Elucidating the mechanism of the UiO-66-catalyzed sulfide oxidation: activity and selectivity enhancements through changes in the node coordination environment and solvent
Abstract
Benzoic acid modulators that “cap” the Zr6-oxo-hydroxo cluster nodes in UiO-66 metal–organic frameworks can be removed to increase the number of “open” sites (i.e., those that are terminated with [μ1-OH + μ1-OH2]) up to 5 per node, enabling the “decapped” materials to exhibit enhanced catalytic activity in the oxidation of methyl phenyl sulfide. Here, computational modeling reveals that the labile Zr-μ1-OH groups on these open sites are likely converted into Zr-μ1-OOH species that are active in oxidizing the sulfide as well as its sulfoxide product. In solvents such as CH3CN and CH2Cl2, the sulfoxide product can additionally replace the aquo ligands of the Zr-μ1-OH2 moieties to increase the concentration of the sulfoxide adjacent to the active Zr-μ1-OOH species, resulting in overoxidation to the sulfone. However, the use of CH3OH, a solvent that can compete with the sulfoxide and suppress this binding mode, can retard the overoxidation and lead to higher selectivities for the sulfoxide product.
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of California, Oakland, CA (United States); Northwestern Univ., Evanston, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; Sigma Xi; Defense Threat Reduction Agency (DTRA); National Science Foundation (NSF); International Institute for Nanotechnology (IIN); Keck Foundation; State of Illinois
- OSTI Identifier:
- 1543805
- Alternate Identifier(s):
- OSTI ID: 1485709
- Grant/Contract Number:
- AC02-05CH11231; FG02-03ER15457; G201603152055000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Catalysis Science and Technology
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 2; Journal ID: ISSN 2044-4753
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemistry
Citation Formats
Limvorapitux, Rungmai, Chen, Haoyuan, Mendonca, Matthew L., Liu, Mengtan, Snurr, Randall Q., and Nguyen, SonBinh T. Elucidating the mechanism of the UiO-66-catalyzed sulfide oxidation: activity and selectivity enhancements through changes in the node coordination environment and solvent. United States: N. p., 2018.
Web. doi:10.1039/c8cy01139g.
Limvorapitux, Rungmai, Chen, Haoyuan, Mendonca, Matthew L., Liu, Mengtan, Snurr, Randall Q., & Nguyen, SonBinh T. Elucidating the mechanism of the UiO-66-catalyzed sulfide oxidation: activity and selectivity enhancements through changes in the node coordination environment and solvent. United States. https://doi.org/10.1039/c8cy01139g
Limvorapitux, Rungmai, Chen, Haoyuan, Mendonca, Matthew L., Liu, Mengtan, Snurr, Randall Q., and Nguyen, SonBinh T. Wed .
"Elucidating the mechanism of the UiO-66-catalyzed sulfide oxidation: activity and selectivity enhancements through changes in the node coordination environment and solvent". United States. https://doi.org/10.1039/c8cy01139g. https://www.osti.gov/servlets/purl/1543805.
@article{osti_1543805,
title = {Elucidating the mechanism of the UiO-66-catalyzed sulfide oxidation: activity and selectivity enhancements through changes in the node coordination environment and solvent},
author = {Limvorapitux, Rungmai and Chen, Haoyuan and Mendonca, Matthew L. and Liu, Mengtan and Snurr, Randall Q. and Nguyen, SonBinh T.},
abstractNote = {Benzoic acid modulators that “cap” the Zr6-oxo-hydroxo cluster nodes in UiO-66 metal–organic frameworks can be removed to increase the number of “open” sites (i.e., those that are terminated with [μ1-OH + μ1-OH2]) up to 5 per node, enabling the “decapped” materials to exhibit enhanced catalytic activity in the oxidation of methyl phenyl sulfide. Here, computational modeling reveals that the labile Zr-μ1-OH groups on these open sites are likely converted into Zr-μ1-OOH species that are active in oxidizing the sulfide as well as its sulfoxide product. In solvents such as CH3CN and CH2Cl2, the sulfoxide product can additionally replace the aquo ligands of the Zr-μ1-OH2 moieties to increase the concentration of the sulfoxide adjacent to the active Zr-μ1-OOH species, resulting in overoxidation to the sulfone. However, the use of CH3OH, a solvent that can compete with the sulfoxide and suppress this binding mode, can retard the overoxidation and lead to higher selectivities for the sulfoxide product.},
doi = {10.1039/c8cy01139g},
journal = {Catalysis Science and Technology},
number = 2,
volume = 9,
place = {United States},
year = {Wed Oct 24 00:00:00 EDT 2018},
month = {Wed Oct 24 00:00:00 EDT 2018}
}
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Works referenced in this record:
Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr)
journal, July 2013
- Vermoortele, Frederik; Bueken, Bart; Le Bars, Gaëlle
- Journal of the American Chemical Society, Vol. 135, Issue 31
Surface chemistry of carboxylato-substituted metal oxo clusters – Model systems for nanoparticles
journal, November 2017
- Schubert, Ulrich
- Coordination Chemistry Reviews, Vol. 350
Origin of highly active metal–organic framework catalysts: defects? Defects!
