Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication

Huang, He; Strater, Zack M.; Rauch, Michael; Shee, James; Sisto, Thomas J.; Nuckolls, Colin; Lambert, Tristan H.

doi:10.1002/ange.201906381

Title: Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication

Authors:

Huang, He ^[1]; Strater, Zack M. ^[2]; Rauch, Michael ^[2]; Shee, James ^[2]; Sisto, Thomas J. ^[2]; Nuckolls, Colin ^[2];

^[3]

Department of Chemistry and Chemical Biology Cornell University Ithaca NY 14853 USA
Department of Chemistry Columbia University New York NY 10027 USA
Department of Chemistry and Chemical Biology Cornell University Ithaca NY 14853 USA, Department of Chemistry Columbia University New York NY 10027 USA

Publication Date:: 2019-08-02

Sponsoring Org.:: USDOE

OSTI Identifier:: 1546094

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie

Additional Journal Information:: Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 38; Journal ID: ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Huang, He, Strater, Zack M., Rauch, Michael, Shee, James, Sisto, Thomas J., Nuckolls, Colin, and Lambert, Tristan H. Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication.  Germany: N. p., 2019. 
Web.  doi:10.1002/ange.201906381.

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                    Huang, He, Strater, Zack M., Rauch, Michael, Shee, James, Sisto, Thomas J., Nuckolls, Colin, & Lambert, Tristan H. Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication.  Germany.  https://doi.org/10.1002/ange.201906381

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                    Huang, He, Strater, Zack M., Rauch, Michael, Shee, James, Sisto, Thomas J., Nuckolls, Colin, and Lambert, Tristan H. Fri .  
"Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication".  Germany.  https://doi.org/10.1002/ange.201906381.

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@article{osti_1546094,

  title        = {Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication},

  author       = {Huang, He and Strater, Zack M. and Rauch, Michael and Shee, James and Sisto, Thomas J. and Nuckolls, Colin and Lambert, Tristan H.},

  abstractNote = {},

  doi          = {10.1002/ange.201906381},

  journal      = {Angewandte Chemie},

  number       = 38,

  volume       = 131,

  place        = {Germany},

  year         = {2019},

  month        = {8}

}

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Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication

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Title: Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication

Citation Formats

Solar Synthesis: Prospects in Visible Light Photocatalysis journal, February 2014

Phenothiazine Radical Cation Excited States as Super-oxidants for Energy-Demanding Reactions journal, March 2018

Organic Photoredox Catalysis journal, June 2016

Accurate Oxidation Potentials of Benzene and Biphenyl Derivatives via Electron-Transfer Equilibria and Transient Kinetics journal, August 2009

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Catalysis of Radical Reactions: A Radical Chemistry Perspective journal, October 2015

Tris (dimethylamino)-cyclopropenium radical dication journal, January 1971

Direct Oxygenation of Benzene to Phenol Using Quinolinium Ions as Homogeneous Photocatalysts journal, August 2011

Phototochemistry of cation radicals in solution; photoinduced electron-transfer reactions between alcholos and the N,N,N′,N′,-tetraphenyl-p-phenylenediamine cation radical journal, January 1982

Merging Photochemistry with Electrochemistry: Functional‐Group Tolerant Electrochemical Amination of C(sp 3 )−H Bonds journal, February 2019

Visible-light excitation of iminium ions enables the enantioselective catalytic β-alkylation of enals journal, March 2017

Redox catalysis in organic electrosynthesis: basic principles and recent developments journal, January 2014

Modern Strategies in Electroorganic Synthesis journal, July 2008

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Merging Photochemistry with Electrochemistry: Functional-Group Tolerant Electrochemical Amination of C(sp 3 )−H Bonds journal, March 2019

Synthesis and reactions of porphine-type metal complexes. 15. Carbon-carbon bond formation by light assisted B12-catalysis. Nucleophilic acylation of Michael olefins journal, November 1983

Visible-Light-Induced Oxygenation of Benzene by the Triplet Excited State of 2,3-Dichloro-5,6-dicyano- p -benzoquinone journal, March 2013

