A dicyanobenzoquinone based cathode material for rechargeable lithium and sodium ion batteries
Abstract
Organic quinone materials allow a sustainable approach for electric energy storage, yet, their intrinsic electrical insulation and dissolution into the electrolyte during cycling have hampered their wide applications. To handle these two issues, we have synthesized a novel organic cathode material by anchoring a quinone compound, 2,3-dicyano-p-benzoquinone (DCBQ) with a high redox potential of 3.37 V vs. Li/Li+, onto carbon nanotubes (CNTs) (CNTs-DCBQ) through a facile ‘‘grafting to’’ method. The elaborate combination of excellent electron conductivity and large surface area of CNTs and stable and reversible redox reaction of DCBQ enables CNTs-DCBQ to deliver high reversible capacities of 206.9 and 175.8 mA h g–1 at a current density of 10 mA g–1 and also remarkable capacities of 110.2 and 82.1 mA h g–1 at a higher current density of 200 mA g–1 with a capacity retention approaching 100% after 1000 cycles for lithium and sodium ion batteries, respectively.
- Authors:
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[1];
[1];
[1];
[1];
[1];
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- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE
- OSTI Identifier:
- 1546544
- Alternate Identifier(s):
- OSTI ID: 1544592
- Grant/Contract Number:
- AC05-00OR22725; AC05-00OR22750; AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 30; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Lyu, Hailong, Jafta, Charl J., Popovs, Ilja, Meyer, Harry M., Hachtel, Jordan A., Huang, Jingsong, Sumpter, Bobby G., Dai, Sheng, and Sun, Xiao-Guang. A dicyanobenzoquinone based cathode material for rechargeable lithium and sodium ion batteries. United States: N. p., 2019.
Web. doi:10.1039/c9ta04869c.
Lyu, Hailong, Jafta, Charl J., Popovs, Ilja, Meyer, Harry M., Hachtel, Jordan A., Huang, Jingsong, Sumpter, Bobby G., Dai, Sheng, & Sun, Xiao-Guang. A dicyanobenzoquinone based cathode material for rechargeable lithium and sodium ion batteries. United States. https://doi.org/10.1039/c9ta04869c
Lyu, Hailong, Jafta, Charl J., Popovs, Ilja, Meyer, Harry M., Hachtel, Jordan A., Huang, Jingsong, Sumpter, Bobby G., Dai, Sheng, and Sun, Xiao-Guang. Mon .
"A dicyanobenzoquinone based cathode material for rechargeable lithium and sodium ion batteries". United States. https://doi.org/10.1039/c9ta04869c. https://www.osti.gov/servlets/purl/1546544.
@article{osti_1546544,
title = {A dicyanobenzoquinone based cathode material for rechargeable lithium and sodium ion batteries},
author = {Lyu, Hailong and Jafta, Charl J. and Popovs, Ilja and Meyer, Harry M. and Hachtel, Jordan A. and Huang, Jingsong and Sumpter, Bobby G. and Dai, Sheng and Sun, Xiao-Guang},
abstractNote = {Organic quinone materials allow a sustainable approach for electric energy storage, yet, their intrinsic electrical insulation and dissolution into the electrolyte during cycling have hampered their wide applications. To handle these two issues, we have synthesized a novel organic cathode material by anchoring a quinone compound, 2,3-dicyano-p-benzoquinone (DCBQ) with a high redox potential of 3.37 V vs. Li/Li+, onto carbon nanotubes (CNTs) (CNTs-DCBQ) through a facile ‘‘grafting to’’ method. The elaborate combination of excellent electron conductivity and large surface area of CNTs and stable and reversible redox reaction of DCBQ enables CNTs-DCBQ to deliver high reversible capacities of 206.9 and 175.8 mA h g–1 at a current density of 10 mA g–1 and also remarkable capacities of 110.2 and 82.1 mA h g–1 at a higher current density of 200 mA g–1 with a capacity retention approaching 100% after 1000 cycles for lithium and sodium ion batteries, respectively.},
doi = {10.1039/c9ta04869c},
journal = {Journal of Materials Chemistry. A},
number = 30,
volume = 7,
place = {United States},
year = {2019},
month = {7}
}
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Cited by: 26 works
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Scheme 1: Synthetic scheme for CNTs-DCBQ.
