Stable Tetra‐ and Penta‐Anions in the Gas Phase

doi:10.1002/anie.201903044

This content will become publicly available on July 10, 2020

Title: Stable Tetra‐ and Penta‐Anions in the Gas Phase

Authors:

^[1];

^[1]

Department of PhysicsVirginia Commonwealth University Richmond VA 23284 USA

Publication Date:: 2019-08-12

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1546813

Grant/Contract Number:: [FG02-96ER45579]

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie (International Edition)

Additional Journal Information:: [Journal Name: Angewandte Chemie (International Edition) Journal Volume: 58 Journal Issue: 33]; Journal ID: ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Fang, Hong, and Jena, Puru. Stable Tetra‐ and Penta‐Anions in the Gas Phase.  Germany: N. p., 2019. 
        Web.  doi:10.1002/anie.201903044.

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                    Fang, Hong, & Jena, Puru. Stable Tetra‐ and Penta‐Anions in the Gas Phase.  Germany.  doi:10.1002/anie.201903044.

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                    Fang, Hong, and Jena, Puru. Mon .  
        "Stable Tetra‐ and Penta‐Anions in the Gas Phase".  Germany.  doi:10.1002/anie.201903044.

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@article{osti_1546813,

  title        = {Stable Tetra‐ and Penta‐Anions in the Gas Phase},

  author       = {Fang, Hong and Jena, Puru},

  abstractNote = {},

  doi          = {10.1002/anie.201903044},

  journal      = {Angewandte Chemie (International Edition)},

  number       = [33],

  volume       = [58],

  place        = {Germany},

  year         = {2019},

  month        = {8}

}

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DOI: 10.1002/anie.201903044

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Works referenced in this record:

Structures of Gas-Phase (C ₆₀ ) _n (CN) _m Trianions from Reactions of C ₆₀ with NaCN in Solution
journal, November 1998

Tuinman, Albert A.; Compton, Robert N.
The Journal of Physical Chemistry A, Vol. 102, Issue 48
DOI: 10.1021/jp983212f

The structural significance of the number of skeletal bonding electron-pairs in carboranes, the higher boranes and borane anions, and various transition-metal carbonyl cluster compounds
journal, January 1971

Wade, K.
Journal of the Chemical Society D: Chemical Communications, Issue 15
DOI: 10.1039/c29710000792

Rational design of an argon-binding superelectrophilic anion
journal, April 2019

Mayer, Martin; van Lessen, Valentin; Rohdenburg, Markus
Proceedings of the National Academy of Sciences, Vol. 116, Issue 17
DOI: 10.1073/pnas.1820812116

B(SCN) ₄ ^– : A New Weakly Coordinating Anion in the Tetracyanoborate Family
journal, December 2017

Zhong, Mingmin; Fang, Hong; Jena, Puru
The Journal of Physical Chemistry C, Vol. 122, Issue 25
DOI: 10.1021/acs.jpcc.7b10332

Li-rich antiperovskite superionic conductors based on cluster ions
journal, October 2017

Fang, Hong; Jena, Puru
Proceedings of the National Academy of Sciences, Vol. 114, Issue 42
DOI: 10.1073/pnas.1704086114

Stability of B ₁₂ (CN) ₁₂ ²⁻ : Implications for Lithium and Magnesium Ion Batteries
journal, February 2016

Zhao, Hongmin; Zhou, Jian; Jena, Puru
Angewandte Chemie, Vol. 128, Issue 11
DOI: 10.1002/ange.201600275

The way to systems with the highest possible electron affinity
journal, July 1984

Gutsev, G. L.; Boldyrev, A. I.
Chemical Physics Letters, Vol. 108, Issue 3
DOI: 10.1016/0009-2614(84)87059-1

Role of ligands in the stability of B _n X _n and CB _n−1 X _n (n = 5–10; X = H, F, CN) and their potential as building blocks of electrolytes in lithium ion batteries
journal, January 2017

Zhong, MingMin; Zhou, Jian; Fang, Hong
Physical Chemistry Chemical Physics, Vol. 19, Issue 27
DOI: 10.1039/C7CP02642K

Probing Free Multiply Charged Anions Using Photodetachment Photoelectron Spectroscopy
journal, March 2000

Wang, Lai-Sheng; Wang, Xue-Bin
The Journal of Physical Chemistry A, Vol. 104, Issue 10
DOI: 10.1021/jp9940093

An ESI-MS method for characterization of native and modified oligonucleotides used for RNA interference and other biological applications
journal, February 2008

Shah, Samit; Friedman, Simon H.
Nature Protocols, Vol. 3, Issue 3
DOI: 10.1038/nprot.2007.535

