Effects of Controlled Crystalline Surface of Hydroxyapatite on Methane Oxidation Reactions
Abstract
Hydroxyapatite (HAP, Ca10(PO4)6(OH)2) has a hexagonal prismatic structure that exposes two crystalline surfaces: prism-faceted a- and basal-faceted c-surfaces. Here, the predominant exposure of c-surface was controlled, and its influences in methane oxidation reactions (combustion and oxidative coupling over HAP and lead-substituted HAP (Pb-HAP), respectively) were studied. The c-surface exposure was realized by crystal orientation in HAP-based catalyst film, which was created by an electrochemical deposition of HAP seeds on a titanium substrate, followed by hydrothermal crystallization and peeling off of the crystalline films from the substrate. In comparison to a-surface that is prevalently exposed in unoriented HAP-based catalysts, the c-surface (i.e., (002) crystalline plane) of HAP-based catalysts exhibited up to 47-fold enhancement in areal rate in both reactions. The distinct catalytic activity between these two crystalline surfaces is attributed to the preferential formation of oxide ions and vacancies on c-surfaces. The oxide ions and vacancies in turns function as actives sites for promoting methane activation and complete oxidation into CO2. Density functional theory calculations confirmed the close relationship between different catalytic activities in c-surface of oriented and a-surface of unoriented HAP through the tendency of vacancy formation. Without the presence of vacancies, the methyl or methylene group after methane activationmore »
- Authors:
-
[1];
[2];
- Univ. of Maryland, College Park, MD (United States). Dept. of Chemical and Biomolecular Engineering
- Kansas State Univ., Manhattan, KS (United States). Dept. of Chemical Engineering
- U.S. Army Research Lab., Adelphi, MD (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of California, Oakland, CA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1543698
- Grant/Contract Number:
- AC02-05CH11231; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Catalysis
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 5; Journal ID: ISSN 2155-5435
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; chemistry; hydroxyapatite; crystalline plane; methane conversion; density functional theory; oxygen vacancy
Citation Formats
Oh, Su Cheun, Xu, Jiayi, Tran, Dat T., Liu, Bin, and Liu, Dongxia. Effects of Controlled Crystalline Surface of Hydroxyapatite on Methane Oxidation Reactions. United States: N. p., 2018.
Web. doi:10.1021/acscatal.7b04011.
Oh, Su Cheun, Xu, Jiayi, Tran, Dat T., Liu, Bin, & Liu, Dongxia. Effects of Controlled Crystalline Surface of Hydroxyapatite on Methane Oxidation Reactions. United States. https://doi.org/10.1021/acscatal.7b04011
Oh, Su Cheun, Xu, Jiayi, Tran, Dat T., Liu, Bin, and Liu, Dongxia. Mon .
"Effects of Controlled Crystalline Surface of Hydroxyapatite on Methane Oxidation Reactions". United States. https://doi.org/10.1021/acscatal.7b04011. https://www.osti.gov/servlets/purl/1543698.
@article{osti_1543698,
title = {Effects of Controlled Crystalline Surface of Hydroxyapatite on Methane Oxidation Reactions},
author = {Oh, Su Cheun and Xu, Jiayi and Tran, Dat T. and Liu, Bin and Liu, Dongxia},
abstractNote = {Hydroxyapatite (HAP, Ca10(PO4)6(OH)2) has a hexagonal prismatic structure that exposes two crystalline surfaces: prism-faceted a- and basal-faceted c-surfaces. Here, the predominant exposure of c-surface was controlled, and its influences in methane oxidation reactions (combustion and oxidative coupling over HAP and lead-substituted HAP (Pb-HAP), respectively) were studied. The c-surface exposure was realized by crystal orientation in HAP-based catalyst film, which was created by an electrochemical deposition of HAP seeds on a titanium substrate, followed by hydrothermal crystallization and peeling off of the crystalline films from the substrate. In comparison to a-surface that is prevalently exposed in unoriented HAP-based catalysts, the c-surface (i.e., (002) crystalline plane) of HAP-based catalysts exhibited up to 47-fold enhancement in areal rate in both reactions. The distinct catalytic activity between these two crystalline surfaces is attributed to the preferential formation of oxide ions and vacancies on c-surfaces. The oxide ions and vacancies in turns function as actives sites for promoting methane activation and complete oxidation into CO2. Density functional theory calculations confirmed the close relationship between different catalytic activities in c-surface of oriented and a-surface of unoriented HAP through the tendency of vacancy formation. Without the presence of vacancies, the methyl or methylene group after methane activation forms ethane or ethylene via coupling. The present study explored the effects of HAP crystal orientation in methane oxidation reactions, which revealed distinct catalytic behaviors of crystal surfaces in HAP-based materials.},
doi = {10.1021/acscatal.7b04011},
journal = {ACS Catalysis},
number = 5,
volume = 8,
place = {United States},
year = {2018},
month = {4}
}
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Works referenced in this record:
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Catalysts for combustion of methane and lower alkanes
journal, August 2002
- Choudhary, T. V.; Banerjee, S.; Choudhary, V. R.
