Anchoring carbon nanotubes and post-hydroxylation treatment enhanced Ni nanofiber catalysts towards efficient hydrous hydrazine decomposition for effective hydrogen generation
Abstract
For effective hydrogen generation with remarkable durability, carbon nanotubes (CNTs) grown on Ni nanofibers and their post hydroxylation treatment engendered active Ni nanofiber catalysts an efficient decomposition of hydrous hydrazine with a turnover frequency (TOF) of 19.4 h-1 and an activation energy down to 51.05 KJ mol-1.
- Authors:
-
[1];
[2];
[1];
[10]
- Chinese Academy of Engineering Physics, Jiangyou (China)
- Max Planck Inst. for Chemical Energy Conversion, Mülheim (Germany)
- Hainan Univ., Haikou (China); Univ. of Tennessee, Knoxville, TN (United States)
- Southwest Minzu Univ., Chengdu (China)
- Univ. of Tennessee, Knoxville, TN (United States); Zhengzhou Univ., Zhengzhou (China)
- Zhengzhou Univ. of Light Industry, Zhengzhou (China)
- Shandong Univ. of Science and Technology, Qingdao (China)
- Henan Univ., Kaifeng (China)
- Guangzhou Univ., Guangzhou (China)
- Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE; National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1546532
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 55; Journal Issue: 61; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 08 HYDROGEN
Citation Formats
Yang, Pan, Yang, Lijun, Gao, Qiang, Luo, Qiang, Zhao, Xiaochong, Mai, Xianmin, Fu, Qinglong, Dong, Mengyao, Wang, Jingchuan, Hao, Yawei, Yang, Ruizhu, Lai, Xinchun, Wu, Shide, Shao, Qian, Ding, Tao, Lin, Jing, and Guo, Zhanhu. Anchoring carbon nanotubes and post-hydroxylation treatment enhanced Ni nanofiber catalysts towards efficient hydrous hydrazine decomposition for effective hydrogen generation. United States: N. p., 2019.
Web. doi:10.1039/C9CC04559G.
Yang, Pan, Yang, Lijun, Gao, Qiang, Luo, Qiang, Zhao, Xiaochong, Mai, Xianmin, Fu, Qinglong, Dong, Mengyao, Wang, Jingchuan, Hao, Yawei, Yang, Ruizhu, Lai, Xinchun, Wu, Shide, Shao, Qian, Ding, Tao, Lin, Jing, & Guo, Zhanhu. Anchoring carbon nanotubes and post-hydroxylation treatment enhanced Ni nanofiber catalysts towards efficient hydrous hydrazine decomposition for effective hydrogen generation. United States. https://doi.org/10.1039/C9CC04559G
Yang, Pan, Yang, Lijun, Gao, Qiang, Luo, Qiang, Zhao, Xiaochong, Mai, Xianmin, Fu, Qinglong, Dong, Mengyao, Wang, Jingchuan, Hao, Yawei, Yang, Ruizhu, Lai, Xinchun, Wu, Shide, Shao, Qian, Ding, Tao, Lin, Jing, and Guo, Zhanhu. Thu .
"Anchoring carbon nanotubes and post-hydroxylation treatment enhanced Ni nanofiber catalysts towards efficient hydrous hydrazine decomposition for effective hydrogen generation". United States. https://doi.org/10.1039/C9CC04559G. https://www.osti.gov/servlets/purl/1546532.
@article{osti_1546532,
title = {Anchoring carbon nanotubes and post-hydroxylation treatment enhanced Ni nanofiber catalysts towards efficient hydrous hydrazine decomposition for effective hydrogen generation},
author = {Yang, Pan and Yang, Lijun and Gao, Qiang and Luo, Qiang and Zhao, Xiaochong and Mai, Xianmin and Fu, Qinglong and Dong, Mengyao and Wang, Jingchuan and Hao, Yawei and Yang, Ruizhu and Lai, Xinchun and Wu, Shide and Shao, Qian and Ding, Tao and Lin, Jing and Guo, Zhanhu},
abstractNote = {For effective hydrogen generation with remarkable durability, carbon nanotubes (CNTs) grown on Ni nanofibers and their post hydroxylation treatment engendered active Ni nanofiber catalysts an efficient decomposition of hydrous hydrazine with a turnover frequency (TOF) of 19.4 h-1 and an activation energy down to 51.05 KJ mol-1.},
doi = {10.1039/C9CC04559G},
journal = {ChemComm},
number = 61,
volume = 55,
place = {United States},
year = {Thu Jun 27 00:00:00 EDT 2019},
month = {Thu Jun 27 00:00:00 EDT 2019}
}
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Figures / Tables:
Fig. 1: (a) Contact angles of CNTs, Ni-NF, Ni-CNTs and Ni-CNTs-OH, (b) n(N2+H2)/n(N2H4) versus time for CNTs, Ni-NF, Ni-CNTs and Ni-CNTs-OH at 333 K in 1.0 M NaOH solution (Catalyst = 0.02 g, V(N2H4∙H2O) = 0.08 mL), (c) Durability tests for the decomposition of N2H4∙H2O catalyzed by Ni-NF, NiCNTs andmore »
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