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Title: 31P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues

Abstract

Complexation of nitric acid by ligands containing conjugated aromatic phosphine oxide functionalities affords activated radioprotection through quenching n-dodecane excited states originating from gamma radiolysis.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [1]
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  1. Idaho National Lab. (INL), Idaho Falls, ID (United States)
  2. Western Michigan Univ., Kalamazoo MI (United States)
  3. Valparaiso Univ., IN (United States)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States)
  5. California State Univ. (CalState), Long Beach, CA (United States)
Publication Date:
Research Org.:
Idaho National Lab. (INL), Idaho Falls, ID (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1566070
Alternate Identifier(s):
OSTI ID: 1543412; OSTI ID: 1544591
Report Number(s):
INL/JOU-19-55534-Rev000; BNL-211907-2019-JAAM
Journal ID: ISSN 1477-9226; ICHBD9; TRN: US2000964
Grant/Contract Number:  
AC07-05ID14517; SC0012704; FC02-04ER15533; NE0008406
Resource Type:
Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 48; Journal Issue: 30; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; CMPO; Gamma Radiation; Activated Radioprotection

Citation Formats

Horne, Gregory P., Kiddle, James J., Zarzana, Christopher A., Rae, Cathy, Peller, Julie R., Cook, Andrew R., Mezyk, Stephen P., and Mincher, Bruce J. 31P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues. United States: N. p., 2019. Web. doi:10.1039/C9DT01950B.
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Horne, Gregory P., Kiddle, James J., Zarzana, Christopher A., Rae, Cathy, Peller, Julie R., Cook, Andrew R., Mezyk, Stephen P., & Mincher, Bruce J. 31P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues. United States. https://doi.org/10.1039/C9DT01950B
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Horne, Gregory P., Kiddle, James J., Zarzana, Christopher A., Rae, Cathy, Peller, Julie R., Cook, Andrew R., Mezyk, Stephen P., and Mincher, Bruce J. Mon . "31P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues". United States. https://doi.org/10.1039/C9DT01950B. https://www.osti.gov/servlets/purl/1566070.
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@article{osti_1566070,
title = {31P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues},
author = {Horne, Gregory P. and Kiddle, James J. and Zarzana, Christopher A. and Rae, Cathy and Peller, Julie R. and Cook, Andrew R. and Mezyk, Stephen P. and Mincher, Bruce J.},
abstractNote = {Complexation of nitric acid by ligands containing conjugated aromatic phosphine oxide functionalities affords activated radioprotection through quenching n-dodecane excited states originating from gamma radiolysis.},
doi = {10.1039/C9DT01950B},
journal = {Dalton Transactions},
number = 30,
volume = 48,
place = {United States},
year = {Mon Jul 08 00:00:00 EDT 2019},
month = {Mon Jul 08 00:00:00 EDT 2019}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C9DT01950B
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Cited by: 6 works
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Figures / Tables:

Figure 1 Figure 1: Chemical structures of octylphenyl-N,Ndiisobutylcarbamoylmethyl phosphine oxide (CMPO, A), dioctylphenylphospine oxide (DOPPO, B), trioctylphosphine oxide (TOPO, C), and tetraphenylmethylenediphosphine dioxide (D).
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