape-Control of Pt–Ru Nanocrystals: Tuning Surface Structure for Enhanced Electrocatalytic Methanol Oxidation
journal, January 2018

  • Huang, Liang; Zhang, Xueping; Wang, Qingqing
  • Journal of the American Chemical Society, Vol. 140, Issue 3
  • DOI: 10.1021/jacs.7b12353

Formate, an Active Intermediate for Direct Oxidation of Methanol on Pt Electrode
journal, April 2003

  • Chen, Yan Xia; Miki, Atsushi; Ye, Shen
  • Journal of the American Chemical Society, Vol. 125, Issue 13
  • DOI: 10.1021/ja029044t

Parallel pathways of ethanol oxidation: The effect of ethanol concentration
journal, May 2005


Mechanisms for Ethanol Electrooxidation on Pt(111) and Adsorption Bond Strengths Defining an Ideal Catalyst
journal, November 2014

  • Asiri, Haleema Aied; Anderson, Alfred B.
  • Journal of The Electrochemical Society, Vol. 162, Issue 1
  • DOI: 10.1149/2.0781501jes

Catalytic Pt-on-Au Nanostructures: Why Pt Becomes More Active on Smaller Au Particles
journal, February 2012

  • Zhang, Gui-Rong; Zhao, Dan; Feng, Yuan-Yuan
  • ACS Nano, Vol. 6, Issue 3
  • DOI: 10.1021/nn204378t

Adsorption of Bisulfate and Sulfate Anions on a Pt(111) Electrode
journal, April 2001

  • Kolics, A.; Wieckowski, A.
  • The Journal of Physical Chemistry B, Vol. 105, Issue 13
  • DOI: 10.1021/jp003536f

Surface Composition Tuning of Au–Pt Bimetallic Nanoparticles for Enhanced Carbon Monoxide and Methanol Electro-oxidation
journal, May 2013

  • Suntivich, Jin; Xu, Zhichuan; Carlton, Christopher E.
  • Journal of the American Chemical Society, Vol. 135, Issue 21
  • DOI: 10.1021/ja402072r

Charging up Stationary Energy Storage
journal, January 2019


FePt and CoPt Nanowires as Efficient Catalysts for the Oxygen Reduction Reaction
journal, February 2013


Theoretical surface science and catalysis—calculations and concepts
book, January 2000


Methanol Electro-Oxidation on the Pt Surface: Revisiting the Cyclic Voltammetry Interpretation
journal, April 2016

  • Chung, Dong Young; Lee, Kyung-Jae; Sung, Yung-Eun
  • The Journal of Physical Chemistry C, Vol. 120, Issue 17
  • DOI: 10.1021/acs.jpcc.5b12303