Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Cao, Yuhe; Zhang, Kuang; Sanyal, Oishi; Koros, William J.

doi:10.1002/ange.201906653

Title: Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Abstract

Abstract Dip coating and pyrolysis processes are used to create multi‐layer asymmetric carbon molecular sieve (CMS) hollow fiber membranes with excellent gas separation properties. Coating of an economical engineered support with a high‐performance polyimide to create precursor fibers with a dense skin layer reduces material cost by 25‐fold compared to monolithic precursors or ceramic supports. CMS permeation results with CO ₂ /CH ₄ (50:50) mixed gas feed show attractive CO ₂ /CH ₄ selectivity of 58.8 and CO ₂ permeance of 310 GPU at 35 °C.

Authors:

Cao, Yuhe ^[1]; Zhang, Kuang ^[1]; Sanyal, Oishi ^[1];

^[1]

School of Chemical &, Biomolecular Engineering Georgia Institute of Technology 311 Ferst Dr. NW Atlanta GA 30332 USA

Publication Date:: 2019-07-25

Sponsoring Org.:: USDOE

OSTI Identifier:: 1544901

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie

Additional Journal Information:: Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 35; Journal ID: ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Cao, Yuhe, Zhang, Kuang, Sanyal, Oishi, and Koros, William J. Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers.  Germany: N. p., 2019. 
Web.  doi:10.1002/ange.201906653.

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                    Cao, Yuhe, Zhang, Kuang, Sanyal, Oishi, & Koros, William J. Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers.  Germany.  https://doi.org/10.1002/ange.201906653

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                    Cao, Yuhe, Zhang, Kuang, Sanyal, Oishi, and Koros, William J. Thu .  
"Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers".  Germany.  https://doi.org/10.1002/ange.201906653.

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@article{osti_1544901,

  title        = {Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers},

  author       = {Cao, Yuhe and Zhang, Kuang and Sanyal, Oishi and Koros, William J.},

  abstractNote = {Abstract Dip coating and pyrolysis processes are used to create multi‐layer asymmetric carbon molecular sieve (CMS) hollow fiber membranes with excellent gas separation properties. Coating of an economical engineered support with a high‐performance polyimide to create precursor fibers with a dense skin layer reduces material cost by 25‐fold compared to monolithic precursors or ceramic supports. CMS permeation results with CO 2 /CH 4 (50:50) mixed gas feed show attractive CO 2 /CH 4 selectivity of 58.8 and CO 2 permeance of 310 GPU at 35 °C.},

  doi          = {10.1002/ange.201906653},

  journal      = {Angewandte Chemie},

  number       = 35,

  volume       = 131,

  place        = {Germany},

  year         = {2019},

  month        = {7}

}

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Title: Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Abstract

Citation Formats

Carbon molecular sieve membranes from polyetherimide journal, December 1998

Investigation of porosity of carbon materials and related effects on gas separation properties journal, February 2003

Carbon molecular sieve membranes derived from thermally labile polymer containing blend polymers and their gas separation properties journal, November 2004

Carbon molecular sieve membranes derived from Matrimid® polyimide for nitrogen/methane separation journal, January 2014

Effect of polymer precursors on carbon molecular sieve structure and separation performance properties journal, December 2010

Ultrathin carbon molecular sieve membrane for propylene/propane separation journal, August 2015

Preparation of Carbon Molecular Sieve Membrane and Diffusion of Binary Mixtures in the Membrane journal, December 1994

Enhanced H2/CH4 and H2/CO2 separation by carbon molecular sieve membrane coated on titania modified alumina support: Effects of TiO2 intermediate layer preparation variables on interfacial adhesion journal, July 2016

Carbon membranes from blends of PBI and polyimides for N2/CH4 and CO2/CH4 separation and hydrogen purification journal, February 2009

Precursor Selection and Process Conditions in the Preparation of Carbon Membrane for Gas Separation: A Review journal, April 2011

High-Flux Carbon Molecular Sieve Membranes for Gas Separation journal, June 2017

Effect of block versus random copolyimide structure on hollow fiber membrane spinnability journal, May 2017

Effect of pyrolysis temperature and operating temperature on the performance of nanoporous carbon membranes journal, September 2008

Improvement of CO2/CH4 separation characteristics of polyimides by chemical crosslinking journal, March 1999

