Interrogating the Surface Intermediates and Water Oxidation Products of Boron‐Doped Diamond Electrodes with Scanning Electrochemical Microscopy

Counihan, Michael J.; Setwipatanachai, Worapol; Rodríguez‐López, Joaquín

doi:10.1002/celc.201900659

Title: Interrogating the Surface Intermediates and Water Oxidation Products of Boron‐Doped Diamond Electrodes with Scanning Electrochemical Microscopy

Authors:

Counihan, Michael J. ^[1]; Setwipatanachai, Worapol ^[2]; Rodríguez‐López, Joaquín ^[3]

Department of ChemistryUniversity of Illinois at Urbana-Champaign 600 South Mathews Avenue, Urbana Illinois 61801 Untied States, Joint Center for Energy Storage Research (JCESR)
Department of ChemistryUniversity of Illinois at Urbana-Champaign 600 South Mathews Avenue, Urbana Illinois 61801 Untied States
Department of ChemistryUniversity of Illinois at Urbana-Champaign 600 South Mathews Avenue, Urbana Illinois 61801 Untied States, Joint Center for Energy Storage Research (JCESR), Beckman Institute for Advanced Science and Technology

Publication Date:: 2019-07-10

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1542478

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: ChemElectroChem

Additional Journal Information:: Journal Name: ChemElectroChem Journal Volume: 6 Journal Issue: 13; Journal ID: ISSN 2196-0216

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Counihan, Michael J., Setwipatanachai, Worapol, and Rodríguez‐López, Joaquín. Interrogating the Surface Intermediates and Water Oxidation Products of Boron‐Doped Diamond Electrodes with Scanning Electrochemical Microscopy.  Germany: N. p., 2019. 
        Web.  doi:10.1002/celc.201900659.

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                    Counihan, Michael J., Setwipatanachai, Worapol, & Rodríguez‐López, Joaquín. Interrogating the Surface Intermediates and Water Oxidation Products of Boron‐Doped Diamond Electrodes with Scanning Electrochemical Microscopy.  Germany.  doi:https://doi.org/10.1002/celc.201900659

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                    Counihan, Michael J., Setwipatanachai, Worapol, and Rodríguez‐López, Joaquín. Wed .  
        "Interrogating the Surface Intermediates and Water Oxidation Products of Boron‐Doped Diamond Electrodes with Scanning Electrochemical Microscopy".  Germany.  doi:https://doi.org/10.1002/celc.201900659.

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@article{osti_1542478,

  title        = {Interrogating the Surface Intermediates and Water Oxidation Products of Boron‐Doped Diamond Electrodes with Scanning Electrochemical Microscopy},

  author       = {Counihan, Michael J. and Setwipatanachai, Worapol and Rodríguez‐López, Joaquín},

  abstractNote = {},

  doi          = {10.1002/celc.201900659},

  journal      = {ChemElectroChem},

  number       = 13,

  volume       = 6,

  place        = {Germany},

  year         = {2019},

  month        = {7}

}

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DOI: https://doi.org/10.1002/celc.201900659

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Title: Interrogating the Surface Intermediates and Water Oxidation Products of Boron‐Doped Diamond Electrodes with Scanning Electrochemical Microscopy

Citation Formats

Environmental Applications of Boron‐Doped Diamond Electrodes: 2. Soil Remediation and Sensing Applications journal, March 2019

Environmental Applications of Boron‐Doped Diamond Electrodes: 1. Applications in Water and Wastewater Treatment journal, March 2019

Detection and imaging of reactive oxygen species associated with the electrochemical oxygen evolution by hydrodynamic scanning electrochemical microscopy journal, August 2018

A practical guide to using boron doped diamond in electrochemical research journal, January 2015

Surface carbonyl groups on oxidized diamond electrodes journal, September 2000

Interrogation of Surfaces for the Quantification of Adsorbed Species on Electrodes: Oxygen on Gold and Platinum in Neutral Media † journal, December 2008

Nature, Mechanisms and Reactivity of Electrogenerated Reactive Species at Thin‐Film Boron‐Doped Diamond (BDD) Electrodes During Electrochemical Wastewater Treatment journal, March 2019

Electrochemical oxidation of organic pollutants for wastewater treatment journal, October 2018

Surface Interrogation Scanning Electrochemical Microscopy for a Photoelectrochemical Reaction: Water Oxidation on a Hematite Surface journal, February 2018

Impact of Grain-Dependent Boron Uptake on the Electrochemical and Electrical Properties of Polycrystalline Boron Doped Diamond Electrodes journal, March 2006

Electrochemistry and in situ Raman spectroelectrochemistry of low and high quality boron doped diamond layers in aqueous electrolyte solution journal, January 2013

