Ambient synthesis of nanomaterials by in situ heterogeneous metal/ligand reactions

Chang, Boyce S.; Thomas, Brijith; Chen, Jiahao; Tevis, Ian D.; Karanja, Paul; Çınar, Simge; Venkatesh, Amrit; Rossini, Aaron J.; Thuo, Martin M.

doi:10.1039/C9NR05448K

Title: Ambient synthesis of nanomaterials by in situ heterogeneous metal/ligand reactions

Abstract

Coordination polymers are ideal synthons in creating high aspect ratio nanostructures, however, conventional synthetic methods are often restricted to batch-wise and costly processes. Herein, we demonstrate a non-traditional, frugal approach to synthesize 1D coordination polymers by in situ etching of zerovalent metal particle precursors. This procedure is denoted as the heterogeneous metal/ligand reaction and was demonstrated on Group 13 metals as a proof of concept. Simple carboxylic acids supply the etchant protons and ligands for metal ions (conjugate base) in a 1:1 ratio. This scalable reaction produces a 1D polymer that assembles into high-aspect ratio ‘nanobeams’. We demonstrate control over crystal structure and morphology by tuning the: (i) metal center, (ii) stoichiometry and (iii) structure of the ligands. This work presents a general scalable method for continuous, heat free and water-based coordination polymer synthesis.

Authors:

Chang, Boyce S. ^[1]; Thomas, Brijith ^[2];

^[3]; Tevis, Ian D. ^[3]; Karanja, Paul ^[3]; Çınar, Simge ^[3];

^[2];

^[3]

Department of Materials Science and Engineering, Iowa State University, Ames, USA, US DOE Ames Laboratory
US DOE Ames Laboratory, Ames, USA, Department of Chemistry, Iowa State University
Department of Materials Science and Engineering, Iowa State University, Ames, USA

Publication Date:: 2019-07-25

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

OSTI Identifier:: 1543023

Alternate Identifier(s):: OSTI ID: 1556100

Report Number(s):: IS-J-9992
Journal ID: ISSN 2040-3364; NANOHL

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Published Article

Journal Name:: Nanoscale

Additional Journal Information:: Journal Name: Nanoscale Journal Volume: 11 Journal Issue: 29; Journal ID: ISSN 2040-3364

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats


                    Chang, Boyce S., Thomas, Brijith, Chen, Jiahao, Tevis, Ian D., Karanja, Paul, Çınar, Simge, Venkatesh, Amrit, Rossini, Aaron J., and Thuo, Martin M.. Ambient synthesis of nanomaterials by in situ heterogeneous metal/ligand reactions.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9NR05448K.

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                    Chang, Boyce S., Thomas, Brijith, Chen, Jiahao, Tevis, Ian D., Karanja, Paul, Çınar, Simge, Venkatesh, Amrit, Rossini, Aaron J., & Thuo, Martin M.. Ambient synthesis of nanomaterials by in situ heterogeneous metal/ligand reactions.  United Kingdom.  https://doi.org/10.1039/C9NR05448K

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                    Chang, Boyce S., Thomas, Brijith, Chen, Jiahao, Tevis, Ian D., Karanja, Paul, Çınar, Simge, Venkatesh, Amrit, Rossini, Aaron J., and Thuo, Martin M.. Thu .  
"Ambient synthesis of nanomaterials by in situ heterogeneous metal/ligand reactions".  United Kingdom.  https://doi.org/10.1039/C9NR05448K.

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@article{osti_1543023,

  title        = {Ambient synthesis of nanomaterials by in situ heterogeneous metal/ligand reactions},

  author       = {Chang, Boyce S. and Thomas, Brijith and Chen, Jiahao and Tevis, Ian D. and Karanja, Paul and Çınar, Simge and Venkatesh, Amrit and Rossini, Aaron J. and Thuo, Martin M.},

  abstractNote = {Coordination polymers are ideal synthons in creating high aspect ratio nanostructures, however, conventional synthetic methods are often restricted to batch-wise and costly processes. Herein, we demonstrate a non-traditional, frugal approach to synthesize 1D coordination polymers by in situ etching of zerovalent metal particle precursors. This procedure is denoted as the heterogeneous metal/ligand reaction and was demonstrated on Group 13 metals as a proof of concept. Simple carboxylic acids supply the etchant protons and ligands for metal ions (conjugate base) in a 1:1 ratio. This scalable reaction produces a 1D polymer that assembles into high-aspect ratio ‘nanobeams’. We demonstrate control over crystal structure and morphology by tuning the: (i) metal center, (ii) stoichiometry and (iii) structure of the ligands. This work presents a general scalable method for continuous, heat free and water-based coordination polymer synthesis.},

  doi          = {10.1039/C9NR05448K},

  journal      = {Nanoscale},

  number       = 29,

  volume       = 11,

  place        = {United Kingdom},

  year         = {2019},

  month        = {7}

}

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Title: Ambient synthesis of nanomaterials by in situ heterogeneous metal/ligand reactions

Abstract

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