Revealing the Effects of Electrode Crystallographic Orientation on Battery Electrochemistryvia the Anisotropic Lithiation and Sodiation of ReS2
Abstract
Practical application of electrochemical water splitting demands durable, efficient, and non-noble metal catalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Herein, we report a new hydrogen evolution nanowire electrocatalyst, consisting of S-doped CoWP nanoparticles embedded in S- and N-doped carbon matrix (S-CoWP@(S,N)-C), which is in situ transformed from Hofmann-type (Co, W)-based metal–organic framework (MOF) nanowires. Because of S and N doping to the carbon matrix and the S doping to CoWP nanoparticles, the obtained S-CoWP@(S,N)-C catalyst reaches a current density of -10 mA cm–2 at -35 and -67 mV (vs RHE) in acidic and alkaline electrolytes, respectively. Powered by a lead halide perovskite solar cell, an unassisted two-electrode solar water-splitting device using MOF-derived S-CoWP@(S,N)-C HER electrocatalysts and S-CoW@(S,N)-C OER electrocatalysts displays a solar-to-hydrogen conversion efficiency of 10.98%. Our method is highly applicable for developing robust electrocatalysts toward efficient and low-cost solar-driven water splitting.
- Authors:
-
[2];
[2];
[2];
[2];
[2];
[2];
[2];
[2]
- Shanghai Univ., Shanghai (China); Northwestern Univ., Evanston, IL (United States)
- Northwestern Univ., Evanston, IL (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Electrical Energy Storage (CEES); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of California, Oakland, CA (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1543716
- Grant/Contract Number:
- AC02-05CH11231; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Nano
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 8; Journal ID: ISSN 1936-0851
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Chemistry; Science & Technology - Other Topics; Materials Science
Citation Formats
Li, Qianqian, Xu, Yaobin, Yao, Zhenpeng, Kang, Joohoon, Liu, Xiaolong, Wolverton, Chris, Hersam, Mark C., Wu, Jinsong, and Dravid, Vinayak P. Revealing the Effects of Electrode Crystallographic Orientation on Battery Electrochemistryvia the Anisotropic Lithiation and Sodiation of ReS2. United States: N. p., 2018.
Web. doi:10.1021/acsnano.8b02203.
Li, Qianqian, Xu, Yaobin, Yao, Zhenpeng, Kang, Joohoon, Liu, Xiaolong, Wolverton, Chris, Hersam, Mark C., Wu, Jinsong, & Dravid, Vinayak P. Revealing the Effects of Electrode Crystallographic Orientation on Battery Electrochemistryvia the Anisotropic Lithiation and Sodiation of ReS2. United States. https://doi.org/10.1021/acsnano.8b02203
Li, Qianqian, Xu, Yaobin, Yao, Zhenpeng, Kang, Joohoon, Liu, Xiaolong, Wolverton, Chris, Hersam, Mark C., Wu, Jinsong, and Dravid, Vinayak P. Mon .
"Revealing the Effects of Electrode Crystallographic Orientation on Battery Electrochemistryvia the Anisotropic Lithiation and Sodiation of ReS2". United States. https://doi.org/10.1021/acsnano.8b02203. https://www.osti.gov/servlets/purl/1543716.
@article{osti_1543716,
title = {Revealing the Effects of Electrode Crystallographic Orientation on Battery Electrochemistryvia the Anisotropic Lithiation and Sodiation of ReS2},
author = {Li, Qianqian and Xu, Yaobin and Yao, Zhenpeng and Kang, Joohoon and Liu, Xiaolong and Wolverton, Chris and Hersam, Mark C. and Wu, Jinsong and Dravid, Vinayak P.},
abstractNote = {Practical application of electrochemical water splitting demands durable, efficient, and non-noble metal catalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Herein, we report a new hydrogen evolution nanowire electrocatalyst, consisting of S-doped CoWP nanoparticles embedded in S- and N-doped carbon matrix (S-CoWP@(S,N)-C), which is in situ transformed from Hofmann-type (Co, W)-based metal–organic framework (MOF) nanowires. Because of S and N doping to the carbon matrix and the S doping to CoWP nanoparticles, the obtained S-CoWP@(S,N)-C catalyst reaches a current density of -10 mA cm–2 at -35 and -67 mV (vs RHE) in acidic and alkaline electrolytes, respectively. Powered by a lead halide perovskite solar cell, an unassisted two-electrode solar water-splitting device using MOF-derived S-CoWP@(S,N)-C HER electrocatalysts and S-CoW@(S,N)-C OER electrocatalysts displays a solar-to-hydrogen conversion efficiency of 10.98%. Our method is highly applicable for developing robust electrocatalysts toward efficient and low-cost solar-driven water splitting.},
doi = {10.1021/acsnano.8b02203},
journal = {ACS Nano},
number = 8,
volume = 12,
place = {United States},
year = {Mon Jul 09 00:00:00 EDT 2018},
month = {Mon Jul 09 00:00:00 EDT 2018}
}
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