This content will become publicly available on June 12, 2020
[Am(C 5Me 4H) 3], an organometallic americium complex
Abstract
Organometallic synthetic chemistry of transplutonium elements is an area that has been stagnant for decades. Here, we observe the small-scale synthesis, isolated yield, single-crystal X-ray structure, 1H NMR, solution/solid-state UV-vis-nIR spectroscopy, and Density Functional Theory/ab initio Wave Functional Theory calculations on an Am3+ organometallic complex,[Am(C 5Me 4H) 3]. This constitutes the first quantitative data on Am–C bonding in a molecular species.
- Authors:
-
[1];
[1];
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Florida State Univ., Tallahassee, FL (United States)
- Univ. of Iowa, Iowa City, IA (United States)
- Philipps-Universität Marburg (Germany)
- Univ. of California, Irvine, CA (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1542857
- Alternate Identifier(s):
- OSTI ID: 1545167
- Report Number(s):
- LA-UR-19-25159
Journal ID: ISSN 1433-7851
- Grant/Contract Number:
- 89233218CNA000001
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 58; Journal Issue: 34; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Goodwin, Conrad, Su, Jing, Albrecht-Schmitt, Thomas, Blake, Anastasia, Batista, Enrique, Daly, Scott, Dehnen, Stefanie, Evans, William, Gaunt, Andrew, Kozimor, Stosh, Lichtenberger, Niels, Scott, Brian, and Yang, Ping. [Am(C5Me4H)3], an organometallic americium complex. United States: N. p., 2019.
Web. doi:10.1002/anie.201905225.
Goodwin, Conrad, Su, Jing, Albrecht-Schmitt, Thomas, Blake, Anastasia, Batista, Enrique, Daly, Scott, Dehnen, Stefanie, Evans, William, Gaunt, Andrew, Kozimor, Stosh, Lichtenberger, Niels, Scott, Brian, & Yang, Ping. [Am(C5Me4H)3], an organometallic americium complex. United States. doi:10.1002/anie.201905225.
Goodwin, Conrad, Su, Jing, Albrecht-Schmitt, Thomas, Blake, Anastasia, Batista, Enrique, Daly, Scott, Dehnen, Stefanie, Evans, William, Gaunt, Andrew, Kozimor, Stosh, Lichtenberger, Niels, Scott, Brian, and Yang, Ping. Wed .
"[Am(C5Me4H)3], an organometallic americium complex". United States. doi:10.1002/anie.201905225.
@article{osti_1542857,
title = {[Am(C5Me4H)3], an organometallic americium complex},
author = {Goodwin, Conrad and Su, Jing and Albrecht-Schmitt, Thomas and Blake, Anastasia and Batista, Enrique and Daly, Scott and Dehnen, Stefanie and Evans, William and Gaunt, Andrew and Kozimor, Stosh and Lichtenberger, Niels and Scott, Brian and Yang, Ping},
abstractNote = {Organometallic synthetic chemistry of transplutonium elements is an area that has been stagnant for decades. Here, we observe the small-scale synthesis, isolated yield, single-crystal X-ray structure, 1H NMR, solution/solid-state UV-vis-nIR spectroscopy, and Density Functional Theory/ab initio Wave Functional Theory calculations on an Am3+ organometallic complex,[Am(C5Me4H)3]. This constitutes the first quantitative data on Am–C bonding in a molecular species.},
doi = {10.1002/anie.201905225},
journal = {Angewandte Chemie (International Edition)},
number = 34,
volume = 58,
place = {United States},
year = {2019},
month = {6}
}
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Works referencing / citing this record:
Synthesis and Utility of Neptunium(III) Hydrocarbyl Complex
journal, September 2019
- Myers, Alexander J.; Tarlton, Michael L.; Kelley, Steven P.
- Angewandte Chemie International Edition, Vol. 58, Issue 42
[An(H2O)9](CF3SO3)3 (An=U-Cm, Cf): Exploring Their Stability, Structural Chemistry, and Magnetic Behavior by Experiment and Theory
journal, August 2010
- Apostolidis, Christos; Schimmelpfennig, Bernd; Magnani, Nicola
- Angewandte Chemie, Vol. 122, Issue 36
Die Renaissance der nichtwässrigen Uranchemie
journal, June 2015
- Liddle, Stephen T.