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Works referenced in this record:
Development and challenges of LiFePO 4 cathode material for lithium-ion batteries
journal, January 2011
- Yuan, Li-Xia; Wang, Zhao-Hui; Zhang, Wu-Xing
- Energy Environ. Sci., Vol. 4, Issue 2
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Sodium-ion batteries: present and future
journal, January 2017
- Hwang, Jang-Yeon; Myung, Seung-Taek; Sun, Yang-Kook
- Chemical Society Reviews, Vol. 46, Issue 12
A Novel Conductive Polymer-Sulfur Composite Cathode Material for Rechargeable Lithium Batteries
journal, July 2002
- Wang, J.; Yang, J.; Xie, J.
- Advanced Materials, Vol. 14, Issue 13-14, p. 963-965
Rechargeable batteries with organic radical cathodes
journal, June 2002
- Nakahara, K.; Iwasa, S.; Satoh, M.
- Chemical Physics Letters, Vol. 359, Issue 5-6, p. 351-354
Superior radical polymer cathode material with a two-electron process redox reaction promoted by graphene
journal, January 2012
- Guo, Wei; Yin, Ya-Xia; Xin, Sen
- Energy Environ. Sci., Vol. 5, Issue 1
Polyterthiophene/CNT composite as a cathode material for lithium batteries employing an ionic liquid electrolyte
journal, November 2009
- Sivakkumar, S. R.; Howlett, Patrick C.; Winther-Jensen, Bjorn
- Electrochimica Acta, Vol. 54, Issue 27
Lithium Salt of Tetrahydroxybenzoquinone: Toward the Development of a Sustainable Li-Ion Battery
journal, July 2009
- Chen, Haiyan; Armand, Michel; Courty, Matthieu
- Journal of the American Chemical Society, Vol. 131, Issue 25
A quinone-based oligomeric lithium salt for superior Li–organic batteries
journal, January 2014
- Song, Zhiping; Qian, Yumin; Liu, Xizheng
- Energy Environ. Sci., Vol. 7, Issue 12
Polythiophene coated aromatic polyimide enabled ultrafast and sustainable lithium ion batteries
journal, January 2017
- Lyu, Hailong; Liu, Jiurong; Mahurin, Shannon
- Journal of Materials Chemistry A, Vol. 5, Issue 46
Reversible multi-electron redox chemistry of π-conjugated N-containing heteroaromatic molecule-based organic cathodes
journal, May 2017
- Peng, Chengxin; Ning, Guo-Hong; Su, Jie
- Nature Energy, Vol. 2, Issue 7
Toward a High-Performance All-Plastic Full Battery with a'Single Organic Polymer as Both Cathode and Anode
journal, April 2018
- Xie, Jian; Wang, Zilong; Xu, Zhichuan J.
- Advanced Energy Materials, Vol. 8, Issue 21
Aromatic Polyimide/Graphene Composite Organic Cathodes for Fast and Sustainable Lithium-Ion Batteries
journal, January 2018
- Lyu, Hailong; Li, Peipei; Liu, Jiurong
- ChemSusChem, Vol. 11, Issue 4
Recent Progress in Polymeric Carbonyl-Based Electrode Materials for Lithium and Sodium Ion Batteries
journal, November 2018
- Amin, Kamran; Mao, Lijuan; Wei, Zhixiang
- Macromolecular Rapid Communications, Vol. 40, Issue 1
A Universal Organic Cathode for Ultrafast Lithium and Multivalent Metal Batteries
journal, May 2018
- Fan, Xiulin; Wang, Fei; Ji, Xiao
- Angewandte Chemie International Edition, Vol. 57, Issue 24
An Organic Pigment as a High-Performance Cathode for Sodium-Ion Batteries
journal, June 2014
- Luo, Wei; Allen, Marshall; Raju, Vadivukarasi
- Advanced Energy Materials, Vol. 4, Issue 15
Quinone Electrode Materials for Rechargeable Lithium/Sodium Ion Batteries
journal, May 2017
- Wu, Yiwen; Zeng, Ronghua; Nan, Junmin
- Advanced Energy Materials, Vol. 7, Issue 24
Carbonyls: Powerful Organic Materials for Secondary Batteries
journal, April 2015
- Häupler, Bernhard; Wild, Andreas; Schubert, Ulrich S.
