Fabrication of a Pillared ZSM-5 Framework for Shape Selectivity of Ethane Dehydroaromatization
Abstract
Ethane, the second major component of shale gas, is a prospective raw feedstock to valuable chemicals and fuels. Innovative pillared ZSM-5 with various lamellar thicknesses and Si/Al ratios were successfully synthesized with the dual-template method; 0.67 wt % Mo were dispersed over these lamellar ZSM-5, and evaluated for ethane dehydroaromatization. The influence of zeolite morphology and the texture property for the reduction/acidity nature of MoOx species were investigated by X-ray diffraction, scanning electron microscopy, N2-sorption, H2-temperature programmed reduction/oxidation, and NH3-temperature-programmed desorption. The high concentration of acidic sites not only increases ethane conversion and aromatic selectivity, but intensely induces surface coking. Therefore, a moderate Si/Al ratio is utilized to balance catalytic reactivity and stability. Thicker zeolite layers with a long diffusion path exhibited fair ethane conversion, but high aromatization yield. It is of significant importance that the lamellar Mo/MFI catalyst, with Si/Al = 50 and 210 nm layer thickness, demonstrated excellent regenerability during a multicycle reaction/oxidation operation, which could be a promising system for industrial optimization and process deployment.
- Authors:
-
[4];
[4];
[4];
- Guangdong Univ of Technology, Guangzhou (China); West Virginia Univ., Morgantown, WV (United States)
- West Virginia Univ., Morgantown, WV (United States)
- Guangdong Univ of Technology, Guangzhou (China)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1543195
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Industrial and Engineering Chemistry Research
- Additional Journal Information:
- Journal Volume: 58; Journal Issue: 17; Journal ID: ISSN 0888-5885
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Ye, Jiahui, Bai, Lei, Liu, Baoyu, Tian, Hanjing, Hu, Jianli, Polo Garzon, Felipe, Mayes, Richard, Wu, Zili, and Fang, Yanxiong. Fabrication of a Pillared ZSM-5 Framework for Shape Selectivity of Ethane Dehydroaromatization. United States: N. p., 2019.
Web. doi:10.1021/acs.iecr.8b04965.
Ye, Jiahui, Bai, Lei, Liu, Baoyu, Tian, Hanjing, Hu, Jianli, Polo Garzon, Felipe, Mayes, Richard, Wu, Zili, & Fang, Yanxiong. Fabrication of a Pillared ZSM-5 Framework for Shape Selectivity of Ethane Dehydroaromatization. United States. https://doi.org/10.1021/acs.iecr.8b04965
Ye, Jiahui, Bai, Lei, Liu, Baoyu, Tian, Hanjing, Hu, Jianli, Polo Garzon, Felipe, Mayes, Richard, Wu, Zili, and Fang, Yanxiong. Fri .
"Fabrication of a Pillared ZSM-5 Framework for Shape Selectivity of Ethane Dehydroaromatization". United States. https://doi.org/10.1021/acs.iecr.8b04965. https://www.osti.gov/servlets/purl/1543195.
@article{osti_1543195,
title = {Fabrication of a Pillared ZSM-5 Framework for Shape Selectivity of Ethane Dehydroaromatization},
author = {Ye, Jiahui and Bai, Lei and Liu, Baoyu and Tian, Hanjing and Hu, Jianli and Polo Garzon, Felipe and Mayes, Richard and Wu, Zili and Fang, Yanxiong},
abstractNote = {Ethane, the second major component of shale gas, is a prospective raw feedstock to valuable chemicals and fuels. Innovative pillared ZSM-5 with various lamellar thicknesses and Si/Al ratios were successfully synthesized with the dual-template method; 0.67 wt % Mo were dispersed over these lamellar ZSM-5, and evaluated for ethane dehydroaromatization. The influence of zeolite morphology and the texture property for the reduction/acidity nature of MoOx species were investigated by X-ray diffraction, scanning electron microscopy, N2-sorption, H2-temperature programmed reduction/oxidation, and NH3-temperature-programmed desorption. The high concentration of acidic sites not only increases ethane conversion and aromatic selectivity, but intensely induces surface coking. Therefore, a moderate Si/Al ratio is utilized to balance catalytic reactivity and stability. Thicker zeolite layers with a long diffusion path exhibited fair ethane conversion, but high aromatization yield. It is of significant importance that the lamellar Mo/MFI catalyst, with Si/Al = 50 and 210 nm layer thickness, demonstrated excellent regenerability during a multicycle reaction/oxidation operation, which could be a promising system for industrial optimization and process deployment.},
doi = {10.1021/acs.iecr.8b04965},
journal = {Industrial and Engineering Chemistry Research},
number = 17,
volume = 58,
place = {United States},
year = {Fri Apr 05 00:00:00 EDT 2019},
month = {Fri Apr 05 00:00:00 EDT 2019}
}
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Works referencing / citing this record:
Effect of Surface Structure and Adsorption Activity on Implanting of b-Oriented ZSM-5 Zeolite Film on Modified α-Quartz Substrate
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