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Title: O -Functionalization of a cobalt carbonyl generates a terminal cobalt carbyne

Abstract

We describe the synthesis of a series of terminally-bound Co-carbonyl complexes, with the most reduced state amenable to O -functionalization to generate a rare example of a late transition metal carbyne.

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1544442
Grant/Contract Number:  
DOE-0235032
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 55 Journal Issue: 64; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Deegan, Meaghan M., and Peters, Jonas C. O -Functionalization of a cobalt carbonyl generates a terminal cobalt carbyne. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC04032C.
Deegan, Meaghan M., & Peters, Jonas C. O -Functionalization of a cobalt carbonyl generates a terminal cobalt carbyne. United Kingdom. doi:10.1039/C9CC04032C.
Deegan, Meaghan M., and Peters, Jonas C. Wed . "O -Functionalization of a cobalt carbonyl generates a terminal cobalt carbyne". United Kingdom. doi:10.1039/C9CC04032C.
@article{osti_1544442,
title = {O -Functionalization of a cobalt carbonyl generates a terminal cobalt carbyne},
author = {Deegan, Meaghan M. and Peters, Jonas C.},
abstractNote = {We describe the synthesis of a series of terminally-bound Co-carbonyl complexes, with the most reduced state amenable to O -functionalization to generate a rare example of a late transition metal carbyne.},
doi = {10.1039/C9CC04032C},
journal = {ChemComm},
number = 64,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {8}
}

Journal Article:
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Works referenced in this record:

Influence of Ligand Electronic Effects on the Structure of Monovalent Cobalt Complexes
journal, November 2008

  • DuPont, Julie A.; Yap, Glenn P. A.; Riordan, Charles G.
  • Inorganic Chemistry, Vol. 47, Issue 22
  • DOI: 10.1021/ic800813u

Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex
journal, September 2002

  • Jenkins, David M.; Betley, Theodore A.; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 124, Issue 38
  • DOI: 10.1021/ja026852b

Formation of Heterobimetallic Zirconium/Cobalt Diimido Complexes via a Four-Electron Transformation
journal, September 2014

  • Wu, Bing; Hernández Sánchez, Raúl; Bezpalko, Mark W.
  • Inorganic Chemistry, Vol. 53, Issue 19
  • DOI: 10.1021/ic501490e

Dinitrogen Complexes Supported by Tris(phosphino)silyl Ligands
journal, March 2009

  • Whited, Matthew T.; Mankad, Neal P.; Lee, Yunho
  • Inorganic Chemistry, Vol. 48, Issue 6
  • DOI: 10.1021/ic801855y

Silylation of Iron-Bound Carbon Monoxide Affords a Terminal Fe Carbyne
journal, March 2011

  • Lee, Yunho; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 133, Issue 12
  • DOI: 10.1021/ja109678y

M−O Bonding Beyond the Oxo Wall: Spectroscopy and Reactivity of Cobalt(III)-Oxyl and Cobalt(III)-Oxo Complexes
journal, June 2019

  • Andris, Erik; Navrátil, Rafael; Jašík, Juraj
  • Angewandte Chemie International Edition, Vol. 58, Issue 28
  • DOI: 10.1002/anie.201904546

Proton-Coupled Reduction of an Iron Cyanide Complex to Methane and Ammonia
journal, September 2016

  • Rittle, Jonathan; Peters, Jonas C.
  • Angewandte Chemie International Edition, Vol. 55, Issue 40
  • DOI: 10.1002/anie.201606366

Synthesis, structure, and reactivity of a monomeric pentamethylcyclopentadienyliridium(III) imido complex
journal, March 1989

  • Glueck, David S.; Hollander, Frederick J.; Bergman, Robert G.
  • Journal of the American Chemical Society, Vol. 111, Issue 7
  • DOI: 10.1021/ja00189a059

Dinitrogen Chemistry from Trigonally Coordinated Iron and Cobalt Platforms
journal, September 2003

  • Betley, Theodore A.; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 125, Issue 36
  • DOI: 10.1021/ja036687f

N 2 -to-NH 3 Conversion by a triphos-Iron Catalyst and Enhanced Turnover under Photolysis
journal, May 2017

  • Buscagan, Trixia M.; Oyala, Paul H.; Peters, Jonas C.
  • Angewandte Chemie International Edition, Vol. 56, Issue 24
  • DOI: 10.1002/anie.201703244

[(CO)3PPh3FeCNiPr2]⊕, a Novel Stable Carbyneiron Complex Cation
journal, October 1984

  • Fischer, Ernst Otto; Schneider, Johannes; Neugebauer, Dietmar
  • Angewandte Chemie International Edition in English, Vol. 23, Issue 10
  • DOI: 10.1002/anie.198408201