Electrochemical characterization of porous boron-doped diamond prepared using SiO2 fiber template journal, August 2018

Probing Graphene Interfacial Reactivity via Simultaneous and Colocalized Raman–Scanning Electrochemical Microscopy Imaging and Interrogation journal, April 2018

Evidence for the production of hydroxyl radicals at boron-doped diamond electrodes with different sp 3 /sp 2 ratios and its relationship with the anodic oxidation of aniline journal, May 2018

Elementary steps of electrochemical oxidation of single-crystal planes of Au Part II. A chemical and structural basis of oxidation of the (111) plane journal, August 1987

Scanning Electrochemical Microscopy. 60. Quantitative Calibration of the SECM Substrate Generation/Tip Collection Mode and Its Use for the Study of the Oxygen Reduction Mechanism journal, May 2008

Scanning Electrochemical Microscopy: A Comprehensive Review of Experimental Parameters from 1989 to 2015 journal, October 2016

Facet‐Resolved Electrochemistry of Polycrystalline Boron‐Doped Diamond Electrodes: Microscopic Factors Determining the Solvent Window in Aqueous Potassium Chloride Solutions journal, August 2018

Electrogeneration of Hydroxyl Radicals on Boron-Doped Diamond Electrodes journal, January 2003

Electrochemical self-cleaning anodic surfaces for biofouling control during water treatment journal, November 2018

Conductive diamond: synthesis, properties, and electrochemical applications journal, January 2019

Boron Doped Diamond: A Designer Electrode Material for the Twenty-First Century journal, June 2018

Efficient Anodic Degradation of Phenol Paired to Improved Cathodic Production of H 2 O 2 at BDD Electrodes journal, January 2013

In Situ Quantification of Surface Intermediates and Correlation to Discharge Products on Hematite Photoanodes Using a Combined Scanning Electrochemical Microscopy Approach journal, February 2018

Influence of Doping Level on the Electrochemical Oxidation of Formic Acid on Boron Doped Diamond Electrodes journal, January 2011

In situ Fourier transform infrared spectroelectrochemical study of bisulfate and sulfate adsorption on gold, with and without the underpotential deposition of copper journal, July 1993

Quantification of photoelectrogenerated hydroxyl radical on TiO2 by surface interrogation scanning electrochemical microscopy journal, January 2012

Redox Titrations via Surface Interrogation Scanning Electrochemical Microscopy at an Extended Semiconducting Surface for the Quantification of Photogenerated Adsorbed Intermediates journal, October 2015

Synthesis of novel oxidants by electrochemical technology journal, January 2009

Enhanced H 2 O 2 Production at Reductive Potentials from Oxidized Boron-Doped Ultrananocrystalline Diamond Electrodes journal, May 2017

Generation and Detection of Reactive Oxygen Species in Photocatalysis journal, August 2017

Effect of sp3/sp2 Ratio on Boron Doped Diamond Films for Producing Persulfate journal, January 2015

Rate-Limiting O–O Bond Formation Pathways for Water Oxidation on Hematite Photoanode journal, February 2018

Intermittent-contact Scanning Electrochemical Microscopy (IC-SECM) as a Quantitative Probe of Defects in Single Crystal Boron Doped Diamond Electrodes journal, October 2016

Removal of Persistent Organic Contaminants by Electrochemically Activated Sulfate journal, December 2015

Electrochemical Quartz Crystal Microgravimetry of Gold in Perchloric and Sulfuric Acid Solutions journal, January 1999

Increasing the Electric Double‐Layer Capacitance in Boron‐Doped Diamond Electrodes journal, January 2019

Understanding active chlorine species production using boron doped diamond films with lower and higher sp3/sp2 ratio journal, June 2015

Electrochemical conversion/combustion of a model organic pollutant on BDD anode: Role of sp 3 /sp 2 ratio journal, October 2014

Environmental Applications of Boron‐Doped Diamond Electrodes: 2. Soil Remediation and Sensing Applications
journal, March 2019

Environmental Applications of Boron‐Doped Diamond Electrodes: 1. Applications in Water and Wastewater Treatment
journal, March 2019

Detection and imaging of reactive oxygen species associated with the electrochemical oxygen evolution by hydrodynamic scanning electrochemical microscopy
journal, August 2018

A practical guide to using boron doped diamond in electrochemical research
journal, January 2015

Surface carbonyl groups on oxidized diamond electrodes
journal, September 2000

Interrogation of Surfaces for the Quantification of Adsorbed Species on Electrodes: Oxygen on Gold and Platinum in Neutral Media ^†
journal, December 2008

