Structural Transformation and Melting in Gold Shock Compressed to 355 GPa

doi:10.1103/PhysRevLett.123.045702

Title: Structural Transformation and Melting in Gold Shock Compressed to 355 GPa

Abstract

Gold is believed to retain its ambient crystal structure to very high pressures under static and shock compression, enabling its wide use as a pressure marker. Our in situ x-ray diffraction measurements on shock-compressed gold show that it transforms to the body-centered-cubic (bcc) phase, with an onset pressure between 150-176 GPa. Liquid/bcc coexistence was observed between 220-302 GPa and complete melting occurs by 355 GPa. Furthermore, our observation of the lower coordination bcc structure in shocked gold is in marked contrast with theoretical predictions and the reported observation of the hexagonal-close-packed structure under static compression.

Authors:

Sharma, Surinder M. ^[1]; Turneaure, Stefan J. ^[1]; Winey, J. M. ^[1]; Li, Yuelin ^[2]; Rigg, Paulo ^[3]; Schuman, Adam ^[3]; Sinclair, Nicholas ^[3]; Toyoda, Y. ^[1]; Wang, Xiaoming ^[3]; Weir, Nicholas ^[3]; Zhang, Jun ^[3]; Gupta, Y. M. ^[1]

Washington State Univ., Pullman, WA (United States)
Washington State Univ., Argonne, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
Washington State Univ., Argonne, IL (United States)

Publication Date:: 2019-07-24

Research Org.:: Washington State Univ., Pullman, WA (United States). Inst. for Shock Physics

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA), Office of Defense Programs (DP)

OSTI Identifier:: 1545791

Alternate Identifier(s):: OSTI ID: 1545420

Grant/Contract Number:: NA0002007; NA0002442; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review Letters

Additional Journal Information:: Journal Volume: 123; Journal Issue: 4; Journal ID: ISSN 0031-9007

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Sharma, Surinder M., Turneaure, Stefan J., Winey, J. M., Li, Yuelin, Rigg, Paulo, Schuman, Adam, Sinclair, Nicholas, Toyoda, Y., Wang, Xiaoming, Weir, Nicholas, Zhang, Jun, and Gupta, Y. M. Structural Transformation and Melting in Gold Shock Compressed to 355 GPa.  United States: N. p., 2019. 
        Web.  doi:10.1103/PhysRevLett.123.045702.

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                    Sharma, Surinder M., Turneaure, Stefan J., Winey, J. M., Li, Yuelin, Rigg, Paulo, Schuman, Adam, Sinclair, Nicholas, Toyoda, Y., Wang, Xiaoming, Weir, Nicholas, Zhang, Jun, & Gupta, Y. M. Structural Transformation and Melting in Gold Shock Compressed to 355 GPa.  United States.  doi:10.1103/PhysRevLett.123.045702.

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                    Sharma, Surinder M., Turneaure, Stefan J., Winey, J. M., Li, Yuelin, Rigg, Paulo, Schuman, Adam, Sinclair, Nicholas, Toyoda, Y., Wang, Xiaoming, Weir, Nicholas, Zhang, Jun, and Gupta, Y. M. Wed .  
        "Structural Transformation and Melting in Gold Shock Compressed to 355 GPa".  United States.  doi:10.1103/PhysRevLett.123.045702.  https://www.osti.gov/servlets/purl/1545791.

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@article{osti_1545791,

  title        = {Structural Transformation and Melting in Gold Shock Compressed to 355 GPa},

  author       = {Sharma, Surinder M. and Turneaure, Stefan J. and Winey, J. M. and Li, Yuelin and Rigg, Paulo and Schuman, Adam and Sinclair, Nicholas and Toyoda, Y. and Wang, Xiaoming and Weir, Nicholas and Zhang, Jun and Gupta, Y. M.},

  abstractNote = {Gold is believed to retain its ambient crystal structure to very high pressures under static and shock compression, enabling its wide use as a pressure marker. Our in situ x-ray diffraction measurements on shock-compressed gold show that it transforms to the body-centered-cubic (bcc) phase, with an onset pressure between 150-176 GPa. Liquid/bcc coexistence was observed between 220-302 GPa and complete melting occurs by 355 GPa. Furthermore, our observation of the lower coordination bcc structure in shocked gold is in marked contrast with theoretical predictions and the reported observation of the hexagonal-close-packed structure under static compression.},

  doi          = {10.1103/PhysRevLett.123.045702},

  journal      = {Physical Review Letters},

  number       = 4,

  volume       = 123,

  place        = {United States},

  year         = {2019},

  month        = {7}

}

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DOI: 10.1103/PhysRevLett.123.045702

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Title: Structural Transformation and Melting in Gold Shock Compressed to 355 GPa

Abstract

Citation Formats

Ab initio calculations of the elastic and thermodynamic properties of gold under pressure journal, February 2017

Plasticity Induced by Shock Waves in Nonequilibrium Molecular-Dynamics Simulations journal, June 1998