- Applied Catalysis A: General, Vol. 234, Issue 1-2
Crystal Structure of Calcium-Deficient Carbonated Hydroxyapatite. Thermal Decomposition
journal, September 2001
- Ivanova, T. I.; Frank-Kamenetskaya, O. V.; Kol'tsov, A. B.
- Journal of Solid State Chemistry, Vol. 160, Issue 2
Synthesis of Branched Polyethylene by Tandem Catalysis
journal, April 2001
- Komon, Zachary J. A.; Bazan, Guillermo C.
- Macromolecular Rapid Communications, Vol. 22, Issue 7
Radical generation on hydroxyapatite by UV irradiation
journal, January 2004
- Nishikawa, Harumitsu
- Materials Letters, Vol. 58, Issue 1-2
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Dehydroxylation of hydroxyapatite in dense bulk ceramics sintered by spark plasma sintering
journal, August 2012
- Liu, Yi; Shen, Zhijian
- Journal of the European Ceramic Society, Vol. 32, Issue 11
Hydrogen held by solids. XII. Hydroxyapatite catalysts
journal, October 1967
- Bett, John A. S.; Christner, Larry G.; Hall, W. Keith.
- Journal of the American Chemical Society, Vol. 89, Issue 22
Coating of hydroxyapatite films on metal substrates by seeded hydrothermal deposition
journal, May 2011
- Liu, Dongxia; Savino, Keith; Yates, Matthew Z.
- Surface and Coatings Technology, Vol. 205, Issue 16
Catalytic Oxidative Decomposition of Dimethyl Methylphosphonate over Cu-Substituted Hydroxyapatite
journal, January 1994
- Lee, K. Y.; Houalla, M.; Hercules, D. M.
- Journal of Catalysis, Vol. 145, Issue 1
Strontium-substituted hydroxyapatite nanocrystals
journal, February 2007
- Bigi, Adriana; Boanini, Elisa; Capuccini, Chiara
- Inorganica Chimica Acta, Vol. 360, Issue 3
Gold Supported on Hydroxyapatite as a Versatile Multifunctional Catalyst for the Direct Tandem Synthesis of Imines and Oximes
journal, June 2009
- Sun, Hao; Su, Fang-Zheng; Ni, Ji
- Angewandte Chemie International Edition, Vol. 48, Issue 24
Physical parameters of hydroxyapatite adsorption and effect on candidacidal activity of histatins
journal, May 2003
- Yin, A.; Margolis, H. C.; Grogan, J.
- Archives of Oral Biology, Vol. 48, Issue 5
A novel two-step sintering for nano-hydroxyapatite scaffolds for bone tissue engineering
journal, July 2014
- Feng, Pei; Niu, Man; Gao, Chengde
- Scientific Reports, Vol. 4, Issue 1
Morphological regulation and crystal growth of hydrothermal-electrochemically deposited apatite
journal, July 2002
- Ban, Seiji; Hasegawa, Jiro
- Biomaterials, Vol. 23, Issue 14
The Different Catalytic Routes for Methane Valorization: An Assessment of Processes for Liquid Fuels
journal, June 1993
- Fox, Joseph M.
