Non-equilibrium crystallization pathways of manganese oxides in aqueous solution
Abstract
Aqueous precipitation of transition metal oxides normally proceeds through non-equilibrium phases, whose appearance cannot be anticipated from traditional phase diagrams. Without a precise understanding of which metastable phases form, or their lifetimes, targeted synthesis of specific metal oxides can become a trial-and-error process. In this work, we construct a theoretical framework to reveal the nanoscale and metastable energy landscapes of Pourbaix (E-pH) diagrams, providing quantitative insights into the size-dependent thermodynamics of metastable oxide nucleation and growth in water. By combining this framework with classical nucleation theory, we interrogate how solution conditions influence the multistage oxidation pathways of manganese oxides. We calculate that even within the same stability region of a Pourbaix diagram, subtle variations in pH and redox potential can redirect a non-equilibrium crystallization pathway through different metastable intermediates. Our theoretical framework offers a predictive platform to navigate through the thermodynamic and kinetic energy landscape towards the rational synthesis of target materials.
- Authors:
-
[2];
[3];
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Univ. of Southampton (United Kingdom)
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Next Generation of Materials by Design: Incorporating Metastability (CNGMD); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
- OSTI Identifier:
- 1542369
- Grant/Contract Number:
- AC02-05CH11231; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Sun, Wenhao, Kitchaev, Daniil A., Kramer, Denis, and Ceder, Gerbrand. Non-equilibrium crystallization pathways of manganese oxides in aqueous solution. United States: N. p., 2019.
Web. doi:10.1038/s41467-019-08494-6.
Sun, Wenhao, Kitchaev, Daniil A., Kramer, Denis, & Ceder, Gerbrand. Non-equilibrium crystallization pathways of manganese oxides in aqueous solution. United States. https://doi.org/10.1038/s41467-019-08494-6
Sun, Wenhao, Kitchaev, Daniil A., Kramer, Denis, and Ceder, Gerbrand. Mon .
"Non-equilibrium crystallization pathways of manganese oxides in aqueous solution". United States. https://doi.org/10.1038/s41467-019-08494-6. https://www.osti.gov/servlets/purl/1542369.
@article{osti_1542369,
title = {Non-equilibrium crystallization pathways of manganese oxides in aqueous solution},
author = {Sun, Wenhao and Kitchaev, Daniil A. and Kramer, Denis and Ceder, Gerbrand},
abstractNote = {Aqueous precipitation of transition metal oxides normally proceeds through non-equilibrium phases, whose appearance cannot be anticipated from traditional phase diagrams. Without a precise understanding of which metastable phases form, or their lifetimes, targeted synthesis of specific metal oxides can become a trial-and-error process. In this work, we construct a theoretical framework to reveal the nanoscale and metastable energy landscapes of Pourbaix (E-pH) diagrams, providing quantitative insights into the size-dependent thermodynamics of metastable oxide nucleation and growth in water. By combining this framework with classical nucleation theory, we interrogate how solution conditions influence the multistage oxidation pathways of manganese oxides. We calculate that even within the same stability region of a Pourbaix diagram, subtle variations in pH and redox potential can redirect a non-equilibrium crystallization pathway through different metastable intermediates. Our theoretical framework offers a predictive platform to navigate through the thermodynamic and kinetic energy landscape towards the rational synthesis of target materials.},
doi = {10.1038/s41467-019-08494-6},
journal = {Nature Communications},
number = 1,
volume = 10,
place = {United States},
year = {Mon Feb 04 00:00:00 EST 2019},
month = {Mon Feb 04 00:00:00 EST 2019}
}
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Works referenced in this record:
Thermodynamics of manganese oxides: Effects of particle size and hydration on oxidation-reduction equilibria among hausmannite, bixbyite, and pyrolusite
journal, August 2012
- Birkner, N.; Navrotsky, A.