Direct Observation of the α − ε Transition in Shock-Compressed Iron via Nanosecond X-Ray Diffraction journal, August 2005

Phase transition lowering in dynamically compressed silicon journal, September 2018

Theoretical Confirmation of the High Pressure Simple Cubic Phase in Calcium journal, November 1995

Strategies for in situ laser heating in the diamond anvil cell at an X-ray diffraction beamline journal, November 2013

Equations of state of six metals above 94 GPa journal, September 2004

The laser shock station in the dynamic compression sector. I journal, May 2019

High-Pressure Structural Phase Transitions in Na, Mg, and Al journal, March 1982

Laser interferometer for measuring high velocities of any reflecting surface journal, November 1972

�ber den Mechanismus der Stahlh�rtung journal, May 1930

Measurement of Body-Centered Cubic Gold and Melting under Shock Compression journal, July 2019

Real-Time Examination of Atomistic Mechanisms during Shock-Induced Structural Transformation in Silicon journal, July 2016

Why gold is the noblest of all the metals journal, July 1995

The equation of state of the gold calibration standard journal, February 1984

Direct Observations of a Dynamically Driven Phase Transition with in situ X-Ray Diffraction in a Simple Ionic Crystal journal, December 2017

Theoretical prediction of a phase transition in gold journal, April 2001

High-pressure phase diagram of gold from first-principles calculations: Converging to an isotropic atomic stacking order journal, March 2016

Shock adiabatic curves of metals: New data, statistical analysis, and general laws journal, January 1981

Noblest of All Metals Is Structurally Unstable at High Pressure journal, January 2007

Comment on “Theoretical prediction of phase transition in gold” journal, November 2002

Phase transitions under shock-wave loading journal, July 1977

Shock melting and Hugoniot calculations for gold journal, February 1990

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Isothermal equation of state for gold with a He-pressure medium journal, September 2008

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Measurement of temperature in the laser heated diamond anvil cell: comparison between reflective and refractive optics journal, May 2018

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Structural transformations including melting and recrystallization during shock compression and release of germanium up to 45 GPa journal, April 2019

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Equation of state and high-pressure/high-temperature phase diagram of magnesium journal, October 2014

Ab initio calculations of the elastic and thermodynamic properties of gold under pressure
journal, February 2017

Plasticity Induced by Shock Waves in Nonequilibrium Molecular-Dynamics Simulations
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Direct Observation of the $α − ε$ Transition in Shock-Compressed Iron via Nanosecond X-Ray Diffraction
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Phase transition lowering in dynamically compressed silicon
journal, September 2018

Theoretical Confirmation of the High Pressure Simple Cubic Phase in Calcium
journal, November 1995

Strategies for in situ laser heating in the diamond anvil cell at an X-ray diffraction beamline
journal, November 2013

Equations of state of six metals above $94 GPa$
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The laser shock station in the dynamic compression sector. I
journal, May 2019

High-Pressure Structural Phase Transitions in Na, Mg, and Al
journal, March 1982

Laser interferometer for measuring high velocities of any reflecting surface
journal, November 1972

�ber den Mechanismus der Stahlh�rtung
journal, May 1930

Measurement of Body-Centered Cubic Gold and Melting under Shock Compression
journal, July 2019

Real-Time Examination of Atomistic Mechanisms during Shock-Induced Structural Transformation in Silicon
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Why gold is the noblest of all the metals
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The equation of state of the gold calibration standard
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Direct Observations of a Dynamically Driven Phase Transition with in situ X-Ray Diffraction in a Simple Ionic Crystal
journal, December 2017

Theoretical prediction of a phase transition in gold
journal, April 2001

High-pressure phase diagram of gold from first-principles calculations: Converging to an isotropic atomic stacking order
journal, March 2016

Shock adiabatic curves of metals: New data, statistical analysis, and general laws
journal, January 1981

Noblest of All Metals Is Structurally Unstable at High Pressure
journal, January 2007

Comment on “Theoretical prediction of phase transition in gold”
journal, November 2002

Phase transitions under shock-wave loading
journal, July 1977

Shock melting and Hugoniot calculations for gold
journal, February 1990

Hidden pathway during fcc to bcc/bct transformations: Crystallographic origin of slip martensite in steels
journal, September 2018

Isothermal equation of state for gold with a He-pressure medium
journal, September 2008

Phase transitions in alkaline earth metals under pressure
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Theoretical extension of the gold pressure calibration standard beyond 3 Mbars
journal, May 2003

Melting of Copper, Silver, and Gold at High Pressures
journal, May 1966

Lattice dynamics and the high-pressure equation of state of Au
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journal, December 2013

Terapascal static pressure generation with ultrahigh yield strength nanodiamond
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Measurement of temperature in the laser heated diamond anvil cell: comparison between reflective and refractive optics
journal, May 2018

Determining the refractive index of shocked [100] lithium fluoride to the limit of transmissibility
journal, July 2014

Two-dimensional detector software: From real detector to idealised image or two-theta scan
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journal, April 2019

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journal, April 2000

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journal, October 2014