Design and synthesis of capped-paddlewheel-based porous coordination cages

Lorzing, Gregory R.; Gosselin, Aeri J.; Lindner, Brian S.; Bhattacharjee, Rameswar; Yap, Glenn P. A.; Caratzoulas, Stavros; Bloch, Eric D.

doi:10.1039/C9CC05002G

Title: Design and synthesis of capped-paddlewheel-based porous coordination cages

Abstract

A novel cluster capping strategy is employed to leverage the structural diversity of metal–organic cages toward the isolation of porous cages.

Authors:

Lorzing, Gregory R. ^[1]; Gosselin, Aeri J. ^[2];

^[2];

^[3];

^[2]; Caratzoulas, Stavros ^[3];

^[1]

Department of Chemistry and Biochemistry, University of Delaware, Newark, USA, Center for Neutron Science
Department of Chemistry and Biochemistry, University of Delaware, Newark, USA
Catalysis Center for Energy Innovation (CCEI) University of Delaware, Newark, USA

Publication Date:: 2019-08-07

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1544441

Grant/Contract Number:: SC0001004

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Name: ChemComm Journal Volume: 55 Journal Issue: 64; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Lorzing, Gregory R., Gosselin, Aeri J., Lindner, Brian S., Bhattacharjee, Rameswar, Yap, Glenn P. A., Caratzoulas, Stavros, and Bloch, Eric D. Design and synthesis of capped-paddlewheel-based porous coordination cages.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9CC05002G.

Copy to clipboard


                    Lorzing, Gregory R., Gosselin, Aeri J., Lindner, Brian S., Bhattacharjee, Rameswar, Yap, Glenn P. A., Caratzoulas, Stavros, & Bloch, Eric D. Design and synthesis of capped-paddlewheel-based porous coordination cages.  United Kingdom.  https://doi.org/10.1039/C9CC05002G

Copy to clipboard


                    Lorzing, Gregory R., Gosselin, Aeri J., Lindner, Brian S., Bhattacharjee, Rameswar, Yap, Glenn P. A., Caratzoulas, Stavros, and Bloch, Eric D. Wed .  
"Design and synthesis of capped-paddlewheel-based porous coordination cages".  United Kingdom.  https://doi.org/10.1039/C9CC05002G.

Copy to clipboard


                    
@article{osti_1544441,

  title        = {Design and synthesis of capped-paddlewheel-based porous coordination cages},

  author       = {Lorzing, Gregory R. and Gosselin, Aeri J. and Lindner, Brian S. and Bhattacharjee, Rameswar and Yap, Glenn P. A. and Caratzoulas, Stavros and Bloch, Eric D.},

  abstractNote = {A novel cluster capping strategy is employed to leverage the structural diversity of metal–organic cages toward the isolation of porous cages.},

  doi          = {10.1039/C9CC05002G},

  journal      = {ChemComm},

  number       = 64,

  volume       = 55,

  place        = {United Kingdom},

  year         = {2019},

  month        = {8}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1039/C9CC05002G

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 17 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Investigation of Porous Ni-Based Metal–Organic Frameworks Containing Paddle-Wheel Type Inorganic Building Units via High-Throughput Methods
journal, June 2011

Maniam, Palanikumar; Stock, Norbert
Inorganic Chemistry, Vol. 50, Issue 11
DOI: 10.1021/ic200381f

Ligand-Based Phase Control in Porous Molecular Assemblies
journal, March 2018

Barreda, Omar; Bannwart, Gianluca; Yap, Glenn P. A.
ACS Applied Materials & Interfaces, Vol. 10, Issue 14
DOI: 10.1021/acsami.8b02015

A Chiral Molecular Square with Metallo-Corners for Enantioselective Sensing
journal, May 2002

Lee, Suk Joong; Lin, Wenbin
Journal of the American Chemical Society, Vol. 124, Issue 17
DOI: 10.1021/ja0256257

Nanoballs: nanoscale faceted polyhedra with large windows and cavities
journal, January 2001

Moulton, Brian; Lu, Jianjiang; Mondal, Arunendu
Chemical Communications, Issue 9
DOI: 10.1039/b102714j

Copper-based coordination polymers from thiophene and furan dicarboxylates with high isosteric heats of hydrogen adsorption
journal, January 2014

