Enabling liquid vapor analysis using synchrotron VUV single photon ionization mass spectrometry with a microfluidic interface
Abstract
Vacuum ultraviolet (VUV) single photon ionization mass spectrometry (SPI-MS) is a vacuum-based technique typically used for the analysis of gas phase and solid samples, but not for liquids due to the challenge in introducing volatile liquids in a vacuum. Here we present the first demonstration of in situ liquid analysis by integrating the System for Analysis at the Liquid Vacuum Interface (SALVI) microfluidic reactor into VUV SPI-MS. Four representative volatile organic compound (VOC) solutions were used to illustrate the feasibility of liquid analysis. Our results show the accurate mass identification of the VOC molecules and the reliable determination of appearance energy that is consistent with ionization energy for gaseous species in the literature as reported. Finally, this work validates that the vacuum-compatible SALVI microfluidic interface can be utilized at the synchrotron beamline and enable the in situ study of gas-phase molecules evaporating off the surface of a liquid, which holds importance in the study of condensed matter chemistry.
- Authors:
-
[1];
[2];
[2];
[1]
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division; USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1545066
- Alternate Identifier(s):
- OSTI ID: 1608261
- Report Number(s):
- PNNL-SA-139017
Journal ID: ISSN 0034-6748
- Grant/Contract Number:
- AC05-76RL01830; AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Review of Scientific Instruments
- Additional Journal Information:
- Journal Volume: 89; Journal Issue: 11; Journal ID: ISSN 0034-6748
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 47 OTHER INSTRUMENTATION; SALVI; VOCs; appearance energy; ionization energy; liquid; VUV single photon ionization mass spectrometry
Citation Formats
Komorek, Rachael, Xu, Bo, Yao, Juan, Ablikim, Utug, Troy, Tyler P., Kostko, Oleg, Ahmed, Musahid, and Yu, Xiao-Ying. Enabling liquid vapor analysis using synchrotron VUV single photon ionization mass spectrometry with a microfluidic interface. United States: N. p., 2018.
Web. doi:10.1063/1.5048315.
Komorek, Rachael, Xu, Bo, Yao, Juan, Ablikim, Utug, Troy, Tyler P., Kostko, Oleg, Ahmed, Musahid, & Yu, Xiao-Ying. Enabling liquid vapor analysis using synchrotron VUV single photon ionization mass spectrometry with a microfluidic interface. United States. doi:10.1063/1.5048315.
Komorek, Rachael, Xu, Bo, Yao, Juan, Ablikim, Utug, Troy, Tyler P., Kostko, Oleg, Ahmed, Musahid, and Yu, Xiao-Ying. Fri .
"Enabling liquid vapor analysis using synchrotron VUV single photon ionization mass spectrometry with a microfluidic interface". United States. doi:10.1063/1.5048315. https://www.osti.gov/servlets/purl/1545066.
@article{osti_1545066,
title = {Enabling liquid vapor analysis using synchrotron VUV single photon ionization mass spectrometry with a microfluidic interface},
author = {Komorek, Rachael and Xu, Bo and Yao, Juan and Ablikim, Utug and Troy, Tyler P. and Kostko, Oleg and Ahmed, Musahid and Yu, Xiao-Ying},
abstractNote = {Vacuum ultraviolet (VUV) single photon ionization mass spectrometry (SPI-MS) is a vacuum-based technique typically used for the analysis of gas phase and solid samples, but not for liquids due to the challenge in introducing volatile liquids in a vacuum. Here we present the first demonstration of in situ liquid analysis by integrating the System for Analysis at the Liquid Vacuum Interface (SALVI) microfluidic reactor into VUV SPI-MS. Four representative volatile organic compound (VOC) solutions were used to illustrate the feasibility of liquid analysis. Our results show the accurate mass identification of the VOC molecules and the reliable determination of appearance energy that is consistent with ionization energy for gaseous species in the literature as reported. Finally, this work validates that the vacuum-compatible SALVI microfluidic interface can be utilized at the synchrotron beamline and enable the in situ study of gas-phase molecules evaporating off the surface of a liquid, which holds importance in the study of condensed matter chemistry.},
