Perovskite nanowire–block copolymer composites with digitally programmable polarization anisotropy

Zhou, Nanjia; Bekenstein, Yehonadav; Eisler, Carissa N.; Zhang, Dandan; Schwartzberg, Adam M.; Yang, Peidong; Alivisatos, A. Paul; Lewis, Jennifer A.

doi:10.1126/sciadv.aav8141

Title: Perovskite nanowire–block copolymer composites with digitally programmable polarization anisotropy

Journal Article · 31 May 2019 · Science Advances

DOI: https://doi.org/10.1126/sciadv.aav8141 · OSTI ID:1542409

Zhou, Nanjia ^[1];

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Harvard Univ., Cambridge, MA (United States); Westlake Univ., Zhejiang Province (China)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division; Technion-Israel Inst. of Tech., Haifa (Israel)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
Univ. of California, Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
Harvard Univ., Cambridge, MA (United States)

One-dimensional (1D) nanomaterials with highly anisotropic optoelectronic properties are key components in energy harvesting, flexible electronics, and biomedical imaging devices. 3D patterning methods that precisely assemble nanowires with locally controlled composition and orientation would enable new optoelectronic device designs. As an exemplar, we have created and 3D-printed nanocomposite inks composed of brightly emitting colloidal cesium lead halide perovskite (CsPbX₃, X = Cl, Br, and I) nanowires suspended in a polystyrene-polyisoprene-polystyrene block copolymer matrix. The nanowire alignment is defined by the programmed print path, resulting in optical nanocomposites that exhibit highly polarized absorption and emission properties. Several devices have been produced to highlight the versatility of this method, including optical storage, encryption, sensing, and full-color displays.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-05CH11231; SC0001293; DMR-1419807

OSTI ID:: 1542409

Journal Information:: Science Advances, Vol. 5, Issue 5; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

References (60)

