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Title: Effect of ligand substituents on nickel and copper [N 4 ] complexes: electronic and redox behavior, and reactivity towards protons

Abstract

The ligand substituents have a major effect on the redox potentials, catalytic efficiency and robustness of the complexes in HER.

Authors:
 [1];  [1];  [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]
  1. Department of Chemistry, Wayne State University, Detroit, USA
  2. Department of Chemistry, University of Alabama, Huntsville, USA
  3. Instituto de Química, Universidade Federal Fluminense, Niterói, Brazil
  4. Department of Chemistry, Indian Institute of Technology Jammu, Jammu (J&K), India
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1545647
Grant/Contract Number:  
SC0001907
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
New Journal of Chemistry
Additional Journal Information:
Journal Name: New Journal of Chemistry Journal Volume: 43 Journal Issue: 32; Journal ID: ISSN 1144-0546
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Kankanamalage, Pavithra H. A., Ekanayake, Danushka M., Singh, Nirupama, de Morais, Ana C. P., Mazumder, Shivnath, Verani, Cláudio N., Mukherjee, Anusree, and Lanznaster, Mauricio. Effect of ligand substituents on nickel and copper [N 4 ] complexes: electronic and redox behavior, and reactivity towards protons. United Kingdom: N. p., 2019. Web. doi:10.1039/C9NJ01283D.
Kankanamalage, Pavithra H. A., Ekanayake, Danushka M., Singh, Nirupama, de Morais, Ana C. P., Mazumder, Shivnath, Verani, Cláudio N., Mukherjee, Anusree, & Lanznaster, Mauricio. Effect of ligand substituents on nickel and copper [N 4 ] complexes: electronic and redox behavior, and reactivity towards protons. United Kingdom. doi:10.1039/C9NJ01283D.
Kankanamalage, Pavithra H. A., Ekanayake, Danushka M., Singh, Nirupama, de Morais, Ana C. P., Mazumder, Shivnath, Verani, Cláudio N., Mukherjee, Anusree, and Lanznaster, Mauricio. Mon . "Effect of ligand substituents on nickel and copper [N 4 ] complexes: electronic and redox behavior, and reactivity towards protons". United Kingdom. doi:10.1039/C9NJ01283D.
@article{osti_1545647,
title = {Effect of ligand substituents on nickel and copper [N 4 ] complexes: electronic and redox behavior, and reactivity towards protons},
author = {Kankanamalage, Pavithra H. A. and Ekanayake, Danushka M. and Singh, Nirupama and de Morais, Ana C. P. and Mazumder, Shivnath and Verani, Cláudio N. and Mukherjee, Anusree and Lanznaster, Mauricio},
abstractNote = {The ligand substituents have a major effect on the redox potentials, catalytic efficiency and robustness of the complexes in HER.},
doi = {10.1039/C9NJ01283D},
journal = {New Journal of Chemistry},
number = 32,
volume = 43,
place = {United Kingdom},
year = {2019},
month = {8}
}

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Works referenced in this record:

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