journal, January 2016
- Canivet, J.; Vandichel, M.; Farrusseng, D.
- Dalton Transactions, Vol. 45, Issue 10
Defects and disorder in metal organic frameworks
journal, January 2016
- Cheetham, Anthony K.; Bennett, Thomas D.; Coudert, François-Xavier
- Dalton Transactions, Vol. 45, Issue 10
Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals
journal, May 2011
- Schaate, Andreas; Roy, Pascal; Godt, Adelheid
- Chemistry - A European Journal, Vol. 17, Issue 24
Structural defects in metal–organic frameworks (MOFs): Formation, detection and control towards practices of interests
journal, October 2017
- Ren, Jianwei; Ledwaba, Mpho; Musyoka, Nicholas M.
- Coordination Chemistry Reviews, Vol. 349
Hydrolysis and Complexation of N , N -Dimethylformamide in New Nanostructurated Titanium Oxide Hybrid Organic–Inorganic Sols and Gel
journal, June 2011
- Cottineau, Thomas; Richard-Plouet, Mireille; Mevellec, Jean-Yves
- The Journal of Physical Chemistry C, Vol. 115, Issue 25
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012
- Morris, William; Volosskiy, Boris; Demir, Selcuk
- Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
Defective Metal-Organic Frameworks
journal, January 2018
- Dissegna, Stefano; Epp, Konstantin; Heinz, Werner R.
- Advanced Materials, Vol. 30, Issue 37
Supercapacitors of Nanocrystalline Metal–Organic Frameworks
journal, June 2014
- Choi, Kyung Min; Jeong, Hyung Mo; Park, Jung Hyo
- ACS Nano, Vol. 8, Issue 7
Water adsorption in UiO-66: the importance of defects
journal, January 2014
- Ghosh, Pritha; Colón, Yamil J.; Snurr, Randall Q.
- Chem. Commun., Vol. 50, Issue 77
Ultrahigh Surface Area Zirconium MOFs and Insights into the Applicability of the BET Theory
journal, March 2015
- Wang, Timothy C.; Bury, Wojciech; Gómez-Gualdrón, Diego A.
- Journal of the American Chemical Society, Vol. 137, Issue 10
Production of ultra-deep sulfur-free diesels using a sustainable catalytic system based on UiO-66(Zr)
journal, January 2015
- Granadeiro, Carlos M.; Ribeiro, Susana O.; Karmaoui, Mohamed
- Chemical Communications, Vol. 51, Issue 72
An amino-modified Zr-terephthalate metal–organic framework as an acid–base catalyst for cross-aldol condensation
journal, January 2011
- Vermoortele, Frederik; Ameloot, Rob; Vimont, Alexandre
- Chem. Commun., Vol. 47, Issue 5
Molecular catalysis science: Perspective on unifying the fields of catalysis
journal, April 2016
- Ye, Rong; Hurlburt, Tyler J.; Sabyrov, Kairat
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 19
Enhanced acidity of defective MOF-808: effects of the activation process and missing linker defects
journal, January 2018
- Ardila-Suárez, C.; Perez-Beltran, Saul; Ramírez-Caballero, G. E.
