Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Cao, Yuhe; Zhang, Kuang; Sanyal, Oishi; Koros, William J.

doi:10.1002/ange.201906653

Title: Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Journal Article · 24 July 2019 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.201906653 · OSTI ID:1544901

Cao, Yuhe ^[1]; Zhang, Kuang ^[1]; Sanyal, Oishi ^[1];

^[1]

School of Chemical &, Biomolecular Engineering Georgia Institute of Technology 311 Ferst Dr. NW Atlanta GA 30332 USA

Abstract Dip coating and pyrolysis processes are used to create multi‐layer asymmetric carbon molecular sieve (CMS) hollow fiber membranes with excellent gas separation properties. Coating of an economical engineered support with a high‐performance polyimide to create precursor fibers with a dense skin layer reduces material cost by 25‐fold compared to monolithic precursors or ceramic supports. CMS permeation results with CO ₂ /CH ₄ (50:50) mixed gas feed show attractive CO ₂ /CH ₄ selectivity of 58.8 and CO ₂ permeance of 310 GPU at 35 °C.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-04ER15510

OSTI ID:: 1544901

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 35 Vol. 131; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (28)

Ultrathin carbon molecular sieve membrane for propylene/propane separation Ma, Xiaoli; Lin, Y. S.; Wei, Xiaotong AIChE Journal, Vol. 62, Issue 2 https://doi.org/10.1002/aic.15005	journal	August 2015
High-Flux Carbon Molecular Sieve Membranes for Gas Separation Richter, Hannes; Voss, Hartwig; Kaltenborn, Nadine Angewandte Chemie, Vol. 129, Issue 27 https://doi.org/10.1002/ange.201701851	journal	June 2017
High-Flux Carbon Molecular Sieve Membranes for Gas Separation Richter, Hannes; Voss, Hartwig; Kaltenborn, Nadine Angewandte Chemie International Edition, Vol. 56, Issue 27 https://doi.org/10.1002/anie.201701851	journal	June 2017
Investigation of porosity of carbon materials and related effects on gas separation properties Steel, Keisha M.; Koros, William J. Carbon, Vol. 41, Issue 2 https://doi.org/10.1016/S0008-6223(02)00309-3	journal	February 2003
Preparation and gas permeation properties of carbon molecular sieve membranes based on sulfonated phenolic resin Zhou, Weiliang; Yoshino, Makoto; Kita, Hidetoshi Journal of Membrane Science, Vol. 217, Issue 1-2 https://doi.org/10.1016/S0376-7388(03)00074-7	journal	June 2003
Preparation of supported asymmetric carbon molecular sieve membranes Fuertes, A. B.; Centeno, T. A. Journal of Membrane Science, Vol. 144, Issue 1-2 https://doi.org/10.1016/S0376-7388(98)00037-4	journal	June 1998
Improvement of CO2/CH4 separation characteristics of polyimides by chemical crosslinking Staudt-Bickel, Claudia; J. Koros, William Journal of Membrane Science, Vol. 155, Issue 1 https://doi.org/10.1016/S0376-7388(98)00306-8	journal	March 1999
Supported carbon molecular sieve membranes based on a phenolic resin Centeno, Teresa A.; Fuertes, Antonio B. Journal of Membrane Science, Vol. 160, Issue 2 https://doi.org/10.1016/S0376-7388(99)00083-6	journal	July 1999
Carbon molecular sieve membranes from polyetherimide Fuertes, A. B.; Centeno, T. A. Microporous and Mesoporous Materials, Vol. 26, Issue 1-3 https://doi.org/10.1016/S1387-1811(98)00204-2	journal	December 1998
Fabrication of carbon membranes for gas separation––a review Saufi, S. M.; Ismail, A. F. Carbon, Vol. 42, Issue 2 https://doi.org/10.1016/j.carbon.2003.10.022	journal	January 2004
Separation of CO2/CH4 through carbon molecular sieve membranes derived from P84 polyimide Tin, Pei Shi; Chung, Tai-Shung; Liu, Ye Carbon, Vol. 42, Issue 15 https://doi.org/10.1016/j.carbon.2004.07.026	journal	January 2004
An investigation of the effects of pyrolysis parameters on gas separation properties of carbon materials Steel, Keisha M.; Koros, William J. Carbon, Vol. 43, Issue 9 https://doi.org/10.1016/j.carbon.2005.02.028	journal	August 2005
Effect of polymer precursors on carbon molecular sieve structure and separation performance properties Kiyono, Mayumi; Williams, Paul J.; Koros, William J. Carbon, Vol. 48, Issue 15 https://doi.org/10.1016/j.carbon.2010.08.002	journal	December 2010
Carbon molecular sieve gas separation membranes based on an intrinsically microporous polyimide precursor Ma, Xiaohua; Swaidan, Raja; Teng, Baiyang Carbon, Vol. 62 https://doi.org/10.1016/j.carbon.2013.05.057	journal	October 2013