Yang, Jie; Lutz, Martin; Grzech, Anna
CrystEngComm, Vol. 16, Issue 23
DOI: 10.1039/C4CE00145A

Crystal and molecular structure of di-µ-hydroxo-bis[bipyridylcopper( II )] diperchlorate
journal, January 1976

Toofan, Mahmood; Boushehri, A.; Mazhar-Ul-Haque, Mazhar-Ul-Haque
J. Chem. Soc., Dalton Trans., Issue 3
DOI: 10.1039/DT9760000217

High Uptakes of CO ₂ and CH ₄ in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101
journal, July 2008

Llewellyn, Philip L.; Bourrelly, Sandrine; Serre, Christian
Langmuir, Vol. 24, Issue 14
DOI: 10.1021/la800227x

A Metal−Organic Framework with Entatic Metal Centers Exhibiting High Gas Adsorption Affinity
journal, September 2006

Ma, Shengqian; Zhou, Hong-Cai
Journal of the American Chemical Society, Vol. 128, Issue 36
DOI: 10.1021/ja063538z

Preparation and characterization of dinuclear copper(II) complexes containing the [Cu2(μ-OAc)2]2+ core
journal, January 1992

Perlepes, Spiros P.; Huffman, John C.; Christou, George
Polyhedron, Vol. 11, Issue 12
DOI: 10.1016/S0277-5387(00)83140-X

Biomedical and Biochemical Applications of Self-Assembled Metallacycles and Metallacages
journal, June 2013

Cook, Timothy R.; Vajpayee, Vaishali; Lee, Min Hyung
Accounts of Chemical Research, Vol. 46, Issue 11
DOI: 10.1021/ar400010v

Formation of a Highly Reactive Cobalt Nanocluster Crystal within a Highly Negatively Charged Porous Coordination Cage
journal, March 2018

Fang, Yu; Xiao, Zhifeng; Li, Jialuo
Angewandte Chemie International Edition, Vol. 57, Issue 19
DOI: 10.1002/anie.201712372

Highly-Selective and Reversible O₂ Binding in Cr₃(1,3,5-benzenetricarboxylate)₂
journal, June 2010

Murray, Leslie J.; Dinca, Mircea; Yano, Junko
Journal of the American Chemical Society, Vol. 132, Issue 23, p. 7856-7857
DOI: 10.1021/ja1027925

Catalysis in a Cationic Coordination Cage Using a Cavity-Bound Guest and Surface-Bound Anions: Inhibition, Activation, and Autocatalysis
journal, February 2018

Cullen, William; Metherell, Alexander J.; Wragg, Ashley B.
Journal of the American Chemical Society, Vol. 140, Issue 8
DOI: 10.1021/jacs.7b11334

Light-Triggered Guest Uptake and Release by a Photochromic Coordination Cage
journal, December 2012

Han, Muxin; Michel, Reent; He, Bice
Angewandte Chemie International Edition, Vol. 52, Issue 4
DOI: 10.1002/anie.201207373

Precursors for Assembly of Supramolecules Containing Quadruply Bonded Cr24+ Units: Systematic Preparation of Cr2(formamidinate)n(acetate)4–n (n = 2–4)
journal, August 2007

Cotton, F. Albert; Li, Zhong; Murillo, Carlos A.
European Journal of Inorganic Chemistry, Vol. 2007, Issue 22
DOI: 10.1002/ejic.200700414

Design, Synthesis, Structure, and Gas (N₂, Ar, CO₂, CH₄, and H₂) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
journal, May 2005

Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118
DOI: 10.1021/ja042802q

Noble Gas Adsorption in Copper Trimesate, HKUST-1: An Experimental and Computational Study
journal, September 2013

Hulvey, Zeric; Lawler, Keith V.; Qiao, Zhiwei
The Journal of Physical Chemistry C, Vol. 117, Issue 39
DOI: 10.1021/jp408034u

A Chiral Quadruple-Stranded Helicate Cage for Enantioselective Recognition and Separation
journal, April 2012

Xuan, Weimin; Zhang, Mengni; Liu, Yan
Journal of the American Chemical Society, Vol. 134, Issue 16
DOI: 10.1021/ja212132r

Chromium(II) complexes bearing 2,6-substituted N,N ′-diarylformamidinate ligands
journal, January 2000

Cotton, F. Albert; Daniels, Lee M.; Murillo, Carlos A.
Journal of the Chemical Society, Dalton Transactions, Issue 13
DOI: 10.1039/b000326n

