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Title: Role of conductive binder to direct solid–electrolyte interphase formation over silicon anodes

Abstract

With the use of in situ neutron reflectometry (NR) we show how the addition of an electronically conductive polymeric binder, PEFM, mediates the solid–electrolyte interphase (SEI) formation and composition on an amorphous Si (a-Si) electrode as a function of the state-of-charge.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [5]
  1. Department of Materials Science and Engineering, University of Tennessee, Knoxville, USA, Chemical Sciences Division
  2. Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, USA
  3. Neutron Science Laboratory, High Energy Accelerator Research Organization, 203-1 Shirakata, Tokai, Naka, Japan
  4. Electrochemistry Division, Lawrence Berkeley National Laboratory, San Francisco, USA
  5. Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1545403
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print) Journal Volume: 21 Journal Issue: 31; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Browning, Katie L., Browning, James F., Doucet, Mathieu, Yamada, Norifumi L., Liu, Gao, and Veith, Gabriel M. Role of conductive binder to direct solid–electrolyte interphase formation over silicon anodes. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CP02610J.
Browning, Katie L., Browning, James F., Doucet, Mathieu, Yamada, Norifumi L., Liu, Gao, & Veith, Gabriel M. Role of conductive binder to direct solid–electrolyte interphase formation over silicon anodes. United Kingdom. doi:10.1039/C9CP02610J.
Browning, Katie L., Browning, James F., Doucet, Mathieu, Yamada, Norifumi L., Liu, Gao, and Veith, Gabriel M. Wed . "Role of conductive binder to direct solid–electrolyte interphase formation over silicon anodes". United Kingdom. doi:10.1039/C9CP02610J.
@article{osti_1545403,
title = {Role of conductive binder to direct solid–electrolyte interphase formation over silicon anodes},
author = {Browning, Katie L. and Browning, James F. and Doucet, Mathieu and Yamada, Norifumi L. and Liu, Gao and Veith, Gabriel M.},
abstractNote = {With the use of in situ neutron reflectometry (NR) we show how the addition of an electronically conductive polymeric binder, PEFM, mediates the solid–electrolyte interphase (SEI) formation and composition on an amorphous Si (a-Si) electrode as a function of the state-of-charge.},
doi = {10.1039/C9CP02610J},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 31,
volume = 21,
place = {United Kingdom},
year = {2019},
month = {8}
}

Journal Article:
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