Nature, Mechanisms and Reactivity of Electrogenerated Reactive Species at Thin‐Film Boron‐Doped Diamond (BDD) Electrodes During Electrochemical Wastewater Treatment
journal, March 2019

Electrochemical oxidation of organic pollutants for wastewater treatment
journal, October 2018

Surface Interrogation Scanning Electrochemical Microscopy for a Photoelectrochemical Reaction: Water Oxidation on a Hematite Surface
journal, February 2018

Impact of Grain-Dependent Boron Uptake on the Electrochemical and Electrical Properties of Polycrystalline Boron Doped Diamond Electrodes
journal, March 2006

Electrochemistry and in situ Raman spectroelectrochemistry of low and high quality boron doped diamond layers in aqueous electrolyte solution
journal, January 2013

Electrochemical characterization of porous boron-doped diamond prepared using SiO2 fiber template
journal, August 2018

Probing Graphene Interfacial Reactivity via Simultaneous and Colocalized Raman–Scanning Electrochemical Microscopy Imaging and Interrogation
journal, April 2018

Evidence for the production of hydroxyl radicals at boron-doped diamond electrodes with different sp 3 /sp 2 ratios and its relationship with the anodic oxidation of aniline
journal, May 2018

Elementary steps of electrochemical oxidation of single-crystal planes of Au Part II. A chemical and structural basis of oxidation of the (111) plane
journal, August 1987

Scanning Electrochemical Microscopy. 60. Quantitative Calibration of the SECM Substrate Generation/Tip Collection Mode and Its Use for the Study of the Oxygen Reduction Mechanism
journal, May 2008

Scanning Electrochemical Microscopy: A Comprehensive Review of Experimental Parameters from 1989 to 2015
journal, October 2016

Facet‐Resolved Electrochemistry of Polycrystalline Boron‐Doped Diamond Electrodes: Microscopic Factors Determining the Solvent Window in Aqueous Potassium Chloride Solutions
journal, August 2018

Electrogeneration of Hydroxyl Radicals on Boron-Doped Diamond Electrodes
journal, January 2003

Electrochemical self-cleaning anodic surfaces for biofouling control during water treatment
journal, November 2018

Conductive diamond: synthesis, properties, and electrochemical applications
journal, January 2019

Boron Doped Diamond: A Designer Electrode Material for the Twenty-First Century
journal, June 2018

Efficient Anodic Degradation of Phenol Paired to Improved Cathodic Production of H ₂ O ₂ at BDD Electrodes
journal, January 2013

In Situ Quantification of Surface Intermediates and Correlation to Discharge Products on Hematite Photoanodes Using a Combined Scanning Electrochemical Microscopy Approach
journal, February 2018

Influence of Doping Level on the Electrochemical Oxidation of Formic Acid on Boron Doped Diamond Electrodes
journal, January 2011

In situ Fourier transform infrared spectroelectrochemical study of bisulfate and sulfate adsorption on gold, with and without the underpotential deposition of copper
journal, July 1993

Quantification of photoelectrogenerated hydroxyl radical on TiO2 by surface interrogation scanning electrochemical microscopy
journal, January 2012

Redox Titrations via Surface Interrogation Scanning Electrochemical Microscopy at an Extended Semiconducting Surface for the Quantification of Photogenerated Adsorbed Intermediates
journal, October 2015

Synthesis of novel oxidants by electrochemical technology
journal, January 2009

Enhanced H ₂ O ₂ Production at Reductive Potentials from Oxidized Boron-Doped Ultrananocrystalline Diamond Electrodes
journal, May 2017

Generation and Detection of Reactive Oxygen Species in Photocatalysis
journal, August 2017

Effect of sp3/sp2 Ratio on Boron Doped Diamond Films for Producing Persulfate
journal, January 2015

Rate-Limiting O–O Bond Formation Pathways for Water Oxidation on Hematite Photoanode
journal, February 2018

Intermittent-contact Scanning Electrochemical Microscopy (IC-SECM) as a Quantitative Probe of Defects in Single Crystal Boron Doped Diamond Electrodes
journal, October 2016

Removal of Persistent Organic Contaminants by Electrochemically Activated Sulfate
journal, December 2015

Electrochemical Quartz Crystal Microgravimetry of Gold in Perchloric and Sulfuric Acid Solutions
journal, January 1999

Increasing the Electric Double‐Layer Capacitance in Boron‐Doped Diamond Electrodes
journal, January 2019

Understanding active chlorine species production using boron doped diamond films with lower and higher sp3/sp2 ratio
journal, June 2015

Electrochemical conversion/combustion of a model organic pollutant on BDD anode: Role of sp 3 /sp 2 ratio
journal, October 2014