Correlating structure and transport behavior in Li+ and O2 containing pyrrolidinium ionic liquids
Abstract
Using experiments and molecular simulations, we evaluate pyrrolidinium-based ionic liquid Li electrolytes and find that Li+ and O2 transport can be enhanced by varying the pyrrolidinium structure and Li concentration.
- Authors:
-
[1];
[2];
- BMW Technology Office, Mountain View, CA (United States); Mountain View; USA; Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1570269
- Alternate Identifier(s):
- OSTI ID: 1544907
- Report Number(s):
- SAND-2019-10362J
Journal ID: ISSN 1463-9076; PPCPFQ; 679030; TRN: US2100016
- Grant/Contract Number:
- AC04-94AL85000; NA0003525
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP
- Additional Journal Information:
- Journal Volume: 21; Journal Issue: 31; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Gittleson, Forrest S., Ward, Donald K., Jones, Reese E., Zarkesh, Ryan A., Sheth, Tanvi, and Foster, Michael E. Correlating structure and transport behavior in Li+ and O2 containing pyrrolidinium ionic liquids. United States: N. p., 2019.
Web. doi:10.1039/C9CP02355K.
Gittleson, Forrest S., Ward, Donald K., Jones, Reese E., Zarkesh, Ryan A., Sheth, Tanvi, & Foster, Michael E. Correlating structure and transport behavior in Li+ and O2 containing pyrrolidinium ionic liquids. United States. https://doi.org/10.1039/C9CP02355K
Gittleson, Forrest S., Ward, Donald K., Jones, Reese E., Zarkesh, Ryan A., Sheth, Tanvi, and Foster, Michael E. Mon .
"Correlating structure and transport behavior in Li+ and O2 containing pyrrolidinium ionic liquids". United States. https://doi.org/10.1039/C9CP02355K. https://www.osti.gov/servlets/purl/1570269.
@article{osti_1570269,
title = {Correlating structure and transport behavior in Li+ and O2 containing pyrrolidinium ionic liquids},
author = {Gittleson, Forrest S. and Ward, Donald K. and Jones, Reese E. and Zarkesh, Ryan A. and Sheth, Tanvi and Foster, Michael E.},
abstractNote = {Using experiments and molecular simulations, we evaluate pyrrolidinium-based ionic liquid Li electrolytes and find that Li+ and O2 transport can be enhanced by varying the pyrrolidinium structure and Li concentration.},
doi = {10.1039/C9CP02355K},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 31,
volume = 21,
place = {United States},
year = {Mon Jul 15 00:00:00 EDT 2019},
month = {Mon Jul 15 00:00:00 EDT 2019}
}
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Figures / Tables:
Figure 1: Molecular structures. Atoms colored by partial charge (red:-1,blue:+1).
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