- American Mineralogist, Vol. 97, Issue 8-9
Energetics of low-temperature polymorphs of manganese dioxide and oxyhydroxide
journal, July 1997
- Fritsch, Sophie; Post, Jeffrey E.; Navrotsky, Alexandra
- Geochimica et Cosmochimica Acta, Vol. 61, Issue 13
Photochemical Water Oxidation by Crystalline Polymorphs of Manganese Oxides: Structural Requirements for Catalysis
journal, February 2013
- Robinson, David M.; Go, Yong Bok; Mui, Michelle
- Journal of the American Chemical Society, Vol. 135, Issue 9
Role of Electronic Structure in the Susceptibility of Metastable Transition-Metal Oxide Structures to Transformation
journal, December 2004
- Reed, John; Ceder, Gerbrand
- ChemInform, Vol. 35, Issue 50
Seeing crystal formation one particle at a time
journal, March 2020
- Han, Yilong
- Nature Materials, Vol. 19, Issue 4
Recent Insights into Manganese Oxides in Catalyzing Oxygen Reduction Kinetics
journal, September 2015
- Stoerzinger, Kelsey A.; Risch, Marcel; Han, Binghong
- ACS Catalysis, Vol. 5, Issue 10
In situ TEM imaging of CaCO3 nucleation reveals coexistence of direct and indirect pathways
journal, September 2014
- Nielsen, M. H.; Aloni, S.; De Yoreo, J. J.
- Science, Vol. 345, Issue 6201
A Universal Representation of the States of Chemical Matter Including Metastable Configurations in Phase Diagrams
journal, November 2011
- Jansen, Martin; Pentin, Ilya V.; Schön, J. Christian
- Angewandte Chemie, Vol. 124, Issue 1
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
The thermodynamic scale of inorganic crystalline metastability
journal, November 2016
- Sun, Wenhao; Dacek, Stephen T.; Ong, Shyue Ping
- Science Advances, Vol. 2, Issue 11
A Concept for Synthesis Planning in Solid-State Chemistry
journal, January 2003
- Jansen, Martin
- ChemInform, Vol. 34, Issue 3
Concentration and chemical-state profiles at heterogeneous interfaces with sub-nm accuracy from standing-wave ambient-pressure photoemission
journal, November 2014
- Nemšák, Slavomír; Shavorskiy, Andrey; Karslioglu, Osman
- Nature Communications, Vol. 5, Issue 1
The electrical double layer: recent experimental and theoretical developments
journal, July 1990
- Parsons, Roger
- Chemical Reviews, Vol. 90, Issue 5
Understanding crystallization pathways leading to manganese oxide polymorph formation
journal, June 2018
- Chen, Bor-Rong; Sun, Wenhao; Kitchaev, Daniil A.
- Nature Communications, Vol. 9, Issue 1
Towards First Principles-Based Prediction of Highly Accurate Electrochemical Pourbaix Diagrams
journal, July 2015
- Zeng, Zhenhua; Chan, Maria K. Y.; Zhao, Zhi-Jian
- The Journal of Physical Chemistry C, Vol. 119, Issue 32
Electrochemical Stability of Metastable Materials
journal, November 2017
- Singh, Arunima K.; Zhou, Lan; Shinde, Aniketa
- Chemistry of Materials, Vol. 29, Issue 23
Evaluating structure selection in the hydrothermal growth of FeS2 pyrite and marcasite
journal, December 2016
- Kitchaev, Daniil A.; Ceder, Gerbrand
- Nature Communications, Vol. 7, Issue 1
Nanophase Transition Metal Oxides Show Large Thermodynamically Driven Shifts in Oxidation-Reduction Equilibria
journal, October 2010
- Navrotsky, Alexandra; Ma, Chengcheng; Lilova, Kristina
- Science, Vol. 330, Issue 6001
Ground Water Redox Reactions: An Analysis of Equilibrium State Applied to Eh Measurements and Geochemical Modeling
journal, August 1984
- Lindberg, R. D.; Runnells, D. D.
- Science, Vol. 225, Issue 4665
Microbial mediation of Mn(II) and Co(II) precipitation at the O 2 /H 2 S interfaces in two anoxic fjords1 : Mn and Co microbial precipitation
journal, November 1984
- Tebo, Bradley M.; Nealson, Kenneth H.; Emerson, Steven
- Limnology and Oceanography, Vol. 29, Issue 6
Composition, structure, and stability of as a function of oxygen pressure
journal, December 2001
- Reuter, Karsten; Scheffler, Matthias
- Physical Review B, Vol. 65, Issue 3
Oxidation of Mn(II): Initial mineralogy, oxidation state and ageing
journal, February 1985
- Murray, James W.; Dillard, John G.; Giovanoli, Rudolf
- Geochimica et Cosmochimica Acta, Vol. 49, Issue 2
Energetic clues to pathways to biomineralization: Precursors, clusters, and nanoparticles
journal, August 2004
- Navrotsky, A.
