skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects

Abstract

The fracture at the electrode/electrolyte interface occurs for a critical oxygen pressure and an associated electrode overpotential.

Authors:
ORCiD logo [1];  [1];  [1]; ORCiD logo [1]
  1. Department of Materials Science and Engineering, Northwestern University, Evanston, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1546809
Grant/Contract Number:  
0008079
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science Journal Volume: 12 Journal Issue: 10; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Park, Beom-Kyeong, Zhang, Qian, Voorhees, Peter W., and Barnett, Scott A. Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects. United Kingdom: N. p., 2019. Web. doi:10.1039/C9EE01664C.
Park, Beom-Kyeong, Zhang, Qian, Voorhees, Peter W., & Barnett, Scott A. Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects. United Kingdom. doi:10.1039/C9EE01664C.
Park, Beom-Kyeong, Zhang, Qian, Voorhees, Peter W., and Barnett, Scott A. Wed . "Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects". United Kingdom. doi:10.1039/C9EE01664C.
@article{osti_1546809,
title = {Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects},
author = {Park, Beom-Kyeong and Zhang, Qian and Voorhees, Peter W. and Barnett, Scott A.},
abstractNote = {The fracture at the electrode/electrolyte interface occurs for a critical oxygen pressure and an associated electrode overpotential.},
doi = {10.1039/C9EE01664C},
journal = {Energy & Environmental Science},
number = 10,
volume = 12,
place = {United Kingdom},
year = {2019},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9EE01664C

Citation Metrics:
Cited by: 5 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Mechanism of oxygen electrode delamination in solid oxide electrolyzer cells
journal, September 2010


High temperature water electrolysis using metal supported solid oxide electrolyser cells (SOEC)
journal, October 2008


LSM–YSZ interactions and anode delamination in solid oxide electrolysis cells
journal, November 2012


Post-test evaluation of oxygen electrodes from solid oxide electrolysis stacks☆
journal, May 2009

  • Mawdsley, Jennifer R.; David Carter, J.; Jeremy Kropf, A.
  • International Journal of Hydrogen Energy, Vol. 34, Issue 9
  • DOI: 10.1016/j.ijhydene.2008.07.061

Solid Oxide Electrolysis Cells: Degradation at High Current Densities
journal, January 2010

  • Knibbe, Ruth; Traulsen, Marie Lund; Hauch, Anne
  • Journal of The Electrochemical Society, Vol. 157, Issue 8
  • DOI: 10.1149/1.3447752

Durability of Solid Oxide Electrolysis Cells for Syngas Production
journal, January 2013

  • Sun, Xiufu; Chen, Ming; Liu, Yi-Lin
  • Journal of The Electrochemical Society, Vol. 160, Issue 9
  • DOI: 10.1149/2.106309jes

High Temperature Co-Electrolysis of Steam and CO 2 in an SOC Stack: Performance and Durability
journal, April 2013


Degradation mechanism of electrolyte and air electrode in solid oxide electrolysis cells operating at high polarization
journal, February 2013


Electromotive Potential Distribution and Electronic Leak Currents in Working YSZ Based SOCs
conference, January 2009

  • Mogensen, Mogens; Jacobsen, Torben
  • 216th ECS Meeting, ECS Transactions
  • DOI: 10.1149/1.3205660

Electrochemical Energy Storage for Green Grid
journal, May 2011

  • Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
  • Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
  • DOI: 10.1021/cr100290v

The role of fuel cells in energy storage
journal, March 2000


Fe-substituted SrTiO3−δ–Ce0.9Gd0.1O2 composite anodes for solid oxide fuel cells
journal, January 2013

  • Cho, Sungmee; Fowler, Daniel E.; Miller, Elizabeth C.
  • Energy & Environmental Science, Vol. 6, Issue 6
  • DOI: 10.1039/c3ee23791e

Failure mechanism of (La,Sr)MnO3 oxygen electrodes of solid oxide electrolysis cells
journal, August 2011


