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Title: Effects of surface tension and viscosity on gold and silver sputtered onto liquid substrates

Abstract

Here, we report on DC magnetron sputtering of gold and silver onto liquid substrates of varying viscosities and surface tensions. We were able to separate the effects of viscosity from surface tension by depositing the metals onto silicone oils with a range of viscosities. The effects of surface tension were studied by depositing the metals onto squalene, poly(ethylene glycol), and glycerol. It was discovered that dispersed nanoparticles were formed on liquids with low surface tension and low viscosity whereas dense films were formed on liquids with low surface tension and high viscosity. Nanoparticles were formed on both the liquid surface and within the bulk liquid for high surface tension liquids. Our findings can be used to tailor the metal and liquid interaction to fabricate particles and films for various applications in optics, electronics, and catalysis.

Authors:
ORCiD logo [1];  [1]
  1. Univ. of Southern California, Los Angeles, CA (United States)
Publication Date:
Research Org.:
Univ. of Southern California, Los Angeles, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
OSTI Identifier:
1540192
Alternate Identifier(s):
OSTI ID: 1437816
Grant/Contract Number:  
SC0012407; #DE-SC0012407
Resource Type:
Accepted Manuscript
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 112; Journal Issue: 20; Journal ID: ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

De Luna, Mark M., and Gupta, Malancha. Effects of surface tension and viscosity on gold and silver sputtered onto liquid substrates. United States: N. p., 2018. Web. doi:10.1063/1.5026513.
De Luna, Mark M., & Gupta, Malancha. Effects of surface tension and viscosity on gold and silver sputtered onto liquid substrates. United States. doi:10.1063/1.5026513.
De Luna, Mark M., and Gupta, Malancha. Fri . "Effects of surface tension and viscosity on gold and silver sputtered onto liquid substrates". United States. doi:10.1063/1.5026513. https://www.osti.gov/servlets/purl/1540192.
@article{osti_1540192,
title = {Effects of surface tension and viscosity on gold and silver sputtered onto liquid substrates},
author = {De Luna, Mark M. and Gupta, Malancha},
abstractNote = {Here, we report on DC magnetron sputtering of gold and silver onto liquid substrates of varying viscosities and surface tensions. We were able to separate the effects of viscosity from surface tension by depositing the metals onto silicone oils with a range of viscosities. The effects of surface tension were studied by depositing the metals onto squalene, poly(ethylene glycol), and glycerol. It was discovered that dispersed nanoparticles were formed on liquids with low surface tension and low viscosity whereas dense films were formed on liquids with low surface tension and high viscosity. Nanoparticles were formed on both the liquid surface and within the bulk liquid for high surface tension liquids. Our findings can be used to tailor the metal and liquid interaction to fabricate particles and films for various applications in optics, electronics, and catalysis.},
doi = {10.1063/1.5026513},
journal = {Applied Physics Letters},
number = 20,
volume = 112,
place = {United States},
year = {2018},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
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    Works referencing / citing this record:

    Interactions between polymers and liquids during initiated chemical vapor deposition onto liquid substrates
    journal, January 2020

    • De Luna, Mark M.; Karandikar, Prathamesh; Gupta, Malancha
    • Molecular Systems Design & Engineering, Vol. 5, Issue 1
    • DOI: 10.1039/c9me00087a