[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex

Goodwin, Conrad A. P.; Su, Jing; Albrecht‐Schmitt, Thomas E.; Blake, Anastasia V.; Batista, Enrique R.; Daly, Scott R.; Dehnen, Stefanie; Evans, William J.; Gaunt, Andrew J.; Kozimor, Stosh A.; Lichtenberger, Niels; Scott, Brian L.; Yang, Ping

doi:10.1002/ange.201905225

Title: [Am(C ₅ Me ₄ H) ₃ ]: An Organometallic Americium Complex

Journal Article · 25 July 2019 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.201905225 · OSTI ID:1545168

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Chemistry Division Los Alamos National Laboratory Los Alamos NM 87545 USA
Theoretical Division Los Alamos National Laboratory Los Alamos NM 87545 USA
Department of Chemistry and Biochemistry Florida State University 95 Chieftain Way Tallahassee FL 32306 USA
Chemistry Division Los Alamos National Laboratory Los Alamos NM 87545 USA, Department of Chemistry University of Iowa, E311 Chemistry Building Iowa City IA 52245-1294 USA
Department of Chemistry University of Iowa, E311 Chemistry Building Iowa City IA 52245-1294 USA
Fachbereich Chemie und Wissenschaftliches Zentrum für Materialwissenschaften Philipps-Universität Marburg Hans-Meerwein-Strasse 4 35043 Marburg Germany
Department of Chemistry University of California, Irvine 1102 Natural Sciences II Irvine CA 92697-2025 USA
Chemistry Division Los Alamos National Laboratory Los Alamos NM 87545 USA, Fachbereich Chemie und Wissenschaftliches Zentrum für Materialwissenschaften Philipps-Universität Marburg Hans-Meerwein-Strasse 4 35043 Marburg Germany
Materials Physics and Applications Division Los Alamos National Laboratory Los Alamos NM 87545 USA

Abstract We report the small‐scale synthesis, isolated yield, single‐crystal X‐ray structure, ¹ H NMR solution spectroscopy /solid‐state UV/Vis‐nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am ³⁺ organometallic complex, [Am(C ₅ Me ₄ H) ₃ ] ( 1 ). This constitutes the first quantitative data on Am−C bonding in a molecular species.

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Sponsoring Organization:: USDOE

OSTI ID:: 1545168

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 131 Journal Issue: 34; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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