Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects

Park, Beom-Kyeong; Zhang, Qian; Voorhees, Peter W.; Barnett, Scott A.

doi:10.1039/C9EE01664C

Title: Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects

Abstract

The fracture at the electrode/electrolyte interface occurs for a critical oxygen pressure and an associated electrode overpotential.

Authors:

^[1]; Zhang, Qian ^[1]; Voorhees, Peter W. ^[1];

^[1]

Department of Materials Science and Engineering, Northwestern University, Evanston, USA

Publication Date:: 2019-10-09

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1546809

Grant/Contract Number:: 0008079

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Energy & Environmental Science

Additional Journal Information:: Journal Name: Energy & Environmental Science Journal Volume: 12 Journal Issue: 10; Journal ID: ISSN 1754-5692

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Park, Beom-Kyeong, Zhang, Qian, Voorhees, Peter W., and Barnett, Scott A. Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9EE01664C.

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                    Park, Beom-Kyeong, Zhang, Qian, Voorhees, Peter W., & Barnett, Scott A. Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects.  United Kingdom.  https://doi.org/10.1039/C9EE01664C

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                    Park, Beom-Kyeong, Zhang, Qian, Voorhees, Peter W., and Barnett, Scott A. Wed .  
"Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects".  United Kingdom.  https://doi.org/10.1039/C9EE01664C.

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@article{osti_1546809,

  title        = {Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects},

  author       = {Park, Beom-Kyeong and Zhang, Qian and Voorhees, Peter W. and Barnett, Scott A.},

  abstractNote = {The fracture at the electrode/electrolyte interface occurs for a critical oxygen pressure and an associated electrode overpotential.},

  doi          = {10.1039/C9EE01664C},

  journal      = {Energy & Environmental Science},

  number       = 10,

  volume       = 12,

  place        = {United Kingdom},

  year         = {2019},

  month        = {10}

}

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Title: Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects

Abstract

Citation Formats

Mechanism of oxygen electrode delamination in solid oxide electrolyzer cells journal, September 2010

High temperature water electrolysis using metal supported solid oxide electrolyser cells (SOEC) journal, October 2008

LSM–YSZ interactions and anode delamination in solid oxide electrolysis cells journal, November 2012

Post-test evaluation of oxygen electrodes from solid oxide electrolysis stacks☆ journal, May 2009

Solid Oxide Electrolysis Cells: Degradation at High Current Densities journal, January 2010

Modeling and experimental performance of an intermediate temperature reversible solid oxide cell for high-efficiency, distributed-scale electrical energy storage journal, June 2015

Durability of Solid Oxide Electrolysis Cells for Syngas Production journal, January 2013

High Temperature Co-Electrolysis of Steam and CO 2 in an SOC Stack: Performance and Durability journal, April 2013

Degradation mechanism of electrolyte and air electrode in solid oxide electrolysis cells operating at high polarization journal, February 2013

Electromotive Potential Distribution and Electronic Leak Currents in Working YSZ Based SOCs conference, January 2009

Electrochemical Energy Storage for Green Grid journal, May 2011

The role of fuel cells in energy storage journal, March 2000

Fe-substituted SrTiO3−δ–Ce0.9Gd0.1O2 composite anodes for solid oxide fuel cells journal, January 2013

Failure mechanism of (La,Sr)MnO3 oxygen electrodes of solid oxide electrolysis cells journal, August 2011

A perspective on low-temperature solid oxide fuel cells journal, January 2016

Large-scale electricity storage utilizing reversible solid oxide cells combined with underground storage of CO 2 and CH 4 journal, January 2015

Effect of Sr Surface Segregation of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3 − δ Electrode on Its Electrochemical Performance in SOC journal, January 2015

Cobalt-substituted SrTi 0.3 Fe 0.7 O 3−δ : a stable high-performance oxygen electrode material for intermediate-temperature solid oxide electrochemical cells journal, January 2018

Enhanced performance of LSCF cathode through surface modification journal, May 2012

Degradation Mechanisms of La–Sr–Co–Fe–O[sub 3] SOFC Cathodes journal, January 2006