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Cyclopropenium Salts as Cyclable, High-Potential Catholytes in Nonaqueous Media journal, November 2016

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Synthetic Applications of Anodic Electrochemistry journal, December 2000

Photoelectrocatalytic arene C–H amination journal, February 2019

Stable radical dications journal, January 1975

Site-selective arene C-H amination via photoredox catalysis journal, September 2015

Direct Oxygenation of Benzene to Phenol Using Quinolinium Ions as Homogeneous Photocatalysts journal, August 2011

Photoelectrochemical C−H Alkylation of Heteroarenes with Organotrifluoroborates journal, January 2019

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Electrochemistry of heterosubstituted cyclopropenyl cations journal, February 1976

Photoredox Catalysis in Organic Chemistry journal, June 2016

Visible light photoredox catalysis: applications in organic synthesis journal, January 2011

Aminocyclopropenium Ions: Synthesis, Properties, and Applications journal, August 2013

Solar Synthesis: Prospects in Visible Light Photocatalysis
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Phenothiazine Radical Cation Excited States as Super-oxidants for Energy-Demanding Reactions
journal, March 2018

Organic Photoredox Catalysis
journal, June 2016

Accurate Oxidation Potentials of Benzene and Biphenyl Derivatives via Electron-Transfer Equilibria and Transient Kinetics
journal, August 2009

Photoelectrochemical C−H Alkylation of Heteroarenes with Organotrifluoroborates
journal, February 2019

Catalysis of Radical Reactions: A Radical Chemistry Perspective
journal, October 2015

Tris (dimethylamino)-cyclopropenium radical dication
journal, January 1971

Direct Oxygenation of Benzene to Phenol Using Quinolinium Ions as Homogeneous Photocatalysts
journal, August 2011

Phototochemistry of cation radicals in solution; photoinduced electron-transfer reactions between alcholos and the N,N,N′,N′,-tetraphenyl-p-phenylenediamine cation radical
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Merging Photochemistry with Electrochemistry: Functional‐Group Tolerant Electrochemical Amination of C(sp ³ )−H Bonds
journal, February 2019

Visible-light excitation of iminium ions enables the enantioselective catalytic β-alkylation of enals
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Redox catalysis in organic electrosynthesis: basic principles and recent developments
journal, January 2014

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journal, December 2017

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journal, October 2017

Merging Photochemistry with Electrochemistry: Functional-Group Tolerant Electrochemical Amination of C(sp ³ )−H Bonds
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Synthesis and reactions of porphine-type metal complexes. 15. Carbon-carbon bond formation by light assisted B12-catalysis. Nucleophilic acylation of Michael olefins
journal, November 1983

Visible-Light-Induced Oxygenation of Benzene by the Triplet Excited State of 2,3-Dichloro-5,6-dicyano- p -benzoquinone
journal, March 2013

Studies Leading to the Development of a Single-Electron Transfer (SET) Photochemical Strategy for Syntheses of Macrocyclic Polyethers, Polythioethers, and Polyamides
journal, March 2011

Cyclopropenium Salts as Cyclable, High-Potential Catholytes in Nonaqueous Media
journal, November 2016

Katalyse von Radikalreaktionen: Konzepte aus Sicht der Radikalchemie
journal, October 2015

Synthetic Applications of Anodic Electrochemistry
journal, December 2000

Photoelectrocatalytic arene C–H amination
journal, February 2019

Stable radical dications
journal, January 1975

Site-selective arene C-H amination via photoredox catalysis
journal, September 2015

Direct Oxygenation of Benzene to Phenol Using Quinolinium Ions as Homogeneous Photocatalysts
journal, August 2011

Photoelectrochemical C−H Alkylation of Heteroarenes with Organotrifluoroborates
journal, January 2019

Photo-induced oxidant-free oxidative C–H/N–H cross-coupling between arenes and azoles
journal, February 2017

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journal, February 1976

Photoredox Catalysis in Organic Chemistry
journal, June 2016

Visible light photoredox catalysis: applications in organic synthesis
journal, January 2011

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journal, August 2013