Rational Design of Nickel Hydroxide-Based Nanocrystals on Graphene for Ultrafast Energy Storage

Zhao, Bote; Zhang, Lei; Zhang, Qiaobao; Chen, Dongchang; Cheng, Yong; Deng, Xiang; Chen, Yu; Murphy, Ryan; Xiong, Xunhui; Song, Bo; Wong, Ching-Ping; Wang, Ming-Sheng; Liu, Meilin

doi:10.1002/aenm.201702247

Title: Rational Design of Nickel Hydroxide-Based Nanocrystals on Graphene for Ultrafast Energy Storage

Journal Article · 18 December 2017 · Advanced Energy Materials

DOI: https://doi.org/10.1002/aenm.201702247 · OSTI ID:1543465

^[1]; Zhang, Lei ^[1]; Zhang, Qiaobao ^[2]; Chen, Dongchang ^[1]; Cheng, Yong ^[3]; Deng, Xiang ^[1]; Chen, Yu ^[1]; Murphy, Ryan ^[1]; Xiong, Xunhui ^[4]; Song, Bo ^[1]; Wong, Ching-Ping ^[1]; Wang, Ming-Sheng ^[3];

^[1]

Georgia Inst. of Technology, Atlanta, GA (United States)
Georgia Inst. of Technology, Atlanta, GA (United States); Xiamen Univ., Fujian (China)
Xiamen Univ., Fujian (China)
Georgia Inst. of Technology, Atlanta, GA (United States); South China Univ. of Technology, Guangzhou (China)

Abstract Compact, light, and powerful energy storage devices are urgently needed for many emerging applications; however, the development of advanced power sources relies heavily on advances in materials innovation. Here, the findings in rational design, one‐pot synthesis, and characterization of a series of Ni hydroxide‐based electrode materials in alkaline media for fast energy storage are reported. Under the guidance of density functional theory calculations and experimental investigations, a composite electrode composed of Co‐/Mn‐substituted Ni hydroxides grown on reduced graphene oxide (rGO) is designed and prepared, demonstrating capacities of 665 and 427 C g ⁻¹ at current densities of 2 and 20 A g ⁻¹ , respectively. The superior performance is attributed mainly to the low deprotonation energy and the facile electron transport, as elaborated by theoretical calculations. When coupled with an electrode based on organic molecular‐modified rGO, the resulting hybrid device demonstrates an energy density of 74.7 W h kg ⁻¹ at a power density of 1.68 kW kg ⁻¹ while maintaining capacity retention of 91% after 10,000 cycles (20 A g ⁻¹ ). The findings not only provide a promising electrode material for high‐performance hybrid capacitors but also open a new avenue toward knowledge‐based design of efficient electrode materials for other energy storage applications.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC); USDOE

Grant/Contract Number:: AC02-05CH11231; DE‐AC02‐05CH11231

OSTI ID:: 1543465

Alternate ID(s):: OSTI ID: 1413796

Journal Information:: Advanced Energy Materials, Vol. 8, Issue 9; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (71)