Electrical and hydrogen reduction enhances kinetics in doped zirconia and ceria: II . Mapping electrode polarization and vacancy condensation in YSZ journal, October 2017

Highly efficient high temperature electrolysis journal, January 2008

Co-electrolysis of CO2 and H2O in solid oxide cells: Performance and durability journal, June 2011

Durable SOC stacks for production of hydrogen and synthesis gas by high temperature electrolysis journal, July 2011

Mechanisms of Performance Degradation of (La,Sr)(Co,Fe)O 3-δ Solid Oxide Fuel Cell Cathodes journal, January 2016

Degradation of La 0.6 Sr 0.4 Fe 0.8 Co 0.2 O 3-δ Oxygen Electrodes on Ce 0.9 Gd 0.1 O 2-δ Electrolytes during Reversing Current Operation journal, January 2017

Fermi Potential across Working Solid Oxide Cells with Zirconia or Ceria Electrolytes journal, March 2014

Electrolyte degradation in anode supported microtubular yttria stabilized zirconia-based solid oxide steam electrolysis cells at high voltages of operation journal, November 2011

Degradation of (La 0.8 Sr 0.2 ) 0.98 MnO 3−δ –Zr 0.84 Y 0.16 O 2−γ composite electrodes during reversing current operation journal, January 2015

Electrical Energy Storage for the Grid: A Battery of Choices journal, November 2011

High efficiency electrical energy storage using a methane–oxygen solid oxide cell journal, January 2011

Influence of the oxygen electrode and inter-diffusion barrier on the degradation of solid oxide electrolysis cells journal, February 2013

Solid Oxide Fuel Cells damage mechanisms due to Ni-YSZ re-oxidation: Case of the Anode Supported Cell journal, July 2009

Performance of solid oxide electrolysis cell having bi-layered electrolyte during steam electrolysis and carbon dioxide electrolysis journal, January 2011

The Course of Oxygen Partial Pressure and Electric Potentials across an Oxide Electrolyte Cell conference, January 2008

Degradation phenomena in a solid oxide electrolysis cell after 9000 h of operation journal, February 2013

Stability of LSCF electrode with GDC interlayer in YSZ-based solid oxide electrolysis cell journal, September 2014

Understanding degradation of solid oxide electrolysis cells through modeling of electrochemical potential profiles journal, January 2016

Quantitative three-dimensional microstructure of a solid oxide fuel cell cathode journal, May 2009

Eliminating degradation in solid oxide electrochemical cells by reversible operation journal, December 2014

23,000 h steam electrolysis with an electrolyte supported solid oxide cell journal, May 2017

Solid oxide cells with zirconia/ceria Bi-Layer electrolytes fabricated by reduced temperature firing journal, January 2015

Microstructural Degradation of Ni/YSZ Electrodes in Solid Oxide Electrolysis Cells under High Current journal, January 2013

Analysis of self-sustaining recuperative solid oxide electrolysis systems journal, December 2008

Mechanism of oxygen electrode delamination in solid oxide electrolyzer cells
journal, September 2010

High temperature water electrolysis using metal supported solid oxide electrolyser cells (SOEC)
journal, October 2008

LSM–YSZ interactions and anode delamination in solid oxide electrolysis cells
journal, November 2012

Post-test evaluation of oxygen electrodes from solid oxide electrolysis stacks☆
journal, May 2009

Solid Oxide Electrolysis Cells: Degradation at High Current Densities
journal, January 2010

Modeling and experimental performance of an intermediate temperature reversible solid oxide cell for high-efficiency, distributed-scale electrical energy storage
journal, June 2015

Durability of Solid Oxide Electrolysis Cells for Syngas Production
journal, January 2013

High Temperature Co-Electrolysis of Steam and CO ₂ in an SOC Stack: Performance and Durability
journal, April 2013

Degradation mechanism of electrolyte and air electrode in solid oxide electrolysis cells operating at high polarization
journal, February 2013

Electromotive Potential Distribution and Electronic Leak Currents in Working YSZ Based SOCs
conference, January 2009