A perspective on low-temperature solid oxide fuel cells
journal, January 2016

  • Gao, Zhan; Mogni, Liliana V.; Miller, Elizabeth C.
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C5EE03858H

Large-scale electricity storage utilizing reversible solid oxide cells combined with underground storage of CO 2 and CH 4
journal, January 2015

  • Jensen, S. H.; Graves, C.; Mogensen, M.
  • Energy & Environmental Science, Vol. 8, Issue 8
  • DOI: 10.1039/C5EE01485A

Effect of Sr Surface Segregation of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3 − δ Electrode on Its Electrochemical Performance in SOC
journal, January 2015

  • Pan, Zehua; Liu, Qinglin; Zhang, Lan
  • Journal of The Electrochemical Society, Vol. 162, Issue 12
  • DOI: 10.1149/2.0371512jes

Cobalt-substituted SrTi 0.3 Fe 0.7 O 3−δ : a stable high-performance oxygen electrode material for intermediate-temperature solid oxide electrochemical cells
journal, January 2018

  • Zhang, Shan-Lin; Wang, Hongqian; Lu, Matthew Y.
  • Energy & Environmental Science, Vol. 11, Issue 7
  • DOI: 10.1039/C8EE00449H

Enhanced performance of LSCF cathode through surface modification
journal, May 2012


Degradation Mechanisms of La–Sr–Co–Fe–O[sub 3] SOFC Cathodes
journal, January 2006

  • Simner, S. P.; Anderson, M. D.; Engelhard, M. H.
  • Electrochemical and Solid-State Letters, Vol. 9, Issue 10
  • DOI: 10.1149/1.2266160

Electrical and hydrogen reduction enhances kinetics in doped zirconia and ceria: II . Mapping electrode polarization and vacancy condensation in YSZ
journal, October 2017

  • Dong, Yanhao; Chen, I‐Wei
  • Journal of the American Ceramic Society, Vol. 101, Issue 3
  • DOI: 10.1111/jace.15274

Highly efficient high temperature electrolysis
journal, January 2008

  • Hauch, Anne; Ebbesen, Sune Dalgaard; Jensen, Søren Højgaard
  • Journal of Materials Chemistry, Vol. 18, Issue 20
  • DOI: 10.1039/b718822f

Co-electrolysis of CO2 and H2O in solid oxide cells: Performance and durability
journal, June 2011

  • Graves, Christopher; Ebbesen, Sune D.; Mogensen, Mogens
  • Solid State Ionics, Vol. 192, Issue 1
  • DOI: 10.1016/j.ssi.2010.06.014

Durable SOC stacks for production of hydrogen and synthesis gas by high temperature electrolysis
journal, July 2011

  • Ebbesen, Sune Dalgaard; Høgh, Jens; Nielsen, Karsten Agersted
  • International Journal of Hydrogen Energy, Vol. 36, Issue 13
  • DOI: 10.1016/j.ijhydene.2011.03.130

Mechanisms of Performance Degradation of (La,Sr)(Co,Fe)O 3-δ Solid Oxide Fuel Cell Cathodes
journal, January 2016

  • Wang, Hongqian; Yakal-Kremski, Kyle J.; Yeh, Ted
  • Journal of The Electrochemical Society, Vol. 163, Issue 6
  • DOI: 10.1149/2.0031607jes

Degradation of La 0.6 Sr 0.4 Fe 0.8 Co 0.2 O 3-δ Oxygen Electrodes on Ce 0.9 Gd 0.1 O 2-δ Electrolytes during Reversing Current Operation
journal, January 2017

  • Railsback, Justin G.; Wang, Hongqian; Liu, Qinyuan
  • Journal of The Electrochemical Society, Vol. 164, Issue 10
  • DOI: 10.1149/2.0111710jes

Fermi Potential across Working Solid Oxide Cells with Zirconia or Ceria Electrolytes
journal, March 2014