- Advanced Energy Materials, Vol. 5, Issue 11
Quasi-Solid-State Rechargeable Lithium-Ion Batteries with a Calix[4]quinone Cathode and Gel Polymer Electrolyte
journal, July 2013
- Huang, Weiwei; Zhu, Zhiqiang; Wang, Lijiang
- Angewandte Chemie International Edition, Vol. 52, Issue 35
Factors affecting the battery performance of anthraquinone-based organic cathode materials
journal, January 2012
- Xu, Wu; Read, Adam; Koech, Phillip K.
- Journal of Materials Chemistry, Vol. 22, Issue 9
A Novel Coordination Polymer as Positive Electrode Material for Lithium Ion Battery
journal, January 2008
- Xiang, Jiangfeng; Chang, Caixian; Li, Ming
- Crystal Growth & Design, Vol. 8, Issue 1
Electroactive Organic Molecules Immobilized onto Solid Nanoparticles as a Cathode Material for Lithium-Ion Batteries
journal, August 2010
- Genorio, Bostjan; Pirnat, Klemen; Cerc-Korosec, Romana
- Angewandte Chemie International Edition, Vol. 49, Issue 40
Organic Nanohybrids for Fast and Sustainable Energy Storage
journal, February 2014
- Lee, Minah; Hong, Jihyun; Kim, Haegyeom
- Advanced Materials, Vol. 26, Issue 16
A MC/AQ Parasitic Composite as Cathode Material for Lithium Battery
journal, January 2011
- Lei, Zhao; Wei-kun, Wang; An-bang, Wang
- Journal of The Electrochemical Society, Vol. 158, Issue 9
High-Potential Reversible Li Deintercalation in a Substituted Tetrahydroxy-p-benzoquinone Dilithium Salt: An Experimental and Theoretical Study
journal, June 2012
- Barrès, Anne-Lise; Geng , Joaquin; Bonnard, Gaëtan
- Chemistry - A European Journal, Vol. 18, Issue 28
Introduction of two lithiooxycarbonyl groups enhances cyclability of lithium batteries with organic cathode materials
journal, August 2014
- Shimizu, Akihiro; Kuramoto, Hiroki; Tsujii, Yutaka
- Journal of Power Sources, Vol. 260
Polyanthraquinone as a Reliable Organic Electrode for Stable and Fast Lithium Storage
journal, September 2015
- Song, Zhiping; Qian, Yumin; Gordin, Mikhail L.
- Angewandte Chemie, Vol. 127, Issue 47
Quinone-Functionalized Carbon Black Cathodes for Lithium Batteries with High Power Densities
journal, May 2015
- Jaffe, Adam; Saldivar Valdes, Abraham; Karunadasa, Hemamala I.