Reactions of carbon disulfide with (.eta.-cyclopentadienyl)cobalt(I) complexes
journal, December 1983


An Intermediate Cobalt(IV) Nitrido Complex and its N-Migratory Insertion Product
journal, October 2014

  • Zolnhofer, Eva M.; Käß, Martina; Khusniyarov, Marat M.
  • Journal of the American Chemical Society, Vol. 136, Issue 42
  • DOI: 10.1021/ja508144j

Terminal Amido and Imido Complexes of Three-Coordinate Nickel
journal, May 2001

  • Mindiola, Daniel J.; Hillhouse, Gregory L.
  • Journal of the American Chemical Society, Vol. 123, Issue 19
  • DOI: 10.1021/ja010358a

Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex
journal, March 2017

  • Wang, Bin; Lee, Yong-Min; Tcho, Woon-Young
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14839

ME and ME complexes of iron and cobalt that emphasize three-fold symmetry (E=O, N, NR)
journal, April 2011


Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity
journal, October 2008

  • Poverenov, Elena; Efremenko, Irena; Frenkel, Anatoly I.
  • Nature, Vol. 455, Issue 7216
  • DOI: 10.1038/nature07356

Experimental Evidence for p K a -Driven Asynchronicity in C–H Activation by a Terminal Co(III)–Oxo Complex
journal, February 2019

  • Goetz, McKenna K.; Anderson, John S.
  • Journal of the American Chemical Society, Vol. 141, Issue 9
  • DOI: 10.1021/jacs.8b13490

The 15 years of reductive coupling: what have we learned?
journal, March 1993

  • Carnahan, Edmund M.; Protasiewicz, John D.; Lippard, Stephen J.
  • Accounts of Chemical Research, Vol. 26, Issue 3
  • DOI: 10.1021/ar00027a003

A CO-Derived Iron Dicarbyne That Releases Olefin upon Hydrogenation
journal, August 2013

  • Suess, Daniel L. M.; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 135, Issue 34
  • DOI: 10.1021/ja406874k

Terminal Cobalt(III) Imido Complexes Supported by Tris(Carbene) Ligands:  Imido Insertion into the Cobalt−Carbene Bond
journal, December 2004

  • Hu, Xile; Meyer, Karsten
  • Journal of the American Chemical Society, Vol. 126, Issue 50
  • DOI: 10.1021/ja044271b

Fluorocarbene, fluoroolefin, and fluorocarbyne complexes of Rh
journal, January 2017

  • Pell, Christopher J.; Zhu, Yanjun; Huacuja, Rafael
  • Chemical Science, Vol. 8, Issue 4
  • DOI: 10.1039/C6SC05391B

Elucidation of a Low Spin Cobalt(II) System in a Distorted Tetrahedral Geometry
journal, December 2002

  • Jenkins, David M.; Di Bilio, Angel J.; Allen, Matthew J.
  • Journal of the American Chemical Society, Vol. 124, Issue 51
  • DOI: 10.1021/ja026433e

A Sulfido-Bridged Diiron(II) Compound and Its Reactions with Nitrogenase-Relevant Substrates
journal, April 2004

  • Vela, Javier; Stoian, Sebastian; Flaschenriem, Christine J.
  • Journal of the American Chemical Society, Vol. 126, Issue 14
  • DOI: 10.1021/ja049417l

Terminal Oxo and Imido Transition-Metal Complexes of Groups 9-11
journal, June 2013

  • Ray, Kallol; Heims, Florian; Pfaff, Florian Felix
  • European Journal of Inorganic Chemistry, Vol. 2013, Issue 22-23
  • DOI: 10.1002/ejic.201300223

Formation of a Cobalt(III) Imido from a Cobalt(II) Amido Complex. Evidence for Proton-Coupled Electron Transfer
journal, March 2007

  • Cowley, Ryan E.; Bontchev, Ranko P.; Sorrell, John
  • Journal of the American Chemical Society, Vol. 129, Issue 9
  • DOI: 10.1021/ja066899n

Spektroskopische Untersuchungen an Komplexverbindungen II EPR-Spektren des monomeren Kobalt-tetracarbonyls.
journal, October 1965

  • Keller, H. J.; Wawersik, H.
  • Zeitschrift für Naturforschung B, Vol. 20, Issue 10
  • DOI: 10.1515/znb-1965-1002

Isolation of a Terminal Co(III)-Oxo Complex
journal, August 2018

  • Goetz, McKenna K.; Hill, Ethan A.; Filatov, Alexander S.
  • Journal of the American Chemical Society, Vol. 140, Issue 41
  • DOI: 10.1021/jacs.8b07399

Vibrational Spectroscopy and Analysis of Pseudo-tetrahedral Complexes with Metal Imido Bonds
journal, September 2006