Carbon molecular sieve membranes supported on non-modified ceramic tubes for hydrogen separation in membrane reactors journal, September 2012

Fabrication of carbon membranes for gas separation––a review journal, January 2004

Preparation of supported asymmetric carbon molecular sieve membranes journal, June 1998

Preparation and gas permeation properties of carbon molecular sieve membranes based on sulfonated phenolic resin journal, June 2003

High-Flux Carbon Molecular Sieve Membranes for Gas Separation journal, June 2017

New insights into structural evolution in carbon molecular sieve membranes during pyrolysis journal, January 2019

Gas separation of 6FDA–6FpDA membranesEffect of the solvent on polymer surfaces and permselectivity journal, April 2007

Carbon molecular sieve gas separation membranes based on an intrinsically microporous polyimide precursor journal, October 2013

An investigation of the effects of pyrolysis parameters on gas separation properties of carbon materials journal, August 2005

Supported carbon molecular sieve membranes based on a phenolic resin journal, July 1999

High pressure pure- and mixed-gas separation of CO2/CH4 by thermally-rearranged and carbon molecular sieve membranes derived from a polyimide of intrinsic microporosity journal, November 2013

The upper bound revisited journal, July 2008

Separation of CO2/CH4 through carbon molecular sieve membranes derived from P84 polyimide journal, January 2004

Cause and effects of hyperskin features on carbon molecular sieve (CMS) membranes journal, April 2018

Carbon molecular sieve membranes from polyetherimide
journal, December 1998

Investigation of porosity of carbon materials and related effects on gas separation properties
journal, February 2003

Carbon molecular sieve membranes derived from thermally labile polymer containing blend polymers and their gas separation properties
journal, November 2004

Carbon molecular sieve membranes derived from Matrimid® polyimide for nitrogen/methane separation
journal, January 2014

Effect of polymer precursors on carbon molecular sieve structure and separation performance properties
journal, December 2010

Ultrathin carbon molecular sieve membrane for propylene/propane separation
journal, August 2015

Preparation of Carbon Molecular Sieve Membrane and Diffusion of Binary Mixtures in the Membrane
journal, December 1994

Enhanced H2/CH4 and H2/CO2 separation by carbon molecular sieve membrane coated on titania modified alumina support: Effects of TiO2 intermediate layer preparation variables on interfacial adhesion
journal, July 2016

Carbon membranes from blends of PBI and polyimides for N2/CH4 and CO2/CH4 separation and hydrogen purification
journal, February 2009

Precursor Selection and Process Conditions in the Preparation of Carbon Membrane for Gas Separation: A Review
journal, April 2011

High-Flux Carbon Molecular Sieve Membranes for Gas Separation
journal, June 2017

Effect of block versus random copolyimide structure on hollow fiber membrane spinnability
journal, May 2017

Effect of pyrolysis temperature and operating temperature on the performance of nanoporous carbon membranes
journal, September 2008

Improvement of CO2/CH4 separation characteristics of polyimides by chemical crosslinking
journal, March 1999

Carbon molecular sieve membranes supported on non-modified ceramic tubes for hydrogen separation in membrane reactors
journal, September 2012

Fabrication of carbon membranes for gas separation––a review
journal, January 2004

Preparation of supported asymmetric carbon molecular sieve membranes
journal, June 1998

Preparation and gas permeation properties of carbon molecular sieve membranes based on sulfonated phenolic resin
journal, June 2003

High-Flux Carbon Molecular Sieve Membranes for Gas Separation
journal, June 2017

New insights into structural evolution in carbon molecular sieve membranes during pyrolysis
journal, January 2019

Gas separation of 6FDA–6FpDA membranesEffect of the solvent on polymer surfaces and permselectivity
journal, April 2007

Carbon molecular sieve gas separation membranes based on an intrinsically microporous polyimide precursor
journal, October 2013

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journal, August 2005

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journal, July 1999

High pressure pure- and mixed-gas separation of CO2/CH4 by thermally-rearranged and carbon molecular sieve membranes derived from a polyimide of intrinsic microporosity
journal, November 2013

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journal, July 2008

Separation of CO2/CH4 through carbon molecular sieve membranes derived from P84 polyimide
journal, January 2004

Cause and effects of hyperskin features on carbon molecular sieve (CMS) membranes
journal, April 2018