- Proceedings of the National Academy of Sciences, Vol. 101, Issue 33
Electrochemical Stability of Metastable Materials
journal, November 2017
- Singh, Arunima K.; Zhou, Lan; Shinde, Aniketa
- Chemistry of Materials, Vol. 29, Issue 23
Structural and electrochemical properties of the proton / γ-MnO2 system
journal, January 1995
- Chabre, Y.; Pannetier, J.
- Progress in Solid State Chemistry, Vol. 23, Issue 1
Nucleation of metastable aragonite CaCO 3 in seawater
journal, March 2015
- Sun, Wenhao; Jayaraman, Saivenkataraman; Chen, Wei
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 11
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Structural and Electronic Features of β-Ni(OH) 2 and β-NiOOH from First Principles
journal, October 2015
- Tkalych, Alexander J.; Yu, Kuang; Carter, Emily A.
- The Journal of Physical Chemistry C, Vol. 119, Issue 43
Surface Pourbaix diagrams and oxygen reduction activity of Pt, Ag and Ni(111) surfaces studied by DFT
journal, January 2008
- Hansen, Heine A.; Rossmeisl, Jan; Nørskov, Jens K.
- Physical Chemistry Chemical Physics, Vol. 10, Issue 25
Stability of βMnOOH and manganese oxide deposition from springwater
journal, June 1982
- Hem, J. D.; Roberson, C. E.; Fournier, Reba B.
- Water Resources Research, Vol. 18, Issue 3
In situ studies of a platform for metastable inorganic crystal growth and materials discovery
journal, July 2014
- Shoemaker, D. P.; Hu, Y. -J.; Chung, D. Y.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 30
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets
journal, May 2021
- Chen, Ruyi; Cui, Qirui; Liao, Liyang
- Nature Communications, Vol. 12, Issue 1
A Universal Representation of the States of Chemical Matter Including Metastable Configurations in Phase Diagrams
journal, November 2011
- Jansen, Martin; Pentin, Ilya V.; Schön, J. Christian
- Angewandte Chemie International Edition, Vol. 51, Issue 1
Nonequilibrium models for predicting forms of precipitated manganese oxides
journal, November 1983
- Hem, John D.; Lind, Carol J.
- Geochimica et Cosmochimica Acta, Vol. 47, Issue 11
Towards First Principles-Based Prediction of Highly Accurate Electrochemical Pourbaix Diagrams
journal, July 2015
- Zeng, Zhenhua; Chan, Maria K. Y.; Zhao, Zhi-Jian
- The Journal of Physical Chemistry C, Vol. 119, Issue 32
Nanoscale Effects on Thermodynamics and Phase Equilibria in Oxide Systems
journal, July 2011
- Navrotsky, Alexandra
- ChemPhysChem, Vol. 12, Issue 12
Electrochemical phase diagrams for Ti oxides from density functional calculations
journal, December 2015
- Huang, Liang-Feng; Rondinelli, James M.
- Physical Review B, Vol. 92, Issue 24
Python Materials Genomics (pymatgen): A robust, open-source python library for materials analysis
journal, February 2013
- Ong, Shyue Ping; Richards, William Davidson; Jain, Anubhav
- Computational Materials Science, Vol. 68
Prediction of solid-aqueous equilibria: Scheme to combine first-principles calculations of solids with experimental aqueous states
journal, June 2012
- Persson, Kristin A.; Waldwick, Bryn; Lazic, Predrag
- Physical Review B, Vol. 85, Issue 23
Thermodynamics of manganese oxides: Effects of particle size and hydration on oxidation-reduction equilibria among hausmannite, bixbyite, and pyrolusite
journal, August 2012
- Birkner, N.; Navrotsky, A.
