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Title: Entropy-Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO2 Fixation

Abstract

Abstract High‐entropy materials refer to a kind of materials in which five or more metal species were incorporated deliberately into a single lattice with random occupancy. Up to now, such a concept has been only restricted to hard materials, such as high‐entropy alloys and ceramics. Herein we report the synthesis of hybrid high‐entropy materials, polymetallic zeolitic imidazolate framework (also named as high‐entropy zeolitic imidazolate framework, HE‐ZIF), via entropy‐driven room‐temperature mechanochemistry. HE‐ZIF contains five metals including Zn II , Co II , Cd II , Ni II , and Cu II which are dispersed in the ZIF structure randomly. Moreover, HE‐ZIF shows enhanced catalytic conversion of CO 2 into carbonate compared with ZIF‐8 presumably a result of the synergistic effect of the five metal ions as Lewis acid in epoxide activation.

Authors:
 [1];  [2]; ORCiD logo [3];  [3];  [4]; ORCiD logo [3]
  1. Ningbo Univ. (China); Univ. of Tennessee, Knoxville, TN (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States)
  3. Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Ningbo Univ. (China)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1546506
Alternate Identifier(s):
OSTI ID: 1498180
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition); Journal Volume: 58; Journal Issue: 15; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Xu, Wei, Chen, Hao, Jie, Kecheng, Yang, Zhenzhen, Li, Tingting, and Dai, Sheng. Entropy-Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO2 Fixation. United States: N. p., 2019. Web. doi:10.1002/anie.201900787.
Xu, Wei, Chen, Hao, Jie, Kecheng, Yang, Zhenzhen, Li, Tingting, & Dai, Sheng. Entropy-Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO2 Fixation. United States. https://doi.org/10.1002/anie.201900787
Xu, Wei, Chen, Hao, Jie, Kecheng, Yang, Zhenzhen, Li, Tingting, and Dai, Sheng. Mon . "Entropy-Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO2 Fixation". United States. https://doi.org/10.1002/anie.201900787. https://www.osti.gov/servlets/purl/1546506.
@article{osti_1546506,
title = {Entropy-Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO2 Fixation},
author = {Xu, Wei and Chen, Hao and Jie, Kecheng and Yang, Zhenzhen and Li, Tingting and Dai, Sheng},
abstractNote = {Abstract High‐entropy materials refer to a kind of materials in which five or more metal species were incorporated deliberately into a single lattice with random occupancy. Up to now, such a concept has been only restricted to hard materials, such as high‐entropy alloys and ceramics. Herein we report the synthesis of hybrid high‐entropy materials, polymetallic zeolitic imidazolate framework (also named as high‐entropy zeolitic imidazolate framework, HE‐ZIF), via entropy‐driven room‐temperature mechanochemistry. HE‐ZIF contains five metals including Zn II , Co II , Cd II , Ni II , and Cu II which are dispersed in the ZIF structure randomly. Moreover, HE‐ZIF shows enhanced catalytic conversion of CO 2 into carbonate compared with ZIF‐8 presumably a result of the synergistic effect of the five metal ions as Lewis acid in epoxide activation.},
doi = {10.1002/anie.201900787},
journal = {Angewandte Chemie (International Edition)},
number = 15,
volume = 58,
place = {United States},
year = {2019},
month = {2}
}

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