3D Printed Quantum Dot Light-Emitting Diodes Kong, Yong Lin; Tamargo, Ian A.; Kim, Hyoungsoo Nano Letters, Vol. 14, Issue 12 https://doi.org/10.1021/nl5033292	journal	November 2014
Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide Nanowires through Anion-Exchange Reactions Zhang, Dandan; Yang, Yiming; Bekenstein, Yehonadav Journal of the American Chemical Society, Vol. 138, Issue 23 https://doi.org/10.1021/jacs.6b03134	journal	June 2016
Encapsulation of Perovskite Nanocrystals into Macroscale Polymer Matrices: Enhanced Stability and Polarization Raja, Shilpa N.; Bekenstein, Yehonadav; Koc, Matthew A. ACS Applied Materials & Interfaces, Vol. 8, Issue 51 https://doi.org/10.1021/acsami.6b09443	journal	December 2016
Langmuir−Blodgett Silver Nanowire Monolayers for Molecular Sensing Using Surface-Enhanced Raman Spectroscopy Tao, Andrea; Kim, Franklin; Hess, Christian Nano Letters, Vol. 3, Issue 9, p. 1229-1233 https://doi.org/10.1021/nl0344209	journal	September 2003
Biomimetic 4D printing Sydney Gladman, A.; Matsumoto, Elisabetta A.; Nuzzo, Ralph G. Nature Materials, Vol. 15, Issue 4 https://doi.org/10.1038/nmat4544	journal	January 2016
Layer-by-Layer Assembly of Nanowires for Three-Dimensional, Multifunctional Electronics Javey, Ali; Friedman, Robin S. Nano Letters, Vol. 7, Issue 3 https://doi.org/10.1021/nl063056l	journal	March 2007
Radiation Channels Close to a Plasmonic Nanowire Visualized by Back Focal Plane Imaging Hartmann, Nicolai; Piatkowski, Dawid; Ciesielski, Richard ACS Nano, Vol. 7, Issue 11 https://doi.org/10.1021/nn404611q	journal	October 2013
Tunable Anisotropic Photon Emission from Self-Organized CsPbBr ₃ Perovskite Nanocrystals Jurow, Matthew J.; Lampe, Thomas; Penzo, Erika Nano Letters, Vol. 17, Issue 7 https://doi.org/10.1021/acs.nanolett.7b02147	journal	June 2017
CdSe Nanoplatelet Films with Controlled Orientation of their Transition Dipole Moment Gao, Yunan; Weidman, Mark C.; Tisdale, William A. Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b01237	journal	May 2017
Nanowire electronic and optoelectronic devices Li, Yat; Qian, Fang; Xiang, Jie Materials Today, Vol. 9, Issue 10 https://doi.org/10.1016/S1369-7021(06)71650-9	journal	October 2006
Polarization features of optically pumped CdS nanowire lasers Röder, Robert; Ploss, Daniel; Kriesch, Arian Journal of Physics D: Applied Physics, Vol. 47, Issue 39 https://doi.org/10.1088/0022-3727/47/39/394012	journal	September 2014
Direct Nanorod Assembly Using Block Copolymer-Based Supramolecules Thorkelsson, Kari; Mastroianni, Alexander J.; Ercius, Peter Nano Letters, Vol. 12, Issue 1, p. 498-504 https://doi.org/10.1021/nl2040089	journal	December 2011
A nanoscale combing technique for the large-scale assembly of highly aligned nanowires Yao, Jun; Yan, Hao; Lieber, Charles M. Nature Nanotechnology, Vol. 8, Issue 5 https://doi.org/10.1038/nnano.2013.55	journal	April 2013
Colloidal Synthesis of Strongly Fluorescent CsPbBr ₃ Nanowires with Width Tunable down to the Quantum Confinement Regime Imran, Muhammad; Di Stasio, Francesco; Dang, Zhiya Chemistry of Materials, Vol. 28, Issue 18 https://doi.org/10.1021/acs.chemmater.6b03081	journal	September 2016
One-Dimensional Nanostructures: Synthesis, Characterization, and Applications Xia, Y.; Yang, P.; Sun, Y. Advanced Materials, Vol. 15, Issue 5, p. 353-389 https://doi.org/10.1002/adma.200390087	journal	March 2003
SEMICONDUCTOR NANOWIRES AND NANOTUBES Law, Matt; Goldberger, Joshua; Yang, Peidong Annual Review of Materials Research, Vol. 34, Issue 1, p. 83-122 https://doi.org/10.1146/annurev.matsci.34.040203.112300	journal	August 2004
Solution-Phase Synthesis of Cesium Lead Halide Perovskite Nanowires Zhang, Dandan; Eaton, Samuel W.; Yu, Yi Journal of the American Chemical Society, Vol. 137, Issue 29 https://doi.org/10.1021/jacs.5b05404	journal	July 2015
Light-recycling within electronic displays using deep red and near infrared photoluminescent polarizers Menéndez-Velázquez, Amador; Mulder, Carlijn L.; Thompson, Nicholas J. Energy Environ. Sci., Vol. 6, Issue 1 https://doi.org/10.1039/C2EE23265K	journal	January 2013
High-Temperature Photoluminescence of CsPbX ₃ (X = Cl, Br, I) Nanocrystals Diroll, Benjamin T.; Nedelcu, Georgian; Kovalenko, Maksym V. Advanced Functional Materials, Vol. 27, Issue 21 https://doi.org/10.1002/adfm.201606750	journal	March 2017
Capillary Printing of Highly Aligned Silver Nanowire Transparent Electrodes for High-Performance Optoelectronic Devices Kang, Saewon; Kim, Taehyo; Cho, Seungse Nano Letters, Vol. 15, Issue 12 https://doi.org/10.1021/acs.nanolett.5b03019	journal	November 2015