doi = {10.1063/1.5048315},
journal = {Review of Scientific Instruments},
number = 11,
volume = 89,
place = {United States},
year = {2018},
month = {11}
}
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 3 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
In situ detection of methylene blue in tissues by laser desorption vacuum ultraviolet single photon postionization mass spectrometry
journal, November 2013
- Yang, Qing; Hu, Yongjun; Wei, Yanchun
- International Journal of Mass Spectrometry, Vol. 353
Untangling the chemical evolution of Titan's atmosphere and surface–from homogeneous to heterogeneous chemistry
journal, January 2010
- Kaiser, Ralf I.; Maksyutenko, Pavlo; Ennis, Courtney
- Faraday Discussions, Vol. 147
Probing Combustion Chemistry in a Miniature Shock Tube with Synchrotron VUV Photo Ionization Mass Spectrometry
journal, January 2015
- Lynch, Patrick T.; Troy, Tyler P.; Ahmed, Musahid
- Analytical Chemistry, Vol. 87, Issue 4
Electrospray/VUV single-photon ionization mass spectrometry for the analysis of organic compounds
journal, March 2009
- Yang, Zheng; Zhang, Taichang; Pan, Yang
- Journal of the American Society for Mass Spectrometry, Vol. 20, Issue 3
Radical-driven processes within a peptidic sequence of type I collagen upon single-photon ionisation in the gas phase
journal, January 2017
- Schwob, Lucas; Lalande, Mathieu; Egorov, Dmitrii
- Physical Chemistry Chemical Physics, Vol. 19, Issue 34
Dissociative Photoionization of Glycerol and its Dimer Occurs Predominantly via a Ternary Hydrogen-Bridged Ion–Molecule Complex
journal, September 2013
- Bell, Franziska; Ruan, Qiao N.; Golan, Amir
- Journal of the American Chemical Society, Vol. 135, Issue 38
Relationship between Oxidation Level and Optical Properties of Secondary Organic Aerosol
journal, May 2013
- Lambe, Andrew T.; Cappa, Christopher D.; Massoli, Paola
- Environmental Science & Technology, Vol. 47, Issue 12
Making a hybrid microfluidic platform compatible for in situ imaging by vacuum-based techniques
journal, November 2011
- Yang, Li; Yu, Xiao-Ying; Zhu, Zihua
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 29, Issue 6
<em>In Situ</em> Characterization of <em>Shewanella oneidensis</em> MR1 Biofilms by SALVI and ToF-SIMS
journal, January 2017
- Komorek, Rachel; Wei, Wenchao; Yu, Xiaofei
- Journal of Visualized Experiments, Issue 126
Synchrotron Radiation Based Aerosol Time-of-Flight Mass Spectrometry for Organic Constituents
journal, September 2005
- Mysak, Erin R.; Wilson, Kevin R.; Jimenez-Cruz, Michael
- Analytical Chemistry, Vol. 77, Issue 18
Light and Molecular Ions: The Emergence of Vacuum UV Single-Photon Ionization in MS
journal, June 2009
- Hanley, Luke; Zimmermann, Ralf
- Analytical Chemistry, Vol. 81, Issue 11
Soft X-ray spectroscopy of nanoparticles by velocity map imaging
journal, July 2017
- Kostko, O.; Xu, B.; Jacobs, M. I.
- The Journal of Chemical Physics, Vol. 147, Issue 1
Probing liquid surfaces under vacuum using SEM and ToF-SIMS
journal, January 2011
- Yang, Li; Yu, Xiao-Ying; Zhu, Zihua
- Lab on a Chip, Vol. 11, Issue 15
In Situ Molecular Imaging of the Biofilm and Its Matrix
journal, October 2016
- Ding, Yuanzhao; Zhou, Yufan; Yao, Juan
- Analytical Chemistry, Vol. 88, Issue 22
Characterization of Poly(dimethylsiloxane)s by Time-of-Flight Secondary Ion Mass Spectrometry
journal, January 1997
- Dong, Xia; Proctor, Andrew; Hercules, David M.
- Macromolecules, Vol. 30, Issue 1
Photoelectron spectroscopy of carbonyls. Urea, oxamide, oxalic acid, and oxamic acid
journal, July 1975
- Meeks, J. L.; Arnett, J. F.; Larson, D. B.
- Journal of the American Chemical Society, Vol. 97, Issue 14
Chemical imaging of molecular changes in a hydrated single cell by dynamic secondary ion mass spectrometry and super-resolution microscopy
journal, April 2016
- Hua, Xin; Szymanski, Craig; Wang, Zhaoying
- Integrative Biology, Vol. 8, Issue 5
Excited electronic states of the .alpha.-dicarbonyls
journal, July 1974
- Arnett, J. F.; Newkome, G.; Mattice, W. L.