- American Mineralogist, Vol. 97, Issue 8-9
Electrochemical extraction of lithium from LiMn2O4
journal, February 1984
- Thackeray, M. M.; Johnson, P. J.; de Picciotto, L. A.
- Materials Research Bulletin, Vol. 19, Issue 2
Role of Electronic Structure in the Susceptibility of Metastable Transition-Metal Oxide Structures to Transformation
journal, December 2004
- Reed, John; Ceder, Gerbrand
- ChemInform, Vol. 35, Issue 50
Strongly Constrained and Appropriately Normed Semilocal Density Functional
preprint, January 2015
- Sun, Jianwei; Ruzsinszky, Adrienn; Perdew, John P.
- arXiv
In situ Synthesis of Mixed-Valent Manganese Oxide Nanocrystals: An In situ Synchrotron X-ray Diffraction Study
journal, March 2006
- Shen, Xiong-Fei; Ding, Yun-Shuang; Hanson, Jonathan C.
- Journal of the American Chemical Society, Vol. 128, Issue 14
Induction time of a polymorphic transformation
journal, January 2017
- Sun, Wenhao; Ceder, Gerbrand
- CrystEngComm, Vol. 19, Issue 31
Redox properties of birnessite from a defect perspective
journal, August 2017
- Peng, Haowei; McKendry, Ian G.; Ding, Ran
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 36
In situ TEM imaging of CaCO3 nucleation reveals coexistence of direct and indirect pathways
journal, September 2014
- Nielsen, M. H.; Aloni, S.; De Yoreo, J. J.
- Science, Vol. 345, Issue 6201
Surface Pourbaix diagrams and oxygen reduction activity of Pt, Ag and Ni(111) surfaces studied by DFT
journal, January 2008
- Hansen, Heine A.; Rossmeisl, Jan; Nørskov, Jens K.
- Physical Chemistry Chemical Physics, Vol. 10, Issue 25
Evaluating structure selection in the hydrothermal growth of FeS2 pyrite and marcasite
journal, December 2016
- Kitchaev, Daniil A.; Ceder, Gerbrand
- Nature Communications, Vol. 7, Issue 1
Nanophase Transition Metal Oxides Show Large Thermodynamically Driven Shifts in Oxidation-Reduction Equilibria
journal, October 2010
- Navrotsky, Alexandra; Ma, Chengcheng; Lilova, Kristina
- Science, Vol. 330, Issue 6001
Accurate First-Principles Electrochemical Phase Diagrams for Ti Oxides from Density Functional Calculations
text, January 2015
- Huang, Liang-Feng; Rondinelli, James M.
- arXiv
BIOGENIC MANGANESE OXIDES: Properties and Mechanisms of Formation
journal, May 2004
- Tebo, Bradley M.; Bargar, John R.; Clement, Brian G.
- Annual Review of Earth and Planetary Sciences, Vol. 32, Issue 1
Reaction Network of Layer-to-Tunnel Transition of MnO 2
journal, January 2016
- Li, Ye-Fei; Zhu, Sheng-Cai; Liu, Zhi-Pan
- Journal of the American Chemical Society, Vol. 138, Issue 16
Manganese oxide minerals: Crystal structures and economic and environmental significance
journal, March 1999
- Post, J. E.
- Proceedings of the National Academy of Sciences, Vol. 96, Issue 7
Energetics of polymorphs in density functional theory
journal, January 2016
- Kitchaev, Daniil A.; Peng, Haowei; Liu, Yun
- Physical Review B, Vol. 93, Issue 4
A Universal Representation of the States of Chemical Matter Including Metastable Configurations in Phase Diagrams
journal, November 2011
- Jansen, Martin; Pentin, Ilya V.; Schön, J. Christian
- Angewandte Chemie International Edition, Vol. 51, Issue 1
The synthesis of birnessite, cryptomelane, and some other oxides and hydroxides of manganese
journal, December 1971
- McKenzie, R. M.