- Catalysis Science & Technology, Vol. 8, Issue 3
Oxozirconium Methacrylate Clusters: Zr6(OH)4O4(OMc)12 and Zr4O2(OMc)12 (OMc = Methacrylate)
journal, April 1997
- Kickelbick, Guido; Schubert, Ulrich
- Chemische Berichte, Vol. 130, Issue 4
Macrocycles based on magnetically functionalized zirconium oxide clusters
journal, January 2012
- Malaestean, Iurii L.; Kutluca, Meliha; Speldrich, Manfred
- Inorganica Chimica Acta, Vol. 380
Defect Engineering: Tuning the Porosity and Composition of the Metal–Organic Framework UiO-66 via Modulated Synthesis
journal, May 2016
- Shearer, Greig C.; Chavan, Sachin; Bordiga, Silvia
- Chemistry of Materials, Vol. 28, Issue 11
Dynamic acidity in defective UiO-66
journal, January 2016
- Ling, Sanliang; Slater, Ben
- Chemical Science, Vol. 7, Issue 7
Asymmetric oxidation of sulfides by hydrogen peroxide catalyzed by chiral manganese porphyrins in water/methanol solution
journal, April 2013
- Srour, Hassan; Jalkh, Joanna; Le Maux, Paul
- Journal of Molecular Catalysis A: Chemical, Vol. 370
A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores
journal, November 2014
- Feng, Dawei; Wang, Kecheng; Su, Jie
- Angewandte Chemie International Edition, Vol. 54, Issue 1
Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption
journal, May 2013
- Wu, Hui; Chua, Yong Shen; Krungleviciute, Vaiva
- Journal of the American Chemical Society, Vol. 135, Issue 28
Effect of Benzoic Acid as a Modulator in the Structure of UiO-66: An Experimental and Computational Study
journal, April 2017
- Atzori, Cesare; Shearer, Greig C.; Maschio, Lorenzo
- The Journal of Physical Chemistry C, Vol. 121, Issue 17
Control of the ratio of functional and non-functional ligands in clusters of the type Zr 6 O 4 (OH) 4 (carboxylate) 12 for their use as building blocks for inorganic–organic hybrid polymers
journal, January 2004
- Kogler, Franz René; Jupa, Myhedin; Puchberger, Michael
- J. Mater. Chem., Vol. 14, Issue 21
Cluster-based inorganic–organic hybrid materials
journal, January 2011
- Schubert, Ulrich
- Chem. Soc. Rev., Vol. 40, Issue 2
Efficient and selective hydrogen peroxide-mediated oxidation of sulfides in batch and segmented and continuous flow using a peroxometalate-based polymer immobilised ionic liquid phase catalyst
journal, January 2015
- Doherty, S.; Knight, J. G.; Carroll, M. A.
- Green Chemistry, Vol. 17, Issue 3
Definitive Molecular Level Characterization of Defects in UiO-66 Crystals
journal, August 2015
- Trickett, Christopher A.; Gagnon, Kevin J.; Lee, Seungkyu
- Angewandte Chemie International Edition, Vol. 54, Issue 38
Variations in capping the Zr6O4(OH)4 cluster core: X-ray structure analyses of [Zr6(OH)4O4(OOC–CHCH2)10]2(μ-OOC–CHCH2)4 and Zr6(OH)4O4(OOCR)12(PrOH) (R=Ph, CMe=CH2)
journal, January 1999
- Kickelbick, Guido; Wiede, Petra; Schubert, Ulrich
- Inorganica Chimica Acta, Vol. 284, Issue 1
Nature of active sites on UiO-66 and beneficial influence of water in the catalysis of Fischer esterification
journal, August 2017
- Caratelli, Chiara; Hajek, Julianna; Cirujano, Francisco G.
- Journal of Catalysis, Vol. 352
Influence of functionalization of terephthalate linker on the catalytic activity of UiO-66 for epoxide ring opening
journal, December 2016
- Blandez, Juan F.; Santiago-Portillo, Andrea; Navalón, Sergio
- Journal of Molecular Catalysis A: Chemical, Vol. 425
Mild Oxidation with H2O2 over Ti-Containing Molecular Sieves—A very Efficient Method for Removing Aromatic Sulfur Compounds from Fuels
journal, March 2001
- Hulea, Vasile; Fajula, François; Bousquet, Jacques
- Journal of Catalysis, Vol. 198, Issue 2
The Relative Reactivity of Thioethers and Sulfoxides toward Oxygen Transfer Reagents: The Oxidation of Thianthrene 5-Oxide and Related Compounds by MoO5HMPT
journal, July 1995
- Bonchio, Marcella; Conte, Valeria; Assunta De Conciliis, Maria
- The Journal of Organic Chemistry, Vol. 60, Issue 14
Silica sulfuric acid promoted selective oxidation of sulfides to sulfoxides or sulfones in the presence of aqueous H2O2
journal, July 2007
- Shaabani, Ahmad; Rezayan, Ali Hossein
- Catalysis Communications, Vol. 8, Issue 7
Tuning the Surface Chemistry of Metal Organic Framework Nodes: Proton Topology of the Metal-Oxide-Like Zr 6 Nodes of UiO-66 and NU-1000
journal, November 2016
- Yang, Dong; Bernales, Varinia; Islamoglu, Timur
- Journal of the American Chemical Society, Vol. 138, Issue 46
Defects in Metal–Organic Frameworks: Challenge or Opportunity?
journal, August 2015
- Sholl, David S.; Lively, Ryan P.