- Angewandte Chemie, Vol. 127, Issue 30
Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium
journal, September 2016
- Cross, Justin N.; Macor, Joseph A.; Bertke, Jeffery A.
- Angewandte Chemie, Vol. 128, Issue 41
A Structurally Characterized Organometallic Plutonium(IV) Complex
journal, March 2017
- Apostolidis, Christos; Walter, Olaf; Vogt, Jochen
- Angewandte Chemie, Vol. 129, Issue 18
Tri(cyclopentadienyl)americium(III)
journal, January 1966
- Baumgärtner, F.; Fischer, E. O.; Kanellakopulos, B.
- Angewandte Chemie International Edition in English, Vol. 5, Issue 1
[An(H2O)9](CF3SO3)3 (An=U-Cm, Cf): Exploring Their Stability, Structural Chemistry, and Magnetic Behavior by Experiment and Theory
journal, June 2010
- Apostolidis, Christos; Schimmelpfennig, Bernd; Magnani, Nicola
- Angewandte Chemie International Edition, Vol. 49, Issue 36
The Renaissance of Non-Aqueous Uranium Chemistry
journal, June 2015
- Liddle, Stephen T.
- Angewandte Chemie International Edition, Vol. 54, Issue 30
Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium
journal, September 2016
- Cross, Justin N.; Macor, Joseph A.; Bertke, Jeffery A.
- Angewandte Chemie International Edition, Vol. 55, Issue 41
A Structurally Characterized Organometallic Plutonium(IV) Complex
journal, March 2017
- Apostolidis, Christos; Walter, Olaf; Vogt, Jochen
- Angewandte Chemie International Edition, Vol. 56, Issue 18
Solid-State Structure of Tris-Cyclopentadienide Uranium(III) and Plutonium(III)
journal, December 2017
- Apostolidis, Christos; Dutkiewicz, Michał S.; Kovács, Attila
- Chemistry - A European Journal, Vol. 24, Issue 12
Absorption spectrum of KAm(C8H8)2 in the solution
journal, January 1977
- Karraker, D. G.
- Journal of Inorganic and Nuclear Chemistry, Vol. 39, Issue 1
The bonding in tris(η5-cyclopentadienyl) actinide complexes IV: Electronic structural effects in AnCl3 and (η5-C5H5)3An (An ≡ Th — Cf) complexes
journal, April 1989
- Bursten, Bruce E.; Rhodes, Larry F.; Strittmatter, Richard J.
- Journal of the Less Common Metals, Vol. 149
The magnetic behavior of trivalent americium compounds
journal, February 1986
- Soderholm, L.; Edelstein, N.; Moriss, L. R.
- Journal of Magnetism and Magnetic Materials, Vol. 54-57
Bonding, energetic, electronic delocalization and optical properties of MCp3 complexes, where M=Sc, Y, La, Ac, Lu, Ce, Yb and Th
journal, December 2012
- Ferraro, Franklin; Arratia-Pérez, Ramiro
- Chemical Physics Letters, Vol. 554
Organometallic Neptunium Chemistry
journal, August 2017
- Arnold, Polly L.; Dutkiewicz, Michał S.; Walter, Olaf
- Chemical Reviews, Vol. 117, Issue 17
Small-Scale Metal-Based Syntheses of Lanthanide Iodide, Amide, and Cyclopentadienyl Complexes as Analogues for Transuranic Reactions
journal, September 2017
- Windorff, Cory J.; Dumas, Megan T.; Ziller, Joseph W.
- Inorganic Chemistry, Vol. 56, Issue 19
Tutorial on the Role of Cyclopentadienyl Ligands in the Discovery of Molecular Complexes of the Rare-Earth and Actinide Metals in New Oxidation States
journal, September 2016
- Evans, William J.
- Organometallics, Vol. 35, Issue 18
Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C 5 Me 4 H) 3 Ln] Complexes
journal, October 2018
- Jenkins, Tener F.; Woen, David H.; Mohanam, Luke N.