  • Mehn, Mark P.; Brown, Steven D.; Jenkins, David M.
  • Inorganic Chemistry, Vol. 45, Issue 18
  • DOI: 10.1021/ic060670r

Terminal Iron Carbyne Complexes Derived from Arrested CO 2 Reductive Disproportionation
journal, July 2017

  • Mokhtarzadeh, Charles C.; Moore, Curtis E.; Rheingold, Arnold L.
  • Angewandte Chemie International Edition, Vol. 56, Issue 36
  • DOI: 10.1002/anie.201705877

N–H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe–N 2 and Fe–CN Reductions
journal, February 2017

  • Rittle, Jonathan; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 139, Issue 8
  • DOI: 10.1021/jacs.6b12861

Intramolecular C?H Activation by an Open-Shell Cobalt(III) Imido Complex
journal, February 2005

  • Shay, Daniel T.; Yap, Glenn P. A.; Zakharov, Lev N.
  • Angewandte Chemie International Edition, Vol. 44, Issue 10
  • DOI: 10.1002/anie.200462529

A Highly-Reduced Cobalt Terminal Carbyne: Divergent Metal- and α-Carbon-Centered Reactivity
journal, June 2018

  • Mokhtarzadeh, Charles C.; Moore, Curtis E.; Rheingold, Arnold L.
  • Journal of the American Chemical Society, Vol. 140, Issue 26
  • DOI: 10.1021/jacs.8b05019

Synthesis, Structure, and Reactivity of Low-Spin Cobalt(II) Imido Complexes [(Me 3 P) 3 Co(NAr)]
journal, June 2017


Synthesis and X-ray crystal structure of oxotrimesityliridium(V)
journal, August 1993


Infrared spectral evidence for the formation of the new complexes dicarbonyldinitrosylosmium and tetracarbonylcobalt in frozen gas matrices at 20 K
journal, January 1973

  • Crichton, Oliver; Poliakoff, Martyn; Rest, Antony J.
  • Journal of the Chemical Society, Dalton Transactions, Issue 12
  • DOI: 10.1039/dt9730001321

Structural Distortion of the TpCo-L Fragment (Tp = tris(pyrazolyl)borate). Analysis by X-ray Diffraction and Density Functional Theory
journal, January 1996

  • Detrich, Jennifer L.; Konečný, Robert; Vetter, William M.
  • Journal of the American Chemical Society, Vol. 118, Issue 7
  • DOI: 10.1021/ja9523101

Silica supported perchloric acid (HClO4–SiO2): A highly efficient and reusable catalyst for the protection of hydroxyl groups using HMDS under mild and ambient conditions
journal, July 2007

  • Shaterian, Hamid Reza; Shahrekipoor, Fahimeh; Ghashang, Majid
  • Journal of Molecular Catalysis A: Chemical, Vol. 272, Issue 1-2
  • DOI: 10.1016/j.molcata.2007.03.036

Synthesis, Structural Characterization, and Chemistry of a Monomeric Cationic Iridium Carbyne Complex
journal, October 1998

  • Luecke, Hans F.; Bergman, Robert G.
  • Journal of the American Chemical Society, Vol. 120, Issue 42
  • DOI: 10.1021/ja982641o

The aminocarbyne ligand CNH2: metal-centred synthesis from a cyanosilane, preparation and X-ray structure of trans-[ReCl(CNH2)(Ph2PCH2CH2PPh2)2]BF4
journal, January 1986

  • Pombeiro, Armando J. L.; Hughes, David L.; Pickett, Christopher J.
  • Journal of the Chemical Society, Chemical Communications, Issue 3
  • DOI: 10.1039/c39860000246

Electroreduction of co-ordinated cyanide to the aminocarbyne ligand (CNH2) and a pathway for isomerisation of ligating methyleneamide (NCH2): reactions at molybdenum of relevance to cyanide reduction by nitrogenase
journal, January 1989

  • Hughes, David L.; Mohammed, Modher Y.; Pickett, Christopher J.
  • Journal of the Chemical Society, Chemical Communications, Issue 18
  • DOI: 10.1039/c39890001399

Carbamoyl (Carboxamido) Complexes as Precursors for Metallaoxetene, Isonitrile, and Aminomethylidyne Complexes of Iron
journal, January 2000

  • Anderson, Stephen; Hill, Anthony F.; Ng, Ying Thong
  • Organometallics, Vol. 19, Issue 1
  • DOI: 10.1021/om990385y

Isoselenocarbonyl complexes
journal, January 2019

  • Cade, Ian A.; Hill, Anthony F.; McQueen, Caitlin M. A.
  • Dalton Transactions, Vol. 48, Issue 6
  • DOI: 10.1039/C8DT04947E

Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten
journal, August 1990