Metal-organic polyhedra 18 mixed-matrix membranes for gas separation
journal, August 2014

Perez, Edson V.; Balkus, Kenneth J.; Ferraris, John P.
Journal of Membrane Science, Vol. 463
DOI: 10.1016/j.memsci.2014.03.045

Critical Factors Driving the High Volumetric Uptake of Methane in Cu ₃ (btc) ₂
journal, August 2015

Hulvey, Zeric; Vlaisavljevich, Bess; Mason, Jarad A.
Journal of the American Chemical Society, Vol. 137, Issue 33
DOI: 10.1021/jacs.5b06657

Template-Directed Synthesis of Nets Based upon Octahemioctahedral Cages That Encapsulate Catalytically Active Metalloporphyrins
journal, December 2011

Zhang, Zhenjie; Zhang, Linping; Wojtas, Lukasz
Journal of the American Chemical Society, Vol. 134, Issue 2, p. 928-933
DOI: 10.1021/ja208256u

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008

Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
DOI: 10.1021/ja8057953

Cage-Catalyzed Knoevenagel Condensation under Neutral Conditions in Water
journal, December 2011

Murase, Takashi; Nishijima, Yuki; Fujita, Makoto
Journal of the American Chemical Society, Vol. 134, Issue 1
DOI: 10.1021/ja210068f

Azobenzene-Functionalized Metal-Organic Polyhedra for the Optically Responsive Capture and Release of Guest Molecules
journal, May 2014

Park, Jinhee; Sun, Lin-Bing; Chen, Ying-Pin
Angewandte Chemie International Edition, Vol. 53, Issue 23
DOI: 10.1002/anie.201310211

Directed assembly metallocyclic supramolecular systems for molecular recognition and chemical sensing
journal, April 2008

Kumar, Arvind; Sun, Shih-Sheng; Lees, Alistair J.
Coordination Chemistry Reviews, Vol. 252, Issue 8-9
DOI: 10.1016/j.ccr.2007.07.023

Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
journal, August 2012

Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon
Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021
DOI: 10.1021/ja3055639

Self-Assembly of Cationic, Hetero- or Homonuclear Ruthenium(II) Macrocyclic Rectangles and Their Photophysical, Electrochemical, and Biological Studies
journal, December 2011

Vajpayee, Vaishali; Song, Young Ho; Yang, Yoon Jung
Organometallics, Vol. 30, Issue 23
DOI: 10.1021/om200908c

Porous Metal−Organic Polyhedra: 25 Å Cuboctahedron Constructed from 12 Cu₂(CO₂)₄ Paddle-Wheel Building Blocks
journal, May 2001

Eddaoudi, M.; Kim, Jaheon; Wachter, J. B.
Journal of the American Chemical Society, Vol. 123, Issue 18, p. 4368-4369
DOI: 10.1021/ja0104352

In Situ Construction of a Coordination Zirconocene Tetrahedron
journal, November 2013

Liu, Guoliang; Ju, Zhanfeng; Yuan, Daqiang
Inorganic Chemistry, Vol. 52, Issue 24
DOI: 10.1021/ic402428m

Mixed-Valence Iron(II, III) Trimesates with Open Frameworks Modulated by Solvents
journal, September 2007

Xie, Linhua; Liu, Shuxia; Gao, Chaoying
Inorganic Chemistry, Vol. 46, Issue 19
DOI: 10.1021/ic062273m

Cross-linking Zr-based metal–organic polyhedra via postsynthetic polymerization
journal, January 2017

Nam, Dongsik; Huh, Jihyun; Lee, Jiyoung
Chem. Sci., Vol. 8, Issue 11
DOI: 10.1039/C7SC03847J

Synthesis and properties of the metal-organic framework Mo3(BTC)2 (TUDMOF-1)
journal, January 2006

Kramer, Markus; Schwarz, Ulrich; Kaskel, Stefan
Journal of Materials Chemistry, Vol. 16, Issue 23
DOI: 10.1039/b601811d

From Coordination Cages to a Stable Crystalline Porous Hydrogen-Bonded Framework
journal, March 2017

Ju, Zhanfeng; Liu, Guoliang; Chen, Yu-Sheng
Chemistry - A European Journal, Vol. 23, Issue 20
DOI: 10.1002/chem.201700798