A High Energy Density Asymmetric Supercapacitor from Nano-architectured Ni(OH)2/Carbon Nanotube Electrodes Tang, Zhe; Tang, Chun-hua; Gong, Hao Advanced Functional Materials, Vol. 22, Issue 6 https://doi.org/10.1002/adfm.201102796	journal	January 2012
Nickel oxide encapsulated nitrogen-rich carbon hollow spheres with multiporosity for high-performance pseudocapacitors having extremely robust cycle life Kim, Se Yun; Jeong, Hyung Mo; Kwon, Jun Ho Energy & Environmental Science, Vol. 8, Issue 1 https://doi.org/10.1039/C4EE02897J	journal	January 2015
Coordination Polymers Derived General Synthesis of Multishelled Mixed Metal-Oxide Particles for Hybrid Supercapacitors Guan, Bu Yuan; Kushima, Akihiro; Yu, Le Advanced Materials, Vol. 29, Issue 17 https://doi.org/10.1002/adma.201605902	journal	February 2017
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
A review of electrode materials for electrochemical supercapacitors Wang, Guoping; Zhang, Lei; Zhang, Jiujun Chemical Society Reviews, Vol. 41, Issue 2, p. 797-828 https://doi.org/10.1039/C1CS15060J	journal	January 2012
A comprehensive review of Li 4 Ti 5 O 12 -based electrodes for lithium-ion batteries: The latest advancements and future perspectives Zhao, Bote; Ran, Ran; Liu, Meilin Materials Science and Engineering: R: Reports, Vol. 98 https://doi.org/10.1016/j.mser.2015.10.001	journal	December 2015
Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides Oliva, P.; Leonardi, J.; Laurent, J. F. Journal of Power Sources, Vol. 8, Issue 2 https://doi.org/10.1016/0378-7753(82)80057-8	journal	January 1982
Advanced Asymmetric Supercapacitors Based on Ni(OH)2/Graphene and Porous Graphene Electrodes with High Energy Density Yan, Jun; Fan, Zhuangjun; Sun, Wei Advanced Functional Materials, Vol. 22, Issue 12 https://doi.org/10.1002/adfm.201102839	journal	March 2012
Amorphous Ni(OH) ₂ @ three-dimensional Ni core–shell nanostructures for high capacitance pseudocapacitors and asymmetric supercapacitors Su, Yu-Zhi; Xiao, Kang; Li, Nan J. Mater. Chem. A, Vol. 2, Issue 34 https://doi.org/10.1039/C4TA02486A	journal	January 2014
Three-dimensional ultrathin Ni(OH)2 nanosheets grown on nickel foam for high-performance supercapacitors Xiong, Xunhui; Ding, Dong; Chen, Dongchang Nano Energy, Vol. 11 https://doi.org/10.1016/j.nanoen.2014.10.029	journal	January 2015
Interwoven Three-Dimensional Architecture of Cobalt Oxide Nanobrush-Graphene@Ni _x Co _{2 x} (OH) _{6 x} for High-Performance Supercapacitors Qu, Longbing; Zhao, Yunlong; Khan, Aamir Minhas Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/nl504901p	journal	February 2015
Ultrathin Nickel-Cobalt Phosphate 2D Nanosheets for Electrochemical Energy Storage under Aqueous/Solid-State Electrolyte Li, Bing; Gu, Peng; Feng, Yongcheng Advanced Functional Materials, Vol. 27, Issue 12 https://doi.org/10.1002/adfm.201605784	journal	February 2017
Rational Design of Metal-Organic Framework Derived Hollow NiCo ₂ O ₄ Arrays for Flexible Supercapacitor and Electrocatalysis Guan, Cao; Liu, Ximeng; Ren, Weina Advanced Energy Materials, Vol. 7, Issue 12 https://doi.org/10.1002/aenm.201602391	journal	January 2017
Stabilized Octahedral Frameworks in Layered Double Hydroxides by Solid-Solution Mixing of Transition Metals Lee, Ji Hoon; Lee, Hyeon Jeong; Lim, Soo Yeon Advanced Functional Materials, Vol. 27, Issue 7 https://doi.org/10.1002/adfm.201605225	journal	December 2016
Synthesis, characterization and electrochemical properties of aluminum-substituted alpha-Ni(OH)2 hollow spheres Li, Yueming; Li, Weiyang; Chou, Shulei Journal of Alloys and Compounds, Vol. 456, Issue 1-2 https://doi.org/10.1016/j.jallcom.2007.02.073	journal	May 2008
Sulfidation of NiMn-Layered Double Hydroxides/Graphene Oxide Composites toward Supercapacitor Electrodes with Enhanced Performance Chen, Jingwei; Wang, Xu; Wang, Jiangxin Advanced Energy Materials, Vol. 6, Issue 5 https://doi.org/10.1002/aenm.201501745	journal	December 2015
To Be or Not To Be Pseudocapacitive? Brousse, Thierry; Bélanger, Daniel; Long, Jeffrey W. Journal of The Electrochemical Society, Vol. 162, Issue 5 https://doi.org/10.1149/2.0201505jes	journal	January 2015
Ternary Hybrids of Amorphous Nickel Hydroxide-Carbon Nanotube-Conducting Polymer for Supercapacitors with High Energy Density, Excellent Rate Capability, and Long Cycle Life Jiang, Wenchao; Yu, Dingshan; Zhang, Qiang Advanced Functional Materials, Vol. 25, Issue 7 https://doi.org/10.1002/adfm.201403354	journal	January 2015