- Catalysis Reviews, Vol. 35, Issue 2
Development of a,b-plane-oriented hydroxyapatite ceramics as models for living bones and their cell adhesion behavior
journal, May 2013
- Zhuang, Zhi; Fujimi, Takahiko J.; Nakamura, Mariko
- Acta Biomaterialia, Vol. 9, Issue 5
Aerobic Oxidation of Cyclohexane Catalyzed by Size-Controlled Au Clusters on Hydroxyapatite: Size Effect in the Sub-2 nm Regime
journal, December 2010
- Liu, Yongmei; Tsunoyama, Hironori; Akita, Tomoki
- ACS Catalysis, Vol. 1, Issue 1
Hydroxyapatite substituted by transition metals: experiment and theory
journal, January 2016
- Zilm, M. E.; Chen, L.; Sharma, V.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 24
Direct conversion of methane to fuels and chemicals
journal, April 2009
- Holmen, Anders
- Catalysis Today, Vol. 142, Issue 1-2, p. 2-8
Proton transport polarization and depolarization of hydroxyapatite ceramics
journal, May 2001
- Nakamura, Satoshi; Takeda, Hiroaki; Yamashita, Kimihiro
- Journal of Applied Physics, Vol. 89, Issue 10
Selective synthesis of 1-butanol from ethanol over strontium phosphate hydroxyapatite catalysts
journal, July 2011
- Ogo, Shuhei; Onda, Ayumu; Yanagisawa, Kazumichi
- Applied Catalysis A: General, Vol. 402, Issue 1-2
Oxidative coupling of methane using non-stoichiometric lead hydroxyapatite catalyst mixtures
journal, April 2012
- Park, Jai Hyun; Lee, Dae-Won; Im, Sung-Woo
- Fuel, Vol. 94
An Effective Morphology Control of Hydroxyapatite Crystals via Hydrothermal Synthesis
journal, November 2008
- Neira, Inés S.; Kolen’ko, Yury V.; Lebedev, Oleg I.
- Crystal Growth & Design, Vol. 9, Issue 1
An apparent ensemble effect in the oxidative coupling of methane on hydroxyapatites with incorporated lead
journal, January 1995
- Matsumura, Yasuyuki; Sugiyama, Shigeru; Hayashi, Hiromu
- Catalysis Letters, Vol. 30, Issue 1-4
Solubility and surface properties of finely divided hydroxyapatite
journal, January 1973
- Avnimelech, Y.; Moreno, E. C.; Brown, W. E.
- Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry, Vol. 77A, Issue 1
Hydroxyapatite as a liquid chromatographic packing
journal, May 1991
- Kawasaki, Tsutomu
- Journal of Chromatography A, Vol. 544
Oxidative Coupling of Methane to Higher Hydrocarbons
journal, June 1988
- Lee, J. S.; Oyama, S. T.
- Catalysis Reviews, Vol. 30, Issue 2
An Electron spin Resonance Study of Oxygen Radicals on Hydroxyapatite
journal, January 1996
- Kanai, Hiroyoshi; Matsumura, Yasuyuki; Moffat, John B.
- Phosphorus Research Bulletin, Vol. 6, Issue 0
Preparation and characterization of a titanium-substituted hydroxyapatite photocatalyst
journal, April 2007
- Hu, Anmin; Li, Ming; Chang, Chengkang
- Journal of Molecular Catalysis A: Chemical, Vol. 267, Issue 1-2
Catalytic consequences of cation and anion substitutions on rate and mechanism of oxidative coupling of methane over hydroxyapatite catalysts
journal, March 2017
- Oh, Su Cheun; Lei, Yu; Chen, Huiyong
- Fuel, Vol. 191
Reactivity of the Fe 2 O 3 (0001) Surface for Methane Oxidation: A GGA + U Study
journal, March 2016
- Tang, Jia-Jun; Liu, Bin
- The Journal of Physical Chemistry C, Vol. 120, Issue 12
Yttrium-Doped Hydroxyapatite Membranes with High Proton Conductivity
journal, May 2012
- Wei, Xue; Yates, Matthew Z.