Electronic Shell Structure and Abundances of Sodium Clusters
journal, June 1984

Knight, W. D.; Clemenger, Keith; de Heer, Walt A.
Physical Review Letters, Vol. 52, Issue 24
DOI: 10.1103/PhysRevLett.52.2141

Gas-Phase Multiply Charged Anions
journal, November 1995

Scheller, M. K.; Compton, R. N.; Cederbaum, L. S.
Science, Vol. 270, Issue 5239
DOI: 10.1126/science.270.5239.1160

Colossal Stability of Gas-Phase Trianions: Super-Pnictogens
journal, August 2017

Zhao, Tianshan; Zhou, Jian; Wang, Qian
Angewandte Chemie, Vol. 129, Issue 43
DOI: 10.1002/ange.201706764

Electronic Structure and Stability of [B ₁₂ X ₁₂ ] ^2– (X = F–At): A Combined Photoelectron Spectroscopic and Theoretical Study
journal, October 2017

Warneke, Jonas; Hou, Gao-Lei; Aprà, Edoardo
Journal of the American Chemical Society, Vol. 139, Issue 41
DOI: 10.1021/jacs.7b08598

Unusually high stability of B 12 (BO) 12 2− achieved by boronyl ligand manipulation: Theoretical investigation
journal, April 2018

Moon, Jiwon; Baek, Heehyun; Kim, Joonghan
Chemical Physics Letters, Vol. 698
DOI: 10.1016/j.cplett.2018.03.015

Superhalogen-based lithium superionic conductors
journal, January 2017

Fang, Hong; Wang, Shuo; Liu, Junyi
Journal of Materials Chemistry A, Vol. 5, Issue 26
DOI: 10.1039/C7TA01648D

Small Multiply Charged Anions as Building Blocks in Chemistry
journal, January 1996

Boldyrev, Alexander I.; Gutowski, Maciej; Simons, Jack
Accounts of Chemical Research, Vol. 29, Issue 10
DOI: 10.1021/ar960147o

DVM-Xα calculations on the ionization potentials of MXk+1− complex anions and the electron affinities of MXk+1 “superhalogens”
journal, April 1981

Gutsev, G. L.; Boldyrev, A. I.
Chemical Physics, Vol. 56, Issue 3
DOI: 10.1016/0301-0104(81)80150-4

Probing the Electronic Stability of Multiply Charged Anions: Sulfonated Pyrene Tri- and Tetraanions
journal, July 2009

Wang, Xue-Bin; Sergeeva, Alina P.; Xing, Xiao-Peng
Journal of the American Chemical Society, Vol. 131, Issue 28
DOI: 10.1021/ja903615g

The Arrangement of Electrons in Atoms and Molecules.
journal, June 1919

Langmuir, Irving
Journal of the American Chemical Society, Vol. 41, Issue 6
DOI: 10.1021/ja02227a002

Observation of negative electron-binding energy in a molecule
journal, July 1999

Wang, Xue-Bin; Wang, Lai-Sheng
Nature, Vol. 400, Issue 6741
DOI: 10.1038/22286

Multiply charged negative ions by electrospray ionization of polypeptides and proteins
journal, January 1992

Loo, Joseph A.; Loo, Rachel R. Ogorzalek.; Light, Karen J.
Analytical Chemistry, Vol. 64, Issue 1
DOI: 10.1021/ac00025a015

Stability of B ₁₂ (CN) ₁₂ ²⁻ : Implications for Lithium and Magnesium Ion Batteries
journal, February 2016

Zhao, Hongmin; Zhou, Jian; Jena, Puru
Angewandte Chemie International Edition, Vol. 55, Issue 11
DOI: 10.1002/anie.201600275

Stepwise Introduction of Cyano Groups into nido - and closo -Undecaborate Clusters
journal, February 2018

Konieczka, Szymon Z.; Schlüter, Florian; Sindorf, Christoph
Chemistry - A European Journal, Vol. 24, Issue 14
DOI: 10.1002/chem.201704860

Cycloheptatrienylium Oxide
journal, February 1951

von E. Doering, W.; Detert, Francis L.
Journal of the American Chemical Society, Vol. 73, Issue 2
DOI: 10.1021/ja01146a537

B ₁₂ (SCN) ₁₂ ^– : An Ultrastable Weakly Coordinating Dianion
journal, March 2017

Fang, Hong; Jena, Puru
The Journal of Physical Chemistry C, Vol. 121, Issue 14
DOI: 10.1021/acs.jpcc.7b00669

Preparation and X-ray structure of 2-tetrahydroborato-2-berylla-nido-hexaborane(11): insertion of beryllium into a borane cage
journal, January 1976