Multifunctional Iron Oxide Nanoflake/Graphene Composites Derived from Mechanochemical Synthesis for Enhanced Lithium Storage and Electrocatalysis Zhao, Bote; Zheng, Yao; Ye, Fei ACS Applied Materials & Interfaces, Vol. 7, Issue 26 https://doi.org/10.1021/acsami.5b03477	journal	June 2015
Improving the performance of cobalt–nickel hydroxide-based self-supporting electrodes for supercapacitors using accumulative approaches Cheng, Yingwen; Zhang, Hongbo; Varanasi, Chakrapani V. Energy & Environmental Science, Vol. 6, Issue 11 https://doi.org/10.1039/c3ee41143e	journal	January 2013
Ni(OH) ₂ Nanoplates Grown on Graphene as Advanced Electrochemical Pseudocapacitor Materials Wang, Hailiang; Casalongue, Hernan Sanchez; Liang, Yongye Journal of the American Chemical Society, Vol. 132, Issue 21 https://doi.org/10.1021/ja102267j	journal	June 2010
Facile Synthesis of Hematite Quantum-Dot/Functionalized Graphene-Sheet Composites as Advanced Anode Materials for Asymmetric Supercapacitors Xia, Hui; Hong, Caiyun; Li, Bo Advanced Functional Materials, Vol. 25, Issue 4 https://doi.org/10.1002/adfm.201403554	journal	December 2014
Topochemical Synthesis, Anion Exchange, and Exfoliation of Co−Ni Layered Double Hydroxides: A Route to Positively Charged Co−Ni Hydroxide Nanosheets with Tunable Composition Liang, Jianbo; Ma, Renzhi; Iyi, Nobuo Chemistry of Materials, Vol. 22, Issue 2 https://doi.org/10.1021/cm902787u	journal	January 2010
A High-Energy Lithium-Ion Capacitor by Integration of a 3D Interconnected Titanium Carbide Nanoparticle Chain Anode with a Pyridine-Derived Porous Nitrogen-Doped Carbon Cathode Wang, Huanwen; Zhang, Yu; Ang, Huixiang Advanced Functional Materials, Vol. 26, Issue 18 https://doi.org/10.1002/adfm.201505240	journal	March 2016
Where Do Batteries End and Supercapacitors Begin? Simon, P.; Gogotsi, Y.; Dunn, B. Science, Vol. 343, Issue 6176 https://doi.org/10.1126/science.1249625	journal	March 2014
A fast and robust algorithm for Bader decomposition of charge density Henkelman, Graeme; Arnaldsson, Andri; Jónsson, Hannes Computational Materials Science, Vol. 36, Issue 3 https://doi.org/10.1016/j.commatsci.2005.04.010	journal	June 2006
A Novel Phase-Transformation Activation Process toward Ni-Mn-O Nanoprism Arrays for 2.4 V Ultrahigh-Voltage Aqueous Supercapacitors Zuo, Wenhua; Xie, Chaoyue; Xu, Pan Advanced Materials, Vol. 29, Issue 36 https://doi.org/10.1002/adma.201703463	journal	August 2017
Microfabricated Pseudocapacitors Using Ni(OH) ₂ Electrodes Exhibit Remarkable Volumetric Capacitance and Energy Density Kurra, Narendra; Alhebshi, Nuha A.; Alshareef, H. N. Advanced Energy Materials, Vol. 5, Issue 2 https://doi.org/10.1002/aenm.201401303	journal	September 2014
Periodic stacking of 2D charged sheets: Self-assembled superlattice of Ni–Al layered double hydroxide (LDH) and reduced graphene oxide Ge, Xiang; Gu, Changdong; Yin, Zongyou Nano Energy, Vol. 20 https://doi.org/10.1016/j.nanoen.2015.12.020	journal	February 2016
Hierarchical Ni-Co Hydroxide Petals on Mechanically Robust Graphene Petal Foam for High-Energy Asymmetric Supercapacitors Xiong, Guoping; He, Pingge; Wang, Dini Advanced Functional Materials, Vol. 26, Issue 30 https://doi.org/10.1002/adfm.201600879	journal	May 2016
Layer-by-layer β-Ni(OH)2/graphene nanohybrids for ultraflexible all-solid-state thin-film supercapacitors with high electrochemical performance Xie, Junfeng; Sun, Xu; Zhang, Ning Nano Energy, Vol. 2, Issue 1 https://doi.org/10.1016/j.nanoen.2012.07.016	journal	January 2013
NiCo ₂ S ₄ Nanosheets Grown on Nitrogen-Doped Carbon Foams as an Advanced Electrode for Supercapacitors Shen, Laifa; Wang, Jie; Xu, Guiyin Advanced Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1002/aenm.201400977	journal	October 2014
Controlled synthesis of three-phase NixSy/rGO nanoflake electrodes for hybrid supercapacitors with high energy and power density Dai, Shuge; Zhao, Bote; Qu, Chong Nano Energy, Vol. 33 https://doi.org/10.1016/j.nanoen.2017.01.056	journal	March 2017
An ultrafast nickel–iron battery from strongly coupled inorganic nanoparticle/nanocarbon hybrid materials Wang, Hailiang; Liang, Yongye; Gong, Ming Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1921	journal	January 2012