Orientation and morphology of high-density polyethylene film produced by the tubular blowing method and its relationship to process conditions Choi, Kyung-Ju; Spruiell, Joseph E.; White, James L. Journal of Polymer Science: Polymer Physics Edition, Vol. 20, Issue 1 https://doi.org/10.1002/pol.1982.180200103	journal	January 1982
The Surface Tension of Pure Liquid Compounds Jasper, Joseph J. Journal of Physical and Chemical Reference Data, Vol. 1, Issue 4 https://doi.org/10.1063/1.3253106	journal	October 1972
Controlling Particle Location with Mixed Surface Functionalities in Block Copolymer Thin Films Mayeda, Michael K.; Kuan, Wei-Fan; Young, Wen-Shiue Chemistry of Materials, Vol. 24, Issue 14 https://doi.org/10.1021/cm300931z	journal	June 2012
Light emission by magnetic and electric dipoles close to a plane dielectric interface III Radiation patterns of dipoles with arbitrary orientation Lukosz, W. Journal of the Optical Society of America, Vol. 69, Issue 11 https://doi.org/10.1364/JOSA.69.001495	journal	January 1979
Omnidirectional Printing of 3D Microvascular Networks Wu, Willie; DeConinck, Adam; Lewis, Jennifer A. Advanced Materials, Vol. 23, Issue 24 https://doi.org/10.1002/adma.201004625	journal	March 2011
Assessment of Anisotropic Semiconductor Nanorod and Nanoplatelet Heterostructures with Polarized Emission for Liquid Crystal Display Technology Cunningham, Patrick D.; Souza, João B.; Fedin, Igor ACS Nano, Vol. 10, Issue 6 https://doi.org/10.1021/acsnano.5b07949	journal	May 2016
Comparative analysis of imaging configurations and objectives for Fourier microscopy Kurvits, Jonathan A.; Jiang, Mingming; Zia, Rashid Journal of the Optical Society of America A, Vol. 32, Issue 11 https://doi.org/10.1364/JOSAA.32.002082	journal	January 2015
Engineering light absorption in semiconductor nanowire devices Cao, Linyou; White, Justin S.; Park, Joon-Shik Nature Materials, Vol. 8, Issue 8 https://doi.org/10.1038/nmat2477	journal	July 2009
Stretchable Electronic Devices: PDMS-Based Elastomer Tuned Soft, Stretchable, and Sticky for Epidermal Electronics (Adv. Mater. 28/2016) Jeong, Seung Hee; Zhang, Shuo; Hjort, Klas Advanced Materials, Vol. 28, Issue 28 https://doi.org/10.1002/adma.201670191	journal	July 2016
Launching Propagating Surface Plasmon Polaritons by a Single Carbon Nanotube Dipolar Emitter Hartmann, Nicolai; Piredda, Giovanni; Berthelot, Johann Nano Letters, Vol. 12, Issue 1 https://doi.org/10.1021/nl203270b	journal	December 2011
Incorporation of Photoluminescent Polarizers into Liquid Crystal Displays Weder, C. Science, Vol. 279, Issue 5352 https://doi.org/10.1126/science.279.5352.835	journal	February 1998
Highly Polarized Photoluminescence and Photodetection from Single Indium Phosphide Nanowires Wang, J. Science, Vol. 293, Issue 5534 https://doi.org/10.1126/science.1062340	journal	August 2001
Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications Talapin, Dmitri V.; Lee, Jong-Soo; Kovalenko, Maksym V. Chemical Reviews, Vol. 110, Issue 1 https://doi.org/10.1021/cr900137k	journal	January 2010
Effect of unidirectional shear on the structure of triblock copolymers. 2. Polystyrene-polyisoprene-polystyrene Morrison, Faith A.; Winter, H. Henning; Gronski, Wolfram Macromolecules, Vol. 23, Issue 19 https://doi.org/10.1021/ma00221a004	journal	September 1990
Hydroprinting Conductive Patterns onto 3D Structures Saada, Gabriel; Layani, Michael; Chernevousky, Avi Advanced Materials Technologies, Vol. 2, Issue 5 https://doi.org/10.1002/admt.201600289	journal	March 2017
Single-molecule orientations determined by direct emission pattern imaging Lieb, M. Andreas; Zavislan, James M.; Novotny, Lukas Journal of the Optical Society of America B, Vol. 21, Issue 6 https://doi.org/10.1364/JOSAB.21.001210	journal	January 2004
Surface- vs Diffusion-Limited Mechanisms of Anion Exchange in CsPbBr ₃ Nanocrystal Cubes Revealed through Kinetic Studies Koscher, Brent A.; Bronstein, Noah D.; Olshansky, Jacob H. Journal of the American Chemical Society, Vol. 138, Issue 37 https://doi.org/10.1021/jacs.6b08178	journal	September 2016
Polarized fluorescent emission from aligned electrospun nanofiber sheets containing semiconductor nanorods Hasegawa, Masaki; Hirayama, Yuki; Dertinger, Stephan Applied Physics Letters, Vol. 106, Issue 5 https://doi.org/10.1063/1.4907548	journal	February 2015
Self-Assembly of Colloidal Nanocrystals: From Intricate Structures to Functional Materials Boles, Michael A.; Engel, Michael; Talapin, Dmitri V. Chemical Reviews, Vol. 116, Issue 18 https://doi.org/10.1021/acs.chemrev.6b00196	journal	August 2016
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I. Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/nl5048779	journal	February 2015