Gaines, Donald F.; Walsh, Jerry L.
Journal of the Chemical Society, Chemical Communications, Issue 12
DOI: 10.1039/c39760000482

Types of Valence
journal, July 1921

Langmuir, I.
Science, Vol. 54, Issue 1386
DOI: 10.1126/science.54.1386.59

Colossal Stability of Gas-Phase Trianions: Super-Pnictogens
journal, August 2017

Zhao, Tianshan; Zhou, Jian; Wang, Qian
Angewandte Chemie International Edition, Vol. 56, Issue 43
DOI: 10.1002/anie.201706764

Sodium Superionic Conductors Based on Clusters
journal, December 2018

Fang, Hong; Jena, Puru
ACS Applied Materials & Interfaces, Vol. 11, Issue 1
DOI: 10.1021/acsami.8b19003

Structure of the NaxClx+1− (x=1–4) clusters via ab initio genetic algorithm and photoelectron spectroscopy
journal, September 2004

Alexandrova, Anastassia N.; Boldyrev, Alexander I.; Fu, You-Jun
The Journal of Chemical Physics, Vol. 121, Issue 12
DOI: 10.1063/1.1783276

Direct Experimental Probe of the On-Site Coulomb Repulsion in the Doubly Charged Fullerene Anion $C_{70}^{2 -}$
journal, April 2006

Wang, Xue-Bin; Woo, Hin-Koon; Huang, Xin
Physical Review Letters, Vol. 96, Issue 14
DOI: 10.1103/PhysRevLett.96.143002

Chemistry of 2-berylla-nido-hexaborane(11) compounds. Insertion of beryllium into a borane cage
journal, May 1978

Gaines, Donald F.; Walsh, Jerry L.
Inorganic Chemistry, Vol. 17, Issue 5
DOI: 10.1021/ic50183a028

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Similar Records

This content will become publicly available on July 10, 2020

Title: Stable Tetra‐ and Penta‐Anions in the Gas Phase

Citation Formats

Structures of Gas-Phase (C 60 ) n (CN) m Trianions from Reactions of C 60 with NaCN in Solution journal, November 1998

The structural significance of the number of skeletal bonding electron-pairs in carboranes, the higher boranes and borane anions, and various transition-metal carbonyl cluster compounds journal, January 1971

Rational design of an argon-binding superelectrophilic anion journal, April 2019

B(SCN) 4 – : A New Weakly Coordinating Anion in the Tetracyanoborate Family journal, December 2017

Li-rich antiperovskite superionic conductors based on cluster ions journal, October 2017

Stability of B 12 (CN) 12 2− : Implications for Lithium and Magnesium Ion Batteries journal, February 2016

The way to systems with the highest possible electron affinity journal, July 1984

Role of ligands in the stability of B n X n and CB n−1 X n (n = 5–10; X = H, F, CN) and their potential as building blocks of electrolytes in lithium ion batteries journal, January 2017

Probing Free Multiply Charged Anions Using Photodetachment Photoelectron Spectroscopy journal, March 2000

An ESI-MS method for characterization of native and modified oligonucleotides used for RNA interference and other biological applications journal, February 2008

Electronic Shell Structure and Abundances of Sodium Clusters journal, June 1984

Gas-Phase Multiply Charged Anions journal, November 1995

Colossal Stability of Gas-Phase Trianions: Super-Pnictogens journal, August 2017

Electronic Structure and Stability of [B 12 X 12 ] 2– (X = F–At): A Combined Photoelectron Spectroscopic and Theoretical Study journal, October 2017

Unusually high stability of B 12 (BO) 12 2− achieved by boronyl ligand manipulation: Theoretical investigation journal, April 2018

Superhalogen-based lithium superionic conductors journal, January 2017

Small Multiply Charged Anions as Building Blocks in Chemistry journal, January 1996

DVM-Xα calculations on the ionization potentials of MXk+1− complex anions and the electron affinities of MXk+1 “superhalogens” journal, April 1981

Probing the Electronic Stability of Multiply Charged Anions: Sulfonated Pyrene Tri- and Tetraanions journal, July 2009

The Arrangement of Electrons in Atoms and Molecules. journal, June 1919

Observation of negative electron-binding energy in a molecule journal, July 1999

Multiply charged negative ions by electrospray ionization of polypeptides and proteins journal, January 1992

Stability of B 12 (CN) 12 2− : Implications for Lithium and Magnesium Ion Batteries journal, February 2016

Stepwise Introduction of Cyano Groups into nido - and closo -Undecaborate Clusters journal, February 2018