Activity origin and catalyst design principles for electrocatalytic hydrogen evolution on heteroatom-doped graphene Jiao, Yan; Zheng, Yao; Davey, Kenneth Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.130	journal	September 2016
Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution Grimaud, Alexis; Diaz-Morales, Oscar; Han, Binghong Nature Chemistry, Vol. 9, Issue 5 https://doi.org/10.1038/nchem.2695	journal	January 2017
Rechargeable nickel–3D zinc batteries: An energy-dense, safer alternative to lithium-ion Parker, Joseph F.; Chervin, Christopher N.; Pala, Irina R. Science, Vol. 356, Issue 6336 https://doi.org/10.1126/science.aak9991	journal	April 2017
Electrical properties of nickel hydroxide for alkaline cell systems Motori, Antonio; Sandrolini, Franco; Davolio, Giovanni Journal of Power Sources, Vol. 48, Issue 3 https://doi.org/10.1016/0378-7753(94)80032-4	journal	March 1994
Probing Structural Evolution and Charge Storage Mechanism of NiO ₂ H _x Electrode Materials using In Operando Resonance Raman Spectroscopy Chen, Dongchang; Xiong, Xunhui; Zhao, Bote Advanced Science, Vol. 3, Issue 6 https://doi.org/10.1002/advs.201500433	journal	February 2016
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni Biesinger, Mark C.; Payne, Brad P.; Grosvenor, Andrew P. Applied Surface Science, Vol. 257, Issue 7, p. 2717-2730 https://doi.org/10.1016/j.apsusc.2010.10.051	journal	January 2011
High-performance hybrid supercapacitors based on self-supported 3D ultrathin porous quaternary Zn-Ni-Al-Co oxide nanosheets Zhang, Qiaobao; Zhao, Bote; Wang, Jiexi Nano Energy, Vol. 28 https://doi.org/10.1016/j.nanoen.2016.08.049	journal	October 2016
Nanoporous Ni(OH) ₂ Thin Film on 3D Ultrathin-Graphite Foam for Asymmetric Supercapacitor Ji, Junyi; Zhang, Li Li; Ji, Hengxing ACS Nano, Vol. 7, Issue 7 https://doi.org/10.1021/nn4021955	journal	June 2013
A high-energy, long cycle-life hybrid supercapacitor based on graphene composite electrodes Zhao, Bote; Chen, Dongchang; Xiong, Xunhui Energy Storage Materials, Vol. 7 https://doi.org/10.1016/j.ensm.2016.11.010	journal	April 2017
Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts Subbaraman, Ram; Tripkovic, Dusan; Chang, Kee-Chul Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3313	journal	May 2012
Metallic Layered Polyester Fabric Enabled Nickel Selenide Nanostructures as Highly Conductive and Binderless Electrode with Superior Energy Storage Performance Nagaraju, Goli; Cha, Sung Min; Sekhar, S. Chandra Advanced Energy Materials, Vol. 7, Issue 4 https://doi.org/10.1002/aenm.201601362	journal	October 2016
Pseudocapacitive Charge Storage in Thick Composite MoS ₂ Nanocrystal-Based Electrodes Cook, John B.; Kim, Hyung-Seok; Lin, Terri C. Advanced Energy Materials, Vol. 7, Issue 2 https://doi.org/10.1002/aenm.201601283	journal	October 2016
Spherical α-Ni(OH)2 nanoarchitecture grown on graphene as advanced electrochemical pseudocapacitor materials Yang, Shubin; Wu, Xilin; Chen, Changlun Chemical Communications, Vol. 48, Issue 22 https://doi.org/10.1039/c2cc16565a	journal	January 2012
Raman Microspectrometry Applied to the Study of Electrode Materials for Lithium Batteries Baddour-Hadjean, Rita; Pereira-Ramos, Jean-Pierre Chemical Reviews, Vol. 110, Issue 3 https://doi.org/10.1021/cr800344k	journal	March 2010
Improved performances of β-Ni(OH)2@reduced-graphene-oxide in Ni-MH and Li-ion batteries Li, Baojun; Cao, Huaqiang; Shao, Jin Chemical Communications, Vol. 47, Issue 11 https://doi.org/10.1039/c0cc04507a	journal	January 2011
Hierarchical self-assembly of ultrathin nickel hydroxide nanoflakes for high-performance supercapacitors Jiang, Hao; Zhao, Ting; Li, Chunzhong Journal of Materials Chemistry, Vol. 21, Issue 11 https://doi.org/10.1039/c0jm03830j	journal	January 2011
Characterization of Active Material Deposited at the Nickel Hydroxide Electrode by Electrochemical Impregnation Portemer, F. Journal of The Electrochemical Society, Vol. 139, Issue 3 https://doi.org/10.1149/1.2069283	journal	January 1992
Large-scale synthesis of coaxial carbon nanotube/Ni(OH)2 composites for asymmetric supercapacitor application Salunkhe, Rahul R.; Lin, Jianjian; Malgras, Victor Nano Energy, Vol. 11 https://doi.org/10.1016/j.nanoen.2014.09.030	journal	January 2015