The designed ‘self-assembly’ of a three-dimensional molecule containing six quadruply-bonded Mo24+ units
journal, January 1999

Albert Cotton, F.; Daniels, Lee M.; Lin, Chun
Chemical Communications, Issue 9
DOI: 10.1039/a901645g

Solvothermal growth of a ruthenium metal–organic framework featuring HKUST-1 structure type as thin films on oxide surfaces
journal, January 2011

Kozachuk, Olesia; Yusenko, Kirill; Noei, Heshmat
Chemical Communications, Vol. 47, Issue 30
DOI: 10.1039/c1cc11107h

Similar Records in DOE PAGES and OSTI.GOV collections:

Design and synthesis of capped-paddlewheel-based porous coordination cages

Journal Article Lorzing, Gregory R. ; Gosselin, Eric J. ; Lindner, Brian S. ; ... - ChemComm

A novel cluster capping strategy is employed to leverage the structural diversity of metal–organic cages toward the isolation of porous cages.
https://doi.org/10.1039/c9cc05002g
Synthesis, characterization, and polymerization of capped paddlewheel porous cages

Journal Article Deegan, Meaghan M. ; Bloch, Eric D. - Dalton Transactions

Although paddlewheel-based structures are common among permanently porous metal–organic materials, suitable strategies for the isolation of metal node-terminated, capped paddlewheel-based cage structures remain limited. We explored the use of chelating dicarboxylate ligand derivates (esp) for the isolation of trimesate-linked cages, Mo₁₂(btc)₄(esp)₆, that are structural analogs of the small octahedral pore of HKUST-1. The porosity of these novel cages is appreciably higher than that of previously reported structures of this type. We also demonstrate that pillaring the isolated cage with DABCO generated an amorphous polymer that featured exceptional thermal stability and enhanced porosity.
https://doi.org/10.1039/d0dt04361c

Full Text Available
Porous metal–organic alloys based on soluble coordination cages

Journal Article Antonio, Alexandra M. ; Korman, Kyle J. ; Yap, Glenn P. A. ; ... - Chemical Science

Diverse strategies for the preparation of mixed-metal three-dimensional porous solids abound, although many of them lend themselves only moderate levels of tunability. Herein, we report the design and synthesis of surface functionalized permanently microporous coordination cages and their use in the isolation of mixed metal solids. Judicious alkoxide-based ligand functionalization was utilized to tune the solubility of starting copper(II)-based cages and their resulting compatibility with the mixed-cage approach described here. We further prepared a family of isostructural molybdenum(II) cages for a subset of the ligands. The preparation of mixed-metal cage solids proceeds under facile conditions where solutions of parent cagesmore »« less
https://doi.org/10.1039/D0SC04941G
Design and synthesis of aryl-functionalized carbazole-based porous coordination cages

Journal Article Rowland, Casey A. ; Lorzing, Gregory R. ; Bhattacharjee, Rameswar ; ... - ChemComm

A subset of coordination cages have garnered considerable recent attention for their potential permanent porosity in the solid state. Herein, we report a series of functionalized carbazole-based cages of the structure type M₁₂(R-cdc)₁₂ (M = Cr, Cu, Mo) where the functional groups include a range of aromatic substituents. Single-crystal X-ray structure determinations reveal a variety of intercage interactions in these materials, largely governed by pi–pi stacking. Density functional theory for a subset of these cages was used to confirm that the nature of the increased stability of aryl-functionalized cages is a result of inter-cage ligand interactions.
Cited by 7
https://doi.org/10.1039/d0cc03910a

Full Text Available
Novel syntheses of carbazole-3,6-dicarboxylate ligands and their utilization for porous coordination cages

Journal Article Rowland, Casey A. ; Yap, Glenn A. ; Bloch, Eric D. - Dalton Transactions

The molecular nature, and thus potential solubility, of coordination cages endows them with a number of advantages as compared to metal–organic frameworks and other extended network solids. However, their lack of three-dimensional connectivity typically limits their thermal stability as inter-cage interactions in these materials are relatively weak. This is particularly the case for carbazole-based coordination cages. Here, we report the design and synthesis of a benzyl-functionalized octahedral coordination cage that displays moderate surface area and increased thermal stability as compared to its unfunctionalized counterpart. Structural analysis suggests the increased thermal stability is a result of aryl–aryl interactions between ligand groupsmore »« less
https://doi.org/10.1039/d0dt01149e