Cycloheptatrienylium Oxide journal, February 1951

B 12 (SCN) 12 – : An Ultrastable Weakly Coordinating Dianion journal, March 2017

Preparation and X-ray structure of 2-tetrahydroborato-2-berylla-nido-hexaborane(11): insertion of beryllium into a borane cage journal, January 1976

Types of Valence journal, July 1921

Colossal Stability of Gas-Phase Trianions: Super-Pnictogens journal, August 2017

Sodium Superionic Conductors Based on Clusters journal, December 2018

Structure of the NaxClx+1− (x=1–4) clusters via ab initio genetic algorithm and photoelectron spectroscopy journal, September 2004

Direct Experimental Probe of the On-Site Coulomb Repulsion in the Doubly Charged Fullerene Anion C 70 2 − journal, April 2006

Chemistry of 2-berylla-nido-hexaborane(11) compounds. Insertion of beryllium into a borane cage journal, May 1978

Structures of Gas-Phase (C ₆₀ ) _n (CN) _m Trianions from Reactions of C ₆₀ with NaCN in Solution
journal, November 1998

The structural significance of the number of skeletal bonding electron-pairs in carboranes, the higher boranes and borane anions, and various transition-metal carbonyl cluster compounds
journal, January 1971

Rational design of an argon-binding superelectrophilic anion
journal, April 2019

B(SCN) ₄ ^– : A New Weakly Coordinating Anion in the Tetracyanoborate Family
journal, December 2017

Li-rich antiperovskite superionic conductors based on cluster ions
journal, October 2017

Stability of B ₁₂ (CN) ₁₂ ²⁻ : Implications for Lithium and Magnesium Ion Batteries
journal, February 2016

The way to systems with the highest possible electron affinity
journal, July 1984

Role of ligands in the stability of B _n X _n and CB _n−1 X _n (n = 5–10; X = H, F, CN) and their potential as building blocks of electrolytes in lithium ion batteries
journal, January 2017

Probing Free Multiply Charged Anions Using Photodetachment Photoelectron Spectroscopy
journal, March 2000

An ESI-MS method for characterization of native and modified oligonucleotides used for RNA interference and other biological applications
journal, February 2008

Electronic Shell Structure and Abundances of Sodium Clusters
journal, June 1984

Gas-Phase Multiply Charged Anions
journal, November 1995

Colossal Stability of Gas-Phase Trianions: Super-Pnictogens
journal, August 2017

Electronic Structure and Stability of [B ₁₂ X ₁₂ ] ^2– (X = F–At): A Combined Photoelectron Spectroscopic and Theoretical Study
journal, October 2017

Unusually high stability of B 12 (BO) 12 2− achieved by boronyl ligand manipulation: Theoretical investigation
journal, April 2018

Superhalogen-based lithium superionic conductors
journal, January 2017

Small Multiply Charged Anions as Building Blocks in Chemistry
journal, January 1996

DVM-Xα calculations on the ionization potentials of MXk+1− complex anions and the electron affinities of MXk+1 “superhalogens”
journal, April 1981

Probing the Electronic Stability of Multiply Charged Anions: Sulfonated Pyrene Tri- and Tetraanions
journal, July 2009

The Arrangement of Electrons in Atoms and Molecules.
journal, June 1919

Observation of negative electron-binding energy in a molecule
journal, July 1999

Multiply charged negative ions by electrospray ionization of polypeptides and proteins
journal, January 1992

Stability of B ₁₂ (CN) ₁₂ ²⁻ : Implications for Lithium and Magnesium Ion Batteries
journal, February 2016

Stepwise Introduction of Cyano Groups into nido - and closo -Undecaborate Clusters
journal, February 2018

Cycloheptatrienylium Oxide
journal, February 1951

B ₁₂ (SCN) ₁₂ ^– : An Ultrastable Weakly Coordinating Dianion
journal, March 2017

Preparation and X-ray structure of 2-tetrahydroborato-2-berylla-nido-hexaborane(11): insertion of beryllium into a borane cage
journal, January 1976

Types of Valence
journal, July 1921

Colossal Stability of Gas-Phase Trianions: Super-Pnictogens
journal, August 2017

Sodium Superionic Conductors Based on Clusters
journal, December 2018

Structure of the NaxClx+1− (x=1–4) clusters via ab initio genetic algorithm and photoelectron spectroscopy
journal, September 2004

Direct Experimental Probe of the On-Site Coulomb Repulsion in the Doubly Charged Fullerene Anion $C_{70}^{2 -}$
journal, April 2006

Chemistry of 2-berylla-nido-hexaborane(11) compounds. Insertion of beryllium into a borane cage
journal, May 1978