- Chemistry of Materials, Vol. 24, Issue 10
CH 4 conversion to value added products: Potential, limitations and extensions of a single step heterogeneous catalysis
journal, December 2016
- Taifan, William; Baltrusaitis, Jonas
- Applied Catalysis B: Environmental, Vol. 198
Synthesis of ethylene via oxidative coupling of methane I. Determination of active catalysts
journal, January 1982
- Keller, G.
- Journal of Catalysis, Vol. 73, Issue 1
Orientation-Selective Alignments of Hydroxyapatite Nanoblocks through Epitaxial Attachment in a and c Directions
journal, April 2016
- Nakamura, Kazuki; Nakagawa, Yoshitaka; Kageyama, Hiroyuki
- Langmuir, Vol. 32, Issue 16
High Selective Conversion of Methane to Carbon Monoxide and the Effects of Chlorine Additives in the Gas and Solid Phases on the Oxidation of Methane on Strontium Hydroxyapatites
journal, February 1997
- Sugiyama, Shigeru; Minami, Toshimitsu; Higaki, Tomonori
- Industrial & Engineering Chemistry Research, Vol. 36, Issue 2
Revealing Hydroxyapatite Nanoparticle Surface Structure by CO Adsorption: A Combined B3LYP and Infrared Study
journal, November 2013
- Chiatti, Fabio; Corno, Marta; Sakhno, Yuriy
- The Journal of Physical Chemistry C, Vol. 117, Issue 48
Thermal decomposition and reconstitution of hydroxyapatite in air atmosphere
journal, October 1999
- Liao, Chun-Jen; Lin, Feng-Huei; Chen, Ko-Shao
- Biomaterials, Vol. 20, Issue 19
Facilitated transport of Cu with hydroxyapatite nanoparticles in saturated sand: Effects of solution ionic strength and composition
journal, November 2011
- Wang, Dengjun; Paradelo, Marcos; Bradford, Scott A.
- Water Research, Vol. 45, Issue 18
A high active type of hydroxyapatite for photocatalytic decomposition of dimethyl sulfide under UV irradiation
journal, January 2004
- Nishikawa, Harumitsu
- Journal of Molecular Catalysis A: Chemical, Vol. 207, Issue 2
First-principles study of vacancy formation in hydroxyapatite
journal, January 2007
- Matsunaga, Katsuyuki; Kuwabara, Akihide
- Physical Review B, Vol. 75, Issue 1
Investigation of the behaviour of a Pd/γ-Al2O3 catalyst during methane combustion reaction using in situ DRIFT spectroscopy
journal, October 2005
- Demoulin, O.; Navez, M.; Ruiz, P.
- Applied Catalysis A: General, Vol. 295, Issue 1
The Fischer–Tropsch process: 1950–2000
journal, January 2002
- Dry, Mark E.
- Catalysis Today, Vol. 71, Issue 3-4
Studies of acid catalyzed reactions XII. Alcohol decomposition over hydroxyapatite catalysts
journal, April 1973
- Kibby, C.
- Journal of Catalysis, Vol. 29, Issue 1
Microstructural Engineering of Hydroxyapatite Membranes to Enhance Proton Conductivity
journal, December 2009
- Liu, Dongxia; Savino, Keith; Yates, Matthew Z.
- Advanced Functional Materials, Vol. 19, Issue 24
The Catalytic Oxidative Coupling of Methane
journal, May 1995
- Lunsford, Jack H.
- Angewandte Chemie International Edition in English, Vol. 34, Issue 9
Selective oxidative coupling of methane catalysed over hydroxyapatite ion-exchanged with lead
journal, January 1994
- Matsumura, Yasuyuki; Moffat, John B.; Sugiyama, Shigeru
- Journal of the Chemical Society, Faraday Transactions, Vol. 90, Issue 14
Adsorption of Some Essential Amino Acids on Hydroxyapatite
journal, June 2001
- El Shafei, Gamal M. S.; Moussa, Nabawaya A.