Dual Support System Ensuring Porous Co-Al Hydroxide Nanosheets with Ultrahigh Rate Performance and High Energy Density for Supercapacitors Wu, Xiaoliang; Jiang, Lili; Long, Conglai Advanced Functional Materials, Vol. 25, Issue 11 https://doi.org/10.1002/adfm.201404142	journal	January 2015
Formation of nickel cobalt sulfide ball-in-ball hollow spheres with enhanced electrochemical pseudocapacitive properties Shen, Laifa; Yu, Le; Wu, Hao Bin Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7694	journal	March 2015
Atomic-level energy storage mechanism of cobalt hydroxide electrode for pseudocapacitors Deng, Ting; Zhang, Wei; Arcelus, Oier Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15194	journal	May 2017
Homogeneously dispersed multimetal oxygen-evolving catalysts Zhang, B.; Zheng, X.; Voznyy, O. Science, Vol. 352, Issue 6283 https://doi.org/10.1126/science.aaf1525	journal	March 2016
Advanced Ti-Doped Fe ₂ O ₃ @PEDOT Core/Shell Anode for High-Energy Asymmetric Supercapacitors Zeng, Yinxiang; Han, Yi; Zhao, Yitong Advanced Energy Materials, Vol. 5, Issue 12 https://doi.org/10.1002/aenm.201402176	journal	April 2015
Phosphate Ion Functionalized Co ₃ O ₄ Ultrathin Nanosheets with Greatly Improved Surface Reactivity for High Performance Pseudocapacitors Zhai, Teng; Wan, Liming; Sun, Shuo Advanced Materials, Vol. 29, Issue 7 https://doi.org/10.1002/adma.201604167	journal	December 2016
A tailored double perovskite nanofiber catalyst enables ultrafast oxygen evolution Zhao, Bote; Zhang, Lei; Zhen, Dongxing Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14586	journal	February 2017
Synthesis of Nitrogen-Rich Nanotubes with Internal Compartments having Open Mesoporous Channels and Utilization to Hybrid Full-Cell Capacitors Enabling High Energy and Power Densities over Robust Cycle Life Won, Jong Ho; Jeong, Hyung Mo; Kang, Jeung Ku Advanced Energy Materials, Vol. 7, Issue 1 https://doi.org/10.1002/aenm.201601355	journal	September 2016
Nickel-Cobalt Layered Double Hydroxide Nanosheets for High-performance Supercapacitor Electrode Materials Chen, Hao; Hu, Linfeng; Chen, Min Advanced Functional Materials, Vol. 24, Issue 7 https://doi.org/10.1002/adfm.201301747	journal	September 2013
A Simple Electrochemical Route to Access Amorphous Mixed-Metal Hydroxides for Supercapacitor Electrode Materials Li, Hongbo; Gao, Yuqian; Wang, Chengxin Advanced Energy Materials, Vol. 5, Issue 6 https://doi.org/10.1002/aenm.201401767	journal	December 2014
Construction of High-Capacitance 3D CoO@Polypyrrole Nanowire Array Electrode for Aqueous Asymmetric Supercapacitor Zhou, Cheng; Zhang, Yangwei; Li, Yuanyuan Nano Letters, Vol. 13, Issue 5 https://doi.org/10.1021/nl400378j	journal	April 2013
What Nano Can Do for Energy Storage Gogotsi, Yury ACS Nano, Vol. 8, Issue 6 https://doi.org/10.1021/nn503164x	journal	May 2014
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode Nørskov, J. K.; Rossmeisl, J.; Logadottir, A. The Journal of Physical Chemistry B, Vol. 108, Issue 46 https://doi.org/10.1021/jp047349j	journal	November 2004
Three-dimensional graphene and their integrated electrodes Xia, X. H.; Chao, D. L.; Zhang, Y. Q. Nano Today, Vol. 9, Issue 6 https://doi.org/10.1016/j.nantod.2014.12.001	journal	December 2014
Towards the computational design of solid catalysts Nørskov, J.; Bligaard, T.; Rossmeisl, J. Nature Chemistry, Vol. 1, Issue 1, p. 37-46 https://doi.org/10.1038/nchem.121	journal	April 2009
Ultrafast high-capacity NiZn battery with NiAlCo-layered double hydroxide Gong, Ming; Li, Yanguang; Zhang, Hongbo Energy & Environmental Science, Vol. 7, Issue 6 https://doi.org/10.1039/c4ee00317a	journal	January 2014
Enhanced Structural Stability of Nickel–Cobalt Hydroxide via Intrinsic Pillar Effect of Metaborate for High-Power and Long-Life Supercapacitor Electrodes Chen, Yuanzhen; Pang, Wei Kong; Bai, Haihua Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b04427	journal	December 2016
Nickel Hydroxide as an Active Material for the Positive Electrode in Rechargeable Alkaline Batteries Chen, J. Journal of The Electrochemical Society, Vol. 146, Issue 10 https://doi.org/10.1149/1.1392522	journal	January 1999
Synthesis and electrochemical characterization of mesoporous CoxNi1−x layered double hydroxides as electrode materials for supercapacitors Hu, Zhong-Ai; Xie, Yu-Long; Wang, Yao-Xian Electrochimica Acta, Vol. 54, Issue 10 https://doi.org/10.1016/j.electacta.2008.11.035	journal	April 2009

