[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex
Abstract
Abstract We report the small‐scale synthesis, isolated yield, single‐crystal X‐ray structure, 1 H NMR solution spectroscopy /solid‐state UV/Vis‐nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am 3+ organometallic complex, [Am(C 5 Me 4 H) 3 ] ( 1 ). This constitutes the first quantitative data on Am−C bonding in a molecular species.
- Authors:
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[1];
[2];
[3];
[4];
[2];
[5];
[6];
[7];
[1];
[1];
[8];
[9];
[2]
- Chemistry Division Los Alamos National Laboratory Los Alamos NM 87545 USA
- Theoretical Division Los Alamos National Laboratory Los Alamos NM 87545 USA
- Department of Chemistry and Biochemistry Florida State University 95 Chieftain Way Tallahassee FL 32306 USA
- Chemistry Division Los Alamos National Laboratory Los Alamos NM 87545 USA, Department of Chemistry University of Iowa, E311 Chemistry Building Iowa City IA 52245-1294 USA
- Department of Chemistry University of Iowa, E311 Chemistry Building Iowa City IA 52245-1294 USA
- Fachbereich Chemie und Wissenschaftliches Zentrum für Materialwissenschaften Philipps-Universität Marburg Hans-Meerwein-Strasse 4 35043 Marburg Germany
- Department of Chemistry University of California, Irvine 1102 Natural Sciences II Irvine CA 92697-2025 USA
- Chemistry Division Los Alamos National Laboratory Los Alamos NM 87545 USA, Fachbereich Chemie und Wissenschaftliches Zentrum für Materialwissenschaften Philipps-Universität Marburg Hans-Meerwein-Strasse 4 35043 Marburg Germany
- Materials Physics and Applications Division Los Alamos National Laboratory Los Alamos NM 87545 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1545168
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 34; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Goodwin, Conrad A. P., Su, Jing, Albrecht‐Schmitt, Thomas E., Blake, Anastasia V., Batista, Enrique R., Daly, Scott R., Dehnen, Stefanie, Evans, William J., Gaunt, Andrew J., Kozimor, Stosh A., Lichtenberger, Niels, Scott, Brian L., and Yang, Ping. [Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex. Germany: N. p., 2019.
Web. doi:10.1002/ange.201905225.
Goodwin, Conrad A. P., Su, Jing, Albrecht‐Schmitt, Thomas E., Blake, Anastasia V., Batista, Enrique R., Daly, Scott R., Dehnen, Stefanie, Evans, William J., Gaunt, Andrew J., Kozimor, Stosh A., Lichtenberger, Niels, Scott, Brian L., & Yang, Ping. [Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex. Germany. https://doi.org/10.1002/ange.201905225
Goodwin, Conrad A. P., Su, Jing, Albrecht‐Schmitt, Thomas E., Blake, Anastasia V., Batista, Enrique R., Daly, Scott R., Dehnen, Stefanie, Evans, William J., Gaunt, Andrew J., Kozimor, Stosh A., Lichtenberger, Niels, Scott, Brian L., and Yang, Ping. Thu .
"[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex". Germany. https://doi.org/10.1002/ange.201905225.
@article{osti_1545168,
title = {[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex},
author = {Goodwin, Conrad A. P. and Su, Jing and Albrecht‐Schmitt, Thomas E. and Blake, Anastasia V. and Batista, Enrique R. and Daly, Scott R. and Dehnen, Stefanie and Evans, William J. and Gaunt, Andrew J. and Kozimor, Stosh A. and Lichtenberger, Niels and Scott, Brian L. and Yang, Ping},
abstractNote = {Abstract We report the small‐scale synthesis, isolated yield, single‐crystal X‐ray structure, 1 H NMR solution spectroscopy /solid‐state UV/Vis‐nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am 3+ organometallic complex, [Am(C 5 Me 4 H) 3 ] ( 1 ). This constitutes the first quantitative data on Am−C bonding in a molecular species.},
doi = {10.1002/ange.201905225},
journal = {Angewandte Chemie},
number = 34,
volume = 131,
place = {Germany},
year = {2019},
month = {7}
}
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