[Am(C5Me4H)3], an organometallic americium complex
Abstract
Organometallic synthetic chemistry of transplutonium elements is an area that has been stagnant for decades. Here, we observe the small-scale synthesis, isolated yield, single-crystal X-ray structure, 1H NMR, solution/solid-state UV-vis-nIR spectroscopy, and Density Functional Theory/ab initio Wave Functional Theory calculations on an Am3+ organometallic complex,[Am(C5Me4H)3]. This constitutes the first quantitative data on Am–C bonding in a molecular species.
- Authors:
-
[1];
[1];
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Florida State Univ., Tallahassee, FL (United States)
- Univ. of Iowa, Iowa City, IA (United States)
- Philipps-Universität Marburg (Germany)
- Univ. of California, Irvine, CA (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Actinide Science & Technology (CAST); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1542857
- Alternate Identifier(s):
- OSTI ID: 1545167
- Report Number(s):
- LA-UR-19-25159
Journal ID: ISSN 1433-7851
- Grant/Contract Number:
- 89233218CNA000001
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 58; Journal Issue: 34; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Goodwin, Conrad, Su, Jing, Albrecht-Schmitt, Thomas, Blake, Anastasia, Batista, Enrique, Daly, Scott, Dehnen, Stefanie, Evans, William, Gaunt, Andrew, Kozimor, Stosh, Lichtenberger, Niels, Scott, Brian, and Yang, Ping. [Am(C5Me4H)3], an organometallic americium complex. United States: N. p., 2019.
Web. doi:10.1002/anie.201905225.
Goodwin, Conrad, Su, Jing, Albrecht-Schmitt, Thomas, Blake, Anastasia, Batista, Enrique, Daly, Scott, Dehnen, Stefanie, Evans, William, Gaunt, Andrew, Kozimor, Stosh, Lichtenberger, Niels, Scott, Brian, & Yang, Ping. [Am(C5Me4H)3], an organometallic americium complex. United States. https://doi.org/10.1002/anie.201905225
Goodwin, Conrad, Su, Jing, Albrecht-Schmitt, Thomas, Blake, Anastasia, Batista, Enrique, Daly, Scott, Dehnen, Stefanie, Evans, William, Gaunt, Andrew, Kozimor, Stosh, Lichtenberger, Niels, Scott, Brian, and Yang, Ping. Wed .
"[Am(C5Me4H)3], an organometallic americium complex". United States. https://doi.org/10.1002/anie.201905225. https://www.osti.gov/servlets/purl/1542857.
@article{osti_1542857,
title = {[Am(C5Me4H)3], an organometallic americium complex},
author = {Goodwin, Conrad and Su, Jing and Albrecht-Schmitt, Thomas and Blake, Anastasia and Batista, Enrique and Daly, Scott and Dehnen, Stefanie and Evans, William and Gaunt, Andrew and Kozimor, Stosh and Lichtenberger, Niels and Scott, Brian and Yang, Ping},
abstractNote = {Organometallic synthetic chemistry of transplutonium elements is an area that has been stagnant for decades. Here, we observe the small-scale synthesis, isolated yield, single-crystal X-ray structure, 1H NMR, solution/solid-state UV-vis-nIR spectroscopy, and Density Functional Theory/ab initio Wave Functional Theory calculations on an Am3+ organometallic complex,[Am(C5Me4H)3]. This constitutes the first quantitative data on Am–C bonding in a molecular species.},
doi = {10.1002/anie.201905225},
journal = {Angewandte Chemie (International Edition)},
number = 34,
volume = 58,
place = {United States},
year = {2019},
month = {6}
}
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