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Fabrication of g-C₃N₄ Nanomesh-Anchored Amorphous NiCoP₂O₇: Tuned Cycling Life and the Dynamic Behavior of a Hybrid Capacitor Matheswaran, Priyadharshini; Karuppiah, Pandi; Chen, Shen-Ming ACS Omega, Vol. 3, Issue 12 https://doi.org/10.1021/acsomega.8b02635	journal	December 2018
Synthesis and Electrochemical Performance of Molybdenum Disulfide-Reduced Graphene Oxide-Polyaniline Ternary Composites for Supercapacitors Bai, Li-Zhong; Wang, Yan-Hui; Cheng, Shuai-Shuai Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00218	journal	June 2018
Fabrication of WO3·2H2O/BC Hybrids by the Radiation Method for Enhanced Performance Supercapacitors Yang, Fan; Jia, Jinzhi; Mi, Rui Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00290	journal	August 2018
Tuning the Catalytic Activity of Ir@Pt Nanoparticles Through Controlling Ir Core Size on Cathode Performance for PEM Fuel Cell Application Zheng, Hao-Bo; An, Lu; Zheng, Yuying Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00299	journal	July 2018
Urchin-Like Ni2/3Co1/3(CO3)1/2(OH)·0.11H2O for High-Performance Supercapacitors Jiang, Zi-Min; Xu, Ting-Ting; Yan, Cong-Cong Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00431	journal	September 2018
Plane Double-Layer Structure of AC@S Cathode Improves Electrochemical Performance for Lithium-Sulfur Battery Tao, Zengren; Yang, Zhiyun; Guo, Yafang Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00447	journal	October 2018
Nitrogen-Doped Multi-Scale Porous Carbon for High Voltage Aqueous Supercapacitors Liu, Xichuan; Mi, Rui; Yuan, Lei Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00475	journal	October 2018
Fabrication of Cobalt-Nickel-Zinc Ternary Oxide Nanosheet and Applications for Supercapacitor Electrode Wu, Chun; Chen, Lei; Lou, Xuechun Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00597	journal	November 2018
Facile Synthesis of Manganese Cobalt Oxide/Nickel Cobalt Oxide Composites for High-Performance Supercapacitors Huo, Wang Chen; Liu, Xiao Li; Yuan, Yun Song Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00661	journal	January 2019
Research Progress of NiMn Layered Double Hydroxides for Supercapacitors: A Review Yan, Ai-Lan; Wang, Xin-Chang; Cheng, Ji-Peng Nanomaterials, Vol. 8, Issue 10 https://doi.org/10.3390/nano8100747	journal	September 2018