- Journal of Colloid and Interface Science, Vol. 238, Issue 1
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Thermogravimetric and thermokinetic investigation of the dehydroxylation of a hydroxyapatite powder
journal, April 2004
- Wang, Tao; Dorner-Reisel, Annett; Müller, Eberhard
- Journal of the European Ceramic Society, Vol. 24, Issue 4
Solid-state NMR of bisphosphonates adsorbed on hydroxyapatite
journal, January 2000
- Grossmann, Gisbert; Grossmann, André; Ohms, Gisela
- Magnetic Resonance in Chemistry, Vol. 38, Issue 1
Catalytic aromatization of methane
journal, January 2014
- Spivey, James J.; Hutchings, Graham
- Chem. Soc. Rev., Vol. 43, Issue 3
DRIFTS of Probe Molecules Adsorbed on Magnesia, Zirconia, and Hydroxyapatite Catalysts
journal, April 2015
- Hill, Ian M.; Hanspal, Sabra; Young, Zachary D.
- The Journal of Physical Chemistry C, Vol. 119, Issue 17
Special points for Brillouin-zone integrations
journal, June 1976
- Monkhorst, Hendrik J.; Pack, James D.
- Physical Review B, Vol. 13, Issue 12, p. 5188-5192
Hydroxyapatite as a novel support for gold and ruthenium catalysts Behaviour in the water gas shift reaction
journal, May 2003
- Venugopal, A.
- Applied Catalysis A: General, Vol. 245, Issue 1
Formation of oxygen radicals by coordinatively unsaturated oxygen anions on hydroxyapatite
journal, October 1998
- Matsumura, Yasuyuki; Kanai, Hiroyoshi; Moffat, John B.
- Journal of Molecular Catalysis A: Chemical, Vol. 135, Issue 3
Hydroxyapatite, an exceptional catalyst for the gas-phase deoxygenation of bio-oil by aldol condensation
journal, January 2014
- Rodrigues, E. G.; Keller, T. C.; Mitchell, S.
- Green Chem., Vol. 16, Issue 12
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Comparative Estimates of Bacterial Affinities and Adsorption Sites on Hydroxyapatite Surfaces
journal, March 1978
- Clark, W. B.; Bammann, L. L.; Gibbons, R. J.
- Infection and Immunity, Vol. 19, Issue 3
Low Symmetry Polymorph of Hydroxyapatite. Theoretical Equilibrium Morphology of the Monoclinic Ca 5 (OH)(PO 4 ) 3
journal, April 2014
- Aquilano, Dino; Bruno, Marco; Rubbo, Marco
- Crystal Growth & Design, Vol. 14, Issue 6
Catalysis of a hydroxyapatite-bound Ru complex: efficient heterogeneous oxidation of primary amines to nitriles in the presence of molecular oxygen
journal, January 2001
- Mori, Kohsuke; Yamaguchi, Kazuya; Mizugaki, Tomoo
- Chemical Communications, Issue 5
Crystal Structure of Hydroxyapatite
journal, December 1964
- Kay, M. I.; Young, R. A.; Posner, A. S.
- Nature, Vol. 204, Issue 4963
Powder diffraction studies of synthetic calcium and lead apatites
journal, January 2000
- Kim, Jean Y.; Fenton, Ronald R.; Hunter, Brett A.
- Australian Journal of Chemistry, Vol. 53, Issue 8
Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts
journal, November 1997
- Iglesia, Enrique
- Applied Catalysis A: General, Vol. 161, Issue 1-2
Transport behavior of humic acid-modified nano-hydroxyapatite in saturated packed column: Effects of Cu, ionic strength, and ionic composition
journal, August 2011
- Wang, Dengjun; Chu, Lingyang; Paradelo, Marcos
- Journal of Colloid and Interface Science, Vol. 360, Issue 2
Controlled Synthesis of Hydroxyapatite-Supported Palladium Complexes as Highly Efficient Heterogeneous Catalysts
journal, September 2002
- Mori, Kohsuke; Yamaguchi, Kazuya; Hara, Takayoshi
- Journal of the American Chemical Society, Vol. 124, Issue 39
Lead-Calcium Hydroxyapatite: Cation Effects in the Oxidative Coupling of Methane
journal, January 1995
- Matsumura, Yasuyuki; Sugiyama, Shigeru; Hayashi, Hiromu
- Journal of Solid State Chemistry, Vol. 114, Issue 1
Electronic and crystallographic structure of apatites
journal, April 2003
- Calderín, L.; Stott, M. J.; Rubio, A.