- Journal of the American Chemical Society, Vol. 96, Issue 14
Multiphoton ionization photoelectron spectroscopy and two-color multiphoton ionization threshold spectroscopy on the hydrogen bonded phenol and 7-azaindole in a supersonic jet
journal, June 1984
- Fuke, Kiyokazu; Yoshiuchi, Hidetoshi; Kaya, Koji
- Chemical Physics Letters, Vol. 108, Issue 2
Deciphering the aqueous chemistry of glyoxal oxidation with hydrogen peroxide using molecular imaging
journal, January 2017
- Sui, Xiao; Zhou, Yufan; Zhang, Fei
- Physical Chemistry Chemical Physics, Vol. 19, Issue 31
Direct Determination of the Ionization Energies of PtC, PtO, and PtO 2 with VUV Radiation †
journal, October 2008
- Citir, Murat; Metz, Ricardo B.; Belau, Leonid
- The Journal of Physical Chemistry A, Vol. 112, Issue 39
Vacuum Ultraviolet Photoionization of Complex Chemical Systems
journal, May 2016
- Kostko, Oleg; Bandyopadhyay, Biswajit; Ahmed, Musahid
- Annual Review of Physical Chemistry, Vol. 67, Issue 1
Capturing the transient species at the electrode–electrolyte interface by in situ dynamic molecular imaging
journal, January 2016
- Yu, Jiachao; Zhou, Yufan; Hua, Xin
- Chemical Communications, Vol. 52, Issue 73
Photochemical Kinetics of Pyruvic Acid in Aqueous Solution
journal, April 2014
- Reed Harris, Allison E.; Ervens, Barbara; Shoemaker, Richard K.
- The Journal of Physical Chemistry A, Vol. 118, Issue 37
A VUV Photoionization and Ab Initio Determination of the Ionization Energy of a Gas-Phase Sugar (Deoxyribose)
journal, December 2011
- Ghosh, Debashree; Golan, Amir; Takahashi, Lynelle K.
- The Journal of Physical Chemistry Letters, Vol. 3, Issue 1
A photoionization study of the energetics of the C7H7+ ion formed from C7H8 precursors
journal, August 1978
- Traeger, J. C.; McLoughlin, R. G.
- International Journal of Mass Spectrometry and Ion Physics, Vol. 27, Issue 4
Vacuum Ultraviolet (VUV) Photoionization of Small Water Clusters
journal, October 2007
- Belau, Leonid; Wilson, Kevin R.; Leone, Stephen R.
- The Journal of Physical Chemistry A, Vol. 111, Issue 40
Determination of the Ionization Potentials of Security-Relevant Substances with Single Photon Ionization Mass Spectrometry Using Synchrotron Radiation
journal, February 2008
- Schramm, E.; Mühlberger, F.; Mitschke, S.
- Applied Spectroscopy, Vol. 62, Issue 2
Reassessing the atmospheric oxidation mechanism of toluene
journal, July 2017
- Ji, Yuemeng; Zhao, Jun; Terazono, Hajime
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 31
Two coexisting liquid phases in switchable ionic liquids
journal, January 2017
- Yao, Juan; Lao, David B.; Sui, Xiao
- Physical Chemistry Chemical Physics, Vol. 19, Issue 34
Thermal Vaporization of Biological Nanoparticles: Fragment-Free Vacuum Ultraviolet Photoionization Mass Spectra of Tryptophan, Phenylalanine−Glycine−Glycine, and β-Carotene
journal, February 2006
- Wilson, Kevin R.; Jimenez-Cruz, Michael; Nicolas, Christophe
- The Journal of Physical Chemistry A, Vol. 110, Issue 6
Imaging liquids using microfluidic cells
journal, May 2013
- Yu, Xiao-Ying; Liu, Bingwen; Yang, Li
- Microfluidics and Nanofluidics, Vol. 15, Issue 6
Conformation specific and charge directed reactivity of radical cation intermediates of α-substituted (amino, hydroxy, and keto) bioactive carboxylic acids
journal, January 2010
- Bhattacharya, Atanu; Shin, Joong-Won; Clawson, Keven J.