Full Text Available

Similar Records

Title: Design and synthesis of capped-paddlewheel-based porous coordination cages

Abstract

Citation Formats

Investigation of Porous Ni-Based Metal–Organic Frameworks Containing Paddle-Wheel Type Inorganic Building Units via High-Throughput Methods journal, June 2011

Ligand-Based Phase Control in Porous Molecular Assemblies journal, March 2018

A Chiral Molecular Square with Metallo-Corners for Enantioselective Sensing journal, May 2002

Nanoballs: nanoscale faceted polyhedra with large windows and cavities journal, January 2001

Copper-based coordination polymers from thiophene and furan dicarboxylates with high isosteric heats of hydrogen adsorption journal, January 2014

Crystal and molecular structure of di-µ-hydroxo-bis[bipyridylcopper( II )] diperchlorate journal, January 1976

High Uptakes of CO 2 and CH 4 in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101 journal, July 2008

A Metal−Organic Framework with Entatic Metal Centers Exhibiting High Gas Adsorption Affinity journal, September 2006

Preparation and characterization of dinuclear copper(II) complexes containing the [Cu2(μ-OAc)2]2+ core journal, January 1992

Biomedical and Biochemical Applications of Self-Assembled Metallacycles and Metallacages journal, June 2013

Formation of a Highly Reactive Cobalt Nanocluster Crystal within a Highly Negatively Charged Porous Coordination Cage journal, March 2018

Highly-Selective and Reversible O2 Binding in Cr3(1,3,5-benzenetricarboxylate)2 journal, June 2010

Catalysis in a Cationic Coordination Cage Using a Cavity-Bound Guest and Surface-Bound Anions: Inhibition, Activation, and Autocatalysis journal, February 2018

Light-Triggered Guest Uptake and Release by a Photochromic Coordination Cage journal, December 2012

Precursors for Assembly of Supramolecules Containing Quadruply Bonded Cr24+ Units: Systematic Preparation of Cr2(formamidinate)n(acetate)4–n (n = 2–4) journal, August 2007

Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra journal, May 2005

Noble Gas Adsorption in Copper Trimesate, HKUST-1: An Experimental and Computational Study journal, September 2013

A Chiral Quadruple-Stranded Helicate Cage for Enantioselective Recognition and Separation journal, April 2012

Chromium(II) complexes bearing 2,6-substituted N,N ′-diarylformamidinate ligands journal, January 2000

Metal-organic polyhedra 18 mixed-matrix membranes for gas separation journal, August 2014

Critical Factors Driving the High Volumetric Uptake of Methane in Cu 3 (btc) 2 journal, August 2015

Template-Directed Synthesis of Nets Based upon Octahemioctahedral Cages That Encapsulate Catalytically Active Metalloporphyrins journal, December 2011

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability journal, October 2008

Cage-Catalyzed Knoevenagel Condensation under Neutral Conditions in Water journal, December 2011

Azobenzene-Functionalized Metal-Organic Polyhedra for the Optically Responsive Capture and Release of Guest Molecules journal, May 2014

Directed assembly metallocyclic supramolecular systems for molecular recognition and chemical sensing journal, April 2008

Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? journal, August 2012

Self-Assembly of Cationic, Hetero- or Homonuclear Ruthenium(II) Macrocyclic Rectangles and Their Photophysical, Electrochemical, and Biological Studies journal, December 2011

Porous Metal−Organic Polyhedra: 25 Å Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks journal, May 2001

In Situ Construction of a Coordination Zirconocene Tetrahedron journal, November 2013

Mixed-Valence Iron(II, III) Trimesates with Open Frameworks Modulated by Solvents journal, September 2007

Cross-linking Zr-based metal–organic polyhedra via postsynthetic polymerization journal, January 2017

Synthesis and properties of the metal-organic framework Mo3(BTC)2 (TUDMOF-1) journal, January 2006

From Coordination Cages to a Stable Crystalline Porous Hydrogen-Bonded Framework journal, March 2017

The designed ‘self-assembly’ of a three-dimensional molecule containing six quadruply-bonded Mo24+ units journal, January 1999

Solvothermal growth of a ruthenium metal–organic framework featuring HKUST-1 structure type as thin films on oxide surfaces journal, January 2011