- Mineralogical Magazine, Vol. 38, Issue 296
A Concept for Synthesis Planning in Solid-State Chemistry
journal, October 2002
- Jansen, Martin
- Angewandte Chemie International Edition, Vol. 41, Issue 20
A topological screening heuristic for low-energy, high-index surfaces
journal, March 2018
- Sun, Wenhao; Ceder, Gerbrand
- Surface Science, Vol. 669
In situ studies of a platform for metastable inorganic crystal growth and materials discovery
journal, July 2014
- Shoemaker, D. P.; Hu, Y. -J.; Chung, D. Y.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 30
Recent Insights into Manganese Oxides in Catalyzing Oxygen Reduction Kinetics
journal, September 2015
- Stoerzinger, Kelsey A.; Risch, Marcel; Han, Binghong
- ACS Catalysis, Vol. 5, Issue 10
Strongly Constrained and Appropriately Normed Semilocal Density Functional
journal, July 2015
- Sun, Jianwei; Ruzsinszky, Adrienn; Perdew, John P.
- Physical Review Letters, Vol. 115, Issue 3
Oxidation of Mn(II): Initial mineralogy, oxidation state and ageing
journal, February 1985
- Murray, James W.; Dillard, John G.; Giovanoli, Rudolf
- Geochimica et Cosmochimica Acta, Vol. 49, Issue 2
Efficient creation and convergence of surface slabs
journal, November 2013
- Sun, Wenhao; Ceder, Gerbrand
- Surface Science, Vol. 617
Electrochemical trapping of metastable Mn 3+ ions for activation of MnO 2 oxygen evolution catalysts
journal, May 2018
- Morgan Chan, Zamyla; Kitchaev, Daniil A.; Nelson Weker, Johanna
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 23
Efficient creation and convergence of surface slabs
journal, November 2013
- Sun, Wenhao; Ceder, Gerbrand
- Surface Science, Vol. 617
Formation Mechanisms of Nanocrystalline MnO 2 Polymorphs under Hydrothermal Conditions
journal, January 2018
- Birgisson, Steinar; Saha, Dipankar; Iversen, Bo B.
- Crystal Growth & Design, Vol. 18, Issue 2
Ground Water Redox Reactions: An Analysis of Equilibrium State Applied to Eh Measurements and Geochemical Modeling
journal, August 1984
- Lindberg, R. D.; Runnells, D. D.
- Science, Vol. 225, Issue 4665
Microbial mediation of Mn(II) and Co(II) precipitation at the O 2 /H 2 S interfaces in two anoxic fjords1 : Mn and Co microbial precipitation
journal, November 1984
- Tebo, Bradley M.; Nealson, Kenneth H.; Emerson, Steven
- Limnology and Oceanography, Vol. 29, Issue 6
Properties of real metallic surfaces: Effects of density functional semilocality and van der Waals nonlocality
journal, October 2017
- Patra, Abhirup; Bates, Jefferson E.; Sun, Jianwei
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 44
Thermodynamics of Phase Selection in MnO 2 Framework Structures through Alkali Intercalation and Hydration
journal, February 2017
- Kitchaev, Daniil A.; Dacek, Stephen T.; Sun, Wenhao
- Journal of the American Chemical Society, Vol. 139, Issue 7
Nonequilibrium models for predicting forms of precipitated manganese oxides
journal, November 1983
- Hem, John D.; Lind, Carol J.
- Geochimica et Cosmochimica Acta, Vol. 47, Issue 11
Python Materials Genomics (pymatgen): A robust, open-source python library for materials analysis
journal, February 2013
- Ong, Shyue Ping; Richards, William Davidson; Jain, Anubhav
- Computational Materials Science, Vol. 68
A topological screening heuristic for low-energy, high-index surfaces
journal, March 2018
- Sun, Wenhao; Ceder, Gerbrand
- Surface Science, Vol. 669
Manganese oxide minerals: Crystal structures and economic and environmental significance
journal, March 1999
- Post, J. E.
- Proceedings of the National Academy of Sciences, Vol. 96, Issue 7
Concentration and chemical-state profiles at heterogeneous interfaces with sub-nm accuracy from standing-wave ambient-pressure photoemission
journal, November 2014
- Nemšák, Slavomír; Shavorskiy, Andrey; Karslioglu, Osman
- Nature Communications, Vol. 5, Issue 1
Formation Mechanisms of Nanocrystalline MnO 2 Polymorphs under Hydrothermal Conditions
journal, January 2018
- Birgisson, Steinar; Saha, Dipankar; Iversen, Bo B.