- Organometallics, Vol. 37, Issue 21
Conversion of Americia to Anhydrous Trivalent Americium Halides
journal, January 2019
- Galley, Shane S.; Sperling, Joseph M.; Windorff, Cory J.
- Organometallics, Vol. 38, Issue 3
Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes
journal, October 2012
- Jones, Matthew B.; Gaunt, Andrew J.
- Chemical Reviews, Vol. 113, Issue 2
Methyl Displacements from Cyclopentadienyl Ring Planes in Sterically Crowded (C 5 Me 5 ) 3 M Complexes
journal, October 2005
- Evans, William J.; Kozimor, Stosh A.; Ziller, Joseph W.
- Inorganic Chemistry, Vol. 44, Issue 22
Synthesis, Structure, and 15 N NMR Studies of Paramagnetic Lanthanide Complexes Obtained by Reduction of Dinitrogen
journal, December 2006
- Evans, William J.; Rego, Daniel B.; Ziller, Joseph W.
- Inorganic Chemistry, Vol. 45, Issue 26
Paramagnetism of Aqueous Actinide Cations. Part I: Perchloric Acid Media
journal, February 2014
- Wall, Thomas F.; Jan, Steve; Autillo, Matthieu
- Inorganic Chemistry, Vol. 53, Issue 5
Actinide Gas-Phase Chemistry: Reactions of An + and AnO + [An = Th, U, Np, Pu, Am] with Nitriles and Butylamine
journal, January 1999
- Gibson, John K.
- Inorganic Chemistry, Vol. 38, Issue 1
Bonding in tris(.eta.5-cyclopentadienyl) actinide complexes. 5. A comparison of the bonding in neptunium, plutonium, and transplutonium compounds with that in lanthanide compounds and a transition-metal analog
journal, January 1991
- Strittmatter, Richard J.; Bursten, Bruce E.
- Journal of the American Chemical Society, Vol. 113, Issue 2
Structural, Spectroscopic, and Theoretical Comparison of Traditional vs Recently Discovered Ln 2+ Ions in the [K(2.2.2-cryptand)][(C 5 H 4 SiMe 3 ) 3 Ln] Complexes: The Variable Nature of Dy 2+ and Nd 2+
journal, December 2014
- Fieser, Megan E.; MacDonald, Matthew R.; Krull, Brandon T.
- Journal of the American Chemical Society, Vol. 137, Issue 1
Gas-Phase Transuranium Organometallic Chemistry: Reactions of Np + , Pu + , NpO + , and PuO + with Alkenes
journal, March 1998
- Gibson, John K.
- Journal of the American Chemical Society, Vol. 120, Issue 11
Identification of the Formal +2 Oxidation State of Plutonium: Synthesis and Characterization of {Pu II [C 5 H 3 (SiMe 3 ) 2 ] 3 } −
journal, March 2017
- Windorff, Cory J.; Chen, Guo P.; Cross, Justin N.
- Journal of the American Chemical Society, Vol. 139, Issue 11
Covalency in Americium(III) Hexachloride
journal, June 2017
- Cross, Justin N.; Su, Jing; Batista, Enrique R.
- Journal of the American Chemical Society, Vol. 139, Issue 25
Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {Np II [C 5 H 3 (SiMe 3 ) 2 ] 3 } 1–
journal, May 2018
- Su, Jing; Windorff, Cory J.; Batista, Enrique R.
- Journal of the American Chemical Society, Vol. 140, Issue 24
Americium Organometallic Ions Produced by Laser Ablation of AmO 2 in Polyimide
journal, June 1998
- Gibson, John K.
- The Journal of Physical Chemistry A, Vol. 102, Issue 24
Gas-Phase Reactions of Americium Ion, Am + , with Alkenes
journal, June 1998
- Gibson, John K.
- Organometallics, Vol. 17, Issue 12
Evidence for covalence in a N-donor complex of americium(iii)
journal, January 2013
- Adam, Christian; Kaden, Peter; Beele, Björn B.
- Dalton Transactions, Vol. 42, Issue 39
Absorption Spectrum of Americium Tricyclopentadienide
journal, July 1969
- Pappalardo, R.; Carnall, W. T.; Fields, P. R.
- The Journal of Chemical Physics, Vol. 51, Issue 2