DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Revisiting the charge compensation mechanisms in LiNi0.8Co0.2-yAlyO2 systems

Journal Article · · Materials Horizons
DOI: https://doi.org/10.1039/C9MH00765B · OSTI ID:1544447
ORCiD logo [1];  [2];  [3];  [4];  [5]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [6];  [7];  [2];  [2];  [8];  [9];  [10]; ORCiD logo [6]; ORCiD logo [11];  [3];  [2]; ORCiD logo [12]; ORCiD logo [1]
  1. Department of Physics; Applied Physics, and Astronomy; Binghamton University; New York 13902; USA
  2. Energy Storage Research Group; Department of Materials Science and Engineering; Rutgers University; North Brunswick; New Jersey 08902
  3. Materials Department; University of California Santa Barbara; Santa Barbara; USA
  4. Department of Chemistry; Binghamton University; New York 13902; USA
  5. Materials Science & Engineering; Binghamton University; Binghamton; USA; Advanced Light Source
  6. Department of Chemistry; University of Cambridge; Cambridge; UK
  7. Materials Science & Engineering; Binghamton University; Binghamton; USA
  8. Department of Chemistry; Stony Brook University; Stony Brook; USA
  9. Diamond Light Source Ltd.; Diamond House; Harwell Science and Innovation Campus; Didcot; UK
  10. X-ray Science Division; Advanced Photon Source; Argonne National Laboratory; Argonne; USA
  11. Department of Chemistry; University of Southern California; Los Angeles; USA
  12. Advanced Light Source; Lawrence Berkeley National Laboratory; Berkeley; USA

The emergence of oxidized oxygen RIXS features at high voltages for Ni-rich layered oxide cathodes.

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
SC0012583
OSTI ID:
1544447
Journal Information:
Materials Horizons, Journal Name: Materials Horizons Journal Issue: 10 Vol. 6; ISSN 2051-6347; ISSN MHAOAL
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United Kingdom
Language:
English

References (78)