Electrochemical Energy Storage for Green Grid
journal, May 2011

The role of fuel cells in energy storage
journal, March 2000

Fe-substituted SrTiO3−δ–Ce0.9Gd0.1O2 composite anodes for solid oxide fuel cells
journal, January 2013

Failure mechanism of (La,Sr)MnO3 oxygen electrodes of solid oxide electrolysis cells
journal, August 2011

A perspective on low-temperature solid oxide fuel cells
journal, January 2016

Large-scale electricity storage utilizing reversible solid oxide cells combined with underground storage of CO ₂ and CH ₄
journal, January 2015

Effect of Sr Surface Segregation of La _0.6 Sr _0.4 Co _0.2 Fe _0.8 O _{3 − δ} Electrode on Its Electrochemical Performance in SOC
journal, January 2015

Cobalt-substituted SrTi _0.3 Fe _0.7 O _3−δ : a stable high-performance oxygen electrode material for intermediate-temperature solid oxide electrochemical cells
journal, January 2018

Enhanced performance of LSCF cathode through surface modification
journal, May 2012

Degradation Mechanisms of La–Sr–Co–Fe–O[sub 3] SOFC Cathodes
journal, January 2006

Electrical and hydrogen reduction enhances kinetics in doped zirconia and ceria: II . Mapping electrode polarization and vacancy condensation in YSZ
journal, October 2017

Highly efficient high temperature electrolysis
journal, January 2008

Co-electrolysis of CO2 and H2O in solid oxide cells: Performance and durability
journal, June 2011

Durable SOC stacks for production of hydrogen and synthesis gas by high temperature electrolysis
journal, July 2011

Mechanisms of Performance Degradation of (La,Sr)(Co,Fe)O _3-δ Solid Oxide Fuel Cell Cathodes
journal, January 2016

Degradation of La _0.6 Sr _0.4 Fe _0.8 Co _0.2 O _3-δ Oxygen Electrodes on Ce _0.9 Gd _0.1 O _2-δ Electrolytes during Reversing Current Operation
journal, January 2017

Fermi Potential across Working Solid Oxide Cells with Zirconia or Ceria Electrolytes
journal, March 2014

Electrolyte degradation in anode supported microtubular yttria stabilized zirconia-based solid oxide steam electrolysis cells at high voltages of operation
journal, November 2011

Degradation of (La _0.8 Sr _0.2 ) _0.98 MnO _3−δ –Zr _0.84 Y _0.16 O _2−γ composite electrodes during reversing current operation
journal, January 2015

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011

High efficiency electrical energy storage using a methane–oxygen solid oxide cell
journal, January 2011

Influence of the oxygen electrode and inter-diffusion barrier on the degradation of solid oxide electrolysis cells
journal, February 2013

Solid Oxide Fuel Cells damage mechanisms due to Ni-YSZ re-oxidation: Case of the Anode Supported Cell
journal, July 2009

Performance of solid oxide electrolysis cell having bi-layered electrolyte during steam electrolysis and carbon dioxide electrolysis
journal, January 2011

The Course of Oxygen Partial Pressure and Electric Potentials across an Oxide Electrolyte Cell
conference, January 2008

Degradation phenomena in a solid oxide electrolysis cell after 9000 h of operation
journal, February 2013

Stability of LSCF electrode with GDC interlayer in YSZ-based solid oxide electrolysis cell
journal, September 2014

Understanding degradation of solid oxide electrolysis cells through modeling of electrochemical potential profiles
journal, January 2016

Quantitative three-dimensional microstructure of a solid oxide fuel cell cathode
journal, May 2009

Eliminating degradation in solid oxide electrochemical cells by reversible operation
journal, December 2014

23,000 h steam electrolysis with an electrolyte supported solid oxide cell
journal, May 2017

Solid oxide cells with zirconia/ceria Bi-Layer electrolytes fabricated by reduced temperature firing
journal, January 2015

Microstructural Degradation of Ni/YSZ Electrodes in Solid Oxide Electrolysis Cells under High Current
journal, January 2013

Analysis of self-sustaining recuperative solid oxide electrolysis systems
journal, December 2008