- Physical Chemistry Chemical Physics, Vol. 12, Issue 33
<em>In Situ</em> Characterization of Boehmite Particles in Water Using Liquid SEM
journal, January 2017
- Yao, Juan; Arey, Bruce W.; Yang, Li
- Journal of Visualized Experiments, Issue 127
In situ chemical probing of the electrode–electrolyte interface by ToF-SIMS
journal, January 2014
- Liu, Bingwen; Yu, Xiao-Ying; Zhu, Zihua
- Lab Chip, Vol. 14, Issue 5
In situ SEM and ToF-SIMS analysis of IgG conjugated gold nanoparticles at aqueous surfaces : In situ SEM and ToF-SIMS analysis of aqueous Au nanoparticles
journal, March 2013
- Yang, Li; Zhu, Zihua; Yu, Xiao-Ying
- Surface and Interface Analysis, Vol. 46, Issue 4
Heterogeneous Photochemistry of Oxalic Acid on Mauritanian Sand and Icelandic Volcanic Ash
journal, August 2012
- Styler, Sarah A.; Donaldson, D. J.
- Environmental Science & Technology, Vol. 46, Issue 16
Photoelectron spectra of carbonyls
journal, January 1975
- McGlynn, S. P.; Meeks, J. L.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 6, Issue 4
Photoelectron spectra of carbonyls, carbonates, oxalates and esterification effects
journal, January 1976
- McGlynn, S. P.; Meeks, J. L.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 8, Issue 2
Desorption Dynamics, Internal Energies, and Imaging of Organic Molecules from Surfaces with Laser Desorption and Vacuum Ultraviolet (VUV) Photoionization
journal, August 2011
- Kostko, Oleg; Takahashi, Lynelle K.; Ahmed, Musahid
- Chemistry - An Asian Journal, Vol. 6, Issue 11
The direct observation of secondary radical chain chemistry in the heterogeneous reaction of chlorine atoms with submicron squalane droplets
journal, January 2011
- Liu, Chen-Lin; Smith, Jared D.; Che, Dung L.
- Physical Chemistry Chemical Physics, Vol. 13, Issue 19
Accurate ionization potentials of phenol and phenol‐(H 2 O) from the electric field dependence of the pump–probe photoionization threshold
journal, March 1990
- Lipert, Robert J.; Colson, Steven D.
- The Journal of Chemical Physics, Vol. 92, Issue 5
Toward the Oxidation of the Phenyl Radical and Prevention of PAH Formation in Combustion Systems
journal, November 2014
- Parker, Dorian S. N.; Kaiser, Ralf I.; Troy, Tyler P.
- The Journal of Physical Chemistry A, Vol. 119, Issue 28
Characterization of polysiloxanes with different functional groups by time-of-flight secondary ion mass spectrometry
journal, April 1998
- Dong, Xia; Gusev, Arkady; Hercules, David M.
- Journal of the American Society for Mass Spectrometry, Vol. 9, Issue 4
Dynamics and Kinetics at the Gas−Liquid Interface
journal, January 1996
- Nathanson, Gilbert M.; Davidovits, Paul; Worsnop, Douglas R.
- The Journal of Physical Chemistry, Vol. 100, Issue 31
In situ molecular imaging of a hydrated biofilm in a microfluidic reactor by ToF-SIMS
journal, January 2014
- Hua, Xin; Yu, Xiao-Ying; Wang, Zhaoying
- The Analyst, Vol. 139, Issue 7
A vacuum ultraviolet photoionization study on the thermal decomposition of ammonium perchlorate
journal, January 2018
- Góbi, Sándor; Zhao, Long; Xu, Bo
- Chemical Physics Letters, Vol. 691
A new instrument of VUV laser desorption/ionization mass spectrometry imaging with micrometer spatial resolution and low level of molecular fragmentation
journal, November 2017
- Wang, Jia; Liu, Feng; Mo, Yuxiang
- Review of Scientific Instruments, Vol. 88, Issue 11
Photoionization and Dissociative Photoionization Study of Cholesterol by IR Laser Desorption/Tunable Synchrotron VUV Photoionization Mass Spectrometry
journal, April 2009
- Pan, Yang; Zhang, Li-dong; Guo, Hui-jun
- Chinese Journal of Chemical Physics, Vol. 22, Issue 2
Gas–liquid interactions in solution
journal, January 2005
- Costa Gomes, M. F.; Pádua, A. A. H.
- Pure and Applied Chemistry, Vol. 77, Issue 3
Works referencing / citing this record:
From atoms to aerosols: probing clusters and nanoparticles with synchrotron based mass spectrometry and X-ray spectroscopy
journal, January 2020
- Ahmed, Musahid; Kostko, Oleg
- Physical Chemistry Chemical Physics, Vol. 22, Issue 5