Anionic Redox in Rechargeable Lithium Batteries journal June 2017
Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries journal August 2013
Narrowing the Gap between Theoretical and Practical Capacities in Li-Ion Layered Oxide Cathode Materials journal July 2017
Synthesis and Structure Refinement of LiCoO2Single Crystals journal November 1998
In Situ Structural and Electrochemical Study of Ni1−xCoxO2 Metastable Oxides Prepared by Soft Chemistry journal October 1999
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode journal January 2018
High Reversibility of Lattice Oxygen Redox Quantified by Direct Bulk Probes of Both Anionic and Cationic Redox Reactions journal February 2019
Aluminum-doped lithium nickel cobalt oxide electrodes for high-power lithium-ion batteries journal April 2004
Soft X-ray absorption spectroscopy studies on the chemically delithiated commercial LiCoO2 cathode material journal December 2007
Electronic structural changes of the electrochemically Li-ion deintercalated LiNi0.8Co0.15Al0.05O2 cathode material investigated by X-ray absorption spectroscopy journal December 2007
Local structural changes in LiMn1.5Ni0.5O4 spinel cathode material for lithium-ion batteries journal June 2014
Transition-metal redox evolution in LiNi0.5Mn0.3Co0.2O2 electrodes at high potentials journal August 2017
Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering journal June 2018
A high-capacity P2 Na2/3Ni1/3Mn2/3O2 cathode material for sodium ion batteries with oxygen activity journal August 2018
Structural and Electrochemical Investigation of Na + Insertion into High-Voltage Spinel Electrodes journal March 2015
Identifying the Distribution of Al 3+ in LiNi 0.8 Co 0.15 Al 0.05 O 2 journal October 2016
Lithium Extraction Mechanism in Li-Rich Li 2 MnO 3 Involving Oxygen Hole Formation and Dimerization journal September 2016
Understanding and Controlling Anionic Electrochemical Activity in High-Capacity Oxides for Next Generation Li-Ion Batteries journal January 2017
Reaction Heterogeneity in LiNi 0.8 Co 0.15 Al 0.05 O 2 Induced by Surface Layer journal August 2017
Decoupling Cationic–Anionic Redox Processes in a Model Li-Rich Cathode via Operando X-ray Absorption Spectroscopy journal November 2017
Evolution of the Electrode–Electrolyte Interface of LiNi 0.8 Co 0.15 Al 0.05 O 2 Electrodes Due to Electrochemical and Thermal Stress journal January 2018
Phase Evolution and Degradation Modes of Rm Li x Ni 1– yz Co y Al z O 2 Electrodes Cycled Near Complete Delithiation journal October 2018
X-ray Photoemission Spectroscopy Study of Cationic and Anionic Redox Processes in High-Capacity Li-Ion Battery Layered-Oxide Electrodes journal January 2016
Charge-Transfer-Induced Lattice Collapse in Ni-Rich NCM Cathode Materials during Delithiation journal October 2017
Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights journal October 2015
Spectroscopic Signature of Oxidized Oxygen States in Peroxides journal October 2018
Electrolyte-Induced Surface Transformation and Transition-Metal Dissolution of Fully Delithiated LiNi 0.8 Co 0.15 Al 0.05 O 2 journal June 2017
Intergranular Cracking as a Major Cause of Long-Term Capacity Fading of Layered Cathodes journal May 2017
Molecular Orbital Principles of Oxygen-Redox Battery Electrodes journal October 2017
Nickel-Rich Layered Cathode Materials for Automotive Lithium-Ion Batteries: Achievements and Perspectives journal December 2016
Investigation of Changes in the Surface Structure of Li x Ni 0.8 Co 0.15 Al 0.05 O 2 Cathode Materials Induced by the Initial Charge journal December 2013
Challenges for Rechargeable Li Batteries journal February 2010
Anion Redox Chemistry in the Cobalt Free 3d Transition Metal Oxide Intercalation Electrode Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2 journal August 2016
Collapse of LiNi 1– xy Co x Mn y O 2 Lattice at Deep Charge Irrespective of Nickel Content in Lithium-Ion Batteries journal March 2019
Oxygen Contribution on Li-Ion Intercalation−Deintercalation in LiCoO 2 Investigated by O K-Edge and Co L-Edge X-ray Absorption Spectroscopy journal March 2002
Ultrathin Coatings on Nano-LiCoO2 for Li-Ion Vehicular Applications journal February 2011
Promise and reality of post-lithium-ion batteries with high energy densities journal March 2016
Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen journal March 2016
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials journal May 2016
Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2 journal January 2018
Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries journal December 2016
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries journal March 2014
Metal segregation in hierarchically structured cathode materials for high-energy lithium batteries journal January 2016
High-energy cathode material for long-life and safe lithium batteries journal March 2009
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes journal July 2013
Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides journal December 2017
Elucidating anionic oxygen activity in lithium-rich layered oxides journal March 2018
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries journal April 2018
A high rate Li-rich layered MNC cathode material for lithium-ion batteries journal January 2015
The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries journal January 2016
Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries journal January 2017
A review of Ni-based layered oxides for rechargeable Li-ion batteries journal January 2017
Lithium manganese oxyfluoride as a new cathode material exhibiting oxygen redox journal January 2018
Oxygen activity and peroxide formation as charge compensation mechanisms in Li 2 MnO 3 journal January 2017
Identifying the chemical and structural irreversibility in LiNi 0.8 Co 0.15 Al 0.05 O 2 – a model compound for classical layered intercalation journal January 2018
7Li MAS NMR study of electrochemically deintercalated LixNi0.30Co0.70O2 phases: evidence of electronic and ionic mobility, and redox processes journal January 2001
Selective observation of the two oxygen atoms at different sites in the carboxyl group (–COOH) of liquid acetic acid journal January 2009
Continuous monitoring of the bulk oxidation states in Li x Ni 1 / 3 Mn 1 / 3 Co 1 / 3 O 2 during charging and discharging journal November 2016
High-efficiency in situ resonant inelastic x-ray scattering (iRIXS) endstation at the Advanced Light Source journal March 2017
High-capacity electrode materials for rechargeable lithium batteries: Li 3 NbO 4 -based system with cation-disordered rocksalt structure journal June 2015
Ab initiomolecular dynamics for liquid metals journal January 1993
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium journal May 1994
Projector augmented-wave method journal December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
Ab initio study of lithium intercalation in metal oxides and metal dichalcogenides journal July 1997
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study journal January 1998
First-principles investigation of phase stability in Li x CoO 2 journal August 1998
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure journal September 1998
Role of Oxygen Holes in Li x CoO 2 Revealed by Soft X-Ray Spectroscopy journal August 2013
Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)] journal February 1997
ISODISPLACE : a web-based tool for exploring structural distortions journal July 2006
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal June 2005
In Situ X-Ray Absorption Studies of a High-Rate LiNi[sub 0.85]Co[sub 0.15]O[sub 2] Cathode Material journal January 2000
Structural Changes in a Li-Rich 0.5Li 2 MnO 3 * 0.5LiMn 0.4 Ni 0.4 Co 0.2 O 2 Cathode Material for Li-Ion Batteries: A Local Perspective journal January 2016
Sensitivity and Limitations of Structures from X-ray and Neutron-Based Diffraction Analyses of Transition Metal Oxide Lithium-Battery Electrodes journal January 2017
Raman Microscopy of Lithium-Manganese-Rich Transition Metal Oxide Cathodes journal November 2014
Studying the Charging Process of a Lithium-Ion Battery toward 10 V by In Situ X-ray Absorption and Diffraction: Lithium Insertion/Extraction with Side Reactions at Positive and Negative Electrodes journal January 2016