  • Jacobsen, T.; Chatzichristodoulou, C.; Mogensen, M. B.
  • ECS Transactions, Vol. 61, Issue 1
  • DOI: 10.1149/06101.0203ecst

Electrolyte degradation in anode supported microtubular yttria stabilized zirconia-based solid oxide steam electrolysis cells at high voltages of operation
journal, November 2011


Degradation of (La 0.8 Sr 0.2 ) 0.98 MnO 3−δ –Zr 0.84 Y 0.16 O 2−γ composite electrodes during reversing current operation
journal, January 2015

  • Hughes, Gareth A.; Railsback, Justin G.; Yakal-Kremski, Kyle J.
  • Faraday Discussions, Vol. 182
  • DOI: 10.1039/C5FD00020C

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


High efficiency electrical energy storage using a methane–oxygen solid oxide cell
journal, January 2011

  • Bierschenk, David M.; Wilson, James R.; Barnett, Scott A.
  • Energy Environ. Sci., Vol. 4, Issue 3, p. 944-951
  • DOI: 10.1039/C0EE00457J

Influence of the oxygen electrode and inter-diffusion barrier on the degradation of solid oxide electrolysis cells
journal, February 2013


Solid Oxide Fuel Cells damage mechanisms due to Ni-YSZ re-oxidation: Case of the Anode Supported Cell
journal, July 2009


Performance of solid oxide electrolysis cell having bi-layered electrolyte during steam electrolysis and carbon dioxide electrolysis
journal, January 2011

  • Kim-Lohsoontorn, Pattaraporn; Laosiripojana, Navadol; Bae, Joongmyeon
  • Current Applied Physics, Vol. 11, Issue 1
  • DOI: 10.1016/j.cap.2010.11.114

The Course of Oxygen Partial Pressure and Electric Potentials across an Oxide Electrolyte Cell
conference, January 2008

  • Jacobsen, Torben; Mogensen, Mogens
  • 213th ECS Meeting, ECS Transactions
  • DOI: 10.1149/1.3050398

Degradation phenomena in a solid oxide electrolysis cell after 9000 h of operation
journal, February 2013


Stability of LSCF electrode with GDC interlayer in YSZ-based solid oxide electrolysis cell
journal, September 2014


Understanding degradation of solid oxide electrolysis cells through modeling of electrochemical potential profiles
journal, January 2016


Quantitative three-dimensional microstructure of a solid oxide fuel cell cathode
journal, May 2009

  • Wilson, James R.; Duong, Anh T.; Gameiro, Marcio
  • Electrochemistry Communications, Vol. 11, Issue 5, p. 1052-1056
  • DOI: 10.1016/j.elecom.2009.03.010

Eliminating degradation in solid oxide electrochemical cells by reversible operation
journal, December 2014

  • Graves, Christopher; Ebbesen, Sune Dalgaard; Jensen, Søren Højgaard
  • Nature Materials, Vol. 14, Issue 2
  • DOI: 10.1038/nmat4165

23,000 h steam electrolysis with an electrolyte supported solid oxide cell
journal, May 2017


Solid oxide cells with zirconia/ceria Bi-Layer electrolytes fabricated by reduced temperature firing
journal, January 2015

  • Gao, Zhan; Zenou, Victor Y.; Kennouche, David
  • Journal of Materials Chemistry A, Vol. 3, Issue 18
  • DOI: 10.1039/C5TA01964H

Microstructural Degradation of Ni/YSZ Electrodes in Solid Oxide Electrolysis Cells under High Current
journal, January 2013

  • Chen, Ming; Liu, Yi-Lin; Bentzen, Janet Jonna
  • Journal of The Electrochemical Society, Vol. 160, Issue 8
  • DOI: 10.1149/2.098308jes

Analysis of self-sustaining recuperative solid oxide electrolysis systems
journal, December 2008