Photoaligned Nanorod Enhancement Films with Polarized Emission for Liquid-Crystal-Display Applications Srivastava, Abhishek K.; Zhang, Wanlong; Schneider, Julian Advanced Materials, Vol. 29, Issue 33 https://doi.org/10.1002/adma.201701091	journal	June 2017
One-Dimensional Nanostructures: Synthesis, Characterization, and Applications Xia, Younan; Yang, Peidong; Sun, Yugang ChemInform, Vol. 34, Issue 22 https://doi.org/10.1002/chin.200322236	journal	June 2003
The surface tension of pure liquid compounds Zettlemoyer, A. C. Journal of Colloid and Interface Science, Vol. 46, Issue 1 https://doi.org/10.1016/0021-9797(74)90042-3	journal	January 1974
Polarization features of optically pumped CdS nanowire lasers Röder, Robert; Ploss, Daniel; Kriesch, Arian arXiv https://doi.org/10.48550/arxiv.1407.6744	text	January 2014
Colloidal Synthesis of Strongly Fluorescent CsPbBr3 Nanowires with Width Tunable down to the Quantum Confinement Regime Imran, Muhammad; Di Stasio, Francesco; Dang, Zhiya arXiv https://doi.org/10.48550/arxiv.1610.07909	text	January 2016
Omnidirectional Printing of 3D Microvascular Networks Wu, Willie; DeConinck, Adam; Lewis, Jennifer A. Advanced Materials, Vol. 23, Issue 24 https://doi.org/10.1002/adma.201004625	journal	March 2011
Orientation and morphology of high-density polyethylene film produced by the tubular blowing method and its relationship to process conditions Choi, Kyung-Ju; Spruiell, Joseph E.; White, James L. Journal of Polymer Science: Polymer Physics Edition, Vol. 20, Issue 1 https://doi.org/10.1002/pol.1982.180200103	journal	January 1982
Self-Assembly of Colloidal Nanocrystals: From Intricate Structures to Functional Materials Boles, Michael A.; Engel, Michael; Talapin, Dmitri V. Chemical Reviews, Vol. 116, Issue 18 https://doi.org/10.1021/acs.chemrev.6b00196	journal	August 2016
Capillary Printing of Highly Aligned Silver Nanowire Transparent Electrodes for High-Performance Optoelectronic Devices Kang, Saewon; Kim, Taehyo; Cho, Seungse Nano Letters, Vol. 15, Issue 12 https://doi.org/10.1021/acs.nanolett.5b03019	journal	November 2015
CdSe Nanoplatelet Films with Controlled Orientation of their Transition Dipole Moment Gao, Yunan; Weidman, Mark C.; Tisdale, William A. Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b01237	journal	May 2017
Encapsulation of Perovskite Nanocrystals into Macroscale Polymer Matrices: Enhanced Stability and Polarization Raja, Shilpa N.; Bekenstein, Yehonadav; Koc, Matthew A. ACS Applied Materials & Interfaces, Vol. 8, Issue 51 https://doi.org/10.1021/acsami.6b09443	journal	December 2016
Assessment of Anisotropic Semiconductor Nanorod and Nanoplatelet Heterostructures with Polarized Emission for Liquid Crystal Display Technology Cunningham, Patrick D.; Souza, João B.; Fedin, Igor ACS Nano, Vol. 10, Issue 6 https://doi.org/10.1021/acsnano.5b07949	journal	May 2016
Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications Talapin, Dmitri V.; Lee, Jong-Soo; Kovalenko, Maksym V. Chemical Reviews, Vol. 110, Issue 1 https://doi.org/10.1021/cr900137k	journal	January 2010
Solution-Phase Synthesis of Cesium Lead Halide Perovskite Nanowires Zhang, Dandan; Eaton, Samuel W.; Yu, Yi Journal of the American Chemical Society, Vol. 137, Issue 29 https://doi.org/10.1021/jacs.5b05404	journal	July 2015
Surface- vs Diffusion-Limited Mechanisms of Anion Exchange in CsPbBr ₃ Nanocrystal Cubes Revealed through Kinetic Studies Koscher, Brent A.; Bronstein, Noah D.; Olshansky, Jacob H. Journal of the American Chemical Society, Vol. 138, Issue 37 https://doi.org/10.1021/jacs.6b08178	journal	September 2016
Launching Propagating Surface Plasmon Polaritons by a Single Carbon Nanotube Dipolar Emitter Hartmann, Nicolai; Piredda, Giovanni; Berthelot, Johann Nano Letters, Vol. 12, Issue 1 https://doi.org/10.1021/nl203270b	journal	December 2011
Engineering light absorption in semiconductor nanowire devices Cao, Linyou; White, Justin S.; Park, Joon-Shik Nature Materials, Vol. 8, Issue 8 https://doi.org/10.1038/nmat2477	journal	July 2009
Evolution of unique nano-cylindrical structure in poly(styrene-b-isoprene-b-styrene) prepared under “dynamic packing injection moulding” Zhao, Yongsheng; Su, Bin; Chen, Feng Soft Matter, Vol. 11, Issue 11 https://doi.org/10.1039/c4sm02463j	journal	January 2015
The Surface Tension of Pure Liquid Compounds Jasper, Joseph J. Journal of Physical and Chemical Reference Data, Vol. 1, Issue 4 https://doi.org/10.1063/1.3253106	journal	October 1972
Highly Polarized Photoluminescence and Photodetection from Single Indium Phosphide Nanowires Wang, J. Science, Vol. 293, Issue 5534 https://doi.org/10.1126/science.1062340	journal	August 2001

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