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Title: Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride

Authors:
 [1];  [2];  [1];  [1];  [3];  [1];  [3]; ORCiD logo [1]
+ Show Author Affiliations
  1. Center for Catalytic Science and Technology, Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy Street Newark DE 19716 USA
  2. Department of Physics, Florida A&M University, Tallahassee FL 32307 USA
  3. Chemistry Division, Brookhaven National Laboratory, Upton NY 11973 USA, Department of Chemical Engineering, Columbia University, New York NY 10027 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1545935
Grant/Contract Number:  
SC0016537; FG02-13ER16381
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition) Journal Volume: 58 Journal Issue: 39; Journal ID: ISSN 1433-7851
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Yang, Xuan, Kattel, Shyam, Nash, Jared, Chang, Xiaoxia, Lee, Ji Hoon, Yan, Yushan, Chen, Jingguang G., and Xu, Bingjun. Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride. Germany: N. p., 2019. Web. doi:10.1002/anie.201906449.
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Yang, Xuan, Kattel, Shyam, Nash, Jared, Chang, Xiaoxia, Lee, Ji Hoon, Yan, Yushan, Chen, Jingguang G., & Xu, Bingjun. Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride. Germany. doi:10.1002/anie.201906449.
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Yang, Xuan, Kattel, Shyam, Nash, Jared, Chang, Xiaoxia, Lee, Ji Hoon, Yan, Yushan, Chen, Jingguang G., and Xu, Bingjun. Thu . "Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride". Germany. doi:10.1002/anie.201906449.
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@article{osti_1545935,
title = {Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride},
author = {Yang, Xuan and Kattel, Shyam and Nash, Jared and Chang, Xiaoxia and Lee, Ji Hoon and Yan, Yushan and Chen, Jingguang G. and Xu, Bingjun},
abstractNote = {},
doi = {10.1002/anie.201906449},
journal = {Angewandte Chemie (International Edition)},
number = 39,
volume = 58,
place = {Germany},
year = {2019},
month = {8}
}
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Journal Article:
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This content will become publicly available on July 31, 2020
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DOI:  10.1002/anie.201906449
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Works referenced in this record:

Computational Predictions of Catalytic Activity of Zincblende (110) Surfaces of Metal Nitrides for Electrochemical Ammonia Synthesis
journal, March 2017

  • Abghoui, Younes; Skúlason, Egill
  • The Journal of Physical Chemistry C, Vol. 121, Issue 11
  • DOI: 10.1021/acs.jpcc.7b00196

Recent advances in metal nitrides as high-performance electrode materials for energy storage devices
journal, January 2015

  • Balogun, Muhammad-Sadeeq; Qiu, Weitao; Wang, Wang
  • Journal of Materials Chemistry A, Vol. 3, Issue 4
  • DOI: 10.1039/C4TA05565A

Au Sub-Nanoclusters on TiO 2 toward Highly Efficient and Selective Electrocatalyst for N 2 Conversion to NH 3 at Ambient Conditions
journal, February 2017

How a century of ammonia synthesis changed the world
journal, September 2008

  • Erisman, Jan Willem; Sutton, Mark A.; Galloway, James
  • Nature Geoscience, Vol. 1, Issue 10
  • DOI: 10.1038/ngeo325

Electroreduction of N 2 to Ammonia at Ambient Conditions on Mononitrides of Zr, Nb, Cr, and V: A DFT Guide for Experiments
journal, December 2015

Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles
journal, September 2018

  • Yang, Xuan; Nash, Jared; Anibal, Jacob
  • Journal of the American Chemical Society, Vol. 140, Issue 41
  • DOI: 10.1021/jacs.8b08379

Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
journal, November 2004

  • Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 46
  • DOI: 10.1021/jp047349j

Electrochemical Nitrogen Reduction Reaction on Noble Metal Catalysts in Proton and Hydroxide Exchange Membrane Electrolyzers
journal, January 2017

  • Nash, Jared; Yang, Xuan; Anibal, Jacob
  • Journal of The Electrochemical Society, Vol. 164, Issue 14
  • DOI: 10.1149/2.0071802jes

Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids
journal, January 2017

  • Zhou, Fengling; Azofra, Luis Miguel; Ali, Muataz
  • Energy & Environmental Science, Vol. 10, Issue 12
  • DOI: 10.1039/C7EE02716H

Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store
journal, October 2012

  • Kitano, Masaaki; Inoue, Yasunori; Yamazaki, Youhei
  • Nature Chemistry, Vol. 4, Issue 11
  • DOI: 10.1038/nchem.1476

Favoring the unfavored: Selective electrochemical nitrogen fixation using a reticular chemistry approach
journal, March 2018

  • Lee, Hiang Kwee; Koh, Charlynn Sher Lin; Lee, Yih Hong
  • Science Advances, Vol. 4, Issue 3
  • DOI: 10.1126/sciadv.aar3208

Synthesis of ammonia directly from air and water at ambient temperature and pressure
journal, January 2013

  • Lan, Rong; Irvine, John T. S.; Tao, Shanwen
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep01145

Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocages
journal, July 2018

Promoting nitrogen electroreduction to ammonia with bismuth nanocrystals and potassium cations in water
journal, March 2019

Transition Metal Nitride Catalysts for Electrochemical Reduction of Nitrogen to Ammonia at Ambient Conditions
journal, January 2015

Ambient ammonia synthesis via palladium-catalyzed electrohydrogenation of dinitrogen at low overpotential
journal, May 2018

Effect of Cationic Promoters on the Kinetics of Ammonia Synthesis Catalyzed by Ruthenium Supported on Zeolite X
journal, October 1998

  • Bécue, Thierry; Davis, Robert J.; Garces, Juan M.
  • Journal of Catalysis, Vol. 179, Issue 1
  • DOI: 10.1006/jcat.1998.2212

Ammonia synthesis from N 2 and H 2 O using a lithium cycling electrification strategy at atmospheric pressure
journal, January 2017

  • McEnaney, Joshua M.; Singh, Aayush R.; Schwalbe, Jay A.
  • Energy & Environmental Science, Vol. 10, Issue 7
  • DOI: 10.1039/C7EE01126A

Single-Boron Catalysts for Nitrogen Reduction Reaction
journal, February 2019

  • Liu, Chuangwei; Li, Qinye; Wu, Chengzhang
  • Journal of the American Chemical Society, Vol. 141, Issue 7
  • DOI: 10.1021/jacs.8b13165

A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements
journal, May 2019

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