Carbon molecular sieve membranes derived from Matrimid® polyimide for nitrogen/methane separation Ning, Xue; Koros, William J. Carbon, Vol. 66, p. 511-522 https://doi.org/10.1016/j.carbon.2013.09.028	journal	January 2014
New insights into structural evolution in carbon molecular sieve membranes during pyrolysis Adams, Jason S.; Itta, Arun K.; Zhang, Chen Carbon, Vol. 141 https://doi.org/10.1016/j.carbon.2018.09.039	journal	January 2019
Carbon molecular sieve membranes supported on non-modified ceramic tubes for hydrogen separation in membrane reactors Briceño, Kelly; Iulianelli, Adolfo; Montané, Daniel International Journal of Hydrogen Energy, Vol. 37, Issue 18 https://doi.org/10.1016/j.ijhydene.2012.06.069	journal	September 2012
Carbon molecular sieve membranes derived from thermally labile polymer containing blend polymers and their gas separation properties Kim, Youn Kook; Park, Ho Bum; Lee, Young Moo Journal of Membrane Science, Vol. 243, Issue 1-2 https://doi.org/10.1016/j.memsci.2004.05.001	journal	November 2004
Gas separation of 6FDA–6FpDA membranesEffect of the solvent on polymer surfaces and permselectivity Recio, R.; Palacio, L.; Pradanos, P. Journal of Membrane Science, Vol. 293, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.01.022	journal	April 2007
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
Effect of pyrolysis temperature and operating temperature on the performance of nanoporous carbon membranes Anderson, Clare J.; Pas, Steven J.; Arora, Gaurav Journal of Membrane Science, Vol. 322, Issue 1 https://doi.org/10.1016/j.memsci.2008.04.064	journal	September 2008
Carbon membranes from blends of PBI and polyimides for N2/CH4 and CO2/CH4 separation and hydrogen purification Hosseini, Seyed Saeid; Chung, Tai Shung Journal of Membrane Science, Vol. 328, Issue 1-2 https://doi.org/10.1016/j.memsci.2008.12.005	journal	February 2009
High pressure pure- and mixed-gas separation of CO2/CH4 by thermally-rearranged and carbon molecular sieve membranes derived from a polyimide of intrinsic microporosity Swaidan, Raja; Ma, Xiaohua; Litwiller, Eric Journal of Membrane Science, Vol. 447 https://doi.org/10.1016/j.memsci.2013.07.057	journal	November 2013
Enhanced H2/CH4 and H2/CO2 separation by carbon molecular sieve membrane coated on titania modified alumina support: Effects of TiO2 intermediate layer preparation variables on interfacial adhesion Tseng, Hui-Hsin; Wang, Ching-Ting; Zhuang, Guo-Liang Journal of Membrane Science, Vol. 510 https://doi.org/10.1016/j.memsci.2016.02.036	journal	July 2016
Effect of block versus random copolyimide structure on hollow fiber membrane spinnability Qiu, Wulin; Liu, Lu; Koros, William J. Journal of Membrane Science, Vol. 529 https://doi.org/10.1016/j.memsci.2017.01.050	journal	May 2017
Cause and effects of hyperskin features on carbon molecular sieve (CMS) membranes Sanyal, Oishi; Hicks, Stephanie T.; Bhuwania, Nitesh Journal of Membrane Science, Vol. 551 https://doi.org/10.1016/j.memsci.2018.01.021	journal	April 2018
Preparation of Carbon Molecular Sieve Membrane and Diffusion of Binary Mixtures in the Membrane Chen, Y. D.; Yang, R. T. Industrial & Engineering Chemistry Research, Vol. 33, Issue 12 https://doi.org/10.1021/ie00036a033	journal	December 1994
Precursor Selection and Process Conditions in the Preparation of Carbon Membrane for Gas Separation: A Review Salleh, W. N. W.; Ismail, A. F.; Matsuura, T. Separation & Purification Reviews, Vol. 40, Issue 4 https://doi.org/10.1080/15422119.2011.555648	journal	April 2011

Similar Records

Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Journal Article · 2019 · Angewandte Chemie (International Edition) · OSTI ID:1594576

Cao, Yuhe; Zhang, Kuang; Sanyal, Oishi; +1 more

Above‐T _g Annealing Benefits in Nanoparticle‐Stabilized Carbon Molecular Sieve Membrane Pyrolysis for Improved Gas Separation

Journal Article · 2024 · Angewandte Chemie · OSTI ID:2281735

Cao, Yuhe; Liu, Zhongyun; Koros, William J.

Synergistic Tuning of Microstructure and Morphology in Carbon Molecular Sieve Hollow Fibers for Propylene/Propane Separation

Journal Article · 2024 · Angewandte Chemie (International Edition) · OSTI ID:2475859

Liu, Zhongyun; Cao, Yuhe; Koros, William J.

Title: Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Citation Formats

References (28)

Similar Records

Related Subjects