- Chemistry of Materials, Vol. 27, Issue 10
Electrochemically stabilised quinone based electrode composites for Li-ion batteries
journal, February 2012
- Pirnat, Klemen; Dominko, Robert; Cerc-Korosec, Romana
- Journal of Power Sources, Vol. 199
Rechargeable organic lithium-ion batteries using electron-deficient benzoquinones as positive-electrode materials with high discharge voltages
journal, January 2014
- Yokoji, Takato; Matsubara, Hiroshi; Satoh, Masaharu
- J. Mater. Chem. A, Vol. 2, Issue 45
Universal quinone electrodes for long cycle life aqueous rechargeable batteries
journal, June 2017
- Liang, Yanliang; Jing, Yan; Gheytani, Saman
- Nature Materials, Vol. 16, Issue 8
Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All-Solid-State Sodium Batteries
journal, February 2018
- Chi, Xiaowei; Liang, Yanliang; Hao, Fang
- Angewandte Chemie International Edition, Vol. 57, Issue 10
Organic Electrode Materials for Rechargeable Lithium Batteries
journal, May 2012
- Liang, Yanliang; Tao, Zhanliang; Chen, Jun
- Advanced Energy Materials, Vol. 2, Issue 7
Design Strategies for Promising Organic Positive Electrodes in Lithium-Ion Batteries: Quinones and Carbon Materials
journal, October 2017
- Kim, Ki Chul
- Industrial & Engineering Chemistry Research, Vol. 56, Issue 42
Role of Oxygen Functional Groups in Carbon Nanotube/Graphene Freestanding Electrodes for High Performance Lithium Batteries
journal, June 2012
- Byon, Hye Ryung; Gallant, Betar M.; Lee, Seung Woo
- Advanced Functional Materials, Vol. 23, Issue 8
Radical Polymer-Wrapped SWNTs at a Molecular Level: High-Rate Redox Mediation Through a Percolation Network for a Transparent Charge-Storage Material
journal, August 2011
- Choi, Wonsung; Ohtani, Shota; Oyaizu, Kenichi
- Advanced Materials, Vol. 23, Issue 38
Grafting of a redox polymer onto carbon nanotubes for high capacity battery materials
journal, January 2015
- Ernould, Bruno; Devos, Marine; Bourgeois, Jean-Pierre
- Journal of Materials Chemistry A, Vol. 3, Issue 16
Alkali Metal Ion Storage of Quinone Molecules Grafted on Single-Walled Carbon Nanotubes at Low Temperature
journal, November 2018
- Li, Canghao; Nakamura, Motoumi; Inayama, Shunya
- ACS Omega, Vol. 3, Issue 11
Hexaazatriphenylene derivatives/GO composites as organic cathodes for lithium ion batteries
journal, January 2018
- Wang, Jinquan; Tee, Kaize; Lee, Yuhang
- Journal of Materials Chemistry A, Vol. 6, Issue 6
Electron binding energies of TCNQ and TCNE
journal, October 1996
- Zakrzewski, V. G.; Dolgounitcheva, O.; Ortiz, J. V.
- The Journal of Chemical Physics, Vol. 105, Issue 14
Rechargeable quasi-solid state lithium battery with organic crystalline cathode
journal, June 2012
- Hanyu, Yuki; Honma, Itaru
- Scientific Reports, Vol. 2, Issue 1
Solvent Effect in the Electrochemical Reduction of p-Quinones in Several Aprotic Solvents
journal, January 1990
- Sasaki, Kazuo
- Journal of The Electrochemical Society, Vol. 137, Issue 8
Electron affinities of benzo-, naphtho-, and anthraquinones determined from gas-phase equilibria measurements
journal, January 1988
- Heinis, Thomas.; Chowdhury, Swapan.; Scott, Susannah L.
- Journal of the American Chemical Society, Vol. 110, Issue 2
Gaussian-3 (G3) theory for molecules containing first and second-row atoms
journal, November 1998
- Curtiss, Larry A.; Raghavachari, Krishnan; Redfern, Paul C.
- The Journal of Chemical Physics, Vol. 109, Issue 18
Uncertainties in Scaling Factors for ab Initio Vibrational Frequencies
journal, September 2005
- Irikura, Karl K.; Johnson, Russell D.; Kacker, Raghu N.
- The Journal of Physical Chemistry A, Vol. 109, Issue 37
Synthesis of Six-Membered Functionalized Carbocyclic Compounds by One-Pot Reaction of Hydroquinone Derivatives and Dienes
journal, October 2011
- Cai, Guang-Rong; Guan, Zhi; He, Yan-Hong
- Synthetic Communications, Vol. 41, Issue 20
Nitration of phenolic compounds and oxidation of hydroquinones using tetrabutylammonium chromate and dichromate under aprotic conditions
journal, January 2011
- Pourali, Ali Reza; Goli, Arezou
- Journal of Chemical Sciences, Vol. 123, Issue 1
2D Supramolecular networks of dibenzonitrilediacetylene on Ag(111) stabilized by intermolecular hydrogen bonding
journal, January 2017
- Galeotti, G.; Ebrahimi, M.; Lipton-Duffin, J.