- Physical Review B, Vol. 67, Issue 13
Effect of fluorine addition on the corrosion resistance of hydroxyapatite ceramics
journal, January 2004
- Chen, Yanming; Miao, Xigeng
- Ceramics International, Vol. 30, Issue 7
Fast Oxide Ion Conduction Due to Carbonate Substitution in Hydroxyapatite: Rapid Communications of the American Ceramic Society
journal, September 2010
- Tanaka, Yumi; Kikuchi, Mai; Tanaka, Kazumasa
- Journal of the American Ceramic Society, Vol. 93, Issue 11
Surface design and functions of hydroxyapatite.
journal, January 1989
- Aoki, Hideki
- Hyomen Kagaku, Vol. 10, Issue 2
Structural, textural and acid–base properties of carbonate-containing hydroxyapatites
journal, January 2014
- Silvester, Lishil; Lamonier, Jean-François; Vannier, Rose-Noëlle
- J. Mater. Chem. A, Vol. 2, Issue 29
Metal Phosphate-Supported Pt Catalysts for CO Oxidation
journal, December 2014
- Qian, Xiaoshuang; Qin, Hongmei; Meng, Tao
- Materials, Vol. 7, Issue 12
Adsorption of Cd (II) and Zn (II) from aqueous solutions using magnetic hydroxyapatite nanoparticles as adsorbents
journal, August 2010
- Feng, Yuan; Gong, Ji-Lai; Zeng, Guang-Ming
- Chemical Engineering Journal, Vol. 162, Issue 2
On the Induction Period of Methane Aromatization over Mo-Based Catalysts
journal, August 2000
- Ma, Ding; Shu, Yuying; Cheng, Mojie
- Journal of Catalysis, Vol. 194, Issue 1
Progress in the direct catalytic conversion of methane to fuels and chemicals
journal, July 2016
- Karakaya, Canan; Kee, Robert J.
- Progress in Energy and Combustion Science, Vol. 55
Formation of c-axis Aligned Polycrystal Hydroxyapatite Using High Magnetic Field with Mechanical Sample Rotation
journal, January 2005
- Akiyama, Jun; Hashimoto, Masami; Takadama, Hiroaki
- MATERIALS TRANSACTIONS, Vol. 46, Issue 2
Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen
journal, May 2014
- Guo, X.; Fang, G.; Li, G.
- Science, Vol. 344, Issue 6184
Catalytic oxidative coupling of methane over hydroxyapatite modified with lead
journal, September 1993
- Matsumura, Yasuyuki; Moffat, John B.
- Catalysis Letters, Vol. 17, Issue 3-4
Bifunctional Catalysis of Mo/HZSM-5 in the Dehydroaromatization of Methane to Benzene and Naphthalene XAFS/TG/DTA/MASS/FTIR Characterization and Supporting Effects
journal, January 1999
- Liu, Shetian; Wang, Linsheng; Ohnishi, Ryuichiro
- Journal of Catalysis, Vol. 181, Issue 2
A review on the thermal stability of calcium apatites
journal, September 2011
- Tõnsuaadu, Kaia; Gross, Kārlis Agris; Plūduma, Liene
- Journal of Thermal Analysis and Calorimetry, Vol. 110, Issue 2
Works referencing / citing this record:
Cationic Substitutions in Hydroxyapatite: Current Status of the Derived Biofunctional Effects and Their In Vitro Interrogation Methods
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- Tite, Teddy; Popa, Adrian-Claudiu; Balescu, Liliana
- Materials, Vol. 11, Issue 11
Hydroxyapatite nanowires rich in [Ca–O–P] sites for ethanol direct coupling showing high C 6–12 alcohol yield
journal, January 2019
- Wang, Qing-Nan; Zhou, Bai-Chuan; Weng, Xue-Fei
- Chemical Communications, Vol. 55, Issue 70
Cationic Substitutions in Hydroxyapatite: Current Status of the Derived Biofunctional Effects and Their In Vitro Interrogation Methods
journal, October 2018
- Tite, Teddy; Popa, Adrian-Claudiu; Balescu, Liliana
- Materials, Vol. 11, Issue 11
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