- Crystal Growth & Design, Vol. 18, Issue 2
Structural and Electronic Features of β-Ni(OH) 2 and β-NiOOH from First Principles
journal, October 2015
- Tkalych, Alexander J.; Yu, Kuang; Carter, Emily A.
- The Journal of Physical Chemistry C, Vol. 119, Issue 43
The synthesis of birnessite, cryptomelane, and some other oxides and hydroxides of manganese
journal, December 1971
- McKenzie, R. M.
- Mineralogical Magazine, Vol. 38, Issue 296
Understanding crystallization pathways leading to manganese oxide polymorph formation
journal, June 2018
- Chen, Bor-Rong; Sun, Wenhao; Kitchaev, Daniil A.
- Nature Communications, Vol. 9, Issue 1
Role of Electronic Structure in the Susceptibility of Metastable Transition-Metal Oxide Structures to Transformation
journal, October 2004
- Reed, John; Ceder, Gerbrand
- Chemical Reviews, Vol. 104, Issue 10
Reaction Network of Layer-to-Tunnel Transition of MnO 2
journal, January 2016
- Li, Ye-Fei; Zhu, Sheng-Cai; Liu, Zhi-Pan
- Journal of the American Chemical Society, Vol. 138, Issue 16
Simplified Procedure for Constructing Pourbaix Diagrams
journal, December 1967
- Verink, Ellis D.
- CORROSION, Vol. 23, Issue 12
The relative importance of manganese and iron oxides and organic matter in the sorption of trace metals by surficial lake sediments
journal, March 1992
- Young, Leah Bendell; Harvey, Harold H.
- Geochimica et Cosmochimica Acta, Vol. 56, Issue 3
The electrical double layer: recent experimental and theoretical developments
journal, July 1990
- Parsons, Roger
- Chemical Reviews, Vol. 90, Issue 5
The thermodynamic scale of inorganic crystalline metastability
journal, November 2016
- Sun, Wenhao; Dacek, Stephen T.; Ong, Shyue Ping
- Science Advances, Vol. 2, Issue 11
BIOGENIC MANGANESE OXIDES: Properties and Mechanisms of Formation
journal, May 2004
- Tebo, Bradley M.; Bargar, John R.; Clement, Brian G.
- Annual Review of Earth and Planetary Sciences, Vol. 32, Issue 1
Energetic clues to pathways to biomineralization: Precursors, clusters, and nanoparticles
journal, August 2004
- Navrotsky, A.
- Proceedings of the National Academy of Sciences, Vol. 101, Issue 33
Redox properties of birnessite from a defect perspective
journal, August 2017
- Peng, Haowei; McKendry, Ian G.; Ding, Ran
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 36
Studien über die Bildung und Umwandlung fester Körper
journal, January 1897
- Ostwald, W.
- Zeitschrift für Physikalische Chemie, Vol. 22U, Issue 1
Keimbildungsgeschwindigkeit und OSTWALDsche Stufenregel
journal, January 1933
- Stranski, I. N.; Totomanow, D.
- Zeitschrift für Physikalische Chemie, Vol. 163A, Issue 1
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Epitaxial stabilization versus interdiffusion: synthetic routes to metastable cubic HfO 2 and HfV 2 O 7 from the core–shell arrangement of precursors
journal, January 2019
- Fleer, Nathan A.; Thomas, Melonie P.; Andrews, Justin L.
- Nanoscale, Vol. 11, Issue 44
Understanding crystallization pathways leading to manganese oxide polymorph formation
journal, June 2018
- Chen, Bor-Rong; Sun, Wenhao; Kitchaev, Daniil A.
- Nature Communications, Vol. 9, Issue 1
Bound manganese oxides capable of reducing the bacteriochlorophyll dimer of modified reaction centers from Rhodobacter sphaeroides
journal, October 2019
- Espiritu, Eduardo; Chamberlain, Kori D.; Williams, JoAnn C.
- Photosynthesis Research, Vol. 143, Issue 2
Freezing water at constant volume and under confinement
journal, February 2020
- Powell-Palm, Matthew J.; Rubinsky, Boris; Sun, Wenhao
- Communications Physics, Vol. 3, Issue 1