- Physical Chemistry Chemical Physics, Vol. 19, Issue 16
Adsorption of benzonitrile and alkyl cyanides on evaporated nickel and palladium films studied by XPS
journal, January 1987
- Nakayama, T.; Inamura, K.; Inoue, Y.
- Surface Science, Vol. 179, Issue 1
Rapid fabrication of thick spray-layer-by-layer carbon nanotube electrodes for high power and energy devices
journal, January 2013
- Kim, Sung Yeol; Hong, Jinkee; Kavian, Reza
- Energy & Environmental Science, Vol. 6, Issue 3
Über die Zuordnung von Wellenfunktionen und Eigenwerten zu den Einzelnen Elektronen Eines Atoms
journal, January 1934
- Koopmans, T.
- Physica, Vol. 1, Issue 1-6
Electrochemical lithium-ion storage properties of quinone molecules encapsulated in single-walled carbon nanotubes
journal, January 2016
- Ishii, Yosuke; Tashiro, Kosuke; Hosoe, Kento
- Physical Chemistry Chemical Physics, Vol. 18, Issue 15
Quinone molecules encapsulated in SWCNTs for low-temperature Na ion batteries
journal, July 2017
- Li, Canghao; Ishii, Yosuke; Inayama, Shunya
- Nanotechnology, Vol. 28, Issue 35
Renewable-Biomolecule-Based Full Lithium-Ion Batteries
journal, March 2016
- Hu, Pengfei; Wang, Hua; Yang, Yun
- Advanced Materials, Vol. 28, Issue 18
Bioinspired Redox-Active Catechol-Bearing Polymers as Ultrarobust Organic Cathodes for Lithium Storage
journal, September 2017
- Patil, Nagaraj; Aqil, Abdelhafid; Ouhib, Farid
- Advanced Materials, Vol. 29, Issue 40
Cross-conjugated oligomeric quinones for high performance organic batteries
journal, July 2017
- Jing, Yan; Liang, Yanliang; Gheytani, Saman
- Nano Energy, Vol. 37
Electroactive Organic Molecules Immobilized onto Solid Nanoparticles as a Cathode Material for Lithium-Ion Batteries
journal, August 2010
- Genorio, Bostjan; Pirnat, Klemen; Cerc-Korosec, Romana
- Angewandte Chemie, Vol. 122, Issue 40
Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All-Solid-State Sodium Batteries
journal, February 2018
- Chi, Xiaowei; Liang, Yanliang; Hao, Fang
- Angewandte Chemie, Vol. 130, Issue 10
A Universal Organic Cathode for Ultrafast Lithium and Multivalent Metal Batteries
journal, May 2018
- Fan, Xiulin; Wang, Fei; Ji, Xiao
- Angewandte Chemie, Vol. 130, Issue 24
Polyanthraquinone as a Reliable Organic Electrode for Stable and Fast Lithium Storage
journal, September 2015
- Song, Zhiping; Qian, Yumin; Gordin, Mikhail L.
- Angewandte Chemie International Edition, Vol. 54, Issue 47
Adsorption of benzonitrile and alkyl cyanides on evaporated nickel and palladium films studied by xps
journal, January 1987
- Nakayama, T.; Inamura, K.; Inoue, Y.
- Surface Science Letters, Vol. 179, Issue 1
Works referencing / citing this record:
Bioinspired large-scale production of multidimensional high-rate anodes for both liquid & solid-state lithium ion batteries
journal, January 2019
- Shen, Shenghui; Zhang, Shengzhao; Deng, Shengjue
- Journal of Materials Chemistry A, Vol. 7, Issue 40
Triple Layer Tungsten Trioxide, Graphene, and Polyaniline Composite Films for Combined Energy Storage and Electrochromic Applications
journal, December 2019
- Lyu, Hailong
- Polymers, Vol. 12, Issue 1
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