Investigation of Porous Ni-Based Metal–Organic Frameworks Containing Paddle-Wheel Type Inorganic Building Units via High-Throughput Methods
journal, June 2011

Ligand-Based Phase Control in Porous Molecular Assemblies
journal, March 2018

A Chiral Molecular Square with Metallo-Corners for Enantioselective Sensing
journal, May 2002

Nanoballs: nanoscale faceted polyhedra with large windows and cavities
journal, January 2001

Copper-based coordination polymers from thiophene and furan dicarboxylates with high isosteric heats of hydrogen adsorption
journal, January 2014

Crystal and molecular structure of di-µ-hydroxo-bis[bipyridylcopper( II )] diperchlorate
journal, January 1976

High Uptakes of CO ₂ and CH ₄ in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101
journal, July 2008

A Metal−Organic Framework with Entatic Metal Centers Exhibiting High Gas Adsorption Affinity
journal, September 2006

Preparation and characterization of dinuclear copper(II) complexes containing the [Cu2(μ-OAc)2]2+ core
journal, January 1992

Biomedical and Biochemical Applications of Self-Assembled Metallacycles and Metallacages
journal, June 2013

Formation of a Highly Reactive Cobalt Nanocluster Crystal within a Highly Negatively Charged Porous Coordination Cage
journal, March 2018

Highly-Selective and Reversible O₂ Binding in Cr₃(1,3,5-benzenetricarboxylate)₂
journal, June 2010

Catalysis in a Cationic Coordination Cage Using a Cavity-Bound Guest and Surface-Bound Anions: Inhibition, Activation, and Autocatalysis
journal, February 2018

Light-Triggered Guest Uptake and Release by a Photochromic Coordination Cage
journal, December 2012

Precursors for Assembly of Supramolecules Containing Quadruply Bonded Cr24+ Units: Systematic Preparation of Cr2(formamidinate)n(acetate)4–n (n = 2–4)
journal, August 2007

Design, Synthesis, Structure, and Gas (N₂, Ar, CO₂, CH₄, and H₂) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
journal, May 2005

Noble Gas Adsorption in Copper Trimesate, HKUST-1: An Experimental and Computational Study
journal, September 2013

A Chiral Quadruple-Stranded Helicate Cage for Enantioselective Recognition and Separation
journal, April 2012

Chromium(II) complexes bearing 2,6-substituted N,N ′-diarylformamidinate ligands
journal, January 2000

Metal-organic polyhedra 18 mixed-matrix membranes for gas separation
journal, August 2014

Critical Factors Driving the High Volumetric Uptake of Methane in Cu ₃ (btc) ₂
journal, August 2015

Template-Directed Synthesis of Nets Based upon Octahemioctahedral Cages That Encapsulate Catalytically Active Metalloporphyrins
journal, December 2011

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008

Cage-Catalyzed Knoevenagel Condensation under Neutral Conditions in Water
journal, December 2011

Azobenzene-Functionalized Metal-Organic Polyhedra for the Optically Responsive Capture and Release of Guest Molecules
journal, May 2014

Directed assembly metallocyclic supramolecular systems for molecular recognition and chemical sensing
journal, April 2008

Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
journal, August 2012

Self-Assembly of Cationic, Hetero- or Homonuclear Ruthenium(II) Macrocyclic Rectangles and Their Photophysical, Electrochemical, and Biological Studies
journal, December 2011

Porous Metal−Organic Polyhedra: 25 Å Cuboctahedron Constructed from 12 Cu₂(CO₂)₄ Paddle-Wheel Building Blocks
journal, May 2001

In Situ Construction of a Coordination Zirconocene Tetrahedron
journal, November 2013

Mixed-Valence Iron(II, III) Trimesates with Open Frameworks Modulated by Solvents
journal, September 2007

Cross-linking Zr-based metal–organic polyhedra via postsynthetic polymerization
journal, January 2017

Synthesis and properties of the metal-organic framework Mo3(BTC)2 (TUDMOF-1)
journal, January 2006

From Coordination Cages to a Stable Crystalline Porous Hydrogen-Bonded Framework
journal, March 2017

The designed ‘self-assembly’ of a three-dimensional molecule containing six quadruply-bonded Mo24+ units
journal, January 1999

Solvothermal growth of a ruthenium metal–organic framework featuring HKUST-1 structure type as thin films on oxide surfaces
journal, January 2011