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 17
Polymers Reinforced by Covalently Bonded Inorganic Clusters
journal, October 2001
- Schubert, Ulrich
- Chemistry of Materials, Vol. 13, Issue 10
Isoreticular synthesis and modification of frameworks with the UiO-66 topology
journal, January 2010
- Garibay, Sergio J.; Cohen, Seth M.
- Chemical Communications, Vol. 46, Issue 41, p. 7700-7702
Enhancement of Oxidative Desulfurization Performance over UiO-66(Zr) by Titanium Ion Exchange
journal, June 2017
- Ye, Gan; Qi, Hui; Li, Xiaolin
- ChemPhysChem, Vol. 18, Issue 14
Defect-Engineered Metal-Organic Frameworks
journal, June 2015
- Fang, Zhenlan; Bueken, Bart; De Vos, Dirk E.
- Angewandte Chemie International Edition, Vol. 54, Issue 25
Size- and shape-dependent catalytic performances of oxidation and reduction reactions on nanocatalysts
journal, January 2016
- Cao, Shaowen; Tao, Franklin (Feng); Tang, Yu
- Chemical Society Reviews, Vol. 45, Issue 17
A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology
journal, December 2014
- Feng, Dawei; Gu, Zhi-Yuan; Chen, Ying-Pin
- Journal of the American Chemical Society, Vol. 136, Issue 51
Zr-based metal–organic frameworks: design, synthesis, structure, and applications
journal, January 2016
- Bai, Yan; Dou, Yibo; Xie, Lin-Hua
- Chemical Society Reviews, Vol. 45, Issue 8
Hydrolytic Stability and Hydrogen Peroxide Activation of Zirconium-Based Oxoclusters: Hydrolytic Stability of Zirconium-Based Oxoclusters
journal, November 2014
- Faccioli, Francesco; Bauer, Matthias; Pedron, Danilo
- European Journal of Inorganic Chemistry, Vol. 2015, Issue 2
New zirconium and zirconium–titanium oxo cluster types by expansion or metal substitution of the octahedral Zr6O8 structural motif
journal, June 2015
- Artner, Christine; Czakler, Matthias; Schubert, Ulrich
- Inorganica Chimica Acta, Vol. 432
Metal–Organic Framework (MOF) Defects under Control: Insights into the Missing Linker Sites and Their Implication in the Reactivity of Zirconium-Based Frameworks
journal, August 2015
- Gutov, Oleksii V.; Hevia, Miguel González; Escudero-Adán, Eduardo C.
- Inorganic Chemistry, Vol. 54, Issue 17
Periodic Trends in Olefin Epoxidation over Group IV and V Framework-Substituted Zeolite Catalysts: A Kinetic and Spectroscopic Study
journal, May 2017
- Bregante, Daniel T.; Flaherty, David W.
- Journal of the American Chemical Society, Vol. 139, Issue 20
A facile synthesis of UiO-66, UiO-67 and their derivatives
journal, January 2013
- Katz, Michael J.; Brown, Zachary J.; Colón, Yamil J.
- Chemical Communications, Vol. 49, Issue 82
Influence of a Confined Methanol Solvent on the Reactivity of Active Sites in UiO-66
journal, January 2018
- Caratelli, Chiara; Hajek, Julianna; Rogge, Sven M. J.
- ChemPhysChem, Vol. 19, Issue 4
High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites
journal, January 2014
- Li, Liangjun; Tang, Sifu; Wang, Chao
- Chemical Communications, Vol. 50, Issue 18
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014
- Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao
- Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381
One Step Backward Is Two Steps Forward: Enhancing the Hydrolysis Rate of UiO-66 by Decreasing [OH – ]
journal, July 2015
- Katz, Michael J.; Klet, Rachel C.; Moon, Su-Young
- ACS Catalysis, Vol. 5, Issue 8
The new type of [Zr6(μ3-O)4(μ3-OH)4] cluster core: Crystal structure and spectral characterization of [Zr6O4(OH)4(OOCR)12] (R=But, C(CH3)2Et)
journal, February 2007
- Piszczek, P.; Radtke, A.; Grodzicki, A.
- Polyhedron, Vol. 26, Issue 3
When defects turn into virtues: The curious case of zirconium-based metal-organic frameworks
journal, July 2017
- Taddei, Marco
- Coordination Chemistry Reviews, Vol. 343
A metal–organic framework for oxidative desulfurization: UIO-66(Zr) as a catalyst
journal, December 2017
- Zhang, Xiaotian; Huang, Pengcheng; Liu, Aili
- Fuel, Vol. 209
Pore Surface Engineering with Controlled Loadings of Functional Groups via Click Chemistry in Highly Stable Metal–Organic Frameworks
journal, August 2012
- Jiang, Hai-Long; Feng, Dawei; Liu, Tian-Fu
- Journal of the American Chemical Society, Vol. 134, Issue 36
Boosting Catalytic Performance of Metal–Organic Framework by Increasing the Defects via a Facile and Green Approach
journal, September 2017
- Ye, Gan; Zhang, Dan; Li, Xiangfu
- ACS Applied Materials & Interfaces, Vol. 9, Issue 40
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008
- Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
- Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
Tuned to Perfection: Ironing Out the Defects in Metal–Organic Framework UiO-66
journal, July 2014
- Shearer, Greig C.; Chavan, Sachin; Ethiraj, Jayashree
- Chemistry of Materials, Vol. 26, Issue 14
An efficient combination of Zr-MOF and microwave irradiation in catalytic Lewis acid Friedel–Crafts benzoylation
journal, January 2016
- Doan, Tan L. H.; Dao, Thong Q.; Tran, Hai N.
- Dalton Transactions, Vol. 45, Issue 18
Degradation of Paraoxon and the Chemical Warfare Agents VX, Tabun, and Soman by the Metal–Organic Frameworks UiO-66-NH 2 , MOF-808, NU-1000, and PCN-777
journal, September 2017
- de Koning, Martijn C.; van Grol, Marco; Breijaert, Troy
- Inorganic Chemistry, Vol. 56, Issue 19
Non-hydrolytic synthesis of mesoporous silica–titania catalysts for the mild oxidation of sulfur compounds with hydrogen peroxide
journal, January 2008
- Cojocariu, Ana Mihaela; Mutin, P. Hubert; Dumitriu, Emil
- Chemical Communications, Issue 42
MOFs and their grafted analogues: regioselective epoxide ring-opening with Zr 6 nodes
journal, January 2016
- Thornburg, Nicholas E.; Liu, Yangyang; Li, Peng
- Catalysis Science & Technology, Vol. 6, Issue 17
Probing the correlations between the defects in metal–organic frameworks and their catalytic activity by an epoxide ring-opening reaction
journal, January 2016
- Liu, Yangyang; Klet, Rachel C.; Hupp, Joseph T.
- Chemical Communications, Vol. 52, Issue 50
Heterometal expansion of oxozirconium carboxylate clusters
journal, January 2011
- Malaestean, Iurii L.; Speldrich, Manfred; Ellern, Arkady
- Dalton Trans., Vol. 40, Issue 2
Water-Stable Zirconium-Based Metal-Organic Framework Material with High-Surface Area and Gas-Storage Capacities
journal, August 2014
- Gutov, Oleksii V.; Bury, Wojciech; Gomez-Gualdron, Diego A.
- Chemistry - A European Journal, Vol. 20, Issue 39
A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores
journal, November 2014
- Feng, Dawei; Wang, Kecheng; Su, Jie
- Angewandte Chemie, Vol. 127, Issue 1
Definitive Molecular Level Characterization of Defects in UiO-66 Crystals
journal, August 2015
- Trickett, Christopher A.; Gagnon, Kevin J.; Lee, Seungkyu
- Angewandte Chemie, Vol. 127, Issue 38
Hydrolytic Stability and Hydrogen Peroxide Activation of Zirconium‐Based Oxoclusters
journal, January 2015
- Faccioli, Francesco; Bauer, Matthias; Pedron, Danilo
- European Journal of Inorganic Chemistry, Vol. 2015, Issue 2
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journal, January 2019
- Torbina, Viktoriia; Salaev, Mikhail; Vodyankina, Olga
- RSC Advances, Vol. 9, Issue 45
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journal, January 2020
- Rajendran, Antony; Cui, Tian-you; Fan, Hong-xia
- Journal of Materials Chemistry A, Vol. 8, Issue 5
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journal, December 2019
- Stawowy, Michalina; Ciesielski, Radosław; Maniecki, Tomasz
